Surfactant science and technology:
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | German |
| Published: |
Weinheim [u.a.]
VCH
1988
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Literaturverz. S. 327 - 329 |
| Physical Description: | XIII, 351 S. Ill., graph. Darst. |
| ISBN: | 352726695X 0895733390 |
Staff View
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Record in the Search Index
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| adam_text | TABLE OF CONTENTS
CHAPTER ONE-SURFACTANT SCIENCE AND TECHNOLOGY
AN OVERVIEW
INTRODUCTION 1
A BRIEF HISTORY OF SURFACTANT SCIENCE AND TECHNOLOGY 3
SURFACES, INTERFACES, AND SURFACTANT STRUCTURES 6
THE NATURE OF INTERFACES 7
MOLECULES AT INTERFACES 10
THE SURFACTANT PERSONALITY 12
SURFACTANT BUILDING BLOCKS 13
THE ECONOMIC ROLE OF SURFACTANTS 15
MODERN SURFACTANT CONSUMPTION 17
SURFACTANTS IN THE ENVIRONMENT 19
A SURFACTANT GLOSSARY 22
THE SHAPE OF THINGS TO COME 26
CHAPTER TWO - THE ORGANIC CHEMISTRY OF SURFACTANTS
INTRODUCTION YY
V
27
THE MANY FACES OF DODECANE 28
THE CLASSIFICATION OF SURFACTANTS 31
SURFACTANT SOLUBILIZING GROUPS 32
COMMON SURFACTANT HYDROPHOBIC GROUPS 34
FATTY ACIDS 34
PARAFFINS 36
OLEFINS 36
ALKYLBENZENES 37
ALCOHOLS 38
ALKYLPHENOLS 39
POLYOXYPROPYLENES 39
FLUOROCARBONS 40
SILICONE SURFACTANTS 41
ANIONIC SURFACTANTS 42
SULFATE ESTERS 44
FATTY ALCOHOL SULFATES 45
SULFATED FATTY ACID CONDENSATION PRODUCTS 46
SULFATED ETHERS 47
SULFATED FATS AND OILS 48
SULFONIC ACID SALTS 49
ALIPHATIC SULFONATES 49
ALKYLARYLSULFONATES 51
A-SULFOCARBOXYLIC ACIDS AND THEIR DERIVATIVES 53
MISCELLANEOUS SULFO ESTER AND AMIDE SURFACTANTS 55
V
HTTP://D-NB.INFO/881063762
VI
CONTENTS
ALKYL GLYGERYL ETHER SULFONATES 58
CARBOXYLATE SOAPS AND DETERGENTS 59
LIGNINSULFONATES 60
PHOSPHORIC ACID ESTERS AND RELATED SURFACTANTS 61
CATIONIC SURFACTANTS 62
TEXTILES AND CLEANING APPLICATION 65
ANTIBACTERIAL APPLICATIONS 65
CORROSION PROTECTION 66
ORE FLOTATION 66
ASPHALT EMULSIONS 67
MISCELLANEOUS APPLICATIONS 67
NONIONIC SURFACTANTS 67
POLYOXYETHYLENE-BASED SURFACTANTS 68
DERIVATIVES OF POLYGLYCEROLS AND OTHER POLYOLS 69
BLOCK COPOLYMER NONIONIC SURFACTANTS 71
MISCELLANEOUS NONIONIC SURFACTANTS 73
AMPHOTERIC SURFACTANTS 74
IMIDAZOLINE DERIVATIVES 75
SURFACE ACTIVE BETAINES AND SULFOBETAINES 77
PHOSPHATIDES AND RELATED AMPHOTERIC SURFACTANTS 78
CHAPTER THREE - SURFACTANTS IN SOLUTION: MICELLIZATION AND
RELATED ASSOCIATION PHENOMENA
INTRODUCTION 81
SURFACTANT SOLUBILITY AND THE KRAFFT TEMPERATURE 82
THE PHASE SPECTRUM OF SURFACTANTS IN SOLUTION 84
THE HISTORY OF THE MICELLAR THEORY 90
MANIFESTATIONS OF MICELLE FORMATION 91
THERMODYNAMICS OF DILUTE SURFACTANT SOLUTIONS 95
CLASSICAL THEORIES OF MICELLE FORMATION 96
MOLECULAR GEOMETRY AND MICELLE FORMATION 101
EXPERIMENTAL OBSERVATIONS OF MICELLAR SYSTEMS 104
MICELLAR AGGREGATION NUMBERS 104
THE CRITICAL MICELLE CONCENTRATION 106
THE HYDROPHOBIC GROUP 107
THE HYDROPHILIC GROUP 118
COUNTERION EFFECTS ON MICELLIZATION 121
THE EFFECT OF ADDITIVES ON THE MICELLIZATION PROCESS 121
ELECTROLYTE EFFECTS ON MICELLE FORMATION 122
THE EFFECT OF PH 124
THE EFFECTS OF ADDED ORGANIC MATERIALS 126
THE EFFECT OF TEMPERATURE ON MICELLIZATION 128
MICELLE FORMATION IN MIXED SURFACTANT SYSTEMS 129
MICELLE FORMATION IN NONAQUEOUS MEDIA 132
VESICLES AND LIPID MEMBRANES 135
THE MICELLE AND BEYOND 136
CONTENTS VII
VESICLES 138
POLYMERIZED VESICLES AND LIPID BILAYERS 141
POLYMER/SURFACTANT INTERACTIONS 142
NONIONIC POLYMERS 145
IONIC PROTEINS AND PROTEINS 147
CHAPTER FOUR - SOLUBILIZATION, MICROEMULSIONS, AND MICELLAR
CATALYSIS
INTRODUCTION
SOLUBILIZATION IN SURFACTANT MICELLES
THE LOCUS OF SOLUBILIZATION IN MICELLES
SURFACTANT STRUCTURE AND THE SOLUBILIZATION PROCESS
SOLUBILIZATION AND THE NATURE OF THE ADDITIVE
THE EFFECT OF TEMPERATURE ON SOLUBILIZATION PHENOMENA
THE EFFECTS OF NONELECTROLYTE COSOLUTES
THE EFFECTS OF ADDED ELECTROLYTE
MISCELLANEOUS FACTORS AFFECTING SOLUBILIZATION
POLYMERS, SURFACTANTS, AND SOLUBILIZATION
MICROEMULSIONS
SURFACTANTS, COSURFACTANTS, AND MICROEMULSION FORMATION
MICELLAR CATALYSIS
MICELLAR CATALYSIS IN AQUEOUS SOLVENT
MICELLAR CATALYSIS IN NONAQUEOUS SOLVENTS
CHAPTER FIVE - SURFACE ACTIVITY AND THE LIQUID/VAPOR
INTERFACE
INTRODUCTION 183
INTERFACES AND THE ADSORPTION PHENOMENON 183
A THERMODYNAMIC PICTURE OF ADSORPTION 185
THE EFFECT OF SURFACE CURVATURE 190
THE SURFACE TENSION OF SOLUTIONS 191
SURFACTANTS AND THE REDUCTION OF SURFACE TENSION 193
EFFICIENCY, EFFECTIVENESS, AND SURFACTANT STRUCTURE 195
CHAPTER SIX - EMULSIONS
INTRODUCTION 209
THE LIQUID/LIQUID INTERFACE 210
GENERAL CONSIDERATIONS OF EMULSION STABILITY 212
THE LIFETIMES OF TYPICAL EMULSIONS 215
THEORIES OF EMULSION STABILITY 217
EMULSION TYPE AND THE NATURE OF THE SURFACTANT 220
SURFACE ACTIVITY AND EMULSION STABILITY 222
SOME MECHANISMS OF EMULSION STABILIZATION 223
MIXED SURFACTANT SYSTEMS AND INTERFACIAL COMPLEXES 228
LIQUID CRYSTALS AND EMULSION STABILITY 230
153
154
156
158
162
165
167
169
170
170
172
177
179
179
181
VIII
CONTENTS
SURFACTANT STRUCTURE AND EMULSION PERFORMANCE 234
THE HYDROPHILE-LIPOPHILE BALANCE (HLB) 235
THE EFFECTS OF ADDITIVES ON HLB 241
PHASE INVERSION TEMPERATURE (PIT) 242
APPLICATION OF HLB AND PIT IN EMULSION FORMULATION 243
MULTIPLE EMULSIONS 245
NOMENCLATURE FOR MULTIPLE EMULSIONS 246
PREPARATION AND STABILITY OF MULTIPLE EMULSIONS 247
PRIMARY EMULSION BREAKDOWN 249
THE SURFACTANTS AND PHASE COMPONENTS 250
CHAPTER SEVEN - FOAMS
INTRODUCTION 255
THE PHYSICAL BASIS FOR FOAM FORMATION 256
THE PHYSICAL ROLE OF THE SURFACTANT IN FOAMS 260
FOAM FORMATION AND SURFACTANT STRUCTURE 263
LIQUID CRYSTALS AND FOAM STABILITY 266
THE EFFECTS OF ADDITIVES ON SURFACTANT FOAMING PROPERTIES 267
FOAM INHIBITION 268
CHEMICAL STRUCTURES OF ANTIFOAMING AGENTS 270
A SUMMARY OF THE FOAMING AND ANTIFOAMING ACTIVITY OF
ADDITIVES 271
CHAPTER EIGHT - SURFACTANTS AT THE SOLID/LIQUID INTERFACE
INTRODUCTION 273
THE NATURE OF SOLID SURFACES 274
LIQUID VERSUS SOLID SURFACES 278
ADSORPTION AT THE SOLID/LIQUID INTERFACE 279
ADSORPTION ISOTHERMS 280
MECHANISMS OF SURFACTANT ADSORPTION 282
THE ELECTRICAL DOUBLE LAYER 286
THE MECHANICS OF SURFACTANT ADSORPTION 289
ADSORPTION AND THE NATURE OF THE ADSORBENT SURFACE 290
NONPOLAR, HYDROPHOBIC SURFACES 291
POLAR, UNCHARGED SURFACES 292
SURFACES HAVING DISCRETE ELECTRICAL CHARGES 292
SURFACTANT STRUCTURE AND ADSORPTION FROM SOLUTION 295
SURFACES POSSESSING STRONG CHARGE SITES 296
ADSORPTION BY UNCHARGED, POLAR SURFACES 300
SURFACTANTS AT NONPOLAR, HYDROPHOBIC SURFACES 300
THE EFFECT OF SURFACTANT ADSORPTION ON THE CHARACTER OF THE
SOLID SURFACE 301
WETTING AND RELATED PHENOMENA 303
SURFACTANT MANIPULATION OF THE WETTING PROCESS 307
SOME PRACTICAL ASPECTS OF WETTING CONTROL BY SURFACTANTS 311
CONTENTS
DETERGENCY AND SOIL REMOVAL 311
THE CLEANING PROCESS 311
SOIL TYPES 312
SOLID SOIL REMOVAL 314
LIQUID SOIL REMOVAL 315
REDEPOSITION 316
CORRELATIONS OF SURFACTANT STRUCTURE AND DETERGENCY 317
NONAQUEOUS CLEANING SOLUTIONS 320
ENHANCED OIL RECOVERY 321
SUSPENSIONS OF SOLIDS IN LIQUIDS 324
A FINAL COMMENT 325
BIBLIOGRAPHY 327
REFERENCES 331
INDEX
345
|
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| illustrated | Illustrated |
| indexdate | 2024-07-09T22:14:07Z |
| institution | BVB |
| isbn | 352726695X 0895733390 |
| language | German |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-019120227 |
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| physical | XIII, 351 S. Ill., graph. Darst. |
| publishDate | 1988 |
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| spelling | Myers, Drew Verfasser aut Surfactant science and technology Drew Myers Weinheim [u.a.] VCH 1988 XIII, 351 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Literaturverz. S. 327 - 329 Oberflächenchemie (DE-588)4126166-5 gnd rswk-swf Grenzflächenaktiver Stoff (DE-588)4158138-6 gnd rswk-swf Grenzflächenaktiver Stoff (DE-588)4158138-6 s DE-604 Oberflächenchemie (DE-588)4126166-5 s DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=019120227&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Myers, Drew Surfactant science and technology Oberflächenchemie (DE-588)4126166-5 gnd Grenzflächenaktiver Stoff (DE-588)4158138-6 gnd |
| subject_GND | (DE-588)4126166-5 (DE-588)4158138-6 |
| title | Surfactant science and technology |
| title_auth | Surfactant science and technology |
| title_exact_search | Surfactant science and technology |
| title_full | Surfactant science and technology Drew Myers |
| title_fullStr | Surfactant science and technology Drew Myers |
| title_full_unstemmed | Surfactant science and technology Drew Myers |
| title_short | Surfactant science and technology |
| title_sort | surfactant science and technology |
| topic | Oberflächenchemie (DE-588)4126166-5 gnd Grenzflächenaktiver Stoff (DE-588)4158138-6 gnd |
| topic_facet | Oberflächenchemie Grenzflächenaktiver Stoff |
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