Molecular spectroscopy:
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Oxford [u.a.]
Oxford University Press
2003
|
| Edition: | Reprinted |
| Series: | Oxford chemistry primers
55 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Includes bibliographical references |
| Physical Description: | VI, 89 S. graph. Darst. |
| ISBN: | 019855785X |
Staff View
MARC
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Record in the Search Index
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|---|---|
| adam_text | Contents
1 Radiation and matter 1
1.1
Introduction
1
1.2
The basic
spectroscopie experiment
1
1.3
Electromagnetic radiation
2
1.4
The interaction between radiation and matter
3
1.5
Relative energy units in spectroscopy
4
2
Quantization and molecular energy levels
6
2.1
Introduction
6
2.2
The
Schrödinger
equation
6
2.3
Molecular wavefunctions: Bom-Oppenheimer
separation
8
2.4 Pauli
exclusion principle: nuclear statistical weights
10
3
Transition probabilities and selection rules
14
3.1
Spectroscopie
transitions
14
3.2
Radiative relaxation; Einstein A and
В
coefficients
15
3.3
Absorption coefficients
17
3.4
Spectroscopie
selection rules and intensities
17
4
Rotational spectroscopy
21
4.1
Introduction
21
4.2
The rotational Hamiltonian: eigenvalues and
eigenvectors
21
4.3
Rotational wavefunctions, form and symmetry
23
4.4
Selection rules and the rotational spectrum
24
4.5
Centrifugal distortion
26
4.6
Determination of bond lengths; vibrational averaging
28
4.7
The Stark effect: molecules in electric fields
29
5
Vibrational spectroscopy
32
5.1
Introduction
32
5.2
The simple harmonic oscillator: reduction to
one-body form
34
5.3
Eigenvalues and eigenfunctions of the simple
harmonic oscillator
35
5.4
The quantum harmonic oscillator: non-classical
behaviour
38
5.5
Vibrational selection rules and spectrum of
the simple harmonic oscillator
39
5.6
The anharmonic oscillator
40
5.7
Energy levels of the vibrating rotator
42
5.8
The vibration-rotation spectrum
45
vi
Contents
6
Raman spectroscopy
50
6.1
Introduction
50
6.2
The nature of the interaction in Raman scattering:
selection rules
51
6.3
Rotational Raman spectroscopy
53
6.4
Vibrational Raman spectrum
55
7
Electronic spectroscopy
57
7.1
Introduction
57
7.2
Description of electronic states
57
7.3
The vibrational and rotational structure of electronic states
68
7.4
Transitions in electronic spectroscopy: selection rules
69
7.5
The vibrational (band) structure of an electronic
spectrum
70
7.6
Dissociation and predissociation
74
8
Photoelectron spectroscopy
78
8.1
Introduction
78
8.2
Principles of photoelectron spectroscopy
79
8.3
Examples of a photoelectron spectrum: molecular nitrogen
83
8.4
Autoionization
84
8.5
Zero kinetic energy
(ZEKE)
spectroscopy
85
Bibliography
87
Index
88
|
| adam_txt |
Contents
1 Radiation and matter 1
1.1
Introduction
1
1.2
The basic
spectroscopie experiment
1
1.3
Electromagnetic radiation
2
1.4
The interaction between radiation and matter
3
1.5
Relative energy units in spectroscopy
4
2
Quantization and molecular energy levels
6
2.1
Introduction
6
2.2
The
Schrödinger
equation
6
2.3
Molecular wavefunctions: Bom-Oppenheimer
separation
8
2.4 Pauli
exclusion principle: nuclear statistical weights
10
3
Transition probabilities and selection rules
14
3.1
Spectroscopie
transitions
14
3.2
Radiative relaxation; Einstein A and
В
coefficients
15
3.3
Absorption coefficients
17
3.4
Spectroscopie
selection rules and intensities
17
4
Rotational spectroscopy
21
4.1
Introduction
21
4.2
The rotational Hamiltonian: eigenvalues and
eigenvectors
21
4.3
Rotational wavefunctions, form and symmetry
23
4.4
Selection rules and the rotational spectrum
24
4.5
Centrifugal distortion
26
4.6
Determination of bond lengths; vibrational averaging
28
4.7
The Stark effect: molecules in electric fields
29
5
Vibrational spectroscopy
32
5.1
Introduction
32
5.2
The simple harmonic oscillator: reduction to
one-body form
34
5.3
Eigenvalues and eigenfunctions of the simple
harmonic oscillator
35
5.4
The quantum harmonic oscillator: non-classical
behaviour
38
5.5
Vibrational selection rules and spectrum of
the simple harmonic oscillator
39
5.6
The anharmonic oscillator
40
5.7
Energy levels of the vibrating rotator
42
5.8
The vibration-rotation spectrum
45
vi
Contents
6
Raman spectroscopy
50
6.1
Introduction
50
6.2
The nature of the interaction in Raman scattering:
selection rules
51
6.3
Rotational Raman spectroscopy
53
6.4
Vibrational Raman spectrum
55
7
Electronic spectroscopy
57
7.1
Introduction
57
7.2
Description of electronic states
57
7.3
The vibrational and rotational structure of electronic states
68
7.4
Transitions in electronic spectroscopy: selection rules
69
7.5
The vibrational (band) structure of an electronic
spectrum
70
7.6
Dissociation and predissociation
74
8
Photoelectron spectroscopy
78
8.1
Introduction
78
8.2
Principles of photoelectron spectroscopy
79
8.3
Examples of a photoelectron spectrum: molecular nitrogen
83
8.4
Autoionization
84
8.5
Zero kinetic energy
(ZEKE)
spectroscopy
85
Bibliography
87
Index
88 |
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| illustrated | Illustrated |
| index_date | 2024-07-02T20:28:49Z |
| indexdate | 2024-07-09T21:14:11Z |
| institution | BVB |
| isbn | 019855785X |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-016438656 |
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| physical | VI, 89 S. graph. Darst. |
| publishDate | 2003 |
| publishDateSearch | 2003 |
| publishDateSort | 2003 |
| publisher | Oxford University Press |
| record_format | marc |
| series | Oxford chemistry primers |
| series2 | Oxford chemistry primers |
| spelling | Brown, John M. 1939- Verfasser (DE-588)121025543 aut Molecular spectroscopy John M. Brown Reprinted Oxford [u.a.] Oxford University Press 2003 VI, 89 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Oxford chemistry primers 55 Includes bibliographical references Molecular spectroscopy blmsh Molecular spectroscopy Molekülspektroskopie (DE-588)4128850-6 gnd rswk-swf (DE-588)4151278-9 Einführung gnd-content Molekülspektroskopie (DE-588)4128850-6 s DE-604 Oxford chemistry primers 55 (DE-604)BV004805910 55 Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016438656&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Brown, John M. 1939- Molecular spectroscopy Oxford chemistry primers Molecular spectroscopy blmsh Molecular spectroscopy Molekülspektroskopie (DE-588)4128850-6 gnd |
| subject_GND | (DE-588)4128850-6 (DE-588)4151278-9 |
| title | Molecular spectroscopy |
| title_auth | Molecular spectroscopy |
| title_exact_search | Molecular spectroscopy |
| title_exact_search_txtP | Molecular spectroscopy |
| title_full | Molecular spectroscopy John M. Brown |
| title_fullStr | Molecular spectroscopy John M. Brown |
| title_full_unstemmed | Molecular spectroscopy John M. Brown |
| title_short | Molecular spectroscopy |
| title_sort | molecular spectroscopy |
| topic | Molecular spectroscopy blmsh Molecular spectroscopy Molekülspektroskopie (DE-588)4128850-6 gnd |
| topic_facet | Molecular spectroscopy Molekülspektroskopie Einführung |
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