Holdings: Functional nanomaterials

Functional nanomaterials:

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Bibliographic Details
Main Author:	Geckeler, Kurt E. (Author)
Format:	Book
Language:	English
Published:	Stevenson Ranch, Calif. American Scientific Publishers 2006
Series:	... 10
Subjects:	Materiais nanoestruturados Nanomatériaux Nanomatériaux - Applications industrielles Nanotecnologia Nanostructured materials Nanostructured materials > Industrial applications
Online Access:	Inhaltsverzeichnis
Physical Description:	XXVII, 488 S. Ill., graph. Darst.
ISBN:	9781588830678 1588830675

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adam_text	.................................................................................... FOREWORD V .............................................................. .................. PREFACE .. VII ......................................................................... ABOUT THE EDITORS XK ........................................................................ LIST OF CONTRIBUTORS XXI CHAPTER 1 . MOLECULAR MACHINES FOR PROTEIN DEGRADATION MICHAEL GROLL. MATTHIAS BOCHTLEL; HANS BRANDSTETTER; TIM CLAUSEN. ROBERT HUBER ....................................................... ............ INTRODUCTION ..... 1 .................................................... TLIE ATP-DEPENDENT PROTEASE HSLVU 2 ..................................................................... THE 20S PROTEASOME 5 THE TRICORN PROTEASE AND ITS STRUCTURAL AND FUNCTIONAL RELATIONSHIP WITH ................................................................ DIPEPTIDYL PEPTIDASE IV 22 ...................... THE DEGP PROTEASE CHAPERONE: A MOLECULAR CAGE WITH BOUNCERS 25 ............................................................... CONCLUSION AND OUTLOOK 28 ............................................................................. REFERENCES 30 CHAPTER 2 . NANO-SISED OPTICAL DEVICES FOR APPLICATIONS IN PROTEOMICS AND BIOMOLECULAR ELECTRONICS: ENGINEERED GREEN FLUORESCENT PROTEINS RANIERI BIZZAM; RICCARDO NIFOSI. PASQUALANTONIO PINGUE. VALENTINA TOZZINI. FABIO BELTRAM ........................................................................... 1 . INTRODUCTION 35 2 . OPTICAL CHARACTERISTICS OF WILD TYPE GREEN FLUORESCENT PROTEIN (WTGFP) AND ............................................. GREEN FLUORESCENT PROTEIN (GFP) MUTANTS 36 ...................................................... 3 . APPLICATIONS TO LIVE CE11 IMAGING 39 ..................... 4 . GFP MUTANTS WITH SPECIAL OPTICAL CHARACTERISTICS AND APPLICATIONS 40 ..................................................... 4.1. SINGLE MOLECULE PHOTOPHYSICS 40 ................ 4.2. E2GFP AS OPTICALLY SWITCHING ELEMENT OF BIORNOLECULAR MEMORIES 42 ........................................................... 5 . CONCLUSIONS AND PERSPECTIVES 43 ............................................................................. REFERENCES 44 CHAPTER 3 . SYNTHESES OF CARBON NANOFIBERS AND NANOTUBES BY CATALYTIC DECOMPOSITION OF HYDROCARBONS ON SUPPORTED-NI CATALYSTS KIYOSHI OTSUKA. SAKAE TAKENAKA ................................................. 1 . INTRODUCTION ..................... .. 45 ................................................................... 2 . EXPERIMENTAL DETAILS 46 ................................ 3 . CARBON FIBERS FROM METHANE ON SUPPORTED-NI CATALYSTS 46 ...................................................................... 3.1. INITIAL STAGE 47 ..................................................................... 3.2. MIDDLE STAGE 48 3.3. FINAL STAGE .................................................................. 48 ....... 3.4. STRUCTURAL CHANGE OF THE NI SPECIES DURING THE DECOMPOSITION OF METHANE 49 CONTENTS .... . 4 CARBON NANOFIBERS FROM OTHER ALKANES (ETHANE. PROPANE. N-HEXANE AND N-OCTANE) 49 ................................. . 5 CARBON NANOTUBES FROM CYCLOPENTADIENE AND BENZENE 50 .......................... . 6 REACTION MECHANISM FOR THE FORMATION OF CARBON NANOTUBES 51 ........................................................ 7 . BIDIRECTIONAL CARBON NANOFIBERS 52 ............................................................................. 8 . CONCLUSION 54 ............................................................................. REFERENCES 54 CHAPTER 4 . FUNCTIONALIZATION OF CARBON NANOTUBES DHRITI NEPAL. KURT E . GECKELER ..................................................... 1 . INTRODUCTION TO CARBON NANOTUBES 57 .................................................... 2 . FUNDAMENTALS OF CARBON NANOTUBES 58 ........................................................ 2.1. SYNTHESES AND PURIFICATION 58 ......................................................................... 2.2. SOLUBILITY 59 .................................................................. 2.3. DEBUNDALIZATION 59 ........................................................ 3 . CHEMISTRY OF CARBON NANOTUBES 63 ................................................. 3.1. DIRECT COVALENT FUNCTIONALIZATION 64 ............................................... 3.2. INDIRECT COVALENT FUNCTIONALIZATION 67 ............................................... 3.3. ACID-BASE COUPLING VIA ZWITTERIONS 68 ................................................. 3.4. CARBON NANOTUBES WITH POLYMERS 69 ................................................... 3.5. NON-COVALENT FUNCTIONALIZATION 71 .......................................................... 3.6. METAL-FUNCTIONALIZATION. 73 ............................................ 4 . TOWARD THE CHIRAL SEPARATION OF NANOTUBES 75 ................................................... 5 . CONCLUSIONS .......... ... .. .. 76 ............................................................................. REFERENCES 77 CHAPTER 5 . CALCULATIONS ON SOLVENTS AND CO-SOLVENTS OF CARBON NANOTUBES: CYCLOPYRANOSES FRANCISCO TORRENS ........................................................................... 1 . INTRODUCTION 81 ................. 2 . CYCLODEXTRIN, CORNPLEXES AS MODELS FOR THE BLUE STARCH-IODINE ADDUCT 82 .................................................. 3 . THE AMYLOSE-IODINE-IODIDE COMPLEX 83 ................................................. 4 . SOLUBILITY OF FULLERENES AND NANOTUBES 84 5 . AQUEOUS SOLUBILIZATION OF FULLERENES AND NANOTUBES VIA INCLUSION COMPLEX FORMATION .. 84 6 . MATERIALS AND METHODS ................................................................. 85 7 . RESULTS AND DISCUSSION ................................................................. 85 ............................................................................ 8 . CONCLUSIONS 91 ............................................................................. REFERENCES 91 CHAPTER 6 . STRUCTURE AND PROPERTIES OF CARBON NANOTUBE-BASED FILMS AND FIBERS GEON-WOONG LEE. YOUNG-BIN PARK, SATISH KUMAR ........................................................................... 1 . INTRODUCTION 95 ..................................................................... 2 . SOLUTION PROPERTIES 96 ....................................................................... 3 . CHARACTERIZATION 98 4 . CARBON NANOTUBE (CNT)-BASED FILMS .................................................. 99 ....................................................... 5 . CARBON NANOTUBE-BASED FIBERS 102 6. CARBON NANOTUBE/POLYMER COMPOSITE FILMS AND FIBERS ............................... 102 .................................................................. 7 . CONCLUDING REMARKS 106 ............................................................................ REFERENCES 106 CHAPTER 7 . SCIENCE AND ENGINEERING OF POLYMER NANOFIBERS S . RAMAKNSHNA. K . FUJIHARA. K K. GANESH, W E . EO. 7: C . LIRN .......................................................................... 1 . INTRODUCTION 114 ......................................................... . 2 NANOSCALE UNIQUE PROPERTIES 115 .............................................................. 2.1. PHYSICAL PROPERTIES 115 ............................................................. 2.2. ELECTRICAL PROPERTIES 116 ........................................................... 2.3. MECHANICAL PROPERTIES 116 ............................................................... 2.4. OPTICAL PROPERTIES 116 .......................................... 2.5. ELECTROSPINNING UNIQUE CHARACTERISTICS 116 ................................................ . 3 PARAMETERS OF ELECTROSPINNING PROCESS 117 .................................................... 3.1. POLYMER SOLUTION PARAMETERS 117 ...................................................... 3.2. ELECTROSPINNING PARAMETERS 119 ............................................. 3.3. ELECTROSPUN POLYMER SOLUTION TABLE 121 ............................................................. . 4 POLYMER NANOENGINEERING 122 ................................................ 4.1. CREATION OF DIFFERENT NANOFIBERS 122 .................................. 4.2. UNIFORMITY AND PRODUCTIVITY OF NANOFIBER WEBS 131 ....................................................................... 4.3. PATTERNING 132 ............................................................ 4.4. SECONDARY PROCESSING 135 .............................................. . 5 MODELING OF THE ELECTROSPINNING PROCESS 137 .................................................................... 5.1. INTRODUCTION 137 ........................................... ................. 5.2. PRELIMINARIES ... 137 .................................................................... 5.3. ASSUMPTIONS 138 .......................................................... 5.4. CONSERVATION RELATIONS 139 ................................................................... 5.5. NEWTON S LAW 139 ....................................................................... 5.6. INSTABILITY 140 .......................................................................... 5.7. RESULTS 141 ..................................................................... 5.8. CONCLUSIONS 142 ......................................... . 6 POTENTIAL APPLICATIONS FOR POLYMER NANOFIBERS 143 .................................................................... 6.1. INTRODUCTION 143 ................................. 6.2. POLYMER NANOFIBERS FOR BIOMEDICAL APPLICATIONS 143 ...................................... 6.3. POLYMER NANOFIBERS FOR TISSUE ENGINEERING 144 ...................................... 6.4. POLYMER NANOFIBERS FOR FILTER APPLICATIONS 147 ................................................. 6.5. POLYMER NANOFIBERS FOR SENSING 147 ............................................................................ REFERENCES 148 CHAPTER 8 . NANOPHOTONIC ENSEMBLES FOR BIOMEDICAL AND HOMELAND SECURITY APPLICATIONS CHARLES K SPANGLEL; FANQING MENG. AIJUN GONG, MIKHAIL DROBIZHEV, ALEKSANDER REBANE. ALIAKSANDER KAROTKI. BRENDA D . SPANGLEL; ZHIYONG SUO. E . SCOTT TARTER .......................................................................... 1 . INTRODUCTION 153 2 . DESIGN CRITERIA FOR NEW PHOTODYNAMIC THERAPEUTIC (PDT) AGENTS FOR THE ....................................... NONINVASIVE TREATMENT OF SUBCUTANEOUS NIMORS 154 ...................... 2.1. PORPHYRINS WITH GREATLY ENHANCED TWO-PHOTON ABSORPTION 155 ........ 2.2. TWO-PHOTON THERAPEUTIC AGENTS INCORPORATING TUMOR TARGETING MOIETIES 156 ...................... 2.3. DYAD AND TRIAD ENSEMBLES FOR TARGETED MULTI-PHOTON PDT 157 ........... 3 . NEW DIAGNOSTIC APPROACHES TO THE DETECTION OF CLASS A BIOTERROR PATHOGEN 157 ................ 3.1. DESIGN OF DENDRITIC AGENTS FOR THE IMMOBILIZATION OF ANTIBODIES 158 ........ 3.2. SYNTHESIS OF DENDRITIC TETHERS FOR ANTIBODY ATTACHMENT TO GOLD SURFACES 158 ........... 3.3. NEW FLUORESCENT AGENTS FOR VISUALIZING ANTIBODY-ANTIGEN INTERACTION 159 ....................................................... . 4 SUMMARY AND FUTURE PROSPECTS 160 ............................................................................ REFERENCES 160 CHAPTER 9 . NANOSTRUCTURED MATERIALS WITH ENHANCED MAGNETIC AND CATALYTIC PROPERTIES LI-JUN WAN. CHUN-LI BAI .......................................................................... INTRODUCTION 163 ........................... ORDERED NI-CU NANOWIRE ARRAYS WITH ENHANCED COERCIVITY 164 ........................................................... 2.1. EXPERIMENTAL SECTION. 164 .......................................................... 2.2. RESULTS AND DISCUSSION 165 .................... NOVEL ELECTROCATALYTIC ACTIVITY IN LAYERED NI-CU NANOWIRE ARRAYS 166 ............................................................ 3.1. EXPERIMENTAL SECTION 167 .......................................................... 3.2. RESULTS AND DISCUSSION 167 ............... PT HOLLOW NANOSPHERES: FACILE SYNTHESIS AND ENHANCED ELECTROCATALYSTS 170 ............................................................ 4.1. EXPERIMENTAL SECTION 170 .......................................................... 4.2. RESULTS AND DISCUSSION 171 ......................................................................... REFERENCES 172 CHAPTER 10 . NANOSTRUCTURES BASED ON FULLERENES YULAN WANG, KURT E . GECKELER .......................................................................... . 1 INTRODUCTION 175 ................................ . 2 FULLERENE-BASED NANOSTRUCTURES BY CHEMICAL METHODS 177 ................................................. 2.1. NANOPARTICLES AND NANOSPHERES 177 ...................................................................... 2.2. NANOWIRES 184 ..................................................................... 2.3. NANOLATTICES 186 .................................. 3. FULLERENE-BASED NANOSTRUCTURES BY PHYSICAL METHODS 189 ................................................. 3.1. NANOPARTICLES AND NANOSPHERES 189 ...................................................................... 3.2. NANOWIRES 190 ....................... . 4 EFFECTS ON THE SELF-ASSEMBLY OF FULLERENE-BASED NANOSTRUCTURES 192 ............................................................... 4.1. EFFECT OF SOLVENTS 192 .................................................... 4.2. EFFECT OF CHEMICAL STRUCTURE 195 ........................................ 4.3. EFFECT OF TEMPERATURE AND CONCENTRATION 198 .............................................................. 4.4. EFFECT OF SUBSTRATE 200 ............................................................... 4.5. EFFECT OF PRESSURE 201 ....................................... 5 . APPLICATIONS OF FULLERENE-BASED NANOSTRUCTURES 202 ............................................... 5.1. APPLICATIONS IN MOLECULAR DEVICES 202 ............................................... 5.2. APPLICATIONS IN MATERIALS SCIENCE. 202 ................................................................ 6 . SUMMARY AND OUTLOOK 213 ............................................................................ REFERENCES 215 CHAPTER 11 . NANO-STRUCTURED POLYIMIDES WITH CONTROLLABLE DIELECTRIC PROPERTIES BAO-KU ZHU. SHU-HUI XIE. MYONG HOON LEE. ZHI-KANG XU .......................................................................... . 1 LNTRODUCTION 219 ............................. . 2 POLYIMIDE NANOFOAMS WITH VERY LOW DIELECTRIC CONSTANTS 220 ........................................ 2.1. GENERAL ROUTES TO POLYIMIDE NANOFOAMS 220 ...................................... 2.2. LABILE BLOCK/POLYIMIDE COPOLYMER PROCESS 221 ................................................. 2.3. LABILE PARTICLE TEMPLATE ROUTES 224 ............................. 2.4. POLY(AMIC ACID-CO-AMIC ESTER) PRECURSOR PROCESSES 227 ................................... 3 . LOW DIELECTRIC CONSTANT POLYIMIDE NANOCOMPOSITES 228 ........................................... 4 . HIGH DIELECTRIC CONSTANT PI NANOCOMPOSITE 230 ...................................................... ............ 5 . CONCLUSIONS ... 232 ......................................................................... REFERENCES. 232 CHAPTER 12 . ARRANGEMENT OF POLYMER NANOPARTICLES ON MICRO- AND NANO-FABRICATED SILICON SUBSTRATES MANABU TANAKN. HIROYUKI NISHIDE ..................................................... ................. 1 . INTRODUCTION .. 235 ................................................... 2 . PARTICLE ARRANGEMENT ON SUBSTRATES 236 ...................................... 2.1. ARRANGEMENT OF MICROMETER-SIZED PARTICLES 236 ...................... 2.2. POLYMER PARTICLES WITH SUBMICRO- AND NANOMETER DIAMETER 238 ........................................... 2.3. MICROFABRICATION OF SILICON SUBSTRATES 238 3 . PACKING OF POLYSTYRENE PARTICLES WITHIN MICRO- AND NANO-FABRICATED SILICON BOXES ...... 240 .................................................. 3.1. PACKING OF POLYSTYRENE PARTICLES 240 ................................................. 3.2. EFFECTS OF PARTICLE AND BOX SIZES 240 ........................... 3.3. POLYSTYRENE PARTICLE CHAIN ALONG A NANO-WIDTH STRIPE 241 ................................. 4 . NANOPARTICLE ARRAYS FORMED ON A SILICON NANOETCHPIT 242 4.1. SELECTIVE DEPOSITION OF POLYSTYRENE NANOPARTICLE ON THE SILICON .............................................................. NANOETCHPIT ARRAY 242 .............................. 4.2. FORCES WORKING ON THE PARTICLE DEPOSITION PROCESS 243 5 . ARRANGEMENT OF RADICAL POLYMER PARTICLES ON SILICON SUBSTRATES AND THEIR .......................................................................... APPLICATIONS 244 ....................................... 5.1. POLYMER PARTICLES BEARING STABLE RADICALS 244 ..................................................... 5.2. MAGNETIC FORCE MICROSCOPY 244 .................................. 5.3. RADICAL PARTICLE ARRAY AND ITS MAGNETIC IMAGE 245 ............................................................................ REFERENCES 245 CHAPTER 13 . FLUORESCENT ORGANIC NANOPARTICLES (FON S) WITH STRONGLY ENHANCED EMISSION BYEONG-KWAN AN. SOO YOUNG PARK .......................................................................... 1 . INTRODUCTION 247 .......................... 2 . ENHANCED FLUORESCENT EMISSION FROM ORGANIC NANOPARTICLES 248 ................................................................ 2.1. SILOLE DERIVATIVES 248 ...................................................... 2.2. CYANO-STILBENE DERIVATIVES 248 .................................................. 2.3 . SALICYLIDENE-ANILINE DERIVATIVES 249 ............................................................................ REFERENCES 251 CHAPTER 14 . LUMINESCENT NANOMATERIALS ANUSHREE ROY .......................................................................... 1 . INTRODUCTION 253 .......................................................................... 2 . BRIEF THEORY 254 ................................................................. 2.1. CLASSICAL THEORY 254 ................................................................ 2.2. QUANTUM THEORY 255 ..................................................... 3 . LUMINESCENCE FROM DEFECT STATES 258 ........................................... 4 W ~ ~ ~ I ~ E ~ C E N C E IN L O W DIMENSIONAL SYSTEMS 259 4.1. NANOPARTICLES .................................................................. 259 4.2. NANOWIRES ...................................................................... 267 4.3. QUANTUM WELL ............................ .....-....... 268 .............. 5. ~ONCLUSION ........................................................................... 270 REFERENCES ............................................................................ 271 CHAPTER 15 . COMPOSITES WITH NANOMATERIALS LALIT M . MANOCHA 1 . IN&ODUCTION .............................................................. 275 2. NANOSCALE FILLERS ..................................................................... 276 2.1. NANOCLAYS ....................................................................... 276 .......................................................... 2.2. CARBON NANOMATERIALS 278 ...................................................... 2.3. MODIFI&ION OF NANOTUBES 280 ........................................ 2.4. MODIFICATION OF EQUI-AXED NANOPARTICLES 281 ........................................................... 3 . POLYMER MATRIX COMPOSITES 282 .................................. 3.1. PROCESSING OF POLYMER MATRIX NANOCOMPOSITES 282 ..................................... 3.2. POLYMER MATRIX COMPOSITES WITH NANOTUBES 283 .................................................. 3.3. POLYMER NANOCOMPOSITE FIBERS 284 ..................................... 3.4. POLYMER NANOCOMPOSITE FILMS AND COATINGS 284 .............................................. 3.5. NANOPARTICLES/POLYMER COMPOSITES 284 ........................................................ 3.6. PROPERTIES OF COMPOSITES 285 ........................................ 3.7. APPLICATIONS OF POLYMER NANOCOMPOSITES 286 . . ........................................................... . 4 CERAMIC MATRIX COMPOSITES 286 .......................................... 4.1. PROCESSING OF CERAMIC NANOCOMPOSITES 287 ....................... 4.2. CARBON NANOTUBE REINFORCED CERAMIC MATRIX COMPOSITES 288 ................................................ 4.3. CARBON-CARBON NANOCOMPOSITES 289 ............................................................................ REFERENCES 290 CHAPTER 16 . LIBRARIES OF NANOSIZED. POLYFUNCTIONAL PLATFORMS AND NANOCOMPOSITES FROM SILSESQUIOXANES R . M . LAINE. C . BRICK. M . ROLL. S . SUIAIRNAN. S . G . KIRN. M . Z . ASUNCION. J. CHOI. R . TAMAKI 1 . INTRODUCTION .......................................................................... 295 2 . CONCLUSIONS ........................................................................... 299 REFERENCES .......................................................................... 299 CHAPTER 17 . ULTRAFAST PHOTOINDUCED LNTERFACIAL ELECTRON TRANSFER DYNAMICS IN MOLECULE-LNORGANIC SEMICONDUCTOR NANOCOMPOSITES XIN AI. TIANQUAN LIAN 1 . INTRODUCTION.. ........................................................................ 301 2 . THEORETICAL BACKGROUND ............................................................... 302 3 . EXPERIMENTAL SECTION ................................................................. 303 3.1. TECHNIQUES FOR INTERFACIAL ET MEASUREMENT 303 ..................................... 3.2. ULTRAFAST ?IINABLE INFRARED SPECTROMETER 304 ......................................... 3.3. PREPARATION AND SENSITIZATION OF NANOCRYSTALLINE THIN FILMS ..................... 304 ........................................................... 4 . SEMICONDUCTOR DEPENDENCE 305 ....................... 4.1. ULTRAFAST ELECTRON INJECTION TO TI02 AND BIPHASIC KINETICS 305 .......................................................................... 4.2. NB, O5 307 ............................................................................ 4.3. ZN0 308 ............................................................................ 4.4. SNO, 308 ..................................................... 4.5. SERNICONDUCTOR DEPENDENCE 309 ..................................................... . 5 BRIDGE-ASSISTED ELECLRON TRANSFER 310 ........................ . 6 CONJUGATED POLYMER-INORGANIC SEMICONDUCTOR NANOCOMPOSITES 311 ............................................................................. . 7 SUMMARY 312 ............................................................................ REFERENCES 313 CHAPTER 18 . PHYSICAL PROPERTIES OF NANO-MANGANITES AND CARBON NANOTUBES AMARJOT KAUR DHAMI .......................................................................... INTRODUCTION 317 ............................................................ 1.1. SUPERPARAMAGNETISM 318 ...................................................................... NANO-MANGANITES 318 ............................................................... 2.1. NANO-COMPOSITES 322 ........................................................................... NANOWIRES 322 .................................................................... CARBON NANOTUBES 323 ....................................................................... 4.1. DISCOVERY 323 ............................................................... 4.2. SYNTLIESIS OF CNTS 324 ........................................................... 4.3. MECHANICAL PROPERTIES 328 ............................................................ 4.4. ELECTRONIC PROPERTIES 329 ............................................................. 4.5. MAGNETIC PROPERTIES 330 ...................................................... 4.6. LOW TEMPERATURE BELIAVIOR 331 ......................................................................... NANO BIOTECH 332 .................................................. CONCLUSION .................... .. 333 ............................................................................ REFERENCES 333 CHAPTER 19 . NANOSPINTRONIC DEVICES: MAGNETIC SEMICONDUCTORS. DIGITAL ALLOYS. AND HEUSLERL SEMICONDUCTOR INTERFACES AS NEW MATERIALS A . CONTINENZA. S . PICOZZI .......................................................................... INTRODUCTION 337 ................................................ MAGNETIC SEMICONDUCTOR DIGITAL ALLOYS 339 .................................................................... 2.1. INTRODUCTION 339 ............................................ 2.2. STRUCTURAL AND COINPUTATIONAL DETAILS 340 ........................................................... 2.3. MAGNETIC INTERACTIONS 340 ............................................................ 2.4. ELEC T RONIC PROPERTIES 341 ..................................... 2.5. CARRIERS AND SPIN-POLARIZATION CONFINEMENT 341 .............................................. HEUSLER/SEMICONDUCTOR HETEROSTRUCTURES 343 .................................................................... 3.1. INTRODUCTION 343 .......................................................... 3.2. COMPUTATIONAL DETAILS 345 ........................................ 3.3. CO, MNGE STRAINED ON A GAAS SUBSTRATE 345 ............................ 3.4. DENSITY OF STATES AND INTERFACE STATES AT THE JUNCTION 345 .............................................................. 3.5. MAGNETIC MOMENTS 347 .................................................... 3.6. SPIN-RESOLVED BAND LINE-UP 347 .......................................................... CONCLUSIONS AND PERSPECTIVES 348 ................................................... .................. REFERENCES .. 349 CHAPTER 20 . SUPRAMOLECULAR ASSEMBLY OF ROD-COIL BLOCK MOLECULES INTO ORGANIZED NANOSTRUCTURES MYONGSOO LEE. JA-HYOUNG RYU .......................................................................... . 1 INTRODUCTION 351 ............................................................ . 2 ROD-COIL DIBLOCK SYSTEMS 352 3 . ROD-COII TRIBLOCK SYSTEMS ............................................................ 353 .......................................................... 4 . ROD-COIL MULTIBLOCK SYSTEMS 355 ........................... 5 . SELF-ASSEMBLING MOLECULAR TREES CONTAINING OCTAPHENYLENE 356 .................. 6 . NANOCOMPOSITES AND NANOOBJECTS FROM SUPRAMOLECULAR ROD-BUNDLES 358 ........................................................................... 7 . CONCLUSIONS 359 ............................................................................ REFERENCES 359 CHAPTER 21 . PHOTOFUNCTIONAL SUPRAMOLECULAR SYSTEMS BASED ON POLYMER NANOSHEETS TOK~LJI MIYASHITA. JUN MATS~LI. MASAYA MITSUISHI .......................................................................... INTRODUCTION 361 ........................... PHOTOELECTRIC CONVERSION SYSTEMS WITH POLYMER NANOSHEETS 362 2.1. PHOTOELECTRON TRANSFER SYSTEMS WITH HETERO-DEPOSITED POLYMER NANOSHEETS ..... 362 2.2. PHOTOEXCITED ENERG Y/ ELECTRON TRANSFER SYSTEMS USING POLYMER NANOSHEETS ....... 365 ..................... 2.3. PHOTOCURRENT AMPLIFICATION WITLI SURFACE PLASMON EXCITATION 366 ........................... MOLECULAR LOGIC GATES WITH POLYMER NANOSHEET ASSEMBLIES 368 ................................................ PHOTOCROSSLINKABLE POLYMER NANOSHEET 369 ............................ 4.1. DUAL-TONE PHOTOPATTERNING WITH POLYMER NANOSHEETS 369 ................. 4.2. HIGH SENSITIVITY DELECTION USING OPTICAL WAVEGUIDE TECHNIQUES 370 ............................... GOLD NANOPARTICLE/POLYMER NANOSHEET HYBRID MATERIALS 371 ............................................ TEMPERATURE SENSITIVE POLYMER NANOSHEETS 372 ............................................................................ REFERENCES 375 CHAPTER 22 . NANOENCAPSULATION OF FULLERENE WITH THE HOSTS CYCLODEXTRIN AND CUCURBITURIL FRIEDERICKE CONSTABEL. KURT E . GECKELER ..................................................... ................. 1 . INTRODUCTION ... 377 ............................... . 2 THE CONTAINER MOLECULES CYCLODEXTRIN AND CUCURBITURIL 378 .................................................................... 2.1. CYCLODEXTRINS 378 ................................................................... 2.2. CUCURBITURILS. 379 ......................................................... . 3 ENCAPSULATION WITH FULLERENES 380 ............................................... 3.1. CYCLODEXTRIN-FULLERENE COMPLEXES 380 ............................................... 3.2. CIICURBITURIL-FULLERENE COMPLEXES 385 .................................................. ..................... . 4 CONCIUSIONS .. 391 ............................................................................ REFERENCES 392 CHAPTER 23 . MORPHOLOGICAL CHAMELEONS: PH-DEPENDENT AGGREGATION BEHAVIOR OF SUGAR-BASED GEMINI AMPHIPHILES IN AQUEOUS SOLUTIONS ......................... MARKUS JOHNSSON. JAN B . E N. ENGBERTS 395 CHAPTER 24 . LONTOPHORETIC DRUG DELIVERY USING POLYMER ELECTROLYTE MATERIALS L? 0 . V DU CUNHA. M . M . C . FORTE, A . BARNES. R . J. LNTHAM. R . G . LINFORCL, W S . SCHLINDWEIN .......................................................................... 1 . INTRODUCTION 399 ...................................................... 2 . EARLY IONTOPHORETIC EXPERIMENTS 400 ............................................. . 3 IONTOPHORESIS TRANSDERMAL DRUG DEIIVERY 400 ................................................................................. 4 . SKIN 401 .................................................. . 5 IONTOPHORETIC DEVICE CHARACTERISTICS 402 ...................................................................... 5.1. ELECTRODES 402 ................................................................... 5.2. POWER SUPPLY 402 ................................................................. 5.3. DRUG RESEIVOIRS 402 ............................................... 5.4. DRUGS DELIVERED BY IONTOPHORESIS 404 ................................................................ . 6 PENETRATION ENHANCERS 407 ............................................................ . 7 SUMMARY AND CONCLUSIONS 409 ............................................................................ REFERENCES 409 CHAPTER 25 . PYRAZOLYL EMBRACE AS A SUPRAMOLECULAR SYNTHON: CASE STUDY OF METAL CARBONYL COMPLEXES CONTAINING LINKED TRIS(PYRAZOLYL)METHANE LIGANDS DANIEL L . REGEL; RAD11 E SENZENIUC. JAMES R . GADINIEL; KENNETH J . BLAWN. MARK D . SMITH .......................................................................... 1 . INTRODUCTIOII 411 ............. 2 . SYNTHESIS AND CHARACTERIZATION OF TLIE LIGANDS AND LHEIR META1 COMPLEXES 412 ........................................... 2.1. LIGAND SYNTHESIS AND CLIARACTERIZALION 412 ................................ 2.2. META1 CORNPLEXES SYNTHESIS AND CHARACTERIZATION 413 ............................................... 3 . SOLID STATE STRUCTURES OF THE COMPLEXES 413 .......................... 4 . STUELISTICAL ANALYSIS OF TLIE PYRAZOLYL EMBRACE STRUCTURAL MOTIF 419 ......................................................................... . 5 EXPERIMENTAL 423 .............................................................. 5.1. GENERAL PROCEDURE 423 ................... 5.2. SYNTHESIS OF {RN-C,H,[CH,OCI-I,C(PZ),], [RE(CO),],)(BR), (5) 423 .................. 5.3. SYNTLIESIS OF {P-C,H,[CH,OCH, C(PZ)& [RE(CO),],)(BF,), (6) 423 ................................................... ................... . 6 CONCLUSION .. 423 ............................................................ .......... REFERENCES ... 423 CHAPTER 26 . SELF-ORGANIZATION OF BLOCK COPOLYMERS BASED ON POLYSILANES RICLZARD G . JONES. SIMON J. HOLDER .......................................................................... . 1 INTRODUCTION 425 .................................................................. . 2 SYNTHETIC PROCECLURES 426 ................................................... 2.1. SYNTHESIS OF POLYSILANE BLOCKS 426 ........................................................ 2.2. THE TELECHELIC APPROACLI 426 ................................................... 2.3. THE MACROINITIATOR APPROACH 426 ........................................................ . 3 AGGREGATION AND SELF-ASSEMBLY 427 ................................................. 3.1. HYDROPLIOBIC BLOCK COPOLYMERS 427 ........................................................ . 4 AMPHIPHILIC BLOCK COPOLYMERS 428 .......................................................... .......... . 5 ~ONCLUSION .. 432 ............................................................................ REFERENCES 432 CHAPTER 27 . MODULATION OF THE SUPERSTRUCTURE AND RESPONSE OF MACROMOLECULES THROUGH MOLECULAR LNTERACTIONS AND NANODISPERSION FRANCESCO CIARDELLI. OSVNLDO PIERONI. SIMONA BRONCO. CHIAIA CNPPELLI. GIACOMO RUGGERI. ANDREN PUCCI 1 . INTRODUCTION .......................................................................... 435 ......................... 2 . PHOTOMODULATION OF MACROMOLECULAR STRUCTURE AND PROPERTIES 436 .................................................... 3 . CHEMICAL MODIFICATION OF COLLAGEN 438 ........................... 4 . CATALYTIC BEHAVIOR OF METAL EMBEDDED META1 NANOPARTICLES 439 5 . OPTICAL BEHAVIOR OF GOLD NANOPARTICLES IN POLYMER MATRICES .......................... 440 6 . .FINAL REMARKS ........................................................................ 441 ............................................................................ REFERENCES 441 CHAPTER 28 . CRYSTALLIZATION OF NANOSTRUCTURES BY PLASMA ENHANCED CHEMICAL VAPOR DEPOSITION JING ZHANG, PING YANG. LIN YANG, LEI XIA. YING GUO 1 . INTRODUCTION ....... .. ............................................................... 443 2 . BASIC PROCESS OF PECVD APPLIED IN FABRICATION OF NANOCRYSTALS ....................... 444 3 . INORGANIC SILICON NANOCSYSTALLINE FORMATION BY PECVD ............................... 445 4 . PTFE-LIKE NANOPARTICULATE FILMS, NANOWIRES AND NANOTUBES ......................... 447 5 . CONCLUSIONS .......... .. ............................................................. 450 REFERENCES ............................................................................ 450 CHAPTER 29 . NANOSTRUCTURED TIN DIOXIDE MATERIALS FOR GAS SENSOR APPLICATIONS T A . MILLE6 S . D . BAHNIN, C . PEREZ, M . S . WOOLDRIDGE TNTRODUCTION .......................................................................... 453 1.1. SEMICONDUCTOR GAS SENSORS ..................................................... 453 1.2 . MECHANISMS FOR GAS SENSING IN PURE SNO, SENSORS .............................. 454 ..................... 1.3. MECHANISMS FOR GAS SENSING IN SNOZ SENSORS WITH ADDITIVES 456 SNO, SYNTHESIS METHODS AND MATERIALS CHARACTERIZATION RESULTS ....................... 458 2.1. PURE SNO, ...................................................................... 458 2.2. SNO, WITH ADDITIVES ............................................................. 463 SENSOR PERFORMANCE .. ... ............................................................ 468 3.1. SENSOR TYPES AND FABRICATION METHODS .......................................... 468 3.2. SENSITIVITY ....................................................................... 469 3.3. SELECTIVITY ....................................................................... 472 3.4. STABILITY ......................................................................... 473 3.5. TIME RESPONSE .................................................................. 473 CONCLUDING REMARKS .................................................................. 474 REFERENCES ............................................................................ 475 INDEX ..................................................................................... 477
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language	English
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spelling	Geckeler, Kurt E. Verfasser aut Functional nanomaterials ed. by Kurt E. Geckeler Stevenson Ranch, Calif. American Scientific Publishers 2006 XXVII, 488 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier ... 10 Materiais nanoestruturados larpcal Nanomatériaux Nanomatériaux - Applications industrielles Nanotecnologia larpcal Nanostructured materials Nanostructured materials Industrial applications ... 10 (DE-604)BV022415974 10 OEBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017047130&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis
spellingShingle	Geckeler, Kurt E. Functional nanomaterials ... Materiais nanoestruturados larpcal Nanomatériaux Nanomatériaux - Applications industrielles Nanotecnologia larpcal Nanostructured materials Nanostructured materials Industrial applications
title	Functional nanomaterials
title_auth	Functional nanomaterials
title_exact_search	Functional nanomaterials
title_full	Functional nanomaterials ed. by Kurt E. Geckeler
title_fullStr	Functional nanomaterials ed. by Kurt E. Geckeler
title_full_unstemmed	Functional nanomaterials ed. by Kurt E. Geckeler
title_short	Functional nanomaterials
title_sort	functional nanomaterials
topic	Materiais nanoestruturados larpcal Nanomatériaux Nanomatériaux - Applications industrielles Nanotecnologia larpcal Nanostructured materials Nanostructured materials Industrial applications
topic_facet	Materiais nanoestruturados Nanomatériaux Nanomatériaux - Applications industrielles Nanotecnologia Nanostructured materials Nanostructured materials Industrial applications
url	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017047130&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
volume_link	(DE-604)BV022415974
work_keys_str_mv	AT geckelerkurte functionalnanomaterials

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