PEM fuel cell modeling and simulation using Matlab:
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| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Amsterdam [u.a.]
Academic Press Elsevier
2008
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Includes bibliographical references and index |
| Physical Description: | VIII, 443 S. Ill. |
| ISBN: | 9780123742599 |
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MARC
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| 264 | 1 | |a Amsterdam [u.a.] |b Academic Press Elsevier |c 2008 | |
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| 650 | 4 | |a Proton exchange membrane fuel cells |x Design and construction | |
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Record in the Search Index
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| adam_text | Titel: PEM fuel cell modeling and simulation using Matlab
Autor: Spiegel, Colleen
Jahr: 2008
Contents
Acknowledgments ix
1. An Introduction to Fuel Cells 1
1.1 Introduction 1
1.2 What Is a Fuel Cell? 2
1.3 Why Do We Need Fuel Cells? 4
1.4 History of Fuel Cells 6
1.5 Mathematical Models in the Literature 8
1.6 Creating Mathematical Models 12
Chapter Summary 13
Problems 14
Bibliography 14
2. Fuel Cell Thermodynamics 15
2.1 Introduction 15
2.2 Enthalpy 16
2.3 Specific Heats 18
2.4 Entropy 27
2.5 Free Energy Change of a Chemical Reaction 33
2.6 Fuel Cell Reversible and Net Output Voltage 44
2.7 Theoretical Fuel Cell Efficiency 44
Chapter Summary 47
Problems 47
Bibliography 47
3. Fuel Cell Electrochemistry 49
3.1 Introduction 49
3.2 Basic Electrokinetics Concepts 49
3.3 Charge Transfer 51
3.4 Activation Polarization for Charge Transfer Reactions 53
3.5 Electrode Kinetics 54
3.6 Voltage Losses 64
vi Contents
3.7 Internal Currents and Crossover Currents 74
Chapter Summary 75
Problems 75
Bibliography 76
4. Fuel Cell Charge Transport 77
4.1 Introduction 77
4.2 Voltage Loss Due to Charge Transport 77
4.3 Electron Conductivity of Metals 88
4.4 Ionic Conductivity of Polymer Electrolytes 89
Chapter Summary 94
Problems 96
Bibliography 96
5. Fuel Cell Mass Transport 97
5.1 Introduction 97
5.2 Fuel Cell Mass Balances 98
5.3 Convective Mass Transport from Flow Channels
to Electrode 108
5.4 Diffusive Mass Transport in Electrodes 110
5.5 Convective Mass Transport in Flow Field Plates 114
5.6 Mass Transport Equations in the Literature 120
Chapter Summary 124
Problems 124
Bibliography 125
6. Heat Transfer 127
6.1 Introduction 127
6.2 Basics of Heat Transfer 128
6.3 Fuel Cell Energy Balances 132
6.4 Fuel Cell Heat Management 156
Chapter Summary 164
Problems 164
Bibliography 165
7. Modeling the Proton Exchange Structure 167
7.1 Introduction 167
7.2 Physical Description of the Proton Exchange Membrane 168
7.3 Types of Models 171
7.4 Proton Exchange Membrane Modeling Example 177
Chapter Summary 192
Problems 193
Bibliography 193
8. Modeling the Gas Diffusion Layers 197
8.1 Introduction 197
8.2 Physical Description of the Gas Diffusion Layer 198
Contents vii
8.3 Basics of Modeling Porous Media 199
8.4 Modes of Transport in Porous Media 202
8.5 Types of Models 210
8.6 GDL Modeling Example 215
Chapter Summary 236
Problems 236
Bibliography 239
9. Modeling the Catalyst Layers 243
9.1 Introduction 243
9.2 Physical Description of the PEM Fuel Cell Catalyst
Layers 245
9.3 General Equations 246
9.4 Types of Models 248
9.5 Heat Transport in the Catalyst Layers 255
Chapter Summary 262
Problems 265
Bibliography 265
10. Modeling the Flow Field Plates 269
10.1 Introduction 269
10.2 Flow Field Plate Materials 271
10.3 Flow Field Design 272
10.4 Channel Shape, Dimensions, and Spacing 275
10.5 Pressure Drop in Flow Channels 276
10.6 Heat Transfer from the Plate Channels to the Gas 283
Chapter Summary 296
Problems 296
Bibliography 297
11. Modeling Micro Fuel Cells 299
11.1 Introduction 299
11.2 Micro PEM Fuel Cells in the Literature 301
11.3 Microfluidics 307
11.4 Flow Rates and Pressures 313
11.5 Bubbles and Particles 314
11.6 Capillary Effects 315
11.7 Single-and Two-Phase Pressure Drop 316
11.8 Velocity in Microchannels 318
Chapter Summary 330
Problems 330
Bibliography 332
12. Modeling Fuel Cell Stacks 335
12.1 Introduction 335
12.2 Fuel Cell Stack Sizing 335
viii Contents
12.3 Number of Cells 337
12.4 Stack Configuration 338
12.5 Distribution of Fuel and Oxidants to the Cells 340
12.6 Stack Clamping 346
Chapter Summary 359
Problems 360
Bibliography 360
13. Fuel Cell System Design 365
13.1 Introduction 365
13.2 Fuel Subsystem 366
Chapter Summary 390
Problems 390
Bibliography 391
14. Model Validation 393
14.1 Introduction 393
14.2 Residuals 393
14.3 Normal Distribution of Normal Random Errors 398
14.4 Missing Terms in the Functional Part of the Model 401
14.5 Unnecessary Terms in the Model 405
Chapter Summary 407
Problems 408
Bibliography 408
Appendix A 409
Appendix  411
Appendix C 413
Appendix D 415
Appendix Å 417
Appendix F 419
Appendix G 427
Appendix H 429
Appendix I 431
Appendix J 433
Index 435
|
| adam_txt |
Titel: PEM fuel cell modeling and simulation using Matlab
Autor: Spiegel, Colleen
Jahr: 2008
Contents
Acknowledgments ix
1. An Introduction to Fuel Cells 1
1.1 Introduction 1
1.2 What Is a Fuel Cell? 2
1.3 Why Do We Need Fuel Cells? 4
1.4 History of Fuel Cells 6
1.5 Mathematical Models in the Literature 8
1.6 Creating Mathematical Models 12
Chapter Summary 13
Problems 14
Bibliography 14
2. Fuel Cell Thermodynamics 15
2.1 Introduction 15
2.2 Enthalpy 16
2.3 Specific Heats 18
2.4 Entropy 27
2.5 Free Energy Change of a Chemical Reaction 33
2.6 Fuel Cell Reversible and Net Output Voltage 44
2.7 Theoretical Fuel Cell Efficiency 44
Chapter Summary 47
Problems 47
Bibliography 47
3. Fuel Cell Electrochemistry 49
3.1 Introduction 49
3.2 Basic Electrokinetics Concepts 49
3.3 Charge Transfer 51
3.4 Activation Polarization for Charge Transfer Reactions 53
3.5 Electrode Kinetics 54
3.6 Voltage Losses 64
vi Contents
3.7 Internal Currents and Crossover Currents 74
Chapter Summary 75
Problems 75
Bibliography 76
4. Fuel Cell Charge Transport 77
4.1 Introduction 77
4.2 Voltage Loss Due to Charge Transport 77
4.3 Electron Conductivity of Metals 88
4.4 Ionic Conductivity of Polymer Electrolytes 89
Chapter Summary 94
Problems 96
Bibliography 96
5. Fuel Cell Mass Transport 97
5.1 Introduction 97
5.2 Fuel Cell Mass Balances 98
5.3 Convective Mass Transport from Flow Channels
to Electrode 108
5.4 Diffusive Mass Transport in Electrodes 110
5.5 Convective Mass Transport in Flow Field Plates 114
5.6 Mass Transport Equations in the Literature 120
Chapter Summary 124
Problems 124
Bibliography 125
6. Heat Transfer 127
6.1 Introduction 127
6.2 Basics of Heat Transfer 128
6.3 Fuel Cell Energy Balances 132
6.4 Fuel Cell Heat Management 156
Chapter Summary 164
Problems 164
Bibliography 165
7. Modeling the Proton Exchange Structure 167
7.1 Introduction 167
7.2 Physical Description of the Proton Exchange Membrane 168
7.3 Types of Models 171
7.4 Proton Exchange Membrane Modeling Example 177
Chapter Summary 192
Problems 193
Bibliography 193
8. Modeling the Gas Diffusion Layers 197
8.1 Introduction 197
8.2 Physical Description of the Gas Diffusion Layer 198
Contents vii
8.3 Basics of Modeling Porous Media 199
8.4 Modes of Transport in Porous Media 202
8.5 Types of Models 210
8.6 GDL Modeling Example 215
Chapter Summary 236
Problems 236
Bibliography 239
9. Modeling the Catalyst Layers 243
9.1 Introduction 243
9.2 Physical Description of the PEM Fuel Cell Catalyst
Layers 245
9.3 General Equations 246
9.4 Types of Models 248
9.5 Heat Transport in the Catalyst Layers 255
Chapter Summary 262
Problems 265
Bibliography 265
10. Modeling the Flow Field Plates 269
10.1 Introduction 269
10.2 Flow Field Plate Materials 271
10.3 Flow Field Design 272
10.4 Channel Shape, Dimensions, and Spacing 275
10.5 Pressure Drop in Flow Channels 276
10.6 Heat Transfer from the Plate Channels to the Gas 283
Chapter Summary 296
Problems 296
Bibliography 297
11. Modeling Micro Fuel Cells 299
11.1 Introduction 299
11.2 Micro PEM Fuel Cells in the Literature 301
11.3 Microfluidics 307
11.4 Flow Rates and Pressures 313
11.5 Bubbles and Particles 314
11.6 Capillary Effects 315
11.7 Single-and Two-Phase Pressure Drop 316
11.8 Velocity in Microchannels 318
Chapter Summary 330
Problems 330
Bibliography 332
12. Modeling Fuel Cell Stacks 335
12.1 Introduction 335
12.2 Fuel Cell Stack Sizing 335
viii Contents
12.3 Number of Cells 337
12.4 Stack Configuration 338
12.5 Distribution of Fuel and Oxidants to the Cells 340
12.6 Stack Clamping 346
Chapter Summary 359
Problems 360
Bibliography 360
13. Fuel Cell System Design 365
13.1 Introduction 365
13.2 Fuel Subsystem 366
Chapter Summary 390
Problems 390
Bibliography 391
14. Model Validation 393
14.1 Introduction 393
14.2 Residuals 393
14.3 Normal Distribution of Normal Random Errors 398
14.4 Missing Terms in the Functional Part of the Model 401
14.5 Unnecessary Terms in the Model 405
Chapter Summary 407
Problems 408
Bibliography 408
Appendix A 409
Appendix  411
Appendix C 413
Appendix D 415
Appendix Å 417
Appendix F 419
Appendix G 427
Appendix H 429
Appendix I 431
Appendix J 433
Index 435 |
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| spelling | Spiegel, Colleen Verfasser aut PEM fuel cell modeling and simulation using Matlab Colleen Spiegel Amsterdam [u.a.] Academic Press Elsevier 2008 VIII, 443 S. Ill. txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and index MATLAB Yakıt pilleri - Tasarım ve konstrüksiyon Proton exchange membrane fuel cells Design and construction Proton exchange membrane fuel cells Computer simulation Fuel cells Design and construction MATLAB (DE-588)4329066-8 gnd rswk-swf Brennstoffzelle (DE-588)4008195-3 gnd rswk-swf MATLAB (DE-588)4329066-8 s DE-604 Brennstoffzelle (DE-588)4008195-3 s HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016584881&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Spiegel, Colleen PEM fuel cell modeling and simulation using Matlab MATLAB Yakıt pilleri - Tasarım ve konstrüksiyon Proton exchange membrane fuel cells Design and construction Proton exchange membrane fuel cells Computer simulation Fuel cells Design and construction MATLAB (DE-588)4329066-8 gnd Brennstoffzelle (DE-588)4008195-3 gnd |
| subject_GND | (DE-588)4329066-8 (DE-588)4008195-3 |
| title | PEM fuel cell modeling and simulation using Matlab |
| title_auth | PEM fuel cell modeling and simulation using Matlab |
| title_exact_search | PEM fuel cell modeling and simulation using Matlab |
| title_exact_search_txtP | PEM fuel cell modeling and simulation using Matlab |
| title_full | PEM fuel cell modeling and simulation using Matlab Colleen Spiegel |
| title_fullStr | PEM fuel cell modeling and simulation using Matlab Colleen Spiegel |
| title_full_unstemmed | PEM fuel cell modeling and simulation using Matlab Colleen Spiegel |
| title_short | PEM fuel cell modeling and simulation using Matlab |
| title_sort | pem fuel cell modeling and simulation using matlab |
| topic | MATLAB Yakıt pilleri - Tasarım ve konstrüksiyon Proton exchange membrane fuel cells Design and construction Proton exchange membrane fuel cells Computer simulation Fuel cells Design and construction MATLAB (DE-588)4329066-8 gnd Brennstoffzelle (DE-588)4008195-3 gnd |
| topic_facet | MATLAB Yakıt pilleri - Tasarım ve konstrüksiyon Proton exchange membrane fuel cells Design and construction Proton exchange membrane fuel cells Computer simulation Fuel cells Design and construction Brennstoffzelle |
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