Coordination chemistry of aluminium:
Saved in:
| Other Authors: | |
|---|---|
| Format: | Book |
| Language: | Undetermined |
| Published: |
New York, NY <<[u.a.]>>
VCH
1993
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| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XIII, 234 S. graph. Darst. |
| ISBN: | 1560810599 1560816562 3527281495 3527896562 |
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MARC
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| 245 | 1 | 0 | |a Coordination chemistry of aluminium |c ed. Gregory H. Robinson |
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Record in the Search Index
| _version_ | 1804140340685307904 |
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| adam_text | IMAGE 1
CONTENTS
1. NORMAL AND DATIVE BONDING IN NEUTRAL ALUMINUM COMPOUNDS 1
ARNE HAALAND
1.1. INTRODUCTION 1
1.2 NORMAL AND DATIVE BONDS 2
1.3 DATIVE BONDS AND THE VSEPR MODEL 3
1.4 FAILURES OF THE VSEPR MODEL AND GEMINAL REPULSION RADII 4
1.5 SOME MEAN BOND ENTHALPIES 5
1.6 NORMAL BOND DISTANCES IN COMPOUNDS WITH THREE-COORDINATE ALUMINUM 6
1.7 THE DISSOCIATION ENTHALPIES OF SIMPLE ADDUCTS OF ALANES WITH
ELECTRON DONORS 8
1.8 ALUMINUM-NITROGEN COMPOUNDS 10
1.9. ALUMINUM-PHOSPHORUS COMPOUNDS 25
1.10. ALUMINUM-OXYGEN COMPOUNDS 29
1.11. ALUMINUM-SULFUR COMPOUNDS 41
IMAGE 2
1.12. ALUMINUM-HALOGEN COMPOUNDS 44
1.13. CONCLUSIONS 48
ACKNOWLEDGMENTS 50
REFERENCES 51
2. ORGANOAMINOALANES: UNUSUAL AL-N SYSTEMS 57 GREGORY H. ROBINSON
2.1. INTRODUCTION 57
2.2. INTERACTION OF ALUMINUM ALKYLS WITH SIMPLE AMINES: AL-N CAGES 58
2.3. DIMERS, TRIMERS, AND TETRAMERS: ORGANOALUMINUM CHEMISTRY OF
STERICALLY DEMANDING ARYL AMINES 63
2.4. REACTION OF ORGANOALUMINUM MOIETIES WITH MULTIDENTATE OPEN-CHAIN
AMINES: HIGH COORDINATION NUMBER ALUMINUM COMPLEXES 71
2.5. ORGANOALUMINUM CHEMISTRY OF MACROCYCLIC AMINES 76
2.6. CONCLUSIONS 81
ACKNOWLEDGMENTS 82
REFERENCES 82
3. THE AQUEOUS COORDINATION CHEMISTRY OF ALUMINUM 85
CHRIS ORVIG 3.1. INTRODUCTION 85
3.2. REACTION KINETICS 86
3.3. COMPLEXATION IN WATER 89
3.4. SCHIFF BASE COMPLEXES OF ALUMINUM 109
3.5. APPLICATIONS AND IMPLICATIONS 113
ACKNOWLEDGMENTS 116
REFERENCES 116
IMAGE 3
4. LOW VALENT AND PARAMAGNETIC COMPOUNDS OF
ALUMINUM 123
ANDREW R. BARRON
4.1. INTRODUCTION 123
4.2. ALUMINUM-CARBONYL COMPLEXES 125
4.3. UNSATURATED HYDROCARBONS 129 4.3.1. ALKENES 129
4.3.2. ALKYNES 136
4.4. HYDRIDES 138
4.5. ALKYLS 142
4.6. CLUSTERS 147
4.7. PARAMAGNETIC COMPOUNDS OF AL(III) 151
ACKNOWLEDGMENTS 160
REFERENCES 160
5. THE CHEMISTRY OF ALKOXIDES, THIOLATES, AND THE HEAVIER GROUP 16
DERIVATIVES OF ALUMINUM AND GALLIUM 167
JOHN P. OLIVER*, RAJESH KUMAR, MAJID TAGHIOF
5.1 INTRODUCTION 167
5.2. SYNTHESES 168
5.3. STRUCTURE AND BONDING 172
5.4. NMR STUDIES 182
5.5. R N (ER) 3-N AL*BASE ADDITION COMPOUNDS 186
5.6. BIDENTATE AND POLYDENTATE LIGANDS 190
REFERENCES 191
6. ANIONIC AND CATIONIC ORGANOALUMINUM COMPOUNDS 197
JERRY L. ATWOOD
6.1. INTRODUCTION 197
6.2. LIQUID CLATHRATES BASED ON ANIONIC ORGANOALUMINUM 198
IMAGE 4
6.3. ALUMINOXANES 219
6.4. CATIONIC ORGANOALUMINUM COMPLEXES 224
ACKNOWLEDGMENTS 229
REFERENCES 229
INDEX 233
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| any_adam_object | 1 |
| author2 | Robinson, Gregory H. |
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| author_facet | Robinson, Gregory H. |
| building | Verbundindex |
| bvnumber | BV024381496 |
| classification_rvk | VH 9700 |
| ctrlnum | (OCoLC)246516564 (DE-599)BVBBV024381496 |
| discipline | Chemie / Pharmazie |
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| id | DE-604.BV024381496 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T21:58:26Z |
| institution | BVB |
| isbn | 1560810599 1560816562 3527281495 3527896562 |
| language | Undetermined |
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| owner | DE-83 DE-11 DE-188 |
| owner_facet | DE-83 DE-11 DE-188 |
| physical | XIII, 234 S. graph. Darst. |
| publishDate | 1993 |
| publishDateSearch | 1993 |
| publishDateSort | 1993 |
| publisher | VCH |
| record_format | marc |
| spelling | Coordination chemistry of aluminium ed. Gregory H. Robinson New York, NY <<[u.a.]>> VCH 1993 XIII, 234 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Koordination (DE-588)4032393-6 gnd rswk-swf Aluminiumverbindungen (DE-588)4282756-5 gnd rswk-swf Koordinationslehre (DE-588)4133952-6 gnd rswk-swf Aluminiumorganische Verbindungen (DE-588)4305230-7 gnd rswk-swf Aluminium (DE-588)4001573-7 gnd rswk-swf Koordination (DE-588)4032393-6 s DE-604 Aluminium (DE-588)4001573-7 s Aluminiumverbindungen (DE-588)4282756-5 s Aluminiumorganische Verbindungen (DE-588)4305230-7 s Koordinationslehre (DE-588)4133952-6 s DE-188 Robinson, Gregory H. edt OEBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018361284&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Coordination chemistry of aluminium Koordination (DE-588)4032393-6 gnd Aluminiumverbindungen (DE-588)4282756-5 gnd Koordinationslehre (DE-588)4133952-6 gnd Aluminiumorganische Verbindungen (DE-588)4305230-7 gnd Aluminium (DE-588)4001573-7 gnd |
| subject_GND | (DE-588)4032393-6 (DE-588)4282756-5 (DE-588)4133952-6 (DE-588)4305230-7 (DE-588)4001573-7 |
| title | Coordination chemistry of aluminium |
| title_auth | Coordination chemistry of aluminium |
| title_exact_search | Coordination chemistry of aluminium |
| title_full | Coordination chemistry of aluminium ed. Gregory H. Robinson |
| title_fullStr | Coordination chemistry of aluminium ed. Gregory H. Robinson |
| title_full_unstemmed | Coordination chemistry of aluminium ed. Gregory H. Robinson |
| title_short | Coordination chemistry of aluminium |
| title_sort | coordination chemistry of aluminium |
| topic | Koordination (DE-588)4032393-6 gnd Aluminiumverbindungen (DE-588)4282756-5 gnd Koordinationslehre (DE-588)4133952-6 gnd Aluminiumorganische Verbindungen (DE-588)4305230-7 gnd Aluminium (DE-588)4001573-7 gnd |
| topic_facet | Koordination Aluminiumverbindungen Koordinationslehre Aluminiumorganische Verbindungen Aluminium |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018361284&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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