Introduction to biopolymer physics:
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| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
New Jersey [u.a.]
World Scientific
2008
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Includes bibliographical references (p. 235-241) and index |
| Physical Description: | XI, 247 S. Ill., graph. Darst. 24 cm |
| ISBN: | 9789812776037 9812776036 9789812776044 9812776044 |
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| 100 | 1 | |a Maarel, Johan R. C. van der |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Introduction to biopolymer physics |c Johan R. C. van der Maarel |
| 264 | 1 | |a New Jersey [u.a.] |b World Scientific |c 2008 | |
| 300 | |a XI, 247 S. |b Ill., graph. Darst. |c 24 cm | ||
| 336 | |b txt |2 rdacontent | ||
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| 500 | |a Includes bibliographical references (p. 235-241) and index | ||
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Record in the Search Index
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|---|---|
| adam_text | CONTENTS
Préface vii
CHAPTER 1 BlOPOLYMERS 1
1.1 Introduction 1
1.2 Primary structures 4
1.2.1 Nucleic acid primary structure 4
1.2.2 Protein primary structure 6
1.2.3 Polysaccharide primary structures 9
1.3 Secondary structures 11
1.3.1 Secondary structures of nucleic acids 11
1.3.2 Secondary structures of proteins 14
1.3.3 Secondary structures ofpolysaccharides 17
1.4 Tertiary structure and stabilizing interactions 17
1.5 Questions 20
CHAPTER2 POLYMER CONFORMATION 23
2.1 The idéal chain 23
2.2 The Kuhn chain 26
2.3 The worm-like chain 27
2.4 Excluded volume interactions 32
2.5 Confinement in a tube; introduction to scaling 34
2.6 Deflection in a narrow tube 36
2.7 Stars and radial brushes 38
2.8 Chains under traction 39
2.8.1 An idéal chain under small tension 40
2.8.2 Worm-like chain 40
2.8.3 Swollen chain 42
2.9 From the dilute to the semi-dilute régime 45
2.10 Chain statistics in the semi-dilute régime 49
2.11 Questions 51
ix
x Contents
CHAPTER3 POLYELECTROLYTES 55
3.1 Counterion condensation
3.2 The electrostatic potential
3.3 Non-linear Poisson-Boltzmann theory °°
3.3.1 Polyelectrolytes in excess sait «6
3.3.2 Charge distribution in the cell model 69
3.4 The electrostatic persistence length °
3.5 Electrostatic excluded volume °u
3.6 Flexible chains and electrostatic blobs °
3.7 Spherical polyelectrolyte brushes °
3.7.1 Spherical polyelectrolyte brush without sait 90
3.7.2 Salted spherical polyelectrolyte brush 94
3.8 Polyelectrolytes in the semi-dilute régime 99
3.8.1 Salt-free polyelectrolytes; a hierarchyof blobs 99
3.8.2 Salted polyelectrolytes 101
3.9 Questions 103
CHAPTER 4 POLYMER DYNAMICS 1 ° 5
4.1 Single chain dynamics 105
4.2 Pulling a chain into a hole 111
4.3 Dynamics of non-entangled chains in the semi-dilute régime 114
4.4 Entangled polymer dynamics; reptation 117
4.5 Dynamic scaling of polyelectrolytes 121
4.5.1 Polyelectrolytes without sait 121
4.5.2 Salted polyelectrolytes 124
4.5.3 Comparison with expérimental results 126
4.6 Gel electrophoresis 131
4.7 Questions 134
CHAPTER5 HlGHERORDER STRUCTURES AND THEIR TRANSITIONS 137
5.1 Supercoiled DNA 137
5.1.1 Topology 138
5.1.2 Molecular free energy 142
5.1.3 Long-range structure and branching 151
5.2 Alternate secondary DNA structures 155
5.2.1 B-Z transition j 55
5.2.2 Cruciforms J59
5.3 Helix-coil transition j^l
5.4 Protein folding jgy
5.5 Questions ,-,j
Contents xi
Chapter.6 Mesoscopic structures 175
6.1 Lyotropic liquid crystals 175
6.1.1 Virialtheory 177
6.1.2 Liquid crystalline orientation order 182
6.1.3 Isotropic-anisotropic phase coexistence 185
6.2 Hexagonal packingofDNA 190
6.2.1 Undulation enhanced electrostatic interaction 192
6.2.1 Meltingofthe hexagonal phase 196
6.2.2 DNA équation of state 198
6.3 Bacteriophage DNA packaging 201
6.4 Crowding and entropy driven interactions (depletion) 208
6.4.1 Entropie colloidal interactions in solutions of macromolecules 210
6.4.2 Phase séparation ofsmall particles in a polymer solution 215
6.5 Questions 220
AppendixA: Poisson-Boltzmann theory fora monovalent salt 223
appendix b : summary of scaling laws 227
Appendix C : List of important symbols 229
Recommended reading 233
references 235
Index 243
|
| adam_txt |
CONTENTS
Préface vii
CHAPTER 1 BlOPOLYMERS 1
1.1 Introduction 1
1.2 Primary structures 4
1.2.1 Nucleic acid primary structure 4
1.2.2 Protein primary structure 6
1.2.3 Polysaccharide primary structures 9
1.3 Secondary structures 11
1.3.1 Secondary structures of nucleic acids 11
1.3.2 Secondary structures of proteins 14
1.3.3 Secondary structures ofpolysaccharides 17
1.4 Tertiary structure and stabilizing interactions 17
1.5 Questions 20
CHAPTER2 POLYMER CONFORMATION 23
2.1 The idéal chain 23
2.2 The Kuhn chain 26
2.3 The worm-like chain 27
2.4 Excluded volume interactions 32
2.5 Confinement in a tube; introduction to scaling 34
2.6 Deflection in a narrow tube 36
2.7 Stars and radial brushes 38
2.8 Chains under traction 39
2.8.1 An idéal chain under small tension 40
2.8.2 Worm-like chain 40
2.8.3 Swollen chain 42
2.9 From the dilute to the semi-dilute régime 45
2.10 Chain statistics in the semi-dilute régime 49
2.11 Questions 51
ix
x Contents
CHAPTER3 POLYELECTROLYTES 55
3.1 Counterion condensation
3.2 The electrostatic potential
3.3 Non-linear Poisson-Boltzmann theory °°
3.3.1 Polyelectrolytes in excess sait «6
3.3.2 Charge distribution in the cell model 69
3.4 The electrostatic persistence length '°
3.5 Electrostatic excluded volume °u
3.6 Flexible chains and electrostatic blobs °'
3.7 Spherical polyelectrolyte brushes °'
3.7.1 Spherical polyelectrolyte brush without sait 90
3.7.2 Salted spherical polyelectrolyte brush 94
3.8 Polyelectrolytes in the semi-dilute régime 99
3.8.1 Salt-free polyelectrolytes; a hierarchyof blobs 99
3.8.2 Salted polyelectrolytes 101
3.9 Questions 103
CHAPTER 4 POLYMER DYNAMICS 1 ° 5
4.1 Single chain dynamics 105
4.2 Pulling a chain into a hole 111
4.3 Dynamics of non-entangled chains in the semi-dilute régime 114
4.4 Entangled polymer dynamics; reptation 117
4.5 Dynamic scaling of polyelectrolytes 121
4.5.1 Polyelectrolytes without sait 121
4.5.2 Salted polyelectrolytes 124
4.5.3 Comparison with expérimental results 126
4.6 Gel electrophoresis 131
4.7 Questions 134
CHAPTER5 HlGHERORDER STRUCTURES AND THEIR TRANSITIONS 137
5.1 Supercoiled DNA 137
5.1.1 Topology 138
5.1.2 Molecular free energy 142
5.1.3 Long-range structure and branching 151
5.2 Alternate secondary DNA structures 155
5.2.1 B-Z transition j 55
5.2.2 Cruciforms J59
5.3 Helix-coil transition j^l
5.4 Protein folding jgy
5.5 Questions ,-,j
Contents xi
Chapter.6 Mesoscopic structures 175
6.1 Lyotropic liquid crystals 175
6.1.1 Virialtheory 177
6.1.2 Liquid crystalline orientation order 182
6.1.3 Isotropic-anisotropic phase coexistence 185
6.2 Hexagonal packingofDNA 190
6.2.1 Undulation enhanced electrostatic interaction 192
6.2.1 Meltingofthe hexagonal phase 196
6.2.2 DNA équation of state 198
6.3 Bacteriophage DNA packaging 201
6.4 Crowding and entropy driven interactions (depletion) 208
6.4.1 Entropie colloidal interactions in solutions of macromolecules 210
6.4.2 Phase séparation ofsmall particles in a polymer solution 215
6.5 Questions 220
AppendixA: Poisson-Boltzmann theory fora monovalent salt 223
appendix b : summary of scaling laws 227
Appendix C : List of important symbols 229
Recommended reading 233
references 235
Index 243 |
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| isbn | 9789812776037 9812776036 9789812776044 9812776044 |
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| spelling | Maarel, Johan R. C. van der Verfasser aut Introduction to biopolymer physics Johan R. C. van der Maarel New Jersey [u.a.] World Scientific 2008 XI, 247 S. Ill., graph. Darst. 24 cm txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references (p. 235-241) and index Biopolymers Proteins DNA Biopolymere (DE-588)4006893-6 gnd rswk-swf Biopolymere (DE-588)4006893-6 s DE-604 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016531418&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Maarel, Johan R. C. van der Introduction to biopolymer physics Biopolymers Proteins DNA Biopolymere (DE-588)4006893-6 gnd |
| subject_GND | (DE-588)4006893-6 |
| title | Introduction to biopolymer physics |
| title_auth | Introduction to biopolymer physics |
| title_exact_search | Introduction to biopolymer physics |
| title_exact_search_txtP | Introduction to biopolymer physics |
| title_full | Introduction to biopolymer physics Johan R. C. van der Maarel |
| title_fullStr | Introduction to biopolymer physics Johan R. C. van der Maarel |
| title_full_unstemmed | Introduction to biopolymer physics Johan R. C. van der Maarel |
| title_short | Introduction to biopolymer physics |
| title_sort | introduction to biopolymer physics |
| topic | Biopolymers Proteins DNA Biopolymere (DE-588)4006893-6 gnd |
| topic_facet | Biopolymers Proteins DNA Biopolymere |
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