Modern colorants: synthesis and structures
Saved in:
| Format: | Book |
|---|---|
| Language: | English |
| Published: |
London [u.a.]
Blackie Academic & Professional
1995
|
| Series: | Advances in color chemistry series
3 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XII, 245 S. graph. Darst. |
| ISBN: | 0751402095 |
Staff View
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| adam_text | ADVANCES IN COLOR CHEMISTRY SERIES - VOLUME 3 MODERN COLORANTS:
SYNTHESIS AND STRUCTURE EDITED BY A. T. PETERS CHEMISTRY AND CHEMICAL
TECHNOLOGY UNIVERSITY OF BRADFORD UK AND H. S. FREEMAN DEPARTMENT OF
TEXTILE ENGINEERING, CHEMISTRY & SCIENCE NORTH CAROLINA STATE UNIVERSITY
RALEIGH USA M BLACKIE ACADEMIC & PROFESSIONAL AN IMPRINT OF CHAPMAN &
HALL LONDON * GLASGOW * WEINHEIM * NEW YORK * TOKYO * MELBOURNE * MADRAS
! CONTENTS 1 TRANSITION METALS IN DYE SYNTHESIS 1 A. J. KLAUS 1.1
INTRODUCTION 1 1.2 THE PRINCIPLE OF CYCLOMETALLATION 2 1.3 SYNTHESES OF
METALLACYCLES 4 1.3.1 DIRECT CYCLOMETALLATION 4 1.3.2 TRANSMETALLATION 9
1.3.3 LIGAND EXCHANGE 9 1.4 CLEAVAGE OF THE METAL-CARBON CR-BOND:
PREPARATIVE APPLICATIONS 11 1.4.1 HALOGENATIONS 11 1.4.2 REACTIONS WITH
HYDROXIDE, ALKOXIDES AND ARYLOXIDES 13 1.4.3 REACTIONS WITH ALKYNES 15
1.4.4 REACTIONS WITH ALKENES OR ALKENONES 16 1.4.5 REACTIONS WITH C=0 16
1.4.6 REACTIONS WITH ISONITRILES 20 1.4.7 REACTIONS WITH CYANIDE 22
1.4.8 REACTIONS WITH THIOCYANOGEN 22 1.4.9 REACTIONS WITH SODIUM AMIDE
23 1.4.10 REACTIONS WITH NITRIC ACID 23 1.4.11 REACTIONS WITH ORGANO-TIN
COMPOUNDS 24 1.4.12 REACTIONS WITH ORGANO-LITHIUM COMPOUNDS OR GRIGNARD
REAGENTS 24 1.4.13 REACTIONS WITH ALKYL HALIDES 25 1.4.14 REACTIONS WITH
ACYL HALIDES 26 1.5 MISCELLANEOUS REACTIONS 27 1.5.1 INTRODUCTION OF A
CARBOXYL GROUP 27 1.5.2 INTRODUCTION OF A SULFONIC ACID GROUP 28 1.5.3
OXIDATION OF CYCLOPALLADATED COMPOUNDS: SYNTHESIS OF NAPHTHOLS AND
NAPHTHOQUINONES 29 1.5.4 SYNTHESIS OIORTHO, ORF/ZO-DIHALOGENATED
ANILINES 29 1.6 CATALYTIC REACTIONS 32 1.7 AMINO-INDAZOLES: PRECURSORS
FOR DIAZONIUM AND COUPLING COMPONENTS 34 1.8 CONCLUSIONS 34
ACKNOWLEDGEMENTS 35 REFERENCES 36 2 APPROACHES TO THE DESIGN AND
SYNTHESIS OF NEAR-INFRARED ABSORBING DYES 40 J. GRIFFITHS 2.1
INTRODUCTION 40 2.2 GENERAL APPROACHES TO INFRARED-ABSORBING SYSTEMS 41
2.3 CYANINE-TYPE CHROMOPHORES 44 2.3.1 INCREASING THE LENGTH OF THE
CONJUGATING BRIDGE 45 2.3.2 INCREASING THE EFFECTIVE ELECTRON-DONOR
STRENGTH OF TERMINAL HETEROCYCLIC RESIDUES 47 2.3.3 MODIFICATION OF THE
CONJUGATING BRIDGE 47 2.4 DONOR-ACCEPTOR CHROMOPHORES 50 2.4.1
INCREASING THE LENGTH OF THE CONJUGATING BRIDGE 51 X MODERN COLORANTS
2.4.2 INCREASING THE ELECTRON-DONATING STRENGTH OF THE DONOR 52 2.4.3
INCREASING THE ELECTRON-WITHDRAWING STRENGTH OF THE ACCEPTOR 54 2.4.4
MODIFICATION WITHIN THE CONJUGATING BRIDGE 54 2.4.5 SOME EXAMPLES OF THE
DESIGN OF INFRARED DONOR - ACCEPTOR SYSTEMS 55 2.5 CONCLUSIONS 61
REFERENCES 61 3 ORGANIC PIGMENTS 63 W. S. CZAJKOWSKI 3.1 INTRODUCTION 63
3.2 AZO PIGMENTS AND LAKES 65 3.2.1 AZO PIGMENTS 65 3.2.2 AZO LAKES 71
3.3 PHTHALOCYANINES 76 3.4 CARBOCYCLIC PIGMENTS 77 3.5 HETEROCYCLIC
PIGMENTS 78 3.5.1 ISOINDOLINES 78 3.5.2 PERYLENES 79 3.5.3 QUINACRIDONES
80 3.5.4 DIKETOPYRROLO-PYRROLES . 80 3.5.5 OTHER HETEROCYCLES 82
ACKNOWLEDGEMENTS 84 REFERENCES 84 4 REACTIVE DYES, ESPECIALLY BIREACTIVE
MOLECULES: STRUCTURE AND SYNTHESIS 87 K. CARR 4.1 INTRODUCTION 87 4.2
MONOFUNCTIONAL AND HOMO BI- OR POLYFUNCTIONAL DYES 89 4.2.1
FLUOROCHLOROPYRIMIDINES 89 4.2.2 PHOSPHONIC ACID DYES 91 4.2.3
BIS-MONOCHLOROTRIAZINE DYES 92 4.2.4 MONOFLUOROTRIAZINYL DYES 97 4.2.5
DYES CONTAINING QUATERNARY AMMONIUM GROUPS 98 4.2.6 MONO- AND
POLYVINYLSULPHONYL DYES 102 4.3 HETERO BI- OR POLYFUNCTIONAL DYES 106
4.3.1 VINYL SULPHONE/HALOTRIAZINE DYES 106 4.4 CONCLUSIONS 119
REFERENCES 121 5 NOVEL CHROMOPHORES 123 A. P. CHORLTON 5.1 INTRODUCTION
123 5.2 PIGMENTS 124 5.2.1 DI-KETO-PYRROLOPYRROLES 124 5.2.2
ISOINDOLINES 126 5.2.3 QUINACRIDONES 129 5.2.4 ANNULENES 130 5.2.5 AZA
POLYCYCLICS 132 5.3 DYESTUFFS 134 5.3.1 1,1-DICYANOBUTADIENES 134 5.3.2
QUINODIMETHANES 136 CONTENTS XI 5.3.3 TRIPHENODIOXAZINES AND RELATED
IMINODIMETHANES 139 5.3.4 MISCELLANEOUS CHROMOPHORES 141 5.4 HIGH
TECHNOLOGY APPLICATIONS 144 5.4.1 DITHIOLENES AND RELATED COMPOUNDS 144
5.4.2 SQUARILIUMS AND CROCONIUMS 145 5.4.3 QUINONES 146 5.4.4
MISCELLANEOUS CHROMOPHORES 147 5.4.5 NOVEL CHROMOPHORES FROM NATURAL
PRODUCTS 148 5.5 FUTURE TRENDS 150 REFERENCES 150 6 DYES FOR DYE
DIFFUSION THERMAL TRANSFER (D2T2) PRINTING 154 R. BRADBURY 6.1
INTRODUCTION 154 6.2 PROPERTIES REQUIRED OF D2T2 DYES 155 6.3 MAJOR DYE
CLASSES EVALUATED FOR USE AS D2T2 DYES 156 6.3.1 ANTHRAQUINONE DYES 156
6.3.2 AZODYES 159 6.3.3 METHINES 166 6.3.4 AZAMETHINES 170 6.3.5
MEROCYANINES 173 6.3.6 QUINOPHTHALONES 174 6.4 CONCLUSIONS 175
REFERENCES 175 7 AMPHIPHILIC DYES 177 E. BARNI, P. SAVARINO AND G.
VISCARDI 7.1 INTRODUCTION 177 7.2 AMPHIPHILIC DYES IN LANGMUIR-BLODGETT
FILMS 180 7.3 SYNTHETIC BILAYERS MEMBRANES 190 7.4 INTERACTIONS OF
AMPHIPHILIC DYES WITH ORGANIZED ASSEMBLIES 194 7.5 PHOTOGRAPHIC
PROCESSES 197 7.6 DYEING PROCESSES 198 7.7 ANALYTICAL AND ENVIRONMENTAL
APPLICATIONS 200 7.8 CONCLUSIONS 202 REFERENCES 203 APPENDIX 204 8
COMPUTER-ASSISTED DYESTUFF DESIGN AND SYNTHESIS 213 R. NAEF 8.1
INTRODUCTION 213 8.2 QUANTUM-THEORETICAL METHODS: SCOPE AND LIMITATIONS
214 8.2.1 HMOMETHOD 214 8.2.2 SEMIEMPIRICAL SCF-CI METHODS 216 8.3
EXAMPLES 217 8.3.1 DICHROIC DYES FOR LIQUID CRYSTALS 217 8.3.2
FLUORESCENT DYES 220 8.3.3 HALOCHROMIC DYES 220 8.3.4 NEAR-INFRARED DYES
223 8.3.5 SENSITIZING DYES 227 8.3.6 SOLVATOCHROMISM 228 8.3.7
TAUTOMERISM 230 XLL MODERN COLORANTS 8.4 SYNTHETIC ASPECTS 232 8.5
FUTURE DEVELOPMENTS 236 REFERENCES 238 INDEX 241
|
| adam_txt |
ADVANCES IN COLOR CHEMISTRY SERIES - VOLUME 3 MODERN COLORANTS:
SYNTHESIS AND STRUCTURE EDITED BY A. T. PETERS CHEMISTRY AND CHEMICAL
TECHNOLOGY UNIVERSITY OF BRADFORD UK AND H. S. FREEMAN DEPARTMENT OF
TEXTILE ENGINEERING, CHEMISTRY & SCIENCE NORTH CAROLINA STATE UNIVERSITY
RALEIGH USA M BLACKIE ACADEMIC & PROFESSIONAL AN IMPRINT OF CHAPMAN &
HALL LONDON * GLASGOW * WEINHEIM * NEW YORK * TOKYO * MELBOURNE * MADRAS
! CONTENTS 1 TRANSITION METALS IN DYE SYNTHESIS 1 A. J. KLAUS 1.1
INTRODUCTION 1 1.2 THE PRINCIPLE OF CYCLOMETALLATION 2 1.3 SYNTHESES OF
METALLACYCLES 4 1.3.1 DIRECT CYCLOMETALLATION 4 1.3.2 TRANSMETALLATION 9
1.3.3 LIGAND EXCHANGE 9 1.4 CLEAVAGE OF THE METAL-CARBON CR-BOND:
PREPARATIVE APPLICATIONS 11 1.4.1 HALOGENATIONS 11 1.4.2 REACTIONS WITH
HYDROXIDE, ALKOXIDES AND ARYLOXIDES 13 1.4.3 REACTIONS WITH ALKYNES 15
1.4.4 REACTIONS WITH ALKENES OR ALKENONES 16 1.4.5 REACTIONS WITH C=0 16
1.4.6 REACTIONS WITH ISONITRILES 20 1.4.7 REACTIONS WITH CYANIDE 22
1.4.8 REACTIONS WITH THIOCYANOGEN 22 1.4.9 REACTIONS WITH SODIUM AMIDE
23 1.4.10 REACTIONS WITH NITRIC ACID 23 1.4.11 REACTIONS WITH ORGANO-TIN
COMPOUNDS 24 1.4.12 REACTIONS WITH ORGANO-LITHIUM COMPOUNDS OR GRIGNARD
REAGENTS 24 1.4.13 REACTIONS WITH ALKYL HALIDES 25 1.4.14 REACTIONS WITH
ACYL HALIDES 26 1.5 MISCELLANEOUS REACTIONS 27 1.5.1 INTRODUCTION OF A
CARBOXYL GROUP 27 1.5.2 INTRODUCTION OF A SULFONIC ACID GROUP 28 1.5.3
OXIDATION OF CYCLOPALLADATED COMPOUNDS: SYNTHESIS OF NAPHTHOLS AND
NAPHTHOQUINONES 29 1.5.4 SYNTHESIS OIORTHO, ORF/ZO-DIHALOGENATED
ANILINES 29 1.6 CATALYTIC REACTIONS 32 1.7 AMINO-INDAZOLES: PRECURSORS
FOR DIAZONIUM AND COUPLING COMPONENTS 34 1.8 CONCLUSIONS 34
ACKNOWLEDGEMENTS 35 REFERENCES 36 2 APPROACHES TO THE DESIGN AND
SYNTHESIS OF NEAR-INFRARED ABSORBING DYES 40 J. GRIFFITHS 2.1
INTRODUCTION 40 2.2 GENERAL APPROACHES TO INFRARED-ABSORBING SYSTEMS 41
2.3 CYANINE-TYPE CHROMOPHORES 44 2.3.1 INCREASING THE LENGTH OF THE
CONJUGATING BRIDGE 45 2.3.2 INCREASING THE EFFECTIVE ELECTRON-DONOR
STRENGTH OF TERMINAL HETEROCYCLIC RESIDUES 47 2.3.3 MODIFICATION OF THE
CONJUGATING BRIDGE 47 2.4 DONOR-ACCEPTOR CHROMOPHORES 50 2.4.1
INCREASING THE LENGTH OF THE CONJUGATING BRIDGE 51 X MODERN COLORANTS
2.4.2 INCREASING THE ELECTRON-DONATING STRENGTH OF THE DONOR 52 2.4.3
INCREASING THE ELECTRON-WITHDRAWING STRENGTH OF THE ACCEPTOR 54 2.4.4
MODIFICATION WITHIN THE CONJUGATING BRIDGE 54 2.4.5 SOME EXAMPLES OF THE
DESIGN OF INFRARED DONOR - ACCEPTOR SYSTEMS 55 2.5 CONCLUSIONS 61
REFERENCES 61 3 ORGANIC PIGMENTS 63 W. S. CZAJKOWSKI 3.1 INTRODUCTION 63
3.2 AZO PIGMENTS AND LAKES 65 3.2.1 AZO PIGMENTS 65 3.2.2 AZO LAKES 71
3.3 PHTHALOCYANINES 76 3.4 CARBOCYCLIC PIGMENTS 77 3.5 HETEROCYCLIC
PIGMENTS 78 3.5.1 ISOINDOLINES 78 3.5.2 PERYLENES 79 3.5.3 QUINACRIDONES
80 3.5.4 DIKETOPYRROLO-PYRROLES . 80 3.5.5 OTHER HETEROCYCLES 82
ACKNOWLEDGEMENTS 84 REFERENCES 84 4 REACTIVE DYES, ESPECIALLY BIREACTIVE
MOLECULES: STRUCTURE AND SYNTHESIS 87 K. CARR 4.1 INTRODUCTION 87 4.2
MONOFUNCTIONAL AND HOMO BI- OR POLYFUNCTIONAL DYES 89 4.2.1
FLUOROCHLOROPYRIMIDINES 89 4.2.2 PHOSPHONIC ACID DYES 91 4.2.3
BIS-MONOCHLOROTRIAZINE DYES 92 4.2.4 MONOFLUOROTRIAZINYL DYES 97 4.2.5
DYES CONTAINING QUATERNARY AMMONIUM GROUPS 98 4.2.6 MONO- AND
POLYVINYLSULPHONYL DYES 102 4.3 HETERO BI- OR POLYFUNCTIONAL DYES 106
4.3.1 VINYL SULPHONE/HALOTRIAZINE DYES 106 4.4 CONCLUSIONS 119
REFERENCES 121 5 NOVEL CHROMOPHORES 123 A. P. CHORLTON 5.1 INTRODUCTION
123 5.2 PIGMENTS 124 5.2.1 DI-KETO-PYRROLOPYRROLES 124 5.2.2
ISOINDOLINES 126 5.2.3 QUINACRIDONES 129 5.2.4 ANNULENES 130 5.2.5 AZA
POLYCYCLICS 132 5.3 DYESTUFFS 134 5.3.1 1,1-DICYANOBUTADIENES 134 5.3.2
QUINODIMETHANES 136 CONTENTS XI 5.3.3 TRIPHENODIOXAZINES AND RELATED
IMINODIMETHANES 139 5.3.4 MISCELLANEOUS CHROMOPHORES 141 5.4 HIGH
TECHNOLOGY APPLICATIONS 144 5.4.1 DITHIOLENES AND RELATED COMPOUNDS 144
5.4.2 SQUARILIUMS AND CROCONIUMS 145 5.4.3 QUINONES 146 5.4.4
MISCELLANEOUS CHROMOPHORES 147 5.4.5 NOVEL CHROMOPHORES FROM NATURAL
PRODUCTS 148 5.5 FUTURE TRENDS 150 REFERENCES 150 6 DYES FOR DYE
DIFFUSION THERMAL TRANSFER (D2T2) PRINTING 154 R. BRADBURY 6.1
INTRODUCTION 154 6.2 PROPERTIES REQUIRED OF D2T2 DYES 155 6.3 MAJOR DYE
CLASSES EVALUATED FOR USE AS D2T2 DYES 156 6.3.1 ANTHRAQUINONE DYES 156
6.3.2 AZODYES 159 6.3.3 METHINES 166 6.3.4 AZAMETHINES 170 6.3.5
MEROCYANINES 173 6.3.6 QUINOPHTHALONES 174 6.4 CONCLUSIONS 175
REFERENCES 175 7 AMPHIPHILIC DYES 177 E. BARNI, P. SAVARINO AND G.
VISCARDI 7.1 INTRODUCTION 177 7.2 AMPHIPHILIC DYES IN LANGMUIR-BLODGETT
FILMS 180 7.3 SYNTHETIC BILAYERS MEMBRANES 190 7.4 INTERACTIONS OF
AMPHIPHILIC DYES WITH ORGANIZED ASSEMBLIES 194 7.5 PHOTOGRAPHIC
PROCESSES 197 7.6 DYEING PROCESSES 198 7.7 ANALYTICAL AND ENVIRONMENTAL
APPLICATIONS 200 7.8 CONCLUSIONS 202 REFERENCES 203 APPENDIX 204 8
COMPUTER-ASSISTED DYESTUFF DESIGN AND SYNTHESIS 213 R. NAEF 8.1
INTRODUCTION 213 8.2 QUANTUM-THEORETICAL METHODS: SCOPE AND LIMITATIONS
214 8.2.1 HMOMETHOD 214 8.2.2 SEMIEMPIRICAL SCF-CI METHODS 216 8.3
EXAMPLES 217 8.3.1 DICHROIC DYES FOR LIQUID CRYSTALS 217 8.3.2
FLUORESCENT DYES 220 8.3.3 HALOCHROMIC DYES 220 8.3.4 NEAR-INFRARED DYES
223 8.3.5 SENSITIZING DYES 227 8.3.6 SOLVATOCHROMISM 228 8.3.7
TAUTOMERISM 230 XLL MODERN COLORANTS 8.4 SYNTHETIC ASPECTS 232 8.5
FUTURE DEVELOPMENTS 236 REFERENCES 238 INDEX 241 |
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| index_date | 2024-07-02T20:25:42Z |
| indexdate | 2024-07-09T21:14:00Z |
| institution | BVB |
| isbn | 0751402095 |
| language | English |
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| series | Advances in color chemistry series |
| series2 | Advances in color chemistry series |
| spelling | Modern colorants synthesis and structures ed. by A. T. Peters and H. S. Freeman London [u.a.] Blackie Academic & Professional 1995 XII, 245 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Advances in color chemistry series 3 Colouring agents Chromoforen gtt Colorants - Chimie ram Colorants - Synthèse ram Drukinkt gtt Kleurstoffen gtt Pigmenten gtt Pigments - Synthèse ram Surfactantia gtt Chemie Dyes and dyeing Chemistry Peters, Anthony T. Sonstige oth Advances in color chemistry series 3 (DE-604)BV010466100 3 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016431238&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Modern colorants synthesis and structures Advances in color chemistry series Colouring agents Chromoforen gtt Colorants - Chimie ram Colorants - Synthèse ram Drukinkt gtt Kleurstoffen gtt Pigmenten gtt Pigments - Synthèse ram Surfactantia gtt Chemie Dyes and dyeing Chemistry |
| title | Modern colorants synthesis and structures |
| title_auth | Modern colorants synthesis and structures |
| title_exact_search | Modern colorants synthesis and structures |
| title_exact_search_txtP | Modern colorants synthesis and structures |
| title_full | Modern colorants synthesis and structures ed. by A. T. Peters and H. S. Freeman |
| title_fullStr | Modern colorants synthesis and structures ed. by A. T. Peters and H. S. Freeman |
| title_full_unstemmed | Modern colorants synthesis and structures ed. by A. T. Peters and H. S. Freeman |
| title_short | Modern colorants |
| title_sort | modern colorants synthesis and structures |
| title_sub | synthesis and structures |
| topic | Colouring agents Chromoforen gtt Colorants - Chimie ram Colorants - Synthèse ram Drukinkt gtt Kleurstoffen gtt Pigmenten gtt Pigments - Synthèse ram Surfactantia gtt Chemie Dyes and dyeing Chemistry |
| topic_facet | Colouring agents Chromoforen Colorants - Chimie Colorants - Synthèse Drukinkt Kleurstoffen Pigmenten Pigments - Synthèse Surfactantia Chemie Dyes and dyeing Chemistry |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016431238&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV010466100 |
| work_keys_str_mv | AT petersanthonyt moderncolorantssynthesisandstructures |