Electrochemical surface modification: thin films, functionalization and characterization
Saved in:
| Format: | Book |
|---|---|
| Language: | English |
| Published: |
Weinheim [u.a.]
WILEY-VCH
2008
|
| Series: | Advances in electrochemical science and engineering
10 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Einzelaufnahme eines Zeitschr.-Bd. |
| Physical Description: | XIV, 346 S. Ill., graph. Darst. |
| ISBN: | 9783527314195 3527314199 |
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MARC
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| 245 | 1 | 0 | |a Electrochemical surface modification |b thin films, functionalization and characterization |c ed. by Richard C. Alkire ... |
| 264 | 1 | |a Weinheim [u.a.] |b WILEY-VCH |c 2008 | |
| 300 | |a XIV, 346 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 1 | |a Advances in electrochemical science and engineering |v 10 | |
| 500 | |a Einzelaufnahme eines Zeitschr.-Bd. | ||
| 650 | 7 | |a Chimie des surfaces |2 ram | |
| 650 | 7 | |a Surfaces (physique) |2 ram | |
| 650 | 7 | |a Électrochimie |2 ram | |
| 650 | 4 | |a Electrochemistry | |
| 650 | 4 | |a Surface chemistry | |
| 650 | 4 | |a Surfaces (Physics) | |
| 650 | 0 | 7 | |a Elektrochemie |0 (DE-588)4014241-3 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Oberflächenchemie |0 (DE-588)4126166-5 |2 gnd |9 rswk-swf |
| 655 | 7 | |0 (DE-588)4143413-4 |a Aufsatzsammlung |2 gnd-content | |
| 689 | 0 | 0 | |a Elektrochemie |0 (DE-588)4014241-3 |D s |
| 689 | 0 | 1 | |a Oberflächenchemie |0 (DE-588)4126166-5 |D s |
| 689 | 0 | |5 DE-604 | |
| 700 | 1 | |a Alkire, Richard C. |d 1941- |e Sonstige |0 (DE-588)136277446 |4 oth | |
| 830 | 0 | |a Advances in electrochemical science and engineering |v 10 |w (DE-604)BV004176465 |9 10 | |
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| 999 | |a oai:aleph.bib-bvb.de:BVB01-016696607 | ||
Record in the Search Index
| _version_ | 1804137956511842304 |
|---|---|
| adam_text | ********* ** ***** PREFACE I X * V O L U M E PREFACE X I * LIST
O F C O N T R I B U T O R S X I I I * V A L V E M E T A L ,
SI AND C E R A M I C O X I D E S AS D I E L E C T R I C F I
L M S F O R PASSIVE* AND ACTIVE ELECTRONIC DEVICES 1 *
ALEXANDER MICHAELIS 1.1* I N T R O D U C T I O N 1 * 1.1.1* E X P
E R I M E N T A L A P P R O A C H E S 2 * 1.2* F U N D A M E N
T A L S A N D E X P E R I M E N T A L DETAILS 5 * 1.2.1* E L
E C T R O C H E M I C A L OXIDE LAYER F O R M A T I O N O N
VALVE METALS 5 * 1.2.2* T H E C( U) C U R V E O F A VALVE
METAL ELECTRODE 7 * 1.2.3* A P P L I C A T I O N O F LASERS I N
E L E C T R O C H E M I S T R Y 8 * 1.2.3.1* T H E R M A L
EFFECTS 9 * 1 . 2 . 4 * E L E C T R O C H E M I C A L P H O T O
C U R R E N T M E A S U R E M E N T S ( O P T I C A L J E L E C T
R I C A L * M E T H O D CLASS), I N T R O D U C T I O N O F
A NEW MODEL 10* 1.2.4.1* P H O T O C U R R E N T MODEL FOR U L T R
A - T H I N , A M O R P H O U S F I L M S W I T H TIO Z *
AS A N EXAMPLE 11* 1.3* VALVE METAL S Y S T E M S 15* 1.3.1* T I J
T I O Z S Y S T E M 15* 1.3.1.1* E X P E R I M E N T A L
DETAILS 15* 1 . 3 . 1 . 2 * D E T E R M I N A T I O N O F T I S
U B S T R A T E G R A I N O R I E N T A T I O N BY SAME 1 7 *
1 . 3 . 1 . 3 * P H O T O C U R R E N T S P E C T R A A N D
I P H ( U) M E A S U R E M E N T S O N SINGLE* T I J T I O Z
G R A I N S 18* 1 . 3 . 1 . 4 * M I C R O S C O P I C M O D
I F I C A T I O N O F T H E TIO Z F I L M S BY M E A N S
O F LASER* S C A N N I N G 19* 1 . 3 . 1 . 5 * C H A R A C T E
R I Z A T I O N O F T H E MODIFIED TIO Z F I L M S 21* 1 . 3
. 1 . 6 * P H O T O R E S I S T M I C R O E L E C T R O C H E M I
S T R Y ( N A N O L I T E R D R O P L E T M E T H O D ) 25*
1 . 3 . 1 . 7 * A P P L I C A T I O N S O F P H O T O R E S I S
T M I C R O E L E C T R O D E S 28* 1 . 3 . 1 . 8 * S U M M A R
Y A N D C O N C L U S I O N S FOR T H E T I J T I O Z S Y
S T E M 36* ADVANEES IN ELEETRAEHEMICAL SEIENEE UND ENGINEERING, VAL.
10. EDITED BY R I C H A R D C. A L K I R E , D I E T E R M.
KALB, JACEK L I P K O W S K I A N D P H I L I P N. ROSS C O P Y
R I G H T Z008 WILEY*VCH VERLAG G M B H & CO. KGAA, W E I N H
E I M ISBN: 9 7 8 - 3 - 5 Z 7 - 3 1 4 1 9 * 5 2 VI I CONTENTS 1
. 3 . 2 1 . 3 . 2 . 1 1 . 3 . 2 . 2 1 . 3 . 3 1 . 3 . 3 . 1
1 . 3 . 3 . 2 1 . 3 . 3 . 3 1 . 3 . 4 1 . 3 . 4 . 1 1 . 3
. 4 . 2 1 . 3 . 4 . 3 1 . 3 . 4 . 4 1 . 3 . 4 . 5 1 . 4 1
. 4 . 1 1 . 4 . 1 . 1 1 . 4 . 1 . 2 1 . 4 . 1 . 3 1 . 4 . 2
1 . 4 . 2 . 1 1 . 4 . 2 . 2 1.5 2.1 2.2 2.3 2 . 3 . 1 2 . 3
. 2 2 . 3 . 3 2 . 3 . 4 2 . 3 . 5 2 . 4 2.4.1 2 . 4 . 2
2 . 4 . 2 . 1 2 . 4 . 2 . 2 2 . 4 . 2 . 3 2 . 4 . 3 2 . 4
. 4 2 . 4 . 5 Z R / Z R 0 2 A N D H F / H F 0 2 S Y S T E
M S 3 7 * Z R / Z R 0 2 3 7 * H F / H F 0 2 4 6 * S Y
S T E M S : N B / N B 2 0 S T A / T A 2 0 S A N D A L /
A I 2 0 3 4 8 * N B / N B 2 0 S S Y S T E M 4 9 * A
L / A L 2 0 3 S Y S T E M 53* T A / T A 2 0 S S Y S T E M
5 4 * A P P L I C A T I O N O F V A L V E M E T A L S I N
E L E C T R O L Y T I C C A P A C I T O R M A N U F A C T U R I N
G 5 7 * C A P A C I T O R F U N D A M E N T A L S 5 7 * C
A P A C I T O R D E V I C E TYPES A N D P R O D U C T I O N
O F T A C A P A C I T O R S 62* C U R R E N T D E V E L O P M E
N T T R E N D S FOR TA C A P A C I T O R S A N D R E S E A R
C H * I S S U E S I N V O L V E D 65* E F F E C T O F O X
Y G E N C O N T E N T A N D S I N T E R C O N D I T I O N S
O N D I S L O C A T I O N * F O R M A T I O N 6 7 * T H E
R M A L R U N A W A Y 7 0 * S I / S I 0 2 S Y S T E M 74*
A P P L I C A T I O N O F T H E S I / S I 0 2 S Y S T E M
7 7 * S I / S I 0 2 I N M O S F E T S 7 7 * S I / S I 0 2
I N D R A M S 80* DRAM S T O R A G E C A P A C I T O R (
D E E P T R E N C H ) 8 2 * A L T E R N A T I V E D I E L E
C T R I C M A T E R I A L S 9 0 * T A 2 0 S 92* T I / T I 0
2 95* S U M M A R Y A N D C O N C L U S I O N S 96* R E F E
R E N C E S 99* SUPERCONFORMAL FILM GROWTH 107* THOMAS P. MOFFAT,
OANIEL WHEELER, AND OANIEL JOSE/L I N T R O D U C T I O N 1 0 7 *
D E S T A B I L I Z I N G I N F L U E N C E S 108* S T A B I L I Z
A T I O N A N D S M O O T H I N G M E C H A N I S M S 1 1 0
* G E O M E T R I E L E V E L I N G 1 1 0 * I N H I B I T O
R - B A S E D L E V E L I N G 1 1 0 * B R I G H T E N I N G
BY G R A I N R E F I N E M E N T 111* C A T A L Y S T - D E R I V
E D B R I G H T E N I N G 1 1 2 * S T A B I L I Z A T I O N
A C R O S S L E N G T H S C A L E S 1 1 2 * A D D I T I V E
P R O C E S S E S 113* A D S O R P T I O N K I N E T I C S 1
1 7 * S U R F A C E S E G R E G A T I O N V E R S U S C O N
S U M P T I O N P R O C E S S E S 1 1 7 * A D S O R B A T E S
S E G R E G A T E D O N T O G R O W I N G S U R F A C E 1
1 8 * A D S O R B A T E S I N C O R P O R A T E D I N T O G
R O W I N G D E P O S I T 119* D E A C T I V A T I O N O F A
D S O R B A T E 121* A D S O R B A T E E V O L U T I O N 121* I
M P A C T O N M I C R O S T R U C T U R E 122* Q U A N T I F Y
I N G A D S O R B A T E I N H I B I T I O N O F METAL D E P
O S I T I O N 1 2 5 * C O N T E N T S I VII* 2.4.6 2.4.7 2.4.8
2.4.9 2.4.10 2.4.10.1 2.4.10.2 2.4.10.3 2.5 2.5.1 2.5.2 2.5.3 2.5.3.1
2.5.3.2 2.5.4 2.5.4.1 2.5.4.2 2.5.5 2.6 3* 3.1 3.1.1 3.1.2 3.1.3 3.1.3.1
3.1.3.2 3.2 3.2.1 3.2.1.1 3.2.1.2 3.2.1.3 3.2.2 3.2.2.1 3.3 3.3.1 3.3.2
3.3.2.1 CO-ADSORPTION EFFECTS 130* ACTIVATION OF BLOCKED ELECTRODES BY
COMPETITIVE ADSORPTION* QUANTIFYING THE EFFECTS OF COMPETITIVE
ADSORPTION ON METAL* CATALYSIS OF METAL DEPOSITION 134* OF A CATALYST
135* CATALYST FUNCTION AND CONSUMPTION 138* DEPOSITION 141* SITE
DEPENDENCE OF CHARGE TRANSFER KINETICS 142* CATALYST EVOLUTION 143* SPS
ADSORPTION FROM THE ELECTROLYTE 143* INTERFACE MOTION AND MORPHOLOGICAL
EVOLUTION 146* SHAPE CHANGE SIMULATIONS 146* GEOMETRIC LEVELING 150*
INHIBITOR-BASED LEVELING 153* FEAHLFE FILLING 153* STABILITY ANALYSIS
160* CATALYST-DERIVED BRIGHTENING 161* FEATURE FILLING 161* STABILITY
ANALYSIS 173* BRIDGING THE LENGTH SCALES 176* CONCLUSIONS AND OUTLOOK
179* REFERENCES 179* TRANSITION METAL MACROCYCLES AS ELECTROCATALYSTS
FOR DIOXYGEN* REDUCTION 191* DANIEL A. SCHERSON, ATTILA PALENCS6R, YURIY
TOLMACHEV, A N D I O N E I S T E F A N INTRODUCTION 191* INTRINSIC
PROPERTIES OF SOLUTION PHASE TRANSITION METAL* MACROCYCLIC-MEDIATED
REDUCTION OF DIOXYGEN IN AQUEOUS* ELECTROCATALYSIS 192* DIOXYGEN
REDUCTION IN AQUEOUS ELECTROLYTES: GENERAL ASPECTS 193* TRANSITION METAL
MACROCYCLES 199* GENERAL CHARACTERISTICS 199* ELECTROCATALYTIC
PROPERTIES TOWARD OXYGEN REDUCTION 201* HOMOGENEOUS ELECTROCATALYSIS 2 0
4 * MACROCYCLES 2 0 4 * FORMAL REDOX POTENTIALS AND DIFFUSION
COEFFICIENTS 2 0 4 * MOLECULAR SPECIATION 209* RATES OF HETEROGENEOUS
ELECTRON TRANSFER REACTIONS 211* ELECTROLYTES 212* MODEL SYSTEMS 212*
HETEROGENEOUS ELECTROCATALYSIS 219* ADSORPTION ISOTHERRNS 220*
CHEMICALLY MODIFIED ELECTRODES 221* PREPARATION AND ELECTROCHEMICAL
CHARACTERIZATION 221* VIII I CONTENTS 3.3.2.2* IN SITU SPECTROSCOPIC
CHARACTERIZATION 226* 3.3.3* REDOX ACTIVE CHEMICALLY MODIFIED ELECTRODES
232* 3.3.3.1* THERMODYNAMIC ASPECTS 232* 3.3.3.2* REDOX SPECIATION 235*
3.3.3.3* REDOX DYNAMICS 238* 3.3.4* ELECTROCATALYTIC ASPECTS OF DIOXYGEN
REDUCTION 241* 3.3.4.1* THEORETICAL CONSIDERATIONS 241* 3.3.4.2* MODEL
SYSTEMS 244* 3.4* THERMAL ACTIVATION OF TRANSITION METAL MACROCYCLES
269* 3.4.1* BRIEF INTRODUCTION 269* 3.4.2* ELECTROCHEMICAL
CHARACTERIZATION 269* 3.4.2.1* CYCLIC VOLTAMMETRY 270* 3.4.2.2* OXYGEN
REDUCTION POLARIZATION CURVES 271* 3.4.3* SPECTROSCOPIC AND STRUCTURAL
CHARACTERIZATION 273* 3.4.3.1* PYROLYSIS-MASS SPECTROMETRY 273* 3.4.3.2*
MOSSBAUER EFFECT SPECTROSCOPY 277* 3.4.3.3* X-RAY ABSORPTION FINE
STRUCTURE 278* 3.4.3.4* X-RAY PHOTOELECTRON SPECTROSCOPY 281* 3.4.4* IN
SITU AND QUASI IN SITU SPECTROSCOPIC CHARACTERIZATION 281* 3.4.5*
CONCLUDING REMARKS 283* REFERENCES 285* 4* MULTISCALE MODELING AND
DESIGN OFELEETROCHEMICAL SYSTEMS 289* RICHARD D. BRAATZ, EDMUND G.
SEEBAUER, AND RICHARD C. ALKIRE* 4.1* INTRODUCTION 289* 4.2* BACKGROUND
AND MOTIVATION 291* 4.2.1* MULTISCALE SIMULATION 291* 4.2.2*
ELECTROCHEMICAL SYSTEMS 293* 4.2.3* MIEROELECTRONIC APPLICATIONS 295*
4.2.4* NANOSCALE SCIENCE AND TECHNOLOGY 296* 4.2.5* OTHER
ELECTROCHEMICAL APPLICATIONS 297* 4.3* TREND TOWARD ATOMISTIC/MOLECULAR
SIMULATION 298* 4.3.1* INTEGRATED CIRCUIT EXAMPLE 298* 4.3.2* CONTINUUM
METHODS 300* 4.3.3* MOLECULAR SIMULATION METHODS 300* 4.3.4*
COARSE-GRAINED SIMULATION METHODS 303* 4.4* MULTISCALE SIMULATION 304*
4.5* CHALLENGES AND REQUIREMENTS OF MULTISCALE MODELING 310* 4.6*
ADDRESSING THE CHALLENGES IN MULTISCALE MODELING 311* 4.7* DESIGN BASED
ON MULTISCALE MODELS 315* 4.8* CONCLUDING REMARKS 322* REFERENCES 324*
INDEX 335*
|
| adam_txt |
********* ** ***** PREFACE I X * V O L U M E PREFACE X I * LIST
O F C O N T R I B U T O R S X I I I * V A L V E M E T A L ,
SI AND C E R A M I C O X I D E S AS D I E L E C T R I C F I
L M S F O R PASSIVE* AND ACTIVE ELECTRONIC DEVICES 1 *
ALEXANDER MICHAELIS 1.1* I N T R O D U C T I O N 1 * 1.1.1* E X P
E R I M E N T A L A P P R O A C H E S 2 * 1.2* F U N D A M E N
T A L S A N D E X P E R I M E N T A L DETAILS 5 * 1.2.1* E L
E C T R O C H E M I C A L OXIDE LAYER F O R M A T I O N O N
VALVE METALS 5 * 1.2.2* T H E C( U) C U R V E O F A VALVE
METAL ELECTRODE 7 * 1.2.3* A P P L I C A T I O N O F LASERS I N
E L E C T R O C H E M I S T R Y 8 * 1.2.3.1* T H E R M A L
EFFECTS 9 * 1 . 2 . 4 * E L E C T R O C H E M I C A L P H O T O
C U R R E N T M E A S U R E M E N T S ( O P T I C A L J E L E C T
R I C A L * M E T H O D CLASS), I N T R O D U C T I O N O F
A NEW MODEL 10* 1.2.4.1* P H O T O C U R R E N T MODEL FOR U L T R
A - T H I N , A M O R P H O U S F I L M S W I T H TIO Z *
AS A N EXAMPLE 11* 1.3* VALVE METAL S Y S T E M S 15* 1.3.1* T I J
T I O Z S Y S T E M 15* 1.3.1.1* E X P E R I M E N T A L
DETAILS 15* 1 . 3 . 1 . 2 * D E T E R M I N A T I O N O F T I S
U B S T R A T E G R A I N O R I E N T A T I O N BY SAME 1 7 *
1 . 3 . 1 . 3 * P H O T O C U R R E N T S P E C T R A A N D
I P H ( U) M E A S U R E M E N T S O N SINGLE* T I J T I O Z
G R A I N S 18* 1 . 3 . 1 . 4 * M I C R O S C O P I C M O D
I F I C A T I O N O F T H E TIO Z F I L M S BY M E A N S
O F LASER* S C A N N I N G 19* 1 . 3 . 1 . 5 * C H A R A C T E
R I Z A T I O N O F T H E MODIFIED TIO Z F I L M S 21* 1 . 3
. 1 . 6 * P H O T O R E S I S T M I C R O E L E C T R O C H E M I
S T R Y ( N A N O L I T E R D R O P L E T M E T H O D ) 25*
1 . 3 . 1 . 7 * A P P L I C A T I O N S O F P H O T O R E S I S
T M I C R O E L E C T R O D E S 28* 1 . 3 . 1 . 8 * S U M M A R
Y A N D C O N C L U S I O N S FOR T H E T I J T I O Z S Y
S T E M 36* ADVANEES IN ELEETRAEHEMICAL SEIENEE UND ENGINEERING, VAL.
10. EDITED BY R I C H A R D C. A L K I R E , D I E T E R M.
KALB, JACEK L I P K O W S K I A N D P H I L I P N. ROSS C O P Y
R I G H T Z008 WILEY*VCH VERLAG G M B H & CO. KGAA, W E I N H
E I M ISBN: 9 7 8 - 3 - 5 Z 7 - 3 1 4 1 9 * 5 2 VI I CONTENTS 1
. 3 . 2 1 . 3 . 2 . 1 1 . 3 . 2 . 2 1 . 3 . 3 1 . 3 . 3 . 1
1 . 3 . 3 . 2 1 . 3 . 3 . 3 1 . 3 . 4 1 . 3 . 4 . 1 1 . 3
. 4 . 2 1 . 3 . 4 . 3 1 . 3 . 4 . 4 1 . 3 . 4 . 5 1 . 4 1
. 4 . 1 1 . 4 . 1 . 1 1 . 4 . 1 . 2 1 . 4 . 1 . 3 1 . 4 . 2
1 . 4 . 2 . 1 1 . 4 . 2 . 2 1.5 2.1 2.2 2.3 2 . 3 . 1 2 . 3
. 2 2 . 3 . 3 2 . 3 . 4 2 . 3 . 5 2 . 4 2.4.1 2 . 4 . 2
2 . 4 . 2 . 1 2 . 4 . 2 . 2 2 . 4 . 2 . 3 2 . 4 . 3 2 . 4
. 4 2 . 4 . 5 Z R / Z R 0 2 A N D H F / H F 0 2 S Y S T E
M S 3 7 * Z R / Z R 0 2 3 7 * H F / H F 0 2 4 6 * S Y
S T E M S : N B / N B 2 0 S ' T A / T A 2 0 S A N D A L /
A I 2 0 3 4 8 * N B / N B 2 0 S S Y S T E M 4 9 * A
L / A L 2 0 3 S Y S T E M 53* T A / T A 2 0 S S Y S T E M
5 4 * A P P L I C A T I O N O F V A L V E M E T A L S I N
E L E C T R O L Y T I C C A P A C I T O R M A N U F A C T U R I N
G 5 7 * C A P A C I T O R F U N D A M E N T A L S 5 7 * C
A P A C I T O R D E V I C E TYPES A N D P R O D U C T I O N
O F T A C A P A C I T O R S 62* C U R R E N T D E V E L O P M E
N T T R E N D S FOR TA C A P A C I T O R S A N D R E S E A R
C H * I S S U E S I N V O L V E D 65* E F F E C T O F O X
Y G E N C O N T E N T A N D S I N T E R C O N D I T I O N S
O N D I S L O C A T I O N * F O R M A T I O N 6 7 * T H E
R M A L R U N A W A Y 7 0 * S I / S I 0 2 S Y S T E M 74*
A P P L I C A T I O N O F T H E S I / S I 0 2 S Y S T E M
7 7 * S I / S I 0 2 I N M O S F E T S 7 7 * S I / S I 0 2
I N D R A M S 80* DRAM S T O R A G E C A P A C I T O R (
D E E P T R E N C H ) 8 2 * A L T E R N A T I V E D I E L E
C T R I C M A T E R I A L S 9 0 * T A 2 0 S 92* T I / T I 0
2 95* S U M M A R Y A N D C O N C L U S I O N S 96* R E F E
R E N C E S 99* SUPERCONFORMAL FILM GROWTH 107* THOMAS P. MOFFAT,
OANIEL WHEELER, AND OANIEL JOSE/L I N T R O D U C T I O N 1 0 7 *
D E S T A B I L I Z I N G I N F L U E N C E S 108* S T A B I L I Z
A T I O N A N D S M O O T H I N G M E C H A N I S M S 1 1 0
* G E O M E T R I E L E V E L I N G 1 1 0 * I N H I B I T O
R - B A S E D L E V E L I N G 1 1 0 * B R I G H T E N I N G
BY G R A I N R E F I N E M E N T 111* C A T A L Y S T - D E R I V
E D B R I G H T E N I N G 1 1 2 * S T A B I L I Z A T I O N
A C R O S S L E N G T H S C A L E S 1 1 2 * A D D I T I V E
P R O C E S S E S 113* A D S O R P T I O N K I N E T I C S 1
1 7 * S U R F A C E S E G R E G A T I O N V E R S U S C O N
S U M P T I O N P R O C E S S E S 1 1 7 * A D S O R B A T E S
S E G R E G A T E D O N T O G R O W I N G S U R F A C E 1
1 8 * A D S O R B A T E S I N C O R P O R A T E D I N T O G
R O W I N G D E P O S I T 119* D E A C T I V A T I O N O F A
D S O R B A T E 121* A D S O R B A T E E V O L U T I O N 121* I
M P A C T O N M I C R O S T R U C T U R E 122* Q U A N T I F Y
I N G A D S O R B A T E I N H I B I T I O N O F METAL D E P
O S I T I O N 1 2 5 * C O N T E N T S I VII* 2.4.6 2.4.7 2.4.8
2.4.9 2.4.10 2.4.10.1 2.4.10.2 2.4.10.3 2.5 2.5.1 2.5.2 2.5.3 2.5.3.1
2.5.3.2 2.5.4 2.5.4.1 2.5.4.2 2.5.5 2.6 3* 3.1 3.1.1 3.1.2 3.1.3 3.1.3.1
3.1.3.2 3.2 3.2.1 3.2.1.1 3.2.1.2 3.2.1.3 3.2.2 3.2.2.1 3.3 3.3.1 3.3.2
3.3.2.1 CO-ADSORPTION EFFECTS 130* ACTIVATION OF BLOCKED ELECTRODES BY
COMPETITIVE ADSORPTION* QUANTIFYING THE EFFECTS OF COMPETITIVE
ADSORPTION ON METAL* CATALYSIS OF METAL DEPOSITION 134* OF A CATALYST
135* CATALYST FUNCTION AND CONSUMPTION 138* DEPOSITION 141* SITE
DEPENDENCE OF CHARGE TRANSFER KINETICS 142* CATALYST EVOLUTION 143* SPS
ADSORPTION FROM THE ELECTROLYTE 143* INTERFACE MOTION AND MORPHOLOGICAL
EVOLUTION 146* SHAPE CHANGE SIMULATIONS 146* GEOMETRIC LEVELING 150*
INHIBITOR-BASED LEVELING 153* FEAHLFE FILLING 153* STABILITY ANALYSIS
160* CATALYST-DERIVED BRIGHTENING 161* FEATURE FILLING 161* STABILITY
ANALYSIS 173* BRIDGING THE LENGTH SCALES 176* CONCLUSIONS AND OUTLOOK
179* REFERENCES 179* TRANSITION METAL MACROCYCLES AS ELECTROCATALYSTS
FOR DIOXYGEN* REDUCTION 191* DANIEL A. SCHERSON, ATTILA PALENCS6R, YURIY
TOLMACHEV, A N D I O N E I S T E F A N INTRODUCTION 191* INTRINSIC
PROPERTIES OF SOLUTION PHASE TRANSITION METAL* MACROCYCLIC-MEDIATED
REDUCTION OF DIOXYGEN IN AQUEOUS* ELECTROCATALYSIS 192* DIOXYGEN
REDUCTION IN AQUEOUS ELECTROLYTES: GENERAL ASPECTS 193* TRANSITION METAL
MACROCYCLES 199* GENERAL CHARACTERISTICS 199* ELECTROCATALYTIC
PROPERTIES TOWARD OXYGEN REDUCTION 201* HOMOGENEOUS ELECTROCATALYSIS 2 0
4 * MACROCYCLES 2 0 4 * FORMAL REDOX POTENTIALS AND DIFFUSION
COEFFICIENTS 2 0 4 * MOLECULAR SPECIATION 209* RATES OF HETEROGENEOUS
ELECTRON TRANSFER REACTIONS 211* ELECTROLYTES 212* MODEL SYSTEMS 212*
HETEROGENEOUS ELECTROCATALYSIS 219* ADSORPTION ISOTHERRNS 220*
CHEMICALLY MODIFIED ELECTRODES 221* PREPARATION AND ELECTROCHEMICAL
CHARACTERIZATION 221* VIII I CONTENTS 3.3.2.2* IN SITU SPECTROSCOPIC
CHARACTERIZATION 226* 3.3.3* REDOX ACTIVE CHEMICALLY MODIFIED ELECTRODES
232* 3.3.3.1* THERMODYNAMIC ASPECTS 232* 3.3.3.2* REDOX SPECIATION 235*
3.3.3.3* REDOX DYNAMICS 238* 3.3.4* ELECTROCATALYTIC ASPECTS OF DIOXYGEN
REDUCTION 241* 3.3.4.1* THEORETICAL CONSIDERATIONS 241* 3.3.4.2* MODEL
SYSTEMS 244* 3.4* THERMAL ACTIVATION OF TRANSITION METAL MACROCYCLES
269* 3.4.1* BRIEF INTRODUCTION 269* 3.4.2* ELECTROCHEMICAL
CHARACTERIZATION 269* 3.4.2.1* CYCLIC VOLTAMMETRY 270* 3.4.2.2* OXYGEN
REDUCTION POLARIZATION CURVES 271* 3.4.3* SPECTROSCOPIC AND STRUCTURAL
CHARACTERIZATION 273* 3.4.3.1* PYROLYSIS-MASS SPECTROMETRY 273* 3.4.3.2*
MOSSBAUER EFFECT SPECTROSCOPY 277* 3.4.3.3* X-RAY ABSORPTION FINE
STRUCTURE 278* 3.4.3.4* X-RAY PHOTOELECTRON SPECTROSCOPY 281* 3.4.4* IN
SITU AND QUASI IN SITU SPECTROSCOPIC CHARACTERIZATION 281* 3.4.5*
CONCLUDING REMARKS 283* REFERENCES 285* 4* MULTISCALE MODELING AND
DESIGN OFELEETROCHEMICAL SYSTEMS 289* RICHARD D. BRAATZ, EDMUND G.
SEEBAUER, AND RICHARD C. ALKIRE* 4.1* INTRODUCTION 289* 4.2* BACKGROUND
AND MOTIVATION 291* 4.2.1* MULTISCALE SIMULATION 291* 4.2.2*
ELECTROCHEMICAL SYSTEMS 293* 4.2.3* MIEROELECTRONIC APPLICATIONS 295*
4.2.4* NANOSCALE SCIENCE AND TECHNOLOGY 296* 4.2.5* OTHER
ELECTROCHEMICAL APPLICATIONS 297* 4.3* TREND TOWARD ATOMISTIC/MOLECULAR
SIMULATION 298* 4.3.1* INTEGRATED CIRCUIT EXAMPLE 298* 4.3.2* CONTINUUM
METHODS 300* 4.3.3* MOLECULAR SIMULATION METHODS 300* 4.3.4*
COARSE-GRAINED SIMULATION METHODS 303* 4.4* MULTISCALE SIMULATION 304*
4.5* CHALLENGES AND REQUIREMENTS OF MULTISCALE MODELING 310* 4.6*
ADDRESSING THE CHALLENGES IN MULTISCALE MODELING 311* 4.7* DESIGN BASED
ON MULTISCALE MODELS 315* 4.8* CONCLUDING REMARKS 322* REFERENCES 324*
INDEX 335* |
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| genre_facet | Aufsatzsammlung |
| id | DE-604.BV035027532 |
| illustrated | Illustrated |
| index_date | 2024-07-02T21:48:35Z |
| indexdate | 2024-07-09T21:20:32Z |
| institution | BVB |
| isbn | 9783527314195 3527314199 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-016696607 |
| oclc_num | 216662859 |
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| owner | DE-29T DE-355 DE-BY-UBR DE-92 DE-83 DE-703 |
| owner_facet | DE-29T DE-355 DE-BY-UBR DE-92 DE-83 DE-703 |
| physical | XIV, 346 S. Ill., graph. Darst. |
| publishDate | 2008 |
| publishDateSearch | 2008 |
| publishDateSort | 2008 |
| publisher | WILEY-VCH |
| record_format | marc |
| series | Advances in electrochemical science and engineering |
| series2 | Advances in electrochemical science and engineering |
| spelling | Electrochemical surface modification thin films, functionalization and characterization ed. by Richard C. Alkire ... Weinheim [u.a.] WILEY-VCH 2008 XIV, 346 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Advances in electrochemical science and engineering 10 Einzelaufnahme eines Zeitschr.-Bd. Chimie des surfaces ram Surfaces (physique) ram Électrochimie ram Electrochemistry Surface chemistry Surfaces (Physics) Elektrochemie (DE-588)4014241-3 gnd rswk-swf Oberflächenchemie (DE-588)4126166-5 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Elektrochemie (DE-588)4014241-3 s Oberflächenchemie (DE-588)4126166-5 s DE-604 Alkire, Richard C. 1941- Sonstige (DE-588)136277446 oth Advances in electrochemical science and engineering 10 (DE-604)BV004176465 10 OEBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016696607&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Electrochemical surface modification thin films, functionalization and characterization Advances in electrochemical science and engineering Chimie des surfaces ram Surfaces (physique) ram Électrochimie ram Electrochemistry Surface chemistry Surfaces (Physics) Elektrochemie (DE-588)4014241-3 gnd Oberflächenchemie (DE-588)4126166-5 gnd |
| subject_GND | (DE-588)4014241-3 (DE-588)4126166-5 (DE-588)4143413-4 |
| title | Electrochemical surface modification thin films, functionalization and characterization |
| title_auth | Electrochemical surface modification thin films, functionalization and characterization |
| title_exact_search | Electrochemical surface modification thin films, functionalization and characterization |
| title_exact_search_txtP | Electrochemical surface modification thin films, functionalization and characterization |
| title_full | Electrochemical surface modification thin films, functionalization and characterization ed. by Richard C. Alkire ... |
| title_fullStr | Electrochemical surface modification thin films, functionalization and characterization ed. by Richard C. Alkire ... |
| title_full_unstemmed | Electrochemical surface modification thin films, functionalization and characterization ed. by Richard C. Alkire ... |
| title_short | Electrochemical surface modification |
| title_sort | electrochemical surface modification thin films functionalization and characterization |
| title_sub | thin films, functionalization and characterization |
| topic | Chimie des surfaces ram Surfaces (physique) ram Électrochimie ram Electrochemistry Surface chemistry Surfaces (Physics) Elektrochemie (DE-588)4014241-3 gnd Oberflächenchemie (DE-588)4126166-5 gnd |
| topic_facet | Chimie des surfaces Surfaces (physique) Électrochimie Electrochemistry Surface chemistry Surfaces (Physics) Elektrochemie Oberflächenchemie Aufsatzsammlung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016696607&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV004176465 |
| work_keys_str_mv | AT alkirerichardc electrochemicalsurfacemodificationthinfilmsfunctionalizationandcharacterization |