Biocatalytic separation of isomers using supercritical fluids:
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| 1. Verfasser: | |
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| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
2008
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | 165 S. Ill., graph. Darst. 30 cm |
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Datensatz im Suchindex
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| adam_text | BIOCATALYTIC SEPARATION OF ISOMERS USING SUPERCRITICAL FLUIDS VOM
PROMOTIONSAUSSCHUSS DER TECHNISCHEN UNIVERSITAET HAMBURG-HARBURG ZUR
ERLANGUNG DES AKADEMISCHEN GRADES DOKTOR-INGENIEUR GENEHMIGTE
DISSERTATION VON ALEXANDRE BABO DE ALMEIDA PAIVA AUS LISBOA, PORTUGAL
2008 CONTENTS ACKNOWLEDGEMENTS III LIST OF SYMBOLS VI 1. SUMMARY 10 2.
INTRODUCTION 13 2.1. GREEN CHEMISTRY 13 2.2. ALTERNATIVE GREEN
SOLVENTS 17 2.2.1. SOLVENT FREE PROCESSES 17 2.2.2. WATER 18 2.2.3.
SUPERCRITICAL FLUIDS 18 2.2.3.1. APPLICATIONS 20 2.2.4. IONICLIQUIDS 21
2.2.4.1. APPLICATIONS 23 2.3. BIOCATALYSIS 24 2.3.1. HISTORY OF ENZYME
DEVELOPMENT 24 2.3.2. ENZYME APPLICATIONS 25 2.3.3. LIPASES 27 2.3.4.
BIOCATALYSIS IN SUPERCRITICAL CARBON DIOXIDE 28 2.3.5. ENZYMATIC
PROCESSES IN BIPHASIC SYSTEM 29 2.3.6. CHIRALITY AND ENANTIOMER
SEPARATION 31 2.3.6.1. KINETIC RESOLUTION 32 2.4. PHASE EQUILIBRIUM 35
2.4.1. THE NEED FOR PHASE EQUILIBRIUM 35 2.4.2. PHASE EQUILIBRIA IN
MULTICOMPONENT SYSTEMS 36 2.4.2.1. THERMODYNAMICS OF VAPOR-LIQUID
EQUILIBRIA 37 2.4.3. EQUATIONSOF STATE . 41 2.4.3.1. HISTORY 41
2.4.3.2. EQUATIONSOF STATE FOR MIXTURES 42 2.4.3.3. PREDICTIVE EQUATIONS
OF STATE 45 2.5. STRUCTURE OF THE EXPERIMENTAL SECTION 47 3. PHASE
EQUILIBRIA 50 3.1. EXPERIMENTAL SECTION 50 VII 3.1.1. MATERIALS 51
3.1.2. APPARATES 51 3.1.2.1. VIEW CELL 52 3.1.2.2. SAMPLING SECTION 53
3.1.3. METHOD 54 3.1.4. ANALYSIS 55 3.2. RESULTS 55 3.2.1. TERNARY
SYSTEM (R,S)-L-PHENYLETHANOL / VINYL ACETATE / C02 55 3.2.1.1. MODELING
61 3.2.1.2. PHASE EQUILIBRIUM PREDICTION 64 3.2.2. TERNARY SYSTEM
(R,S)-L-PHENYL-ETHYL ACETATE / VINYL ACETATE / C02 70 3.2.2.1. MODELING
74 3.2.3. TERNARY SYSTEM (R,S)-L-PHENYLETHANOL / (R,S)-L-PHENYL-ETHYL
ACETATE / C02 78 3.2.3.1. MODELING 81 3.2.4. QUATERNARY SYSTEM VINYL
ACETATE / (R,S)-L-PHENYL-ETHYL ACETATE / (R,S)-1- PHENYLETHANOL / C02 85
3.2.4.1. MODELING 91 3.3. SUMMARY CHAPTER 3 92 4. IONIC LIQUID / SCC02
SYSTEM 94 4.1. RESULTS 95 4.2. SUMMARY - CHAPTER 4 97 5. ENANTIOMERIC
KINETIC RESOLUTION IN SCC02 99 5.1. EXPERIMENTAL SECTION 99 5.1.1.
MATERIALS 99 5.1.2. APPARATES AND METHOD 100 5.1.2.1. BATCH REACTION
APPARATES 100 5.1.2.2. CONTINUOUS REACTION APPARATES 103 5.2. RESULTS -
BATCH REACTION 105 5.2.1. VINYL DECANOATE 105 5.2.2. VINYL LAURATE 107
5.2.3. VINYL STEARATE 108 5.2.4. METHYL ESTERS 111 5.2.5. ENZYME AMOUNT
INFLUENCE 113 VIII 5.3. RESULTS - CONTINUOUS REACTION 115 5.4. SUMMARY
CHAPTER 5 118 6. (R,S)-1-PHENYLETHANOL / (R,S)-1-PHENYL-ETHYL LAURATE
SEPARATION 119 6.1. MATERIALS 119 6.2. RESULTS 119 6.3.MODELING 128 6.4.
SUMMARY CHAPTER 6 131 7. CONTINUOUS KINETIC RESOLUTION AND SEPARATION OF
(R,S)-1 -PHENYLETHANOL 133 7.1. MATERIALS 134 7.2. EXPERIMENTAL
APPARATES 134 7.3.EXPERIMENTALMETHOD 138 7.4. RESULTS 139 7.5. SUMMARY
CHAPTER 7 144 8. DISCUSSION 145 REFERENCES 149 APPENDIX A 159 GC
CALIBRATION CURVES 159 CURRICULUM VITAE 164 IX
|
| adam_txt |
BIOCATALYTIC SEPARATION OF ISOMERS USING SUPERCRITICAL FLUIDS VOM
PROMOTIONSAUSSCHUSS DER TECHNISCHEN UNIVERSITAET HAMBURG-HARBURG ZUR
ERLANGUNG DES AKADEMISCHEN GRADES DOKTOR-INGENIEUR GENEHMIGTE
DISSERTATION VON ALEXANDRE BABO DE ALMEIDA PAIVA AUS LISBOA, PORTUGAL
2008 CONTENTS ACKNOWLEDGEMENTS III LIST OF SYMBOLS VI 1. SUMMARY 10 2.
INTRODUCTION 13 2.1. GREEN CHEMISTRY 13 2.2. ALTERNATIVE "GREEN"
SOLVENTS 17 2.2.1. SOLVENT FREE PROCESSES 17 2.2.2. WATER 18 2.2.3.
SUPERCRITICAL FLUIDS 18 2.2.3.1. APPLICATIONS 20 2.2.4. IONICLIQUIDS 21
2.2.4.1. APPLICATIONS 23 2.3. BIOCATALYSIS 24 2.3.1. HISTORY OF ENZYME
DEVELOPMENT 24 2.3.2. ENZYME APPLICATIONS 25 2.3.3. LIPASES 27 2.3.4.
BIOCATALYSIS IN SUPERCRITICAL CARBON DIOXIDE 28 2.3.5. ENZYMATIC
PROCESSES IN BIPHASIC SYSTEM 29 2.3.6. CHIRALITY AND ENANTIOMER
SEPARATION 31 2.3.6.1. KINETIC RESOLUTION 32 2.4. PHASE EQUILIBRIUM 35
2.4.1. THE NEED FOR PHASE EQUILIBRIUM 35 2.4.2. PHASE EQUILIBRIA IN
MULTICOMPONENT SYSTEMS 36 2.4.2.1. THERMODYNAMICS OF VAPOR-LIQUID
EQUILIBRIA 37 2.4.3. EQUATIONSOF STATE .' 41 2.4.3.1. HISTORY 41
2.4.3.2. EQUATIONSOF STATE FOR MIXTURES 42 2.4.3.3. PREDICTIVE EQUATIONS
OF STATE 45 2.5. STRUCTURE OF THE EXPERIMENTAL SECTION 47 3. PHASE
EQUILIBRIA 50 3.1. EXPERIMENTAL SECTION 50 VII 3.1.1. MATERIALS 51
3.1.2. APPARATES 51 3.1.2.1. VIEW CELL 52 3.1.2.2. SAMPLING SECTION 53
3.1.3. METHOD 54 3.1.4. ANALYSIS 55 3.2. RESULTS 55 3.2.1. TERNARY
SYSTEM (R,S)-L-PHENYLETHANOL / VINYL ACETATE / C02 55 3.2.1.1. MODELING
61 3.2.1.2. PHASE EQUILIBRIUM PREDICTION 64 3.2.2. TERNARY SYSTEM
(R,S)-L-PHENYL-ETHYL ACETATE / VINYL ACETATE / C02 70 3.2.2.1. MODELING
74 3.2.3. TERNARY SYSTEM (R,S)-L-PHENYLETHANOL / (R,S)-L-PHENYL-ETHYL
ACETATE / C02 78 3.2.3.1. MODELING 81 3.2.4. QUATERNARY SYSTEM VINYL
ACETATE / (R,S)-L-PHENYL-ETHYL ACETATE / (R,S)-1- PHENYLETHANOL / C02 85
3.2.4.1. MODELING 91 3.3. SUMMARY CHAPTER 3 92 4. IONIC LIQUID / SCC02
SYSTEM 94 4.1. RESULTS 95 4.2. SUMMARY - CHAPTER 4 97 5. ENANTIOMERIC
KINETIC RESOLUTION IN SCC02 99 5.1. EXPERIMENTAL SECTION 99 5.1.1.
MATERIALS 99 5.1.2. APPARATES AND METHOD 100 5.1.2.1. BATCH REACTION
APPARATES 100 5.1.2.2. CONTINUOUS REACTION APPARATES 103 5.2. RESULTS -
BATCH REACTION 105 5.2.1. VINYL DECANOATE 105 5.2.2. VINYL LAURATE 107
5.2.3. VINYL STEARATE 108 5.2.4. METHYL ESTERS 111 5.2.5. ENZYME AMOUNT
INFLUENCE 113 VIII 5.3. RESULTS - CONTINUOUS REACTION 115 5.4. SUMMARY
CHAPTER 5 118 6. (R,S)-1-PHENYLETHANOL / (R,S)-1-PHENYL-ETHYL LAURATE
SEPARATION 119 6.1. MATERIALS 119 6.2. RESULTS 119 6.3.MODELING 128 6.4.
SUMMARY CHAPTER 6 131 7. CONTINUOUS KINETIC RESOLUTION AND SEPARATION OF
(R,S)-1 -PHENYLETHANOL 133 7.1. MATERIALS 134 7.2. EXPERIMENTAL
APPARATES 134 7.3.EXPERIMENTALMETHOD 138 7.4. RESULTS 139 7.5. SUMMARY
CHAPTER 7 144 8. DISCUSSION 145 REFERENCES 149 APPENDIX A 159 GC
CALIBRATION CURVES 159 CURRICULUM VITAE 164 IX |
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| author | Almeida Paiva, Alexandre Babo de 1978- |
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| dewey-full | 547.1223 543 |
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| dewey-ones | 547 - Organic chemistry 543 - Analytical chemistry |
| dewey-raw | 547.1223 543 |
| dewey-search | 547.1223 543 |
| dewey-sort | 3547.1223 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| discipline_str_mv | Chemie / Pharmazie |
| format | Thesis Book |
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| spelling | Almeida Paiva, Alexandre Babo de 1978- Verfasser (DE-588)134290186 aut Biocatalytic separation of isomers using supercritical fluids von Alexandre Babo de Almeida Paiva 2008 165 S. Ill., graph. Darst. 30 cm txt rdacontent n rdamedia nc rdacarrier Hamburg, Techn. Univ., Diss., 2008 Enantiomere Enzymkatalyse Trennverfahren Überkritischer Zustand (DE-588)4113937-9 Hochschulschrift gnd-content GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016728490&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Almeida Paiva, Alexandre Babo de 1978- Biocatalytic separation of isomers using supercritical fluids Enantiomere Enzymkatalyse Trennverfahren Überkritischer Zustand |
| subject_GND | (DE-588)4113937-9 |
| title | Biocatalytic separation of isomers using supercritical fluids |
| title_auth | Biocatalytic separation of isomers using supercritical fluids |
| title_exact_search | Biocatalytic separation of isomers using supercritical fluids |
| title_exact_search_txtP | Biocatalytic separation of isomers using supercritical fluids |
| title_full | Biocatalytic separation of isomers using supercritical fluids von Alexandre Babo de Almeida Paiva |
| title_fullStr | Biocatalytic separation of isomers using supercritical fluids von Alexandre Babo de Almeida Paiva |
| title_full_unstemmed | Biocatalytic separation of isomers using supercritical fluids von Alexandre Babo de Almeida Paiva |
| title_short | Biocatalytic separation of isomers using supercritical fluids |
| title_sort | biocatalytic separation of isomers using supercritical fluids |
| topic | Enantiomere Enzymkatalyse Trennverfahren Überkritischer Zustand |
| topic_facet | Enantiomere Enzymkatalyse Trennverfahren Überkritischer Zustand Hochschulschrift |
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