Relaxation and thermodynamics in polymers: glass transition ; with 8 tables
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Berlin
Akademie-Verl.
1992
|
| Edition: | 1. ed. |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | 256 S. |
| ISBN: | 3055013921 |
Staff View
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Record in the Search Index
| _version_ | 1817318848868646912 |
|---|---|
| adam_text |
ERNST-JOACHIM DONTH
RELAXATION
AND
THERMODYNAMICS
IN
POLYMERS
GLASS
TRANSITION
AKADEMIE VERLAG
TABLE OF CONTENTS
INTRODUCTION 1
I FUNDAMENTALS 3
1.
THE 10-NM SCALE: STRUCTURE ELEMENTS OF 2 . . . 20 NM SIZE 9
1.1 THE 1-NM SCALE: P LEVEL 9
1.2 CLASSIFICATION OF LENGTH SCALES IN POLYMERS 14
1.3 MACROMOLECULAR COILS 14
1.4 POLYMER CONCENTRATION 16
1.5 ENTANGLEMENT 20
1.6 POLYMER NETWORKS 23
1.7 CHAIN FOLDED CRYSTALLITES 25
1.8 STRUCTURE AND DYNAMICS - AN OUTLINE 28
2.
LINEAR RESPONSE 31
2.1 MECHANICAL MODELS FOR VISCOELASTICITY 34
2.2 DISCUSSION OF THE MECHANICAL MODELS 38
2.3 GENERAL LINEAR RESPONSE 38
2.4 RELAXATION AND RETARDATION SPECTRA 43
2.5 CORRELATION FUNCTION AND SPECTRAL DENSITY 45
2.6 FLUCTUATION DISSIPATION THEOREM (FDT) 46
2.7 DIFFERENT ACTIVITIES 50
2.8 GENERAL SCALING PRINCIPLE (GSP). MODE LENGTHS 53
3.
THERMODYNAMICS 59
3.1 NETWORK THERMODYNAMICS 59
3.2 DISCUSSION 60
3.3 FLORY HUGGINS FORMULA 63
3.4 DISCUSSION 65
VIII
CONTENTS
3.5 THERMODYNAMIC SYSTEMS: SPATIAL AND TEMPORAL ASPECTS
3.6
SUBSYSTEMS
3.7
FDT AGAIN: WHAT IS A THERMODYNAMIC EXPERIMENT?
3.8
SMALL SYSTEMS
3.9
FUNCTIONAL SUBSYSTEMS. THERMOKINETIC STRUCTURE
4.
THEORETICAL PHYSICS CODE
4.1 ANALYTICAL METHODS
1.
ORDER PARAMETER AND MEAN FIELD
2.
EFFECTIVE HAMILTONIAN
3.
FIELD THEORY METHODS
4.
RENORMALIZATION
5.
DIRECT CORRELATION FUNCTION
6.
GENERAL LANGEVIN EQUATION (GLE)
7.
RANDOM PHASE APPROXIMATION (RPA)
8. DIRECTORY
4.2 SCALING AND CROSSOVER
1.
GENERAL SCALING PRINCIPLE (GSP) AGAIN
2.
ABSENCE OF TYPICAL LENGTH
3.
REDUCTION OF VARIABLES
4.
REDUCTION AND DIMENSIONAL ANALYSIS
5.
CRITICAL SCALING (WIDOM SCALING)
6.
CROSSOVER
7.
CONFINED SCALING
4.3
COMPUTER SIMULATION
68
70
71
76
78
83
84
84
85
87
88
90
90
93
94
95
96
96
96
98
99
100
100
101
II
RELAXATION
103
5.
THREE SIMPLE MODELS
5.1 BARRIER MODEL. ARRHENIUS MECHANISM
5.2
DISCUSSION
5.3
ROUSE MODES
5.4
DISCUSSION
5.5
REPTATION: TUBE MODEL
5.6
DISCUSSION
105
105
108
114
118
122
125
CONTENTS IX
6. GLASS TRANSITION. MULTIPLICITY IN AMORPHOUS POLYMERS 131
6.1 GLASS TRANSITION IN SIMPLE GLASS FORMERS 132
6.2 COMPARISON: PHASE TRANSITION AND DYNAMIC GLASS TRANSITION 135
6.3
WLF SCALING 138
6.4 IDEAL DYNAMIC GLASS TRANSITION 142
6.5 GLASS TRANSITION MULTIPLICITY 149
6.6 DISPERSION ZONES IN AMORPHOUS POLYMERS 152
1.
SECONDARY RELAXATIONS 152
2.
GENERAL REMARKS TO MAIN AND FLOW TRANSITION AND THEIR
SEQUENTIAL
PREDECESSORS 154
3.
MAIN TRANSITION 155
4.
FLOW TRANSITION (OR TERMINAL ZONE) 156
6.7 DEVIATIONS FROM WLF SCALING 157
6.8 MINIMAL COOPERATIVITY, CAGE EFFECTS, AND EXCESS CLUSTER
SCATTERING
160
1.
MINIMAL COOPERATIVITY AND SPLITTING POINT 160
2.
NONACTIVATED PROCESS 164
3.
EXCESS CLUSTER SCATTERING 166
6.9 ACTIVITY ARRANGEMENT ACROSS DISPERSION ZONES 168
6.10
RJ
ACTIVITY AND
D
ACTIVITY 171
1.
DISPERSION ZONE AND TRANSPORT (OR FLOW) ZONE 171
2.
R\
AND
D
ACTIVITY 175
3.
MODEL FOR FLOW TRANSITION 178
7.
THERMAL GLASS TRANSITION 181
7.1 FICTIVE TEMPERATURE. MATERIAL TIME 183
1.
THE CONCEPTIONS 183
2.
NARAYANASWAMY SCHEME 184
3.
DISCUSSION 185
7.2 FREEZING-IN AT THERMAL GLASS TRANSITION 187
7.3 NONLINEARITY, OVERSHOOTS, AND KOVACS' EXPANSION GAP 191
7.4
PHYSICAL AGING 195
7.5 CONVENTIONAL THERMODYNAMICS OF THERMAL GLASS TRANSITION 198
7.6
LOW TEMPERATURE BEHAVIOR YY 200
X CONTENTS
8. EXAMPLES 205
8.1 RELAXATION CARDS FOR AMORPHOUS POLYMERS 205
8.2 CONTROL OF
T
%
207
8.3 RELAXATION IN POLYMER SOLUTIONS 212
8.4 MIXTURES AND STATISTICAL COPOLYMERS 216
8.5 RELAXATION IN SEMICRYSTALLINE POLYMERS 219
8.6 FREE VOLUME AND CONFIGURATIONAL ENTROPY 222
8.7 IONIC CONDUCTIVITY 226
8.8 GLASS STRUCTURE 230
8.9 THERMOSTIMULATION 232
III THERMODYNAMICS 235
9. THERMODYNAMICS OF MIXTURES 237
9.1
9.2
9.3
9.4
9.5
10.
10.1
10.2
10.3
10.4
10.5
10.6
10.7
MIXING AND EXCESS VARIABLES
SMALL-MOLECULE
MIXTURES
FLORY
HUGGINS AGAIN
POLYMER-POLYMER
MIXTURES AND POLYMER SOLUTIONS
SWELLING EQUILIBRIUM OF POLYMER NETWORKS
COMPATIBILITY OF POLYMERS
TERMINOLOGY
ORNSTEIN
ZERNICKE (OZ) APPROACH TO CRITICAL PHENOMENA
1.
CLASSICAL TREATMENT FOR SMALL-MOLECULE SYSTEMS
2.
ADAPTATION FOR POLYMERS
3.
DISCUSSION
SPINODAL
PHASE DECOMPOSITION
1.
CAHN HILLIARD APPROACH
2.
FURTHER INGREDIENTS
3.
GENERAL DISCUSSION
HOMOGENEOUS
NUCLEATION
DIFFUSION
INTERFACE
MICROPHASE
DECOMPOSITION OF BLOCK COPOLYMERS
239
242
246
249
254
257
257
259
259
261
263
265
265
269
272
273
279
283
285
CONTENTS XI
10.8 GRADIENT TERM AND NATURAL SUBSYSTEM 288
10.9 GRANULATED PHASE DECOMPOSITION 291
11.
SEMICRYSTALLINE POLYMERS 295
11.1 TERMINOLOGY AND SALIENT FACTS 296
11.2 PRIMARY AND SECONDARY NUCLEATION 298
11.3 NUCLEATION-CONTROLLED CRYSTAL GROWTH 302
11.4 CRYSTALLIZATION AND MELTING 305
11.5 WHY LAMELLAS? 309
APPENDICES 311
AL.
FOURIER AND FOURIER LAPLACE TRANSFORMS AS USED IN
THIS
BOOK 311
A2.
MOLECULAR MASS AND CHEMICAL CONFIGURATION OF THE
MONOMERIC
UNIT FOR SEVERAL POLYMERS 313
LISTOFTABLES 315
FREQUENTLY USED SYMBOLS, ACRONYMS, AND SYNONYMS 316
REFERENCES
321
SUBJECT INDEX 339 |
| any_adam_object | 1 |
| author | Donth, Ernst-Joachim 1936-2020 |
| author_GND | (DE-588)107210681 |
| author_facet | Donth, Ernst-Joachim 1936-2020 |
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| author_sort | Donth, Ernst-Joachim 1936-2020 |
| author_variant | e j d ejd |
| building | Verbundindex |
| bvnumber | BV025860049 |
| classification_rvk | UV 3200 |
| ctrlnum | (OCoLC)611467621 (DE-599)BVBBV025860049 |
| discipline | Physik |
| edition | 1. ed. |
| format | Book |
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| id | DE-604.BV025860049 |
| illustrated | Not Illustrated |
| indexdate | 2024-12-02T09:05:10Z |
| institution | BVB |
| isbn | 3055013921 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-019107781 |
| oclc_num | 611467621 |
| open_access_boolean | |
| owner | DE-11 |
| owner_facet | DE-11 |
| physical | 256 S. |
| publishDate | 1992 |
| publishDateSearch | 1992 |
| publishDateSort | 1992 |
| publisher | Akademie-Verl. |
| record_format | marc |
| spelling | Donth, Ernst-Joachim 1936-2020 Verfasser (DE-588)107210681 aut Relaxation and thermodynamics in polymers glass transition ; with 8 tables Ernst-Joachim Donth 1. ed. Berlin Akademie-Verl. 1992 256 S. txt rdacontent n rdamedia nc rdacarrier Thermodynamik (DE-588)4059827-5 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf Relaxation (DE-588)4049365-9 gnd rswk-swf Glas (DE-588)4021142-3 gnd rswk-swf Übergangszustand (DE-588)4186592-3 gnd rswk-swf Relaxation (DE-588)4049365-9 s Polymere (DE-588)4046699-1 s DE-604 Thermodynamik (DE-588)4059827-5 s Glas (DE-588)4021142-3 s 1\p DE-604 Übergangszustand (DE-588)4186592-3 s 2\p DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=019107781&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Donth, Ernst-Joachim 1936-2020 Relaxation and thermodynamics in polymers glass transition ; with 8 tables Thermodynamik (DE-588)4059827-5 gnd Polymere (DE-588)4046699-1 gnd Relaxation (DE-588)4049365-9 gnd Glas (DE-588)4021142-3 gnd Übergangszustand (DE-588)4186592-3 gnd |
| subject_GND | (DE-588)4059827-5 (DE-588)4046699-1 (DE-588)4049365-9 (DE-588)4021142-3 (DE-588)4186592-3 |
| title | Relaxation and thermodynamics in polymers glass transition ; with 8 tables |
| title_auth | Relaxation and thermodynamics in polymers glass transition ; with 8 tables |
| title_exact_search | Relaxation and thermodynamics in polymers glass transition ; with 8 tables |
| title_full | Relaxation and thermodynamics in polymers glass transition ; with 8 tables Ernst-Joachim Donth |
| title_fullStr | Relaxation and thermodynamics in polymers glass transition ; with 8 tables Ernst-Joachim Donth |
| title_full_unstemmed | Relaxation and thermodynamics in polymers glass transition ; with 8 tables Ernst-Joachim Donth |
| title_short | Relaxation and thermodynamics in polymers |
| title_sort | relaxation and thermodynamics in polymers glass transition with 8 tables |
| title_sub | glass transition ; with 8 tables |
| topic | Thermodynamik (DE-588)4059827-5 gnd Polymere (DE-588)4046699-1 gnd Relaxation (DE-588)4049365-9 gnd Glas (DE-588)4021142-3 gnd Übergangszustand (DE-588)4186592-3 gnd |
| topic_facet | Thermodynamik Polymere Relaxation Glas Übergangszustand |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=019107781&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT donthernstjoachim relaxationandthermodynamicsinpolymersglasstransitionwith8tables |