Linear and stereoregular Addition Polymers:
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| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | Undetermined |
| Published: |
New York
Intersc. Publ.
1959
|
| Series: | Polymer reviews. Vol. 2
|
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | X, 571 S. |
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| 100 | 1 | |a Gaylord, Norman G. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Linear and stereoregular Addition Polymers |c Norman G. Gaylord ; Herman F. Mark |
| 264 | 1 | |a New York |b Intersc. Publ. |c 1959 | |
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| 700 | 1 | |a Mark, Herman F. |d 1895-1992 |e Verfasser |0 (DE-588)118640925 |4 aut | |
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Record in the Search Index
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| adam_text | LINEAR AND
STEREOREGULAR
ADDITION POLYMERS:
POLYMERIZATION WITH
CONTROLLED PROPAGATION
By NORMAN G GAYI ORD
Interchemical Corporation, New York
and HERMAN F MARK
Institute of Polymer Research,
Polytechnic Institute of Brooklyn
Foreword by Giulio Natta
/
GME JN-INSTITl
lii rori i c •: Che e unl Gren?gel
cer •: P ;n *e* st af; zur
lor run; icr V/is e _- har en
Frankvurt/Mair
- • Bibliothek —
INTERSCIENCE PUBLISHERS, INC , NEW YORK
INTERSCIENCE PUBLISHERS LTD , LONDON
CONTENTS
Foreword, by Giulio Natta v
Preface vii
I Introduction 1
II Brief Review of Homogeneous Addition Polymerization Kinetics 7
III Adsorption on Surfaces and Complex Formation 19
A Physical and Chemical Adsorption on Solid Surfaces 19
B Complex Compound Formation and Structure 28
1 Coordination Compounds 28
2 Electron Deficient Complexes 34
IV Requirements for Stereospecific Polymerization 37
V The Structure of Olefin Polymers in the Solid State 45
A Paraffins and Polyethylenes • 45
B General Considerations on Regular Arrangement of Substituents in Vinyl
Polymers 50
C Isotactic and Syndyotactic Polymers 54
D Diene Polymers 66
E Acrylic and Vinyl-Type Polymers 71
VI Solution Properties of Linear Polyethylenes and Isotactic Polymers 75
VII Fluid-Bed -Processes: Ziegler-Type Catalysts 87
A Catalyst Composition and Preparation 90
B Influence of Chemical and Physical Nature of Catalyst and Polymeriza
tion Conditions on Polymer Properties 106
C Polymerization Procedures 146
1 Synthesis and Reactions of Aluminum Alkyls and Related Compounds 146
2 Handling of Aluminum Alkyls 153
3 Polymerization Processes 154
4 Isolation of Polymer 158
D In Situ Catalysis 162
E Nature of the Ziegler-Type Catalyst 168
F Kinetics of Complex Catalyst Polymerization 186
G Copolyin erization 213
H Polymerization of Norbornene 217
I Polymerization of Acetylenic Hydrocarbons 219
VIII Additional Fluid-Bed Polymerization Processes 231
A Alfin-Catalyzed Polymerizations 231
1 Composition of Alfin Catalysts 231
2 Alfin Polymers 233
3 Mechanism of Alfin Polymerization 236
ix
X CONTENTS
B Lithium Metal-Catalyzed Polymerizations • 240
1 Catalyst Preparation and Polymerization 240
2 Monomers and Polymers • 243
3 Mechanism 24 0
C Organolithium-Catalyzed Polymerizations 247
1 Catalyst Preparation and Polymerization 247
2 Monomers and Polymers 250
3 Mechanism 255
D Ionic Polymerization of Vinyl Ethers 256
IX Fixed-Bed Polymerization Processes 261
A Supported Chromium Oxide Catalysts 261
1 Catalyst Composition and Preparation 261
2 Polymerization 265
3 Polymers 269
4 Mechanism of Polymerization 274
B Activated Nickel and Alolybdenum Oxide Catalysts 275
1 Catalyst Composition and Preparation 275
2 Polymerization 289
3 Polymers 294
4 Mechanism of Polymerization 298
X Polymerization of Olefin Oxides 305
XI Physical Properties of Olefin Polymers 319
A Introduction 319
B Density and Transition Phenomena 319
C Mechanical Behavior and Other Important 1 roperties 325
XII Tabulated Patent Examples 326
XIII Miscellaneous Organometallic-Catalyzed Polymerization Systems 461
A Organoboron-Catalyzed Polymerizations 461
B Sodium Naphthalenide-Catalyzed Polymerizations 464
C Grignard Reagent-Catalyzed Polymerizations 466
D Silver Alkyl-Catalyzed Polymerizations 467x
E Lead Tetraethyl-Catalyzed Polymerizations 470
F Organocadmium-Catalyzed Polymerizations 471
Appendix
I Introduction 473
IV Requirements for Stereospecific Polymerization 474
V The Structure of Olefin Polymers in the Solii! State 480
VI Solution Properties of Linear Polyethylenes :!lid Isotactic Polymers 489
VII Fluid-Bed Processes: Ziegler-Type Catalyst - 491
VIII Additional Fluid-Bed Polymerization Processes 513
IX Fixed-Bed Polymerization Processes 526
X Polymerization of Olefin Oxides 527
XI Physical Properties of Olefin Polymers 528
XIII Miscellaneous Organometallic-Catalyzed Polymerization Systems 528
Author Index 535
Subject Index 549
Patent Index 565
|
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| illustrated | Not Illustrated |
| indexdate | 2024-07-09T22:01:41Z |
| institution | BVB |
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| physical | X, 571 S. |
| psigel | TUB-nve |
| publishDate | 1959 |
| publishDateSearch | 1959 |
| publishDateSort | 1959 |
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| series2 | Polymer reviews. Vol. 2 |
| spelling | Gaylord, Norman G. Verfasser aut Linear and stereoregular Addition Polymers Norman G. Gaylord ; Herman F. Mark New York Intersc. Publ. 1959 X, 571 S. txt rdacontent n rdamedia nc rdacarrier Polymer reviews. Vol. 2 Mark, Herman F. 1895-1992 Verfasser (DE-588)118640925 aut HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018514683&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Gaylord, Norman G. Mark, Herman F. 1895-1992 Linear and stereoregular Addition Polymers |
| title | Linear and stereoregular Addition Polymers |
| title_auth | Linear and stereoregular Addition Polymers |
| title_exact_search | Linear and stereoregular Addition Polymers |
| title_full | Linear and stereoregular Addition Polymers Norman G. Gaylord ; Herman F. Mark |
| title_fullStr | Linear and stereoregular Addition Polymers Norman G. Gaylord ; Herman F. Mark |
| title_full_unstemmed | Linear and stereoregular Addition Polymers Norman G. Gaylord ; Herman F. Mark |
| title_short | Linear and stereoregular Addition Polymers |
| title_sort | linear and stereoregular addition polymers |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018514683&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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