Phosphine, arsine and stibine Complexes of the transition elements:
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | Undetermined |
| Published: |
Amsterdam
Elsevier
1979
|
| Series: | Studies in inorganic chemistry
1 |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XIV, 546 S. |
| ISBN: | 0444417494 |
Staff View
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| 100 | 1 | |a MacAuliffe, Charles A. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Phosphine, arsine and stibine Complexes of the transition elements |c C. A. McAuliffe and W. Levason |
| 264 | 1 | |a Amsterdam |b Elsevier |c 1979 | |
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| 490 | 0 | |a Studies in inorganic chemistry |v 1 | |
| 700 | 1 | |a Levason, William |e Verfasser |4 aut | |
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Record in the Search Index
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| adam_text | Studies in Inorganic Chemistry 1
Phosphine, Arsine and
Stibine Complexes of
Transition Elements
C A McAuliffe
Senior Lecturer in Chemistry
Department of Chemistry
University of Manchester Institute of Science and Technology
P 0 Box 88
Manchester M60 1QD
United Kingdom
Lecturer in Chemistry
Department of Chemistry
University of Southampton
High field, Southampton
United Kingdom
ELSEVIER SCIENTIFIC PUBLISHING COMPANY
and
W Levason
Amsterdam — Oxford — New York 1979
CONTENTS
CHAPTER I LIGAND SYNTHESES 1
1 Introduction 1
2 Precursors 2
2 1 Halogroup VB Compounds, R,EX 2 O o—Ti
2 2 Alkali Metal Derivatives 6
3 Primary and Secondary Phosphines 7
4 Tertiary Phosphines, Arsines, Stibines and Bismuthines 8
5 Diphosphines 9
6 Diarsines 12
7 Distibines 15
8 Mixed Digroup VB Donor Bidentates 16
9 Multidentate Ligands 21
9 1 Multidentate Phosphines 21
9 2 Multidentate Arsines 24
9 3 Mixed Donors 26
931 Nitrogen Containing Multidentate Ligands 27
932 Sulphur and Selenium Containing Multidentate Ligands 28
933 Oxygen Containing Multidentate Ligands 30
934 Group VB-Olefin Ligands 31
935t Completely Hybrid Ligands 32
10 Other Ligands 33
11 A Recent Guide 34
CHAPTER II TRANSITION METAL COMPLEXES - PREPARATIONS AND PROPERTIES 36
1 Syntheses of Complexes 36
11 Metal Halide and Pseudohalide Complexes 36
1 2 Uncoordinated Anions 39
1 3 Metal(O) Complexes with no Other Ligands 40 i14 Other Types of Complex 41
1 5 Primary and Secondary Phosphine Complexes 41
2 Characterisation of the Complexes 41
2 1 Spectroscopic Techniques 43
211 Mass Spectrometry 43
212 Magnetic Susceptibility Measurements 44
213 Infrared and Raman Spectroscopy 45
214 Electronic Spectroscopy 47
215 Nuclear Magnetic Resonance Spectroscopy 50
2151 Proton NMR 50
2152 Phosphorus-31 55
216 Electron Paramagnetic Resonance Spectroscopy 56
X
217 Mossbauer Spectroscopy 57
218 X-Ray Diffraction 66
3 The Nature of the Metal-Phosphorus Bond 66
CHAPTER III COMPLEXES OF MONODENTATE LIGANDS 69
1 Introduction 69
2 Lanthanides and Actinides 72
3 Titanium, Zirconium and Hafnium 72
4 Vanadium, Niobium and Tantalum 73
5 Chromium, Molybdenum and Tungsten 74
5 1 Zerovalent Complexes 74
5 2 Carbonyl Complexes 74
5 3 Carbonyl Halides 82
5 4 Nitrosyls 83
5 5 Hydrides 84
5 6 Dinitrogen Complexes 84
5 7 Halides 85
6 Manganese, Technetium and Rhenium 90
6 1 Manganese Carbonyls 90
6 2 Manganese Halides 95
6 3 Technetium 95
6 4 Rhenium 96
» 641 Carbonyls 96
642 Nitrosyls 97
643 Hydrides 98
644 Dinitrogen Complexes • 98
645 Halides 99
7 Iron, Ruthenium and Osmium 102
7 1 Iron 102
711 Carbonyls 102
712 Nitrosyls 110
713 Hydrides and Dinitrogen Complexes 111
7 2 Ruthenium and Osmiuin 112
721 Carbonyls 112
722 Carbonyl Halides 114
723 Nitrosyls 117
724 Hydrides 120
725 Halides 122
726 Some Recent Important Studies 126
8 Cobalt, -Rhodium and Iridium 127
8 1 Cobalt 127
811 Zerovalent Compounds 127
XI
812 Carbonyls 127
813 Nitrosyls 131
814 Hydrides 132
815 Cobalt(I) 132
815 Cobalt(II) 134
817 Cobalt(III) 136
8 2 Rhodium 137
821 Carbonyls 137
822 Carbonyl Halides 137
823 Nitrosyls 141
824 Hydrido Complexes 142
825 Halides and Related Complexes 144
8 3 Iridium 149
831 Carbonyls 149
832 Hydridocarbonyls 158
833 Nitrosyls 159
834 Hydrides 161
835 Iridium(I) Halides 164
836 Iridium(III) Halides 165
837 Iridium(IV) Complexes 167
9 Nickel, Palladium and Platinum 167
9 1 Nickel 167
911 Carbonyls 167
912 Nickel(O) Complexes 169
913 Nickel Hydrides and Dinitrof;en Complexes 172
914 Nickel(I) 173
915 Nitrosyls 173
916 Nickel(II) 174
9 2 Palladium and Platinum 178
921 Carbonyls 178
922 Zerovalent Compounds 180
923 Hydrides 184
924 Halides 193
925 Cationic Complexes 197
926 Anionic Complexes 197
927 Bridged Complexes 198
928 Palladium(IV) and Platinum([V) 200
10 Copper, Silver and Gold 201
10 1 Copper 201
10 2 Silver 206
10 3 Gold 207
XII
10 4 Zinc, Cadmium and Mercury 209
CHAPTER IV COMPLEXES OF BIDENTATE LIGANDS 212
1 Introduction 212
2 , Lanthanides and Actinides 215
3 Titanium, Zirconium and Hafnium 215
4 Vanadium, Niobium and Tantalum 216
5 Chromium, Molybdenum and Tungsten 219
5 1 Zerovalent Compounds 219
5 2 Carbonyls 224
5 3 Carbonyl Cations and Carbonyl Halides 2 30
5 4 Nitrosyls 235
5 5 Hydrides and Dinitrogen Complexes 236
5 6 Halide Complexes 237
6 Manganese, Technetium and Rhenium 240
6 1 Manganese 240
611 Carbonyls 240
612 Halides 244
6 2 Technetium 245
6 3 Rhenium ^ 245
631 Carbonyls 245
632 Halide Complexes 247
7 Iron, Ruthenium and Osmium 2 50
7 1 Iron 250
711 Carbonyls 250
712 Nitrosyls 253
713 Hydrides • 254
714 Halides 254
7 2 Ruthenium and Osmium 256
8 Cobalt, Rhodium and Iridium 261
8 1 Cobalt 261
811 Carbonyls 261
812 Halide Complexes 264
8121 Cobalt(I) 264
8122 Cobalt(II) 264
8123 Cobalt(III) 269
8 2 Rhodium and Iridium 271
821 Carbonyls 271
822 Halides 273
9 Nickel, Palladium and Platinum 278
9 1 Nickel 278
911 Carbonyls and Nitrosyls 278
912 Nickel(O) 279
XIII
913 Nickel(II) Halide Complexes 279
9 2 Palladium and Platinum 290
921 Metal(O) and Metal(I) Complexes 290
922 Metal(II) Complexes 291
10 Copper, Silver and Gold 302
10 1 Copper 302
10 2 Silver and Gold 306
11 Zinc, Cadmium and Mercury 307
CHAPTER V COMPLEXES OF MULTIDENTATE LIGANDS 310
1 Introduction 310
2 Groups IVA, VA 312
3 Chromium, Molybdenum and Tungsten 312
3 1 Carbonyls 312
3 2 Halides 316
4 Manganese, Technetium and Rhenium 317
4 1 Carbonyls 317
4 2 Halides y 319
5 Iron, Ruthenium and Osmium 320
5 1 Carbonyls 320
5 2 HajLides 322
6 Cobalt, Rhodium and Iridium 324
6 1 Cobalt 324
611 Carbonyls 324
612 Cobalt(I) 325
613 Cobalt(II) 326
614 Cobalt(III) 331
6 2 Rhodium and Iridium 334
621 Carbonyls 334
622 Rhodium(I) and Iridium(I) 335
623 Rhodium(III) and Iridium(III) 338
7 Nickel, Palladium and Platinum 339
7 1 Nickel 339
711 Carbonyls, Nitrosyls 339
712 Nickel(O) and Nickel(I) 339
713 Nickel(II) 341
7 2 Palladium(II) and Platinum(II) 349
8 Copper and Zinc Sub-groups 351
CHAPTER VI PHOSPHITE, PH0SPH0NITE, PH0SPHINITE AND AMINE-PHOSPHINE
COMPLEXES 356
XIV
1 Introduction 356
7: Lanthanides and Actinides 357
3 Titanium, Zirconium and Hafnium 357
4 Vanadium, Niobium and Tantalum 357
5 Chromium, Molybdenum and Tungsten 357
6 Manganese, Technetium and Rhenium 360
6 1 Manganese 360
6 2 Technetium and Rhenium 3E3
7 Iron, Ruthenium and Osmium 364
7 1 Iron 364
7 2 Ruthenium and Osmium 36 7
8 Cobalt, Rhodium and Iridium 369
8 1 Cobalt 369
8:2 Rhodium and Iridium 374
9 Nickel, Palladium and Platinum 376
9 1 Nickel 376
9 2 Palladium and Platinum 379
10 Copper, Silver and Gold; Mercury j 3 82
CHAPTER VII REACTIONS OF COORDINATED G10UP VP LIGANDS 384
1 Introduction 384
2 Reactions of Olefin-Group VB Ligai ds 391
3 Cyclometallation 400
APPENDIX I PH0SPHINE COMPLEXES AND CAT/LYSIS 414
1 Homogeneous Catalysis 414
1 1 Hydrogenation 414
1 2 Hydroformylation 416
1 3 Hydrosilation 417
1 4 Miscellaneous Catalytic Reactions 417
2 Heterogenised Homogeneous Catalysis 418
2 1 Structures 422
22 Catalytic Reactions 423
APPENDIX II REVIEWS 424
APPENDIX III ABBREVIATIONS 426
REFERENCES 427
SUBJECT INDEX 542
|
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| indexdate | 2024-07-09T22:02:06Z |
| institution | BVB |
| isbn | 0444417494 |
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| series2 | Studies in inorganic chemistry |
| spelling | MacAuliffe, Charles A. Verfasser aut Phosphine, arsine and stibine Complexes of the transition elements C. A. McAuliffe and W. Levason Amsterdam Elsevier 1979 XIV, 546 S. txt rdacontent n rdamedia nc rdacarrier Studies in inorganic chemistry 1 Levason, William Verfasser aut HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018537217&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | MacAuliffe, Charles A. Levason, William Phosphine, arsine and stibine Complexes of the transition elements |
| title | Phosphine, arsine and stibine Complexes of the transition elements |
| title_auth | Phosphine, arsine and stibine Complexes of the transition elements |
| title_exact_search | Phosphine, arsine and stibine Complexes of the transition elements |
| title_full | Phosphine, arsine and stibine Complexes of the transition elements C. A. McAuliffe and W. Levason |
| title_fullStr | Phosphine, arsine and stibine Complexes of the transition elements C. A. McAuliffe and W. Levason |
| title_full_unstemmed | Phosphine, arsine and stibine Complexes of the transition elements C. A. McAuliffe and W. Levason |
| title_short | Phosphine, arsine and stibine Complexes of the transition elements |
| title_sort | phosphine arsine and stibine complexes of the transition elements |
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