Surfactants and polymers in aqueous solution:
Saved in:
| Format: | Book |
|---|---|
| Language: | English |
| Published: |
Chichester
Wiley
2007
|
| Edition: | 2. ed., reprinted with corrections |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis Klappentext |
| Physical Description: | XVI, 545 S. Ill., graph. Darst. |
| ISBN: | 9780471498834 |
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MARC
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| 245 | 1 | 0 | |a Surfactants and polymers in aqueous solution |c Krister Holmberg ... |
| 250 | |a 2. ed., reprinted with corrections | ||
| 264 | 1 | |a Chichester |b Wiley |c 2007 | |
| 300 | |a XVI, 545 S. |b Ill., graph. Darst. | ||
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Record in the Search Index
| _version_ | 1804140652736282624 |
|---|---|
| adam_text | CONTENTS
Preface to the second edition
xiii
Preface to the first edition
xv
1.
INTRODUCTION TO SURFACTANTS
1
Surfactants Adsorb at Interfaces
1
Surfactants Aggregate in Solution
3
Surfactants are Amphiphilic
3
Surface Active Compounds are Plentiful in Nature
5
Surfactant Raw Materials May be Based on Petrochemicals or
Oleochemicals
7
Surfactants are Classified by the Polar Head Group
8
Dermatological. Aspects of Surfactants are Vital Issues
24
The Ecological Impact of Surfactants is of Growing Importance
27
The Rate of
Biodegradation
Depends on Surfactant Structure
30
Environmental Concern is a Strong Driving Force for
Surfactant Development
32
Bibliography
36
2.
SURFACTANT MICELLIZATION
39
Different Amphiphile Systems
39
Surfactants Start to Form Micelles at the CMC
39
CMC Depends on Chemical Structure
43
Temperature and Cosolutes Affect the CMC
46
The Solubility of Surfactants may be Strongly Temperature
Dependent
49
Driving Forces of Micelle Formation and Thermodynamic
Models
52
The Association Process and
Counterion
Binding can be
Monitored by NMR Spectroscopy
55
Hydrophobie
Compounds can be Solubilized in Micelles
57
Micelle Size and Structure may Vary
58
A Geometric Consideration of Chain Packing is Useful
60
Kinetics of Micelle Formation
61
vi
Surfactants and Polymers in Aqueous Solution
Surfactants may Form Aggregates in Solvents other than Water
62
General Comments on Amphiphile Self-Assembly
64
Bibliography
66
3.
PHASE BEHAVIOUR OF CONCENTRATED
SURFACTANT SYSTEMS
67
Micelle Type and Size Vary with Concentration
67
Micellar Growth is Different for Different Systems
70
Surfactant Phases are Built Up by Discrete or Infinite
Self-Assemblies
74
Micellar Solutions can Reach Saturation
76
Structures of Liquid Crystalline Phases
77
How to Determine Phase Diagrams
80
Binary and Ternary Phase Diagrams are Useful Tools: Two
Components
82
Binary and Ternary Phase Diagrams are Useful Tools: Three
Components
85
Surfactant Geometry and Packing Determine Aggregate
Structure: Packing Parameter and Spontaneous Curvature of the
Surfactant Film are Useful Concepts
89
Polar Lipids Show the same Phase Behaviour as other
Amphiphiles
93
Liquid Crystalline Phases may Form in Solvents other than
Water
94
Bibliography
95
4.
PHYSICOCHEMICAL PROPERTIES OF
SURFACTANTS AND POLYMERS CONTAINING
OXYETHYLENE GROUPS
97
Polyoxyethylene Chains make up the Hydrophilic
Part of many Surfactants and Polymers
97
CMC and Micellar Size of Polyoxyethylene-Based
Surfactants are Strongly Temperature Dependent
98
Temperature Dependence can be Studied using Phase Diagrams
100
The L3 or Sponge Phase
103
Sequence of Self-Assembly Structures as a Function of
Temperature
103
The Critical Packing Parameter and the Spontaneous Curvature
Concepts are Useful Tools
103
Clouding is a Characteristic Feature of
Polyoxyethylene-Based Surfactants and Polymers
109
Contents
vii
Physicochemical Properties of Block Copolymers
Containing Polyoxethylene Segments Resemble those of
Polyoxyethylene-Based Surfactants
111
Temperature Anomalies of Oxyethylene-Based Surfactants
and Polymers are Ubiquitous
113
Temperature Anomalies are Present in Solvents other than Water
117
Bibliography
118
5.
MIXED MICELLES
119
Systems of Surfactants with Similar Head Groups
Require no Net Interaction
119
General Treatment of Surfactants Mixtures Requires a Net
Interaction
124
The Concept of Mixed Micelles can also be Applied to
Amphiphiles not Forming Micelles
130
Mixed Surfactant Systems at Higher Concentrations Show
Interesting Features
131
Mixed Surfactant Systems are used Technically
134
Appendix
136
Bibliography
138
6.
MICROEMULSIONS
139
The Term
Microemulsion
is Misleading
139
Phase Behaviour of Oil-Water-Surfactant Systems can be
Illustrated by Phase Diagrams
140
The Choice of Surfactant is Decisive
143
Ternary Phase Diagrams can be Complex
146
How to Approach
Microstructure?
146
Molecular Self-Diffusion can be Measured
147
Confinement, Obstruction and Solvation Determine
Solvent Self-Diffusion in Microemulsions
148
Self-Diffusion Gives Evidence for a Bicontinuous Structure at
Balanced Conditions
151
The
Microstructure
is Governed by Surfactant Properties
152
Bibliography
154
7.
INTERMOLECULAR INTERACTIONS
157
Pair Potentials Act between Two Molecules in a Vacuum
157
The Intermolecular Interaction can be Partitioned
159
Effective Pair Potentials Act between Two Molecules in a Medium
167
Bibliography
174
viii
Surfactants and Polymers in Aqueous Solution
8.
COLLOIDAL FORCES
175
Electric Double-Layer Forces are Important for Colloidal Stability
175
Other Types of Forces Exist
181
Colloidal Forces can be Measured Directly
189
Bibliography
191
9.
POLYMERS IN SOLUTION
193
Polymer Properties are Governed by the Choice of Monomers
193
The Molecular Weight is an Important Parameter
195
Dissolving a Polymer can be a Problem
196
Polymers in Solution can be Characterized by Viscosity
Measurements
196
Polymer Solutions may Undergo Phase Separation
197
Polymers Containing Oxyethylene Groups Phase-Separate
Upon Heating in Aqueous Systems
199
Solvents and Surfactants have Large Effects on Polymer
Solutions
199
The Solubility Parameter Concept is a Useful Tool for Finding
the Right Solvent for a Polymer
201
The Theta Temperature is of Fundamental Importance
203
There are Various Classes of Water-Soluble Polymers
205
Polyelectrolytes are Charged Polymers
207
Polymer Configurations Depend on Solvent
Conditions
207
Bibliography
214
10.
REGULAR SOLUTION THEORY
215
Bragg-Williams Theory Describes Non-ideal Mixtures
215
Flory-Huggins Theory Describes the Phase Behaviour
of Polymer Solutions
223
Bibliography
226
11.
NOVEL SURFACTANTS
227
Gemini Surfactants have an Unusual Structure
227
Cleavable Surfactants are Environmentally Attractive but
are of Interest for other Reasons as well
235
Polymerizable Surfactants are of Particular Interest
for Coatings Applications
246
Polymeric Surfactants Constitute a Chapter of their Own
258
Special Surfactants Give Extreme Surface Tension Reduction
258
Bibliography
259
Contents
ix
12.
SURFACE ACTIVE POLYMERS
261
Surface Active Polymers can be Designed in Different Ways
261
Polymers may have a Hydrophilic Backbone and
Hydrophobie
Side Chains
262
Polymers may have
a
Hydrophobie
Backbone and
Hydrophilic Side Chains
267
Polymers may Consist of Alternating Hydrophilic and
Hydrophobie
Blocks
272
Polymeric Surfactants have Attractive Properties
276
Bibliography
276
13.
SURFACTANT-POLYMER SYSTEMS
277
Polymers can Induce Surfactant Aggregation
277
Attractive Polymer-Surfactant Interactions Depend on both
Polymer and Surfactant
281
Surfactant Association to Surface Active Polymers can be
Strong
283
The Interaction between a Surfactant and a Surface Active
Polymer is Analogous to Mixed Micelle Formation
285
Phase Behaviour of Polymer-Surfactant Mixtures Resembles
that of Mixed Polymer Solutions
288
Phase Behaviour of Polymer-Surfactant Mixtures in Relation to
Polymer-Polymer and Surfactant-Surfactant Mixtures
295
Polymers may Change the Phase Behaviour of Infinite
Surfactant Self-Assemblies
298
There Are Many Technical Applications of Polymer-Surfactant
Mixtures
299
DNA
is Compacted by Cationic Surfactants, which gives
Applications in Gene Therapy
301
Bibliography
303
14.
SURFACTANT-PROTEIN MIXTURES
305
Proteins are Amphiphilic
305
Surfactant-Protein Interactions have a Broad Relevance
306
Surface Tension and Solubilization give Evidence for Surfactant
Binding to Proteins
306
The Binding Isotherms are Complex
308
Protein-Surfactant Solutions may have High Viscosities
310
Protein-Surfactant Solutions may give rise to Phase Separation
311
Surfactants may Induce Denaturation of Proteins
314
Bibliography
315
χ
Surfactants and Polymers in Aqueous Solution
15.
AN INTRODUCTION TO THE RHEOLOGY OF
POLYMER AND SURFACTANT SOLUTIONS
317
Rheology Deals with how Materials Respond to Deformation
317
The Viscosity Measures how a Simple Fluid Responds to Shear
317
The Presence of Particles Changes the Flow Pattern and the
Viscosity
322
The Relationship between Intrinsic Viscosity and Molecular
Mass can be Useful
324
The Rheology is often Complex
324
Viscoelasticity
327
The Rheological Behaviour of Surfactant and Polymer
Solutions Shows an Enormous Variation: Some
Further Examples
329
Bibliography
335
16.
SURFACE TENSION AND ADSORPTION AT THE
AIR-WATER INTERFACE
337
Surface Tension is due to Asymmetric Cohesive Forces
at a Surface
337
Solutes Affect Surface Tension
339
Dynamic Surface Tension is Important
340
The Surface Tension is Related to Adsorption
342
Surfactant Adsorption at the Liquid-Air Surface is Related to
the Critical Packing Parameter
343
Polymer Adsorption can be Misinterpreted
346
Measurement of Surface Tension
347
The Surface and
Interfacial
Tensions can be Understood in
Terms of Molecular Interactions
349
Surface Tension and Adsorption can be Understood in
Terms of the Regular Solution Theory
351
Bibliography
355
17.
ADSORPTION OF SURFACTANTS AT SOLID
SURFACES
357
Surfactant Adsorption is Governed both by the Nature of
the Surfactant and the Surface
357
Model Surfaces and Methods to Determine Adsorption
359
Analysis of Surfactant Adsorption is Frequently Carried out
in Terms of the Langmuir Equation
362
Surfactants Adsorb on
Hydrophobie
Surfaces
365
Surfactants Adsorb on Hydrophilic Surfaces
372
Competitive Adsorption is a Common Phenomenon
380
Bibliography
387
Contents
xi
18.
WETTING AND WETTING AGENTS,
HYDROPHOBIZATION AND
HYDROPHOBIZING AGENTS
389
Liquids Spread at Interfaces
389
The Critical Surface Tension of a Solid is a Useful Concept
391
The Critical Surface Tension can be Applied to Coatings
394
Surface Active Agents can Promote or Prevent Wetting and
Spreading
395
Measuring Contact Angles
399
Bibliography
402
19.
INTERACTION OF POLYMERS WITH SURFACES
403
The Adsorbed Amount Depends on Polymer Molecular Weight
404
The Solvent has a Profound Influence on the Adsorption
407
Electrostatic Interactions Affect the Adsorption
408
Polyelectrolyte Adsorption can be Modelled Theoretically
416
Polyelectrolytes Change the Double-Layer Repulsion
419
Polymer Adsorption is Practically Irreversible
427
The Acid-Base Concept can be Applied to Polymer Adsorption
428
Measurement of Polymer Adsorption
431
Bibliography
435
20.
FOAMING OF SURFACTANT SOLUTIONS
437
There are Transient Foams and Stable Foams
437
Two Conditions must be Fulfilled for a Foam to be Formed
438
There are Four Forces Acting on a Foam
440
The Critical Packing Parameter Concept is a Useful Tool
442
Polymers might Increase or Decrease Foam Stability
446
Particles and Proteins can Stabilize Foams
447
Various Additives are Used to Break Foams
448
Bibliography
450
21.
EMULSIONS AND EMULSIFIERS
451
Emulsions are Dispersions of One Liquid in Another
451
Emulsions can be Very Concentrated
. 452
Emulsions can Break Down According to Different Mechanisms
452
The Emulsion Droplets Need a Potential Energy Barrier
453
The DVLO Theory is a Cornerstone in the Understanding of
Emulsion Stability
456
Emulsifiers are Surfactants that Assist in Creating an Emulsion
458
The HLB Concept
459
The HLB Method of Selecting an Emulsifier is Crude but Simple
461
The PIT Concept
462
xii
Surfactants and Polymers in Aqueous Solution
The PIT Method of Selecting an Emulsifier is often Useful
466
Different Types of Non-Ionic Surfactants can be Used as
Emulsifiers
466
Bancroft s Rule may be Explained by Adsorption
Dynamics of the Surfactant
468
Bancroft s Rule may be Related to the Surfactant Geometry
469
Hydrodynamics may Control what Type of Emulsion will Form
471
Bibliography
471
22.
MICROEMULSIONS FOR SOIL AND OIL REMOVAL
473
Surfactant-Based Cleaning Formulations may act by in situ
Formation of
a
Microemulsion (Detergency) 473
Microemulsion-Based Cleaning Formulations are Efficient
484
Microemulsions were once Believed to be the Solution to
Enhanced Oil Recovery
486
Bibliography
492
23.
CHEMICAL REACTIONS IN
MICROHETEROGENEOUS SYSTEMS
493
Microemulsions can be used as
Minireactors
for Chemical
Reactions
493
Surface Active Reagents may be Subject to Micellar Catalysis
494
Microemulsions are Good Solvents for Organic Synthesis
496
Microemulsions are Useful as Media for Enzymatic Reactions
502
Microemulsions can be Used to Prepare Nanosized Lattices
507
Nanosized Inorganic Particles can be Prepared in
Microemulsions
511
Mesoporous Materials can be Prepared from Surfactant Liquid
Crystals
516
Bibliography
517
Appendices
519
Index
527
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|
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| classification_rvk | VE 7060 |
| ctrlnum | (OCoLC)315607743 (DE-599)GBV598761764 |
| dewey-full | 668.1 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 668 - Technology of other organic products |
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| discipline | Chemie / Pharmazie |
| edition | 2. ed., reprinted with corrections |
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| id | DE-604.BV024629446 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T22:03:23Z |
| institution | BVB |
| isbn | 9780471498834 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-018601057 |
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| owner | DE-83 DE-355 DE-BY-UBR |
| owner_facet | DE-83 DE-355 DE-BY-UBR |
| physical | XVI, 545 S. Ill., graph. Darst. |
| publishDate | 2007 |
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| publishDateSort | 2007 |
| publisher | Wiley |
| record_format | marc |
| spelling | Surfactants and polymers in aqueous solution Krister Holmberg ... 2. ed., reprinted with corrections Chichester Wiley 2007 XVI, 545 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Tensid (DE-588)4128790-3 gnd rswk-swf Wässrige Lösung (DE-588)4124928-8 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf Tensid (DE-588)4128790-3 s Polymere (DE-588)4046699-1 s Wässrige Lösung (DE-588)4124928-8 s DE-604 Holmberg, Krister Sonstige oth Digitalisierung UB Regensburg application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018601057&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Regensburg application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018601057&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Surfactants and polymers in aqueous solution Tensid (DE-588)4128790-3 gnd Wässrige Lösung (DE-588)4124928-8 gnd Polymere (DE-588)4046699-1 gnd |
| subject_GND | (DE-588)4128790-3 (DE-588)4124928-8 (DE-588)4046699-1 |
| title | Surfactants and polymers in aqueous solution |
| title_auth | Surfactants and polymers in aqueous solution |
| title_exact_search | Surfactants and polymers in aqueous solution |
| title_full | Surfactants and polymers in aqueous solution Krister Holmberg ... |
| title_fullStr | Surfactants and polymers in aqueous solution Krister Holmberg ... |
| title_full_unstemmed | Surfactants and polymers in aqueous solution Krister Holmberg ... |
| title_short | Surfactants and polymers in aqueous solution |
| title_sort | surfactants and polymers in aqueous solution |
| topic | Tensid (DE-588)4128790-3 gnd Wässrige Lösung (DE-588)4124928-8 gnd Polymere (DE-588)4046699-1 gnd |
| topic_facet | Tensid Wässrige Lösung Polymere |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018601057&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018601057&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT holmbergkrister surfactantsandpolymersinaqueoussolution |