Molecular characterization and analysis of polymers:
Gespeichert in:
Weitere Verfasser: | |
---|---|
Format: | Buch |
Sprache: | English |
Veröffentlicht: |
Amsterdam [u.a.]
Elsevier
2008
|
Ausgabe: | 1. ed. |
Schriftenreihe: | Wilson & Wilson's comprehensive analytical chemistry
53 |
Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis |
Beschreibung: | XXI, 754 S. Ill., graph. Darst. |
ISBN: | 9780444530561 |
Internformat
MARC
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245 | 1 | 0 | |a Molecular characterization and analysis of polymers |c ed. by John M. Chalmers ... |
250 | |a 1. ed. | ||
264 | 1 | |a Amsterdam [u.a.] |b Elsevier |c 2008 | |
300 | |a XXI, 754 S. |b Ill., graph. Darst. | ||
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490 | 1 | |a Wilson & Wilson's comprehensive analytical chemistry |v 53 | |
650 | 7 | |a Chemische Analyse |2 swd | |
650 | 7 | |a Makromolekulare Chemie |2 swd | |
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Datensatz im Suchindex
_version_ | 1804138361654345728 |
---|---|
adam_text | Contributors to Volume
53 xiii
Volumes in the Series
xv
Preface
xix
Series Editor s Preface
xxi
SECTION I: INTRODUCTION
1.
Introduction
3
John M. Chalmers and Robert J. Meier
1.
The Analytical Competence
3
2.
Contents and Structure
6
3.
Practical Considerations in the Multi-Technique Approach
11
References
12
2.
Polymer Chemistry and
Microstructure
13
Jacques Devaux and Sophie Demoustier-Champagne
1
Introduction
14
2.
Polymer: Definitions IS
3.
From Molecules to Macromolecules
25
4.
Fundamentals of Polymer Chemistry
34
5.
Polymer Degradation
58
6.
Summary
62
References
62
3.
Polymeric Materials: Composition, Uses and Applications
65
J.P. Candlin
1.
Introduction
65
2.
Mode of Polymerisation
66
3.
Polymer Materials: Types and Forms
68
4.
Polymer Additives
87
5.
Summary
117
Bibliography
118
VII
viii Contents
SECTION II:
POLYMER
CHAIN
ANALYSIS
4.
Chain Structure
Characterization
123
Gregory
Beaucage and
Amit
S.
Kulkami
1.
Introduction
to
Structure
in Synthetic
Macromolecules
123
2.
Local Structure
and lts
Ramifications
134
3.
Summary
165
References
166
5.
Chain
End Characterisation
171
Anthony T. Jackson
and Duncan
F.
Robertson
1.
Introduction
171
2.
End Groups in Free
Radical
Polymers
175
3.
End Groups ¡n
Condensation
Polymers
182
4.
End Groups in Polymers from Ionic
Polymerisation
194
5.
Closing Remarks
201
Acknowledgements
201
References
201
6.
Determination of Molecular Weights and
Their Distributions
205
Simone
Wiegand and Werner
Köhler
1.
Introduction
205
2.
Distribution Functions and Averages
208
3.
Methods Based on Colligative Properties
212
4.
Viscometry
218
5.
Scattering Techniques
220
6.
Liquid Chromatography
228
7.
Analytical
Ultracentrifuge
235
8.
Other Methods
237
9.
Practical Examples
241
10.
Conclusion
247
Acknowledgements
248
References
248
SECTION III: POLYMER MORPHOLOGY AND STRUCTURE
7.
Phase Structure and Morphology
255
Rufina
G.
Alamo
1.
Phase Structure and Morphology
255
2.
Supermolecutar Morphology
274
Contents ix
3. Concluding
Remarks
286
Acknowledgements
287
References
287
8.
Characterization of Molecular Orientation
295
Thierry
Lefèvre,
Christian Pellerin and Michel
Pézolet
1.
Introduction
295
2.
Theory
297
3.
Birefringence
301
4.
Infrared Linear Dichroism (IRLD)
305
5.
Raman Spectroscopy and Microspectroscopy
313
6.
Fluorescence Spectroscopy
322
7.
NMR Spectroscopy
325
8.
Х
-Ray Diffraction and Absorption
328
9.
Conclusion
333
References
333
9.
Polymer Networks: Elastomers
337
B. Erman and J.E. Mark
1.
Introduction
338
2.
Structure of a Typical Network
339
3.
Elementary and More Advanced Molecular Theories
341
4.
Phenomenological Theories
351
5.
Some Relevant Simulations
352
6.
Swelling of Networks and Responsive Gels
356
7. Enthalpie
and
Entropie
Contributions to Rubber Elasticity:
The Force-Temperature Relations
358
8. Multimodal
Elastomers
359
9.
Liquid-Crystalline Elastomers
365
10.
Novel Reinforced Elastomers
370
11.
Further Comments on Some Characterization Techniques
374
Acknowledgement
376
References
377
SECTION IV: POLYMER DEGRADATION
10.
Polymer Degradation and Oxidation: An Introduction
387
John M. Chalmers and Robert J. Meier
1.
Introduction
388
2.
Standard Tests and Comparative Methods
390
3.
Spectroscopie
Techniques
402
4.
Thermal Methods
436
5. Chromatographie
Analysis
442
6.
Closing Remarks
447
Acknowledgement
448
References
448
Contents
11.
The Role of Oxidation in Degradation of Polymers:
The Relation of Oxidation to the Light Emission from
Oxidized Polymers
451
Jozef
Rychlý
and
Lyda
Matisová-Rychlá
1
Introduction, Historical Overview and Terminology Associated with the
Degradation and Ageing of Polymers
452
2.
Methodology and Analytical Techniques in Polymer Stability Studies
461
3.
Mechanisms Leading to the Light Emission from Thermally Oxidized Polymers
(Chemiluminescence), Similarities and Differences within Respective
Groups of Polymers
463
4.
General Classification of Chemiluminescence from Polymers
471
5.
Comparison of Chemiluminescence for Isothermal and Non-Isothermal
Conditions with those Obtained by DSC
476
6.
The Effect of Initial Molar Mass on Chemiluminescence Runs
478
7.
The Effect of Temperature on Chemiluminescence Intensity; The Mutual
Relation of Isothermal and Non-Isothermal Studies
480
8.
Relaxation Experiments (Jump Changes of Concentration of Oxygen,
Temperature and Humidity) and Rate Constants of Respective Elementary
Reaction Steps
482
9.
The Effect of Antioxidants and Polymer Stabilizers
483
10.
Isothermal Kinetics of Polymers Oxidation and Its Relation to the
Concentration of Oxygen in Surrounding Atmosphere
487
11.
The Effect of Alkaline Additives on Chemiluminescence Runs:
A Possible Impact
490
12.
Conclusions and Outline of the Further Perspectives
493
Acknowledgements
496
References
496
12.
ESR and ESR Imaging Methods for the Study of Oxidative
Polymer Degradation
499
Shulamith
Schlick
and
Krzysztof Kruczała
1.
Introduction: Polymer Degradation in the Presence of Oxygen
500
2.
Fundamentals of ESR and ESR Imaging
504
3.
ESR as a Tool for the Study of Polymer Degradation
513
4.
ESR Imaging: A Nondestructive Method for Spatially Resolved Polymer
Degradation
517
5.
Concluding Remarks
521
Acknowledgements
521
References
522
SECTION V: POLYMER PRODUCT ANALYSIS
13.
Spatial Imaging/Heterogeneity
527
Peter
Wilhelm
and
Bořil Chernev
1.
Introduction
527
2.
Raman and FTIR Microscopy
529
Contents xi
3.
Examples of Heterogeneous Polymers Investigated by
IR
and Raman Microscopy
538
4.
Other Methods and Comparison of Methods
550
5.
Conclusions
557
References
558
14.
Additive Analysis
561
John Sidwell
1.
Introduction
562
2.
Analytical Techniques for Additive Analysis
563
3.
Analysis of Specific Additives
573
4.
Future Developments in Analytical Methodology
603
References
605
15.
Failure, Defect, and Contaminant Analysis
607
James D. Rancourt, Jennifer Brooks, Sue Mecham,
Alan Sentman, Brian Starr and Jason Todd
1.
Introduction
607
2.
Case Studies
608
3.
Summary
673
References
674
16.
Surface Analysis
675
John M. Chalmers and Robert J. Meier
1.
Introduction
675
2.
A Surface and Spatial Resolution
676
3.
Adhesion
677
4.
Polymer Degradation
679
5.
Polymer Fracture
679
6.
Characterizing Polymer Surfaces
679
7.
Delamination
679
8.
Cure
681
9.
Closing Remark
682
References
682
SECTION VI: POLYMER AND POLYMER PRODUCT DEVELOPMENT:
SUPPORT TECHNIQUES
17.
The Supporting Role of Molecular Modelling and
Computational Chemistry in Polymer Analysis
685
John Kendrick
1.
Introduction
686
2.
Methodologies
687
3.
Infrared and Raman Spectroscopy
693
4.
Photoelectron Spectroscopy and Auger Electron Spectroscopy (AES)
703
XU Contents
5.
Mass Spectrometry
712
6.
Х
-Ray Diffraction
718
7.
Nuclear Magnetic Resonance
722
8.
Electron Spin Resonance
727
9.
Summary
729
References
730
18.
High-Throughput Analysis
735
Robert J. Meier
1.
Introduction
735
2.
Some General Considerations on MTE and the Corresponding
Analytical Needs
737
3.
Analytical Techniques for Medium-Throughput Polymer Analysis
740
4.
Outlook
742
References
743
Subject Index
745
See Color Plate Section at the End of This Book
|
adam_txt |
Contributors to Volume
53 xiii
Volumes in the Series
xv
Preface
xix
Series Editor's Preface
xxi
SECTION I: INTRODUCTION
1.
Introduction
3
John M. Chalmers and Robert J. Meier
1.
The Analytical Competence
3
2.
Contents and Structure
6
3.
Practical Considerations in the Multi-Technique Approach
11
References
12
2.
Polymer Chemistry and
Microstructure
13
Jacques Devaux and Sophie Demoustier-Champagne
1
Introduction
14
2.
Polymer: Definitions IS
3.
From Molecules to Macromolecules
25
4.
Fundamentals of Polymer Chemistry
34
5.
Polymer Degradation
58
6.
Summary
62
References
62
3.
Polymeric Materials: Composition, Uses and Applications
65
J.P. Candlin
1.
Introduction
65
2.
Mode of Polymerisation
66
3.
Polymer Materials: Types and Forms
68
4.
Polymer Additives
87
5.
Summary
117
Bibliography
118
VII
viii Contents
SECTION II:
POLYMER
CHAIN
ANALYSIS
4.
Chain Structure
Characterization
123
Gregory
Beaucage and
Amit
S.
Kulkami
1.
Introduction
to
Structure
in Synthetic
Macromolecules
123
2.
Local Structure
and lts
Ramifications
134
3.
Summary
165
References
166
5.
Chain
End Characterisation
171
Anthony T. Jackson
and Duncan
F.
Robertson
1.
Introduction
171
2.
End Groups in Free
Radical
Polymers
175
3.
End Groups ¡n
Condensation
Polymers
182
4.
End Groups in Polymers from Ionic
Polymerisation
194
5.
Closing Remarks
201
Acknowledgements
201
References
201
6.
Determination of Molecular Weights and
Their Distributions
205
Simone
Wiegand and Werner
Köhler
1.
Introduction
205
2.
Distribution Functions and Averages
208
3.
Methods Based on Colligative Properties
212
4.
Viscometry
218
5.
Scattering Techniques
220
6.
Liquid Chromatography
228
7.
Analytical
Ultracentrifuge
235
8.
Other Methods
237
9.
Practical Examples
241
10.
Conclusion
247
Acknowledgements
248
References
248
SECTION III: POLYMER MORPHOLOGY AND STRUCTURE
7.
Phase Structure and Morphology
255
Rufina
G.
Alamo
1.
Phase Structure and Morphology
255
2.
Supermolecutar Morphology
274
Contents ix
3. Concluding
Remarks
286
Acknowledgements
287
References
287
8.
Characterization of Molecular Orientation
295
Thierry
Lefèvre,
Christian Pellerin and Michel
Pézolet
1.
Introduction
295
2.
Theory
297
3.
Birefringence
301
4.
Infrared Linear Dichroism (IRLD)
305
5.
Raman Spectroscopy and Microspectroscopy
313
6.
Fluorescence Spectroscopy
322
7.
NMR Spectroscopy
325
8.
Х
-Ray Diffraction and Absorption
328
9.
Conclusion
333
References
333
9.
Polymer Networks: Elastomers
337
B. Erman and J.E. Mark
1.
Introduction
338
2.
Structure of a Typical Network
339
3.
Elementary and More Advanced Molecular Theories
341
4.
Phenomenological Theories
351
5.
Some Relevant Simulations
352
6.
Swelling of Networks and Responsive Gels
356
7. Enthalpie
and
Entropie
Contributions to Rubber Elasticity:
The Force-Temperature Relations
358
8. Multimodal
Elastomers
359
9.
Liquid-Crystalline Elastomers
365
10.
Novel Reinforced Elastomers
370
11.
Further Comments on Some Characterization Techniques
374
Acknowledgement
376
References
377
SECTION IV: POLYMER DEGRADATION
10.
Polymer Degradation and Oxidation: An Introduction
387
John M. Chalmers and Robert J. Meier
1.
Introduction
388
2.
Standard Tests and Comparative Methods
390
3.
Spectroscopie
Techniques
402
4.
Thermal Methods
436
5. Chromatographie
Analysis
442
6.
Closing Remarks
447
Acknowledgement
448
References
448
Contents
11.
The Role of Oxidation in Degradation of Polymers:
The Relation of Oxidation to the Light Emission from
Oxidized Polymers
451
Jozef
Rychlý
and
Lyda
Matisová-Rychlá
1
Introduction, Historical Overview and Terminology Associated with the
Degradation and Ageing of Polymers
452
2.
Methodology and Analytical Techniques in Polymer Stability Studies
461
3.
Mechanisms Leading to the Light Emission from Thermally Oxidized Polymers
(Chemiluminescence), Similarities and Differences within Respective
Groups of Polymers
463
4.
General Classification of Chemiluminescence from Polymers
471
5.
Comparison of Chemiluminescence for Isothermal and Non-Isothermal
Conditions with those Obtained by DSC
476
6.
The Effect of Initial Molar Mass on Chemiluminescence Runs
478
7.
The Effect of Temperature on Chemiluminescence Intensity; The Mutual
Relation of Isothermal and Non-Isothermal Studies
480
8.
Relaxation Experiments (Jump Changes of Concentration of Oxygen,
Temperature and Humidity) and Rate Constants of Respective Elementary
Reaction Steps
482
9.
The Effect of Antioxidants and Polymer Stabilizers
483
10.
Isothermal Kinetics of Polymers Oxidation and Its Relation to the
Concentration of Oxygen in Surrounding Atmosphere
487
11.
The Effect of Alkaline Additives on Chemiluminescence Runs:
A Possible Impact
490
12.
Conclusions and Outline of the Further Perspectives
493
Acknowledgements
496
References
496
12.
ESR and ESR Imaging Methods for the Study of Oxidative
Polymer Degradation
499
Shulamith
Schlick
and
Krzysztof Kruczała
1.
Introduction: Polymer Degradation in the Presence of Oxygen
500
2.
Fundamentals of ESR and ESR Imaging
504
3.
ESR as a Tool for the Study of Polymer Degradation
513
4.
ESR Imaging: A Nondestructive Method for Spatially Resolved Polymer
Degradation
517
5.
Concluding Remarks
521
Acknowledgements
521
References
522
SECTION V: POLYMER PRODUCT ANALYSIS
13.
Spatial Imaging/Heterogeneity
527
Peter
Wilhelm
and
Bořil Chernev
1.
Introduction
527
2.
Raman and FTIR Microscopy
529
Contents xi
3.
Examples of Heterogeneous Polymers Investigated by
IR
and Raman Microscopy
538
4.
Other Methods and Comparison of Methods
550
5.
Conclusions
557
References
558
14.
Additive Analysis
561
John Sidwell
1.
Introduction
562
2.
Analytical Techniques for Additive Analysis
563
3.
Analysis of Specific Additives
573
4.
Future Developments in Analytical Methodology
603
References
605
15.
Failure, Defect, and Contaminant Analysis
607
James D. Rancourt, Jennifer Brooks, Sue Mecham,
Alan Sentman, Brian Starr and Jason Todd
1.
Introduction
607
2.
Case Studies
608
3.
Summary
673
References
674
16.
Surface Analysis
675
John M. Chalmers and Robert J. Meier
1.
Introduction
675
2.
A Surface and Spatial Resolution
676
3.
Adhesion
677
4.
Polymer Degradation
679
5.
Polymer Fracture
679
6.
Characterizing Polymer Surfaces
679
7.
Delamination
679
8.
Cure
681
9.
Closing Remark
682
References
682
SECTION VI: POLYMER AND POLYMER PRODUCT DEVELOPMENT:
SUPPORT TECHNIQUES
17.
The Supporting Role of Molecular Modelling and
Computational Chemistry in Polymer Analysis
685
John Kendrick
1.
Introduction
686
2.
Methodologies
687
3.
Infrared and Raman Spectroscopy
693
4.
Photoelectron Spectroscopy and Auger Electron Spectroscopy (AES)
703
XU Contents
5.
Mass Spectrometry
712
6.
Х
-Ray Diffraction
718
7.
Nuclear Magnetic Resonance
722
8.
Electron Spin Resonance
727
9.
Summary
729
References
730
18.
High-Throughput Analysis
735
Robert J. Meier
1.
Introduction
735
2.
Some General Considerations on MTE and the Corresponding
Analytical Needs
737
3.
Analytical Techniques for Medium-Throughput Polymer Analysis
740
4.
Outlook
742
References
743
Subject Index
745
See Color Plate Section at the End of This Book |
any_adam_object | 1 |
any_adam_object_boolean | 1 |
author2 | Chalmers, John M. |
author2_role | edt |
author2_variant | j m c jm jmc |
author_facet | Chalmers, John M. |
building | Verbundindex |
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callnumber-first | Q - Science |
callnumber-label | QD75 |
callnumber-raw | QD75 |
callnumber-search | QD75 |
callnumber-sort | QD 275 |
callnumber-subject | QD - Chemistry |
ctrlnum | (OCoLC)236329183 (DE-599)HBZHT015583574 |
dewey-full | 547.70442 |
dewey-hundreds | 500 - Natural sciences and mathematics |
dewey-ones | 547 - Organic chemistry |
dewey-raw | 547.70442 |
dewey-search | 547.70442 |
dewey-sort | 3547.70442 |
dewey-tens | 540 - Chemistry and allied sciences |
discipline | Chemie / Pharmazie |
discipline_str_mv | Chemie / Pharmazie |
edition | 1. ed. |
format | Book |
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illustrated | Illustrated |
index_date | 2024-07-02T22:59:40Z |
indexdate | 2024-07-09T21:26:58Z |
institution | BVB |
isbn | 9780444530561 |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-016992668 |
oclc_num | 236329183 |
open_access_boolean | |
owner | DE-703 DE-83 |
owner_facet | DE-703 DE-83 |
physical | XXI, 754 S. Ill., graph. Darst. |
publishDate | 2008 |
publishDateSearch | 2008 |
publishDateSort | 2008 |
publisher | Elsevier |
record_format | marc |
series | Wilson & Wilson's comprehensive analytical chemistry |
series2 | Wilson & Wilson's comprehensive analytical chemistry |
spelling | Molecular characterization and analysis of polymers ed. by John M. Chalmers ... 1. ed. Amsterdam [u.a.] Elsevier 2008 XXI, 754 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Wilson & Wilson's comprehensive analytical chemistry 53 Chemische Analyse swd Makromolekulare Chemie swd Polymere swd Polymers Analysis Chalmers, John M. edt Wilson & Wilson's comprehensive analytical chemistry 53 (DE-604)BV000900805 53 Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016992668&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Molecular characterization and analysis of polymers Wilson & Wilson's comprehensive analytical chemistry Chemische Analyse swd Makromolekulare Chemie swd Polymere swd Polymers Analysis |
title | Molecular characterization and analysis of polymers |
title_auth | Molecular characterization and analysis of polymers |
title_exact_search | Molecular characterization and analysis of polymers |
title_exact_search_txtP | Molecular characterization and analysis of polymers |
title_full | Molecular characterization and analysis of polymers ed. by John M. Chalmers ... |
title_fullStr | Molecular characterization and analysis of polymers ed. by John M. Chalmers ... |
title_full_unstemmed | Molecular characterization and analysis of polymers ed. by John M. Chalmers ... |
title_short | Molecular characterization and analysis of polymers |
title_sort | molecular characterization and analysis of polymers |
topic | Chemische Analyse swd Makromolekulare Chemie swd Polymere swd Polymers Analysis |
topic_facet | Chemische Analyse Makromolekulare Chemie Polymere Polymers Analysis |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016992668&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
volume_link | (DE-604)BV000900805 |
work_keys_str_mv | AT chalmersjohnm molecularcharacterizationandanalysisofpolymers |