Arsenic: environmental chemistry, health threats and waste treatment
Saved in:
| Format: | Book |
|---|---|
| Language: | English |
| Published: |
Chichester
Wiley
2009
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Includes bibliographical references and index |
| Physical Description: | XVIII, 569 S. Ill., graph. Darst., Kt. |
| ISBN: | 0470027584 9780470027585 |
Staff View
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| 245 | 1 | 0 | |a Arsenic |b environmental chemistry, health threats and waste treatment |c ed. by Kevin Henke |
| 264 | 1 | |a Chichester |b Wiley |c 2009 | |
| 300 | |a XVIII, 569 S. |b Ill., graph. Darst., Kt. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Includes bibliographical references and index | ||
| 650 | 4 | |a Arsenic | |
| 650 | 4 | |a Arsenic Poisoning | |
| 650 | 4 | |a Arsenic wastes | |
| 650 | 4 | |a Arsenic |x Toxicology | |
| 650 | 4 | |a Arsenic |x chemistry | |
| 650 | 4 | |a Arsenic |x toxicity | |
| 650 | 4 | |a Environmental chemistry | |
| 650 | 4 | |a Groundwater |x Arsenic content | |
| 650 | 4 | |a Waste Management | |
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| 700 | 1 | |a Henke, Kevin R. |e Sonstige |4 oth | |
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Record in the Search Index
| _version_ | 1804140651881693184 |
|---|---|
| adam_text | Contents
List of contributors
xv
Preface
xvii
1.
Introduction
1
Kevin R. Henke
1.1
Arsenic origin, chemistry, and use
1
1.2
Arsenic environmental impacts
2
1.3
Arsenic
toxicity
3
1.4
Arsenic treatment and remediation
3
1.4.1
Introduction
3
1.4.2
Treatment and remediation of water
4
1.4.3
Treatment and remediation of solid wastes, soils, and sediments
4
1.4.4
Treatment of flue gases
5
References
5
2.
Arsenic Chemistry
9
Kevin R. Henke and Aaron Hutchison
2.1
Introduction
9
2.2
Atomic structure and isotopes of arsenic
9
2.3
Arsenic valence state and bonding
10
2.4
Chemistry of arsenic solids
13
2.4.1
Elemental arsenic
13
2.4.2
Common arsenic minerals and other solid arsenic compounds IS
2.4.3
Arsine
and other volatile arsenic compounds
24
2.4.4
Organoarsenicals
24
2.5
Introduction to arsenic oxidation and reduction
26
2.5.1
Arsenic oxidation
26
2.5.2
Arsenic reduction
27
2.6
Introduction to arsenic methylation and demethylation
28
2.7
Arsenic in water
30
2.7.1
Introduction
30
2.7.2
Aqueous solubility of arsenic compounds and thermodynamics
31
2.7.3
Dissolved arsenic species
40
2.7.4
Dissociation of arsenious and arsenic acids
42
2.7.5
Eh-pH diagrams, and their limitations
45
2.7.6 Sorption,
ion exchange, precipitation, and coprecipitation of arsenic in water
46
2.8
Chemistry of gaseous arsenic emissions
57
References
59
viii Contents
3
Arsenic in Natural
Environments 69
Kevin
R.
Henke
3.1
Introduction
69
3.2
Nucleosynthesis: the origin of arsenic
70
3.2.1
The Big Bang
70
3.2.2
Arsenic formation in stars
70
3.3
Arsenic in the universe as a whole
73
3.4
Arsenic chemistry of the solar system
73
3.4.1
Arsenic in the Sun, Moon, and planets
73
3.4.2
Arsenic in meteorites and tektites
74
3.5
Arsenic in the bulk Earth, crusts, and interior
77
3.5.1
Estimating arsenic concentrations of the
buhe
Earth and the Earth s core and mantle
77
3.5.2
The core
78
3.5.3
The mantle
78
3.5.4
The Earth s crusts
79
3.6
Arsenic in
hydrothermal
and geothermal fluids and their deposits
82
3.6.1
Introduction
82
3.6.2
Origins of
hydrothermal
fluids and their arsenic
83
3.6.3
Arsenic chemistry of
hydrothermal
fluids
85
3.6.4
Arsenic mineralogy of
hydrothermal
deposits
91
3.6.5
Surface and near-surface oxidation of
hydrothermal
arsenic
93
3.6.6
Arsenic chemistry in hot springs
94
3.6.7
Arsenic in geothermal power plant scales
95
3.6.8
Arsenic in volcanic gas emissions
96
3.6.9
Environmental impacts of arsenic in
hydrothermal
and geothermal fluids
96
3.7
Oxidation of arsenic-bearing sulfides in geologic materials and mining wastes
97
3.7.1
Oxidation of
sulfide
minerals
97
3.7.2
Factors influencing the oxidation of arsenic-bearing
sulfide
minerals
97
3.7.3
Environmental consequences of
sulfide
and arsenic oxidation
99
3.7.4
Oxidation chemistry of major arsenic-bearing sulfides
102
3.8
Interactions between arsenic and natural organic matter
(NOM)
106
3.9 Sorption
and coprecipitation of arsenic with iron and other (oxy)(hydr)oxides
106
3.9.1
Introduction
106
3.9.2
Iron, aluminum, and manganese (oxy)(hydr)oxides
107
3.9.3 Sulfate (oxy)(hydr)oxides
and related compounds
108
3.10
Arsenate (inorganic As(V)) precipitation
110
3.11
Reductive dissolution of iron and manganese (oxy)(hydr)oxides
110
3.12
Arsenic and
sulfide
at
< 50 °С 114
3.13
Arsenic and its chemistry in mined materials
115
3.13.1
Environmental issues with arsenic-bearing
sulfide
minerals in coal and ore deposits
115
3.13.2
Behavior of arsenic
wimin
mining wastes
115
3.13.3
Movement of arsenic from mining wastes and into the environment
116
3.14
Marine waters and sediments
117
3.14.1
Inorganic arsenic in seawater
117
3.14.2
Marine arsenic cycle
120
3.14.3
Arsenic methylation in marine environments
121
3.14.4
Arsenic in marine sediments
121
Contents ix
3.15
Estuaries
122
3.15.1
Arsenic in estuaries
122
3.15.2
Seasonal effects on arsenic in estuaries
125
3.15.3
Arsenic in pristine estuaries
125
3.15.4
Arsenic in contaminated estuaries
126
3.16
Rivers and other streams
127
3.17
Lakes
136
3.18
Wetlands
145
3.19
Groundwater
146
3.19.1
Subsurface water and groundwater
146
3.19.2
Impacts of arsenic contamination in shallow
(< 1
km deep) groundwaters
148
3.19.3
Dissolved and particulate arsenic in groundwater
148
3.19.4
Arsenic mobility in groundwater
148
3.19.5
Sources of arsenic contamination in groundwater
149
3.19.6
Arsenic chemistry in groundwater
161
3.20
Glacial ice and related sediments
162
3.21
Arsenic in air and wind-blown sediments
163
3.21.1
Arsenic emission sources
163
3.21.2
Arsenic atmospheric chemistry
165
3.21.3
Arsenic in precipitation
166
3.21.4
Arsenic in atmospheric dust
166
3.21.5
Arsenic in wind-blown sediment deposits (loess)
168
3.21.6
Arsenic in soil and sediment gases
168
3.22
Petroleum
168
3.23
Soils
169
3.23.1
Distinguishing between soils and sediments
169
3.23.2
Arsenic chemistry in soils
171
3.23.3
Soil porewater chemistry
178
3.24
Sedimentary rocks
178
3.24.1 Diagenesis
and sedimentary rocks
178
3.24.2
Coal
180
3.24.3
Shales and oil shales
190
3.24.4
Other sedimentary rocks
195
3.25
Metamorphic rocks
196
References
198
Further reading
235
4
Toxicology and Epidemiology of Arsenic and its Compounds
237
Michael F. Hughes, David J. Thomas, and
ЕЫпа
M. Kenyon
4.1
Introduction
237
4.2
Physical and chemical properties of arsenic
238
4.3
Exposure to arsenic
238
4.4
Arsenic disposition and
biotransformation
in mammals
240
4.4.1
Introduction
240
4.4.2
Respiratory deposition and absorption
240
4.4.3
Gastrointestinal absorption
241
4.4.4
Dermal absorption
242
χ
Contents
4.5
Systemie
clearance of arsenic and binding to blood components
243
4.6
Tissue distribution
244
4.7
Placental transfer and distribution in the fetus
246
4.8
Arsenic
biotransformation
247
4.8.1
Introduction
247
4.8.2
Arsenic methylation in humans and other mammals
248
4.8.3
Significance of arsenic methylation
248
4.8.4
Molecular basis of the metabolism of inorganic arsenic
248
4.8.5
Reconciling experimental data and the Challenger scheme
251
4.9
Arsenic excretion
252
4.10
Effects of arsenic exposure
253
4.10.1
Acute exposure
253
4.10.2
Chronic exposure
254
4.11
Cardiovascular
254
254
255
255
255
255
256
256
257
257
257
258
258
259
259
259
260
260
τ
260
261
261
262
262
262
263
263
263
263
264
264
264
265
4.11.1
Introduction
4.11.2
Peripheral vascular disease
4.11.3
Ischemic
heart disease
4.11.4
Cerebrovascular disease
4.11.5
Atherosclerosis
4.11.6
Hypertension
4.12
Endocrine
4.13
Hepatic
4.14
Neurological
4.15
Skin
4.16
Developmental
4.17
Other organ systems
4.18
Cancer
4.18.1
Introduction
4.18.2
Skin
4.18.3
Lung
4.18.4
Bladder
4.19
Animal
ι
models for arsenic-induced
с
4.20
Mechanism of action
4.20.1
Introduction
4.20.2
Replacement of phosphate
4.20.3
Enzyme inhibition
4.20.4
Oxidative stress
4.20.5
Genotoxicity
4.20.6
Alteration of
DNA
repair
4.20.7
Signal transduction
4.20.8
Gene transcription
4.20.9
DNA
methylation
4.20.10
Growth factors
4.21
Regulation of arsenic
References
Contents xi
5
Arsenie
in
Human History and Modern Societies
277
Kevin R. Henke and David A. Atwood
5.1
Introduction
277
5.2
Early recognition and uses of arsenic by humans
278
5.3
Alchemy, development of methods to recover elemental arsenic, and the synthesis of arsenic
compounds
279
5.4
Applications with arsenic
279
5.4.1
Medicinal applications: dangerous quackery and some important drags
279
5.4.2
Pesticides and agricultural applications
280
5.4.3
Chemical weapons
282
5.4.4
Embalming fluids
282
5.4.5
Paints and dyes
283
5.4.6
Wood treatment
284
5.4.7
Semiconductors
286
5.5
Increasing health, safety, and environmental concerns
286
5.6
Arsenic in crime
287
5.7
Poisoning controversies: Napoleon Bonaparte
288
5.8
Arsenic in prospecting, mining, and markets
289
5.8.1
Arsenic as a pathfinder element in prospecting
289
5.8.2
Arsenic mining, production, and market trends
290
5.9
Arsenic in coal and oil shale utilization and their by-products
291
5.9.1
Coal cleaning and combustion
291
5.9.2
Arsenic behavior during combustion
291
5.9.3
Postcombustion
flue gas treatment
295
5.9.4
Arsenic chemistry in coal combustion byproducts
295
5.9.5
Coal gasification
296
5.9.6
Oil shale utilization
2%
References
297
6
Major Occurrences of Elevated Arsenic in Groundwater and Other Natural Waters
303
Abhijit Mukherjee, Alan E. Fryar, and Bethany At. O Shea
6.1
Introduction
303
6.2
Arsenic speciation and mobility in natural waters
304
6.3
Immobilization of arsenic in
hydrologie
systems
304
6.3.1
Precipitation, coprecipitation, and association with sulfides
304
6.3.2
Arsenic sorption on metal (oxyXhydr)oxides
305
6.3.3
Arsenic sorption on clay minerals
306
6.3.4
Carbonate interactions
306
6.4
Mobilization of arsenic in water
309
6.4.1
Competitive
anion
exchange
309
6.4.2
Effect of natural organic matter
(NOM)
310
6.4.3
Effect of
pH
310
6.4.4
Redox-dependent mobilization
311
6.4.5
Complex and colloid formation
311
xii Contents
6.5
Natural
occurrences
of elevated arsenic around the world
313
6.5.1
Introduction
313
6.5.2
Bengal basin, India and Bangladesh
317
6.5.3
Middle Ganges Plain, India
324
6.5.4
Donargarh rift belt, Chattisgarh, central India
326
6.5.5
Terai alluvial plain, Nepal
326
6.5.6
Indus alluvial system, Pakistan
327
6.5.7
Irrawaddy delta,
Myanmar 328
6.5.8
Mekong plain and delta, Cambodia, Vietnam, and Laos
328
6.5.9
Red River delta, Vietnam
331
6.5.10
Yellow River plains, Inner Mongolia, China
332
6.5.11
Taiwan
333
6.5.12
Coastal aquifers of Australia
334
6.5.13
Sedimentary basins and basement complexes of West Africa
334
6.5.14
Western USA
335
6.5.15
New England, USA
336
6.5.16
Northern Chile
337
6.5.17
Chaco
and
Pampa
plains of Argentina
338
References
339
7
Waste Treatment and Remediation Technologies for Arsenic
351
Kevin R. Henke
7.1
Introduction
351
7.2
Treatment technologies for arsenic in water
352
7.2.1
Introduction
352
7.2.2
Preoxidation of
Аѕ(Ш)
in water
353
7.2.3 Sorption
and ion-exchange technologies
357
7.2.4
Precipitation/coprecipitation
390
7.2.5
Permeable reactive barriers
394
7.2.6
Filtration, membranes, and other separation technologies
395
7.2.7
Biological treatment and bioremediation
398
7.2.8
Natural remediation
401
7.3
Treatment technologies for arsenic in solids
401
7.3.1
Introduction
401
7.3.2
Review of various treatment technologies for arsenic in inorganic solids
402
7.3.3
Review of various treatment technologies for chromated copper arsenate
(CCAHreated wood
410
7.4
Treatment technologies for arsenic in gases
414
References
415
APPENDICES
A Common Physical and Chemical Constants and Conversions for Units of Measure
431
Contents xiii
В
Glossary of Terms
437
B.I Introduction
437
B.2 Glossary
437
References
472
С
Arsenic Thermodynamic Data
475
C.I Introduction
475
C.2 Modeling applications with thermodynamic data
493
C.3 Thermodynamic data
493
References
493
D
Locations of Significant Arsenic Contamination
495
References
524
E
Regulation of Arsenic: A Brief Survey and Bibliography
545
E.
1
Introduction
545
E.2 Regulation of arsenic in water
545
E.2.1 Drinking water
546
E.2.
2
Arsenic standards of natural surface waters and groundwaters
549
E.3 Regulation of arsenic in solid and liquid wastes
549
549
550
550
550
550
550
E.4 Sediment and soil guidelines and standards for arsenic
553
553
553
553
554
554
554
554
554
554
E.5 Regulation of arsenic in food and drags
555
555
555
555
E.6 Regulation of arsenic in air
556
556
556
556
Index
559
E.3.1
Bangladesh
E.3.2
European Union
(EU)
E.3.3
Japan
E.3.4
Norway
E.3.5
Taiwan
E.3.6
United States of America
Sediment and soil guidelines and stands
E.4.1
Introduction
E.4.2
Australia
E.4.3
Canada
E.4.4
European Union
E.4.5
Italy
E.4.6
Japan
E.4.7
Korea (South)
E.4.8
Thailand
E.4.9
United States of America
Regulation of arsenic in food and drags
E.5.1
Australia and New Zealand
E.5.2
Canada
E.5.3
United States of America
Regulation of arsenic in air
E.6.1
European Union
E.6.2
United States of America
References
|
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| format | Book |
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| id | DE-604.BV024628878 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T22:03:22Z |
| institution | BVB |
| isbn | 0470027584 9780470027585 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-018600515 |
| oclc_num | 246887672 |
| open_access_boolean | |
| owner | DE-83 DE-384 DE-703 |
| owner_facet | DE-83 DE-384 DE-703 |
| physical | XVIII, 569 S. Ill., graph. Darst., Kt. |
| publishDate | 2009 |
| publishDateSearch | 2009 |
| publishDateSort | 2009 |
| publisher | Wiley |
| record_format | marc |
| spelling | Arsenic environmental chemistry, health threats and waste treatment ed. by Kevin Henke Chichester Wiley 2009 XVIII, 569 S. Ill., graph. Darst., Kt. txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and index Arsenic Arsenic Poisoning Arsenic wastes Arsenic Toxicology Arsenic chemistry Arsenic toxicity Environmental chemistry Groundwater Arsenic content Waste Management Water Pollutants, Chemical Umweltverschmutzung (DE-588)4186812-2 gnd rswk-swf Arsenverbindungen (DE-588)4143104-2 gnd rswk-swf Umwelttoxikologie (DE-588)4121813-9 gnd rswk-swf Arsenbelastung (DE-588)4143081-5 gnd rswk-swf Umweltgeochemie (DE-588)4404136-6 gnd rswk-swf Ökologische Chemie (DE-588)4135167-8 gnd rswk-swf Geochemie (DE-588)4020198-3 gnd rswk-swf Toxikologie (DE-588)4060538-3 gnd rswk-swf Arsen (DE-588)4003041-6 gnd rswk-swf Arsen (DE-588)4003041-6 s Arsenverbindungen (DE-588)4143104-2 s Geochemie (DE-588)4020198-3 s Ökologische Chemie (DE-588)4135167-8 s Toxikologie (DE-588)4060538-3 s DE-604 Arsenbelastung (DE-588)4143081-5 s Umweltgeochemie (DE-588)4404136-6 s Umwelttoxikologie (DE-588)4121813-9 s Umweltverschmutzung (DE-588)4186812-2 s Henke, Kevin R. Sonstige oth Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018600515&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Arsenic environmental chemistry, health threats and waste treatment Arsenic Arsenic Poisoning Arsenic wastes Arsenic Toxicology Arsenic chemistry Arsenic toxicity Environmental chemistry Groundwater Arsenic content Waste Management Water Pollutants, Chemical Umweltverschmutzung (DE-588)4186812-2 gnd Arsenverbindungen (DE-588)4143104-2 gnd Umwelttoxikologie (DE-588)4121813-9 gnd Arsenbelastung (DE-588)4143081-5 gnd Umweltgeochemie (DE-588)4404136-6 gnd Ökologische Chemie (DE-588)4135167-8 gnd Geochemie (DE-588)4020198-3 gnd Toxikologie (DE-588)4060538-3 gnd Arsen (DE-588)4003041-6 gnd |
| subject_GND | (DE-588)4186812-2 (DE-588)4143104-2 (DE-588)4121813-9 (DE-588)4143081-5 (DE-588)4404136-6 (DE-588)4135167-8 (DE-588)4020198-3 (DE-588)4060538-3 (DE-588)4003041-6 |
| title | Arsenic environmental chemistry, health threats and waste treatment |
| title_auth | Arsenic environmental chemistry, health threats and waste treatment |
| title_exact_search | Arsenic environmental chemistry, health threats and waste treatment |
| title_full | Arsenic environmental chemistry, health threats and waste treatment ed. by Kevin Henke |
| title_fullStr | Arsenic environmental chemistry, health threats and waste treatment ed. by Kevin Henke |
| title_full_unstemmed | Arsenic environmental chemistry, health threats and waste treatment ed. by Kevin Henke |
| title_short | Arsenic |
| title_sort | arsenic environmental chemistry health threats and waste treatment |
| title_sub | environmental chemistry, health threats and waste treatment |
| topic | Arsenic Arsenic Poisoning Arsenic wastes Arsenic Toxicology Arsenic chemistry Arsenic toxicity Environmental chemistry Groundwater Arsenic content Waste Management Water Pollutants, Chemical Umweltverschmutzung (DE-588)4186812-2 gnd Arsenverbindungen (DE-588)4143104-2 gnd Umwelttoxikologie (DE-588)4121813-9 gnd Arsenbelastung (DE-588)4143081-5 gnd Umweltgeochemie (DE-588)4404136-6 gnd Ökologische Chemie (DE-588)4135167-8 gnd Geochemie (DE-588)4020198-3 gnd Toxikologie (DE-588)4060538-3 gnd Arsen (DE-588)4003041-6 gnd |
| topic_facet | Arsenic Arsenic Poisoning Arsenic wastes Arsenic Toxicology Arsenic chemistry Arsenic toxicity Environmental chemistry Groundwater Arsenic content Waste Management Water Pollutants, Chemical Umweltverschmutzung Arsenverbindungen Umwelttoxikologie Arsenbelastung Umweltgeochemie Ökologische Chemie Geochemie Toxikologie Arsen |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018600515&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT henkekevinr arsenicenvironmentalchemistryhealththreatsandwastetreatment |