Introduction to dynamic spin chemistry: magnetic field effects on chemical and biochemical reactions
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| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
River Edge, NJ [u.a.]
World Scientific
2004
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| Series: | World Scientific lecture and course notes in chemistry
8 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XI, 254 S. graph. Darst. |
| ISBN: | 9812384235 9789812384232 |
Staff View
MARC
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Record in the Search Index
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| adam_text | Contents Preface 1 1.1 1.2 1.3 1.4 1.5 2 3 1 1 1 2 4 5 Magnetic Properties of Electron and Nuclear Spins Scalar and Vector Products Lorentz Force Potential Energy of a Magnetic Moment Orbital Magnetic Moment Spin Magnetic Moments Introduction to Electron Spin Resonance and Nuclear Magnetic Resonance 9 2.1 Photochemical Primary Processes 2.2 ESR (Electron Spin Resonance) 2.3 NMR (Nuclear Magnetic Resonance). 2.4 The Hyperfine Coupling (HFC) in ESR 2.5 The Spin-Spin Coupling in NMR References 9 11 14 15 17 19 The Radical Pair Mechanism 21 21 22 25 Chemical Reactions through Radical Pairs Singlet and Triplet States of Radical Pairs and Their Mixing Kaptain s Theory for the S-To Conversion Approximations of Recombination Probabilities for S, T, and F-Precursors References 3.1 3.2 3.3 3.4 4 29 30 35 Chemically Induced Dynamic Nuclear Polarization (CIDNP) Discovery of Chemically Induced Magnetic Polarization and ESR Spectra of Radical Pairs 4.2 Theoretical Interpretation of CIDNP by the Radical Pair Mechanism 4.3 Examples of CIDNP References 4.1 v 35 39 42 45
vi 5 47 47 Chemically Induced Dynamic Electron Polarization (CIDEP) Historical Introduction Theoretical Interpretation of CIDEP by the Radical Pair Mechanism 5.3 Theoretical Interpretation of CIDEP by the Triplet Mechanism 5.4 Examples of CIDEP due to the RPM and the Triplet Mechanism 5.5 CIDEP due to Spin-Correlated Radical Pairs References * 5.1 5.2 6 7 Magnetic Field Effects upon Chemical Reactions due to the Radical Pair Mechanism (RPM ) 47 54 56 61 64 75 6.1 Historical Introduction 6.2 Classification of Magnetic Field effects due to the RPM 6.3 Magnetic Field Effects on Product Yields due tothe RPM 6.4 Magnetic Field Effects on Thermal Reactions 6.5 Magnetic Field Effects on Radiation Reactions 6.6 Magnetic Field Effects on Photochemical Reactions 6.7 Magnetic Isotope Effects References 75 77 80 83 85 88 94 95 Magnetic Field Effects due to the Relaxation Mechanism 97 Magnetic Field and Magnetic Isotope Effects Observed in Micellar Solutions 7.2 Proposal of the Relaxation Mechanism 7.3 Magnetic Field Effects on Chemical Reactions through Radical Pairs Involving Heavy Atom-Centered Radicals 7.4 Theoretical Analysis of Relaxation Rates References 7.1 8 Magnetic Field Effects on Chemical Reactions through Biradicals Historical Introduction Magnetic Field Effects on Thermal Reactions through Biradicals 8.3 Magnetic Field Effects on Photochemical Reactions through Biradicals References 8.1 8.2 97 101 103 108 112 117 117 119 120 125
vii 9 Magnetic Isotope Effects (MIEs) 9.1 Introduction 9.2 MIEs of 13C/12C 9.3 MIEs of 15N/14N 9.4 MIEs of 17O/160,18O 9.5 MIEs of 29Si/28Si, 30Si 9.6 MIEs of 33S/32S, 34S, 36S 9.7 MIEs of 73Ge/7OGe, 72Ge, 74Ge, 76Ge 9.8 MIEofSn 9.9 MIEs of 235U/234U, 238U References 127 127 127 131 131 132 133 134 136 136 136 10 Triplet Mechanism (TM) 10.1 Introduction 10.2 Magnetic Field Effects due to the TM 10.3 CIDEP due to the d-type TM References 139 139 141 149 154 11 Theoretical Analysis with the Stochastic Liouville Equation 157 11.1 Density Matrix Method 157 11.2 Density Matrix Treatment for S-To Conversion of Radical Pairs 159 11.3 Effects of Spin Relaxation on Dynamic Behavior of Radical Pairs 165 11.4 Theoretical Analysis of MFEs, CIDNP, and CIDEP with the Density Matrix Method 169 References 171 12 Effects of Ultra-High Magnetic Fields upon Chemical Reactions 12.1 Historical Introduction 12.2 Effects of Ultra-High Magnetic Fields due to the AgM 12.3 Effects of Ultra-High Magnetic Fields due to the RM 12.4 Effects of Ultra-High Magnetic Fields upon Reactions of Kramers Doublet Species 193 References 177 177 177 184 195
viii 13 Effects of Magnetic Fields of High Spin Species 13.1 Magnetic Field Effects of Luminescence 13.2 CIDEP of High Spin Species 13.3 Magnetic Field Effects of High Spin Species References 197 197 201 204 211 14 Optical Detected ESR and Reaction Yield Detected ESR 14.1 Historical Introduction 14.2 ODESR Measurements of Radical Pairs 14.3 RYDESR Studies of Radical Pairs 14.4 ODESR Studies of Radical Pairs References 217 217 219 221 227 232 15 Magnetic Field Effects upon Biochemical Reactions and Biological Processes 15.1 Historical Introduction 15.2 Magnetic Field Effects on Enzyme Reactions 15.3 Effects of Low Magnetic Fields on Chemical Reactions through Radical Pairs References Index 233 233 234 239 245 249
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| illustrated | Illustrated |
| indexdate | 2024-07-09T22:32:04Z |
| institution | BVB |
| isbn | 9812384235 9789812384232 |
| language | English |
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| physical | XI, 254 S. graph. Darst. |
| publishDate | 2004 |
| publishDateSearch | 2004 |
| publishDateSort | 2004 |
| publisher | World Scientific |
| record_format | marc |
| series | World Scientific lecture and course notes in chemistry |
| series2 | World Scientific lecture and course notes in chemistry |
| spelling | Hayashi, Hisaharu Verfasser aut Introduction to dynamic spin chemistry magnetic field effects on chemical and biochemical reactions Hisaharu Hayashi River Edge, NJ [u.a.] World Scientific 2004 XI, 254 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier World Scientific lecture and course notes in chemistry 8 Reaktionsdynamik (DE-588)4301792-7 gnd rswk-swf Kernspin (DE-588)4163636-3 gnd rswk-swf CIDNP (DE-588)4148027-2 gnd rswk-swf Kernspin (DE-588)4163636-3 s Reaktionsdynamik (DE-588)4301792-7 s DE-604 CIDNP (DE-588)4148027-2 s World Scientific lecture and course notes in chemistry 8 (DE-604)BV004467377 8 Digitalisierung UB Regensburg - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=019998696&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Hayashi, Hisaharu Introduction to dynamic spin chemistry magnetic field effects on chemical and biochemical reactions World Scientific lecture and course notes in chemistry Reaktionsdynamik (DE-588)4301792-7 gnd Kernspin (DE-588)4163636-3 gnd CIDNP (DE-588)4148027-2 gnd |
| subject_GND | (DE-588)4301792-7 (DE-588)4163636-3 (DE-588)4148027-2 |
| title | Introduction to dynamic spin chemistry magnetic field effects on chemical and biochemical reactions |
| title_auth | Introduction to dynamic spin chemistry magnetic field effects on chemical and biochemical reactions |
| title_exact_search | Introduction to dynamic spin chemistry magnetic field effects on chemical and biochemical reactions |
| title_full | Introduction to dynamic spin chemistry magnetic field effects on chemical and biochemical reactions Hisaharu Hayashi |
| title_fullStr | Introduction to dynamic spin chemistry magnetic field effects on chemical and biochemical reactions Hisaharu Hayashi |
| title_full_unstemmed | Introduction to dynamic spin chemistry magnetic field effects on chemical and biochemical reactions Hisaharu Hayashi |
| title_short | Introduction to dynamic spin chemistry |
| title_sort | introduction to dynamic spin chemistry magnetic field effects on chemical and biochemical reactions |
| title_sub | magnetic field effects on chemical and biochemical reactions |
| topic | Reaktionsdynamik (DE-588)4301792-7 gnd Kernspin (DE-588)4163636-3 gnd CIDNP (DE-588)4148027-2 gnd |
| topic_facet | Reaktionsdynamik Kernspin CIDNP |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=019998696&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV004467377 |
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