Polymer membranes in biotechnology: preparation, functionalization and application
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| Main Authors: | , , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
London
Imperial College Press
2011
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis Klappentext |
| Physical Description: | XII, 287 S. Ill., graph. Darst. |
| ISBN: | 9781848163805 9781848163799 1848163797 1848163800 |
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MARC
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| 245 | 1 | 0 | |a Polymer membranes in biotechnology |b preparation, functionalization and application |c Seeram Ramakrishna ; Zuwei Ma ; Takeshi Matsuura |
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Record in the Search Index
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| adam_text | Contents
Preface
Membrane and Membrane Separation
Process
............................... 1
1.1
Size exclusion membranes
....................................................... 1
1.1.1 Microfiltration
(MF)
membrane
....................................
З
1.1.2 Ultrafiltration
(UF)
membrane
.......................................
З
1.1.3
Nanofiltration
(NF)
membrane
...................................... 4
1.2
Reverse osmosis (RO) membrane
............................................ 4
1.3
Membrane structures
................................................................ 6
1.3.1
Symmetric and asymmetric membranes
........................ 6
1.3.2
Composite membrane
.................................................... 8
1.4
Polymer membranes
................................................................ 10
1.4.1
Cellulose and its derivatives
.......................................... 10
1.4.2 Polyamide
(Nylon)
......................................................... 11
1.4.3
Polysulfone
.................................................................... 12
1.4.4
Poly(vinyldene fluoride) (PVDF)
.................................. 13
1.4.5
Polytetrafluroethylene (PTFE)
....................................... 14
1.4.6
Polypropylene (PP)
........................................................ 14
1.4.7
Polycarbonate (PC)
........................................................ 15
1.5
Inorganic (ceramic) membranes
.............................................. 15
1.5.1
Sintered ceramic membranes
......................................... 15
1.5.2
Anodized alumina membrane
........................................ 17
1.5.3
Molecular sieves (zeolites)
............................................ 18
1.6
Membrane modules
.................................................................. 19
1.6.1
Plate-and-frame membrane module
............................... 20
1.6.2
Spiral-wound membrane module
................................... 21
1.6.3
Tubular membrane module
............................................ 21
1.6.4
Hollow fibre membrane module
.................................... 22
1.7
Wide variety in membrane s driving force
.............................. 25
L7.1 Gas selective separation
................................................. 26
1.7.2
Pervaporation membrane
............................................... 27
VII
viii Polymer
Membranes
in Biotechnology
1.7.3
Piezodialysis
membrane
................................................ 27
1.7.4
Dialysis membrane
........................................................ 28
1.7.5
Electrical dialysis membrane
......................................... 29
1.7.6
Thermally driven membranes: Membrane distillation...
30
1.8
Membrane s applications
......................................................... 31
1.8.1
Water treatment
............................................................. 32
1.8.2
Biomedical
applications
................................................. 35
2.
Membrane Preparation
.................................................................... 39
2.1
Phase separation method
.......................................................... 39
2.2
Lithography-based membrane preparation techniques
............ 41
2.2.1
Introduction of lithography
............................................ 41
2.2.2
Photo masks and radiation sources in lithography
......... 46
2.2.3
Lithography-based membrane preparation: Direct
photo-etching
................................................................. 48
2.2.4
Micro-imprinting (or embossing) method
..................... 52
2.2.5
Combination of micro-printing and phase separation....
55
2.2.6
Laser interference lithography
....................................... 56
2.3
Non-woven membrane preparation
......................................... 57
2.3.1
Traditional non-woven fabric
........................................ 57
2.3.2
Non-woven polymer fabric by electrospinning
............. 60
2.4
Other membrane preparation methods
..................................... 65
2.4.1
Track-etching
................................................................. 65
2.4.2
Film stretching
............................................................... 67
2.4.3
Laser drilling
.................................................................. 68
2.4.4
Template leaching
.......................................................... 69
2.5
Example: Hollow fibre membrane preparation
........................ 69
3.
Surface Modification of Polymers
.................................................. 71
3.1
Graft copolymerization
............................................................ 72
3.1.1
Radiation-induced graft copolymerization
.................... 73
3.1.2
Plasma-induced graft copolymerization
........................ 76
3.1.3
Oxidization-induced graft copolymerization
................. 77
3.2
Plasma treatment
...................................................................... 77
3.2.1
Plasma physics
............................................................... 78
3.2.2
Gas discharge plasma sources and equipments
............. 81
Contents
ix
3.2.3
Plasma-polymer interactions
.......................................... 87
3.2.4
Hydrophilicity and hydrophilicity manipulation
........... 89
3.2.5
Plasma treatment of polymers with O-, N- or
F-containing gases
......................................................... 89
3.2.6
Depth of plasma treatment and aging of polymer
surfaces after plasma treatment
...................................... 93
3.3
Chemical vapour deposition (CVD)
........................................ 95
3.3.1
Introduction
.................................................................... 95
3.3.2
Chemical versatility of CVD
......................................... 96
3.3.3
PECVD
.......................................................................... 98
3.3.4
Polymer film formed by PECVD: Plasma polymer
....... 100
4.
Immobilization of Functional Molecules and its Chemistry
........... 107
4.1
Nucleophiles and electrophiles
................................................ 107
4.2
Hard and soft nucleophiles and electrophiles
.......................... 112
4.3
Leaving group
.......................................................................... 113
4.4
Chemistry of functional groups
............................................... 116
4.4.1
Carboxyl groups and carbodiimide chemistry
............... 117
4.4.2
Hydroxyl groups
............................................................ 121
4.4.3
Thiol group (-SH)
.......................................................... 125
4.4.4
Aldehyde groups
............................................................ 128
4.4.5
Isocynate group
.............................................................. 129
4.4.6
Epoxide
group
................................................................ 131
4.4.7
Cyanuric chloride (2,4,6-trichlorotriazine)
.................... 132
4.4.8
Amino
groups (RNH2, RiR2NH)
................................... 134
4.5
Modification agents
................................................................. 136
4.5.1
Modification agents for introduction of thiol group
...... 136
4.5.2
Modification agents for introduction of carboxyl
group
.............................................................................. 141
4.5.3
Modification agents for introduction of
amino
group....
141
4.5.4
Modification agents for introduction of aldehyde
group
.............................................................................. 143
4.6
Linking agents
......................................................................... 144
4.6.1
Carbodiimides
................................................................ 144
4.6.2
Carbonyl diimidazole
(CDI)
.......................................... 145
4.6.3
Homobifunctional NHS esters
....................................... 147
χ
Polymer
Membranes
in Biotechnology
4.6.4
Homobifunctional imidoesters
....................................... 148
4.6.5
Homobifunctional sulfhydryl-reactive linking agents
... 150
4.6.6
Other homobifunctional linkers
..................................... 150
4.6.7
Heterobifunctional linking reagents
............................... 150
4.7
Ligand immobilization on polymer surfaces
........................... 154
4.7.1
Polysaccharides
.............................................................. 154
4.7.2
PTFE and PVDF
............................................................ 156
4.7.3
Nylon
............................................................................. 158
4.7.4
Polysulfone and polyethersulfone
.................................. 160
4.7.5
Polyethylene terephthalate) (PET)
............................... 160
5.
Membrane Chromatography
........................................................... 165
5.1
Basics of chromatography
....................................................... 165
5.1.1
Gel filtration chromatography
....................................... 168
5.1.2
Ion-exchange chromatography
...................................... 170
5.1.3 Hydrophobie
interaction chromatography
..................... 171
5.1.4
Reversed-phase chromatography
................................... 172
5.1.5
Affinity chromatography
............................................... 172
5.1.6
Metal chelate affinity chromatography
.......................... 173
5.2
IgG purification by affinity chromatography
........................... 175
5.2.1
IgG structure
.................................................................. 175
5.2.2
Affinity ligands for IgG purification
............................. 177
5.3
Affinity membrane chromatography
....................................... 180
5.4
Theory of affinity membrane chromatography
........................ 183
5.4.1
Band moving in chromatography system
...................... 184
5.4.2
Simulation of chromatography process: Continuous
model
............................................................................. 186
5.4.3
Simulation of chromatography process: Plate model
.... 189
5.4.4
Simulation of affinity membrane chromatography
process using plate model
.............................................. 191
5.5
Affinity membrane materials
................................................... 195
5.5.1
Cellulose and its derivatives
.......................................... 196
5.5.2 Polyamide...................................................................... 198
5.5.3
Polysulphone
.................................................................. 198
5.5.4
Polyethylene and polypropylene
.................................... 199
5.5.5
Monoliths
................................................................................. 200
Contents xi
5.6
Affinity membrane examples
................................................... 201
5.6.1
ELIPSA™......................................................................
201
5.6.2
UltraBind™ affinity membrane (PALL)
....................... 203
5.6.3
Sartobind™ membranes
................................................ 204
5.6.4 Vivapure™
Protein A Mini spin columns
(Sartorious)
.................................................................... 205
6.
Membranes in Biosensors and Bioreactors
..................................... 207
6.1
Membranes in biosensors
......................................................... 207
6.1.1
Amperometric biosensors
.............................................. 207
6.1.2
Gas permeable membranes in amperometric
biosensors
...................................................................... 211
6.1.3
Analyte permeable membrane in amperometric
biosensors
...................................................................... 213
6.1.4
Enzyme immobilized membranes in biosensors
............ 215
6.1.5
Membranes in amperometric gas sensors
...................... 217
6.1.6
Ion-selective membrane for potentiometric
biosensors
...................................................................... 222
6.1.7
Membranes used in enzyme-ISFET biosensors
............. 228
6.1.8
Electrospun nanofibre membrane for biosensors
........... 235
6.2
Membrane-based enzyme bioreactors
...................................... 237
6.3
Membrane bioreactors for waste water treatment
.................... 243
6.3.1
Introduction
.................................................................... 243
6.3.2
Biological treatment rationale
........................................ 245
6.3.3
Basic membrane systems of MBR
................................. 246
6.3.4
Example of MBR: Denitrification
................................. 249
Appendix A Phase Diagrams of Polymer Solutions and Application
255
A.I Phase diagram of solvent polymer (SP) system
...................... 255
A.
2
Derivation of phase diagram of the SP system with a
generalized mathematical method
.......................................... 260
A.3 Phase diagram of
nonsolvent
solvent polymer (NSP)
system
..................................................................................... 261
A.4 Application of phase diagram
................................................. 264
xii Polymer
Membranes
in
Biotechnology
Appendix
В
Plate Model of Chromatography
267
Bibliography
273
Index
285
polymer membranes preparation,
fu
nationalization and applications in
biotechniques including affinity membrane chromatography, membrane-
based biosensc and membrane-based bioreactor.
Following an introduction to the general concept of membrane separation
in Chapter
1,
preparation of polymeric membranes is discussed in
Chapter
2.
The book then describes in Chapter
3
membrane surface
activation, which is a key step in ligand immobilizations. Chapter
4
focuses on ligand immobilization techniques and the organic
mistries behind them. Chapter
5
introduces the application
kof
affinity membrane chromatography. Finally, in Chapter
6,
membranes used in biosensors and gas sensors, enzymatic
membranes used as biosensor and membrane biosensor for
aste
water treatment will be discussed.
ι
A novel filter medium, i.e. nonwoven nanofiber
membre
L and its preparation method, i.e. electrospinning technique.
Il are
also introduced in this book.
I€R
M€MßRRN€S
BIOTECHNOLOGY
!
Preparation,
I Functionalization
I :i Application
(SBN-1
3 978-1
-84в16-380-5(рЬк}
ISBN-10 1-84816-38O-O(pbk)
|
| any_adam_object | 1 |
| author | Ramakrishna, Seeram Ma, Zuwei Matsuura, Takeshi 1936- |
| author_GND | (DE-588)172273161 |
| author_facet | Ramakrishna, Seeram Ma, Zuwei Matsuura, Takeshi 1936- |
| author_role | aut aut aut |
| author_sort | Ramakrishna, Seeram |
| author_variant | s r sr z m zm t m tm |
| building | Verbundindex |
| bvnumber | BV025571420 |
| classification_rvk | VE 7100 |
| classification_tum | WER 070f CIT 157f CIT 978f |
| ctrlnum | (OCoLC)705355265 (DE-599)BVBBV025571420 |
| discipline | Chemie / Pharmazie Werkstoffwissenschaften Chemie-Ingenieurwesen Biotechnologie |
| format | Book |
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| id | DE-604.BV025571420 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T22:36:42Z |
| institution | BVB |
| isbn | 9781848163805 9781848163799 1848163797 1848163800 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-020169714 |
| oclc_num | 705355265 |
| open_access_boolean | |
| owner | DE-11 DE-91G DE-BY-TUM DE-29T DE-634 DE-703 |
| owner_facet | DE-11 DE-91G DE-BY-TUM DE-29T DE-634 DE-703 |
| physical | XII, 287 S. Ill., graph. Darst. |
| publishDate | 2011 |
| publishDateSearch | 2011 |
| publishDateSort | 2011 |
| publisher | Imperial College Press |
| record_format | marc |
| spelling | Ramakrishna, Seeram Verfasser aut Polymer membranes in biotechnology preparation, functionalization and application Seeram Ramakrishna ; Zuwei Ma ; Takeshi Matsuura London Imperial College Press 2011 XII, 287 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Trennverfahren (DE-588)4078395-9 gnd rswk-swf Membranverfahren (DE-588)4231727-7 gnd rswk-swf Membran (DE-588)4038571-1 gnd rswk-swf Polymerfilm (DE-588)4175236-3 gnd rswk-swf Biotechnologie (DE-588)4069491-4 gnd rswk-swf Biotechnologie (DE-588)4069491-4 s Trennverfahren (DE-588)4078395-9 s Membranverfahren (DE-588)4231727-7 s DE-604 Polymerfilm (DE-588)4175236-3 s Membran (DE-588)4038571-1 s Ma, Zuwei Verfasser aut Matsuura, Takeshi 1936- Verfasser (DE-588)172273161 aut Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020169714&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020169714&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Ramakrishna, Seeram Ma, Zuwei Matsuura, Takeshi 1936- Polymer membranes in biotechnology preparation, functionalization and application Trennverfahren (DE-588)4078395-9 gnd Membranverfahren (DE-588)4231727-7 gnd Membran (DE-588)4038571-1 gnd Polymerfilm (DE-588)4175236-3 gnd Biotechnologie (DE-588)4069491-4 gnd |
| subject_GND | (DE-588)4078395-9 (DE-588)4231727-7 (DE-588)4038571-1 (DE-588)4175236-3 (DE-588)4069491-4 |
| title | Polymer membranes in biotechnology preparation, functionalization and application |
| title_auth | Polymer membranes in biotechnology preparation, functionalization and application |
| title_exact_search | Polymer membranes in biotechnology preparation, functionalization and application |
| title_full | Polymer membranes in biotechnology preparation, functionalization and application Seeram Ramakrishna ; Zuwei Ma ; Takeshi Matsuura |
| title_fullStr | Polymer membranes in biotechnology preparation, functionalization and application Seeram Ramakrishna ; Zuwei Ma ; Takeshi Matsuura |
| title_full_unstemmed | Polymer membranes in biotechnology preparation, functionalization and application Seeram Ramakrishna ; Zuwei Ma ; Takeshi Matsuura |
| title_short | Polymer membranes in biotechnology |
| title_sort | polymer membranes in biotechnology preparation functionalization and application |
| title_sub | preparation, functionalization and application |
| topic | Trennverfahren (DE-588)4078395-9 gnd Membranverfahren (DE-588)4231727-7 gnd Membran (DE-588)4038571-1 gnd Polymerfilm (DE-588)4175236-3 gnd Biotechnologie (DE-588)4069491-4 gnd |
| topic_facet | Trennverfahren Membranverfahren Membran Polymerfilm Biotechnologie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020169714&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020169714&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT ramakrishnaseeram polymermembranesinbiotechnologypreparationfunctionalizationandapplication AT mazuwei polymermembranesinbiotechnologypreparationfunctionalizationandapplication AT matsuuratakeshi polymermembranesinbiotechnologypreparationfunctionalizationandapplication |