Catalysis by gold:
Gespeichert in:
| Hauptverfasser: | , , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
London
Imperial College Press
2006
|
| Schriftenreihe: | Catalytic science series
6 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XV, 366 S. Ill., graph. Darst. |
| ISBN: | 1860946585 9781860946585 |
Internformat
MARC
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| 020 | |a 1860946585 |c alk. paper |9 1-86094-658-5 | ||
| 020 | |a 9781860946585 |9 978-1-86094-658-5 | ||
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| 035 | |a (DE-599)BVBBV022883237 | ||
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| 100 | 1 | |a Bond, Geoffrey C. |d 1927- |e Verfasser |0 (DE-588)129582212 |4 aut | |
| 245 | 1 | 0 | |a Catalysis by gold |c Geoffrey C. Bond; Catherine Louis; David T. Thompson |
| 264 | 1 | |a London |b Imperial College Press |c 2006 | |
| 300 | |a XV, 366 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 1 | |a Catalytic science series |v 6 | |
| 650 | 4 | |a Catalysis | |
| 650 | 4 | |a Gold | |
| 650 | 4 | |a Metal catalysts | |
| 650 | 0 | 7 | |a Katalyse |0 (DE-588)4029921-1 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Gold |0 (DE-588)4157819-3 |2 gnd |9 rswk-swf |
| 689 | 0 | 0 | |a Katalyse |0 (DE-588)4029921-1 |D s |
| 689 | 0 | 1 | |a Gold |0 (DE-588)4157819-3 |D s |
| 689 | 0 | |5 DE-604 | |
| 700 | 1 | |a Louis, Catherine |e Verfasser |4 aut | |
| 700 | 1 | |a Thompson, David T. |e Verfasser |4 aut | |
| 830 | 0 | |a Catalytic science series |v 6 |w (DE-604)BV013477807 |9 6 | |
| 856 | 4 | 2 | |m OEBV Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016088189&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-016088189 | ||
Datensatz im Suchindex
| _version_ | 1804137147953840128 |
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| adam_text | * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * P R E F A
C E * V I I * C H A P T E R 1 I N T R O D U C T I O N T O
C A T A L Y S I S * 1 * 1.1 T H E P H E N O M E N O N O F C A T
A L Y S I S . . . . . . . . . . 1 * 1.2 T H E A C T I V A T
I O N E N E R G Y O F C A T A L Y S E D R E A C T I O N S
4 * 1 . 3 W A Y S O F U S I N G H E T E R O G E N E O U S
C A T A L Y S T S 6 * 1.4 U N D E R S T A N D I N G C A T A
L Y S E D R E A C T I O N S . 9 * 1.5 T H E C A T A L Y T
I C A C T I V I T I E S O F M E T A L S 1 7 * 1.6 C A T A
L Y S I S I N B I M E T A L L I C S Y S T E M S 19* R E F E
R E N C E S . . . . . . . . . . . . . . . . 21* C H A P T E R 2
T H E P H Y S I C A L A N D C H E M I C A L P R O P E R T
I E S O F G O L D 2 2 * 2.1* I N T R O D U C T I O N . . . .
. . . . . . . . . . . . . . . 22* 2 . 2 * T H E O R I G I N O F
R E L A T I V I S T I C E F F E C T S . . . . . . . . . . . . . 2
3 * 2 . 3 * C O M P A R I S O N S O F T H E C H E M I S T
R Y O F G O L D W I T H T H A T O F T H E * A D J A
C E N T E L E M E N T S . 2 7 * 2.4* T H E A U R O P H I
L I C B O N D . . . . . . . . . . 29* 2.5* P H Y S I C A
L P R O P E R T I E S O F G O L D A N D A D J A C E N T
E L E M E N T S . 29* 2.5.1 B U L K P R O P E R T I E S * .
29* 2 . 5 . 2 T H E S T R U C T U R E O F S I N G L E - C
R Y S T A L S U R F A C E S . * 31* 2.6 B I M E T A L L I C
S Y S T E M S C O N T A I N I N G G O L D 3 3 * R E F E R E
N C E S . . . . . . . . . . 3 5 * C H A P T E R 3 P
H Y S I C A L P R O P E R T I E S A N D C H A R A C T E R I S A
T I O N O F * S M A L L G O L D P A R T I C L E S 3 7 *
3.1* O V E R V I E W . . . 3 7 * 3 . 2 * W A Y S O
F P R E P A R I N G S M A L L P A R T I C L E S O F G O L
D 40* 3 . 2 . 1 I N T R O D U C T I O N * 40* 3 . 2 . 2 G A
S E O U S C L U S T E R S * 41* 3 . 2 . 3 C O L L O I D A L
G O L D . . * 41* 3 . 2 . 4 O T H E R M E T H O D S . *
44* 3 . 3 * T E C H N I Q U E S F O R T H E S T U D Y
O F S M A L L P A R T I C L E S O F G O L D . 46* 3 . 3 .
1 D E T E R M I N A T I O N O F S I Z E A N D S T R U C T
U R E * 46* 3 . 3 . 2 I N V E S T I G A T I O N O F O P T O
E L E C T R O N I C P A R A M E T E R S * 49* 3 . 3 . 3 O T H E
R M E T H O D S . . . . . . . . . . . . * 51* I X X *
CATALYSIS BY GOLD 3.4 VARIATION OF PHYSICAL PROPERTIES WITH SIZE . . . .
. . . . . . 52* 3.4.1* INTRODUCTION..................... 52* 3.4.2*
STRUCTURE OF GASEOUS AND IIGAND-STABILISED CLUSTERS 53* 3.4.3* STRUCTURE
OF SMALL SUPPORTED GOLD PARTICLES .. 53* 3.4.4* OPTOELECTRONIC
PROPERTIES OF CLUSTERS AND SMALL* SUPPORTED PARTICLES . . . . . . . . .
. . 55* 3.5 METAL-SUPPORT INTERACTIONS . . . . . . . . . . . . .* 59*
3.5.1* PARTICLE SHAPE AND BONDING TO SUPPORT .. 59* 3.5.2* INFLUENCE OF
THE SUPPORT ON GOLD PARTICLES 63* 3.5.3 INFLUENCE OF GOLD PARTICLES ON
THE SUPPORT 64* REFERENCES . 65* CHAPTER 4 PREPARATION OF SUPPORTED GOLD
CATALYSTS 72* 4.1 LNTRODUCTION......................... 72* 4.1.1*
PRINCIPLES OF THE PREPARATION METHODS AND DEFINITIONS 72* 4.1.2* GOLD
SPECIATION . 74* 4.1.3* FULMINATING GOLD . . . . . . . . . . . . . . . .
. 75* 4.2 METHODS OI PREPARATION USING GOLD CHLORIDE PRECURSORS 77*
4.2.1* LMPREGNATION . 77* 4.2.2* COPRECIPITATION . 78* 4.2.3*
DEPOSITION-PRECIPITATION . 79* 4.2.4* DEPOSITION-PRECIPITATION WITH UREA
(DPU) 86* 4.2.5* ANION ADSORPTION . 88* 4.2.6* REMOVAL OF CHLORIDE WHEN
USING GOLD CHLORIDE PRECURSORS 89* 4.3 METHODS OF PREPARATION USING
CHLORIDE-FREE GOLD PRECURSORS 89* 4.3.1* IMPREGNATION IN THE AQUEOUS
PHASE 89* 4.3.2* DEPOSITION OF GOLD-PHOSPHINE COMPLEXES . 90* 4.3.3*
DEPOSITION OI OTHER ORGANOGOLD COMPLEXES 91* 4.3.4* CHEMICAL VAPOUR
DEPOSITION . . . . . . . . 92* 4.3.5* CATION EXCHANGE AND ADSORPTION
..... 93* 4.3.6* DEPOSITION OF COLLOIDAL GOLD ONTO SUPPORTS 93* 4.3.7*
DEPOSITION OF DENDRIMER-STABILISED GOLD PARTICLES 95* 4.4 LESS
CONVENTIONAL METHODS . . . .* 95* 4.4.1* SOL-GEL METHOD . . . . . . 95*
4.4.2* PHOTOCHEMICAL DEPOSITION 96* 4.4.3* SONOCHEMICAL TECHNIQUES . 97*
4.4.4* SPRAY TECHNIQUES . . . . . 97* 4.4.5* LOW-ENERGY CLUSTER OR ATOM
BEAM DEPOSITION 98* 4.4.6* DIRECT OXIDATION OF BULK ALLOY . 99* 4.4.7*
SOLVATED METAL ATOM DISPERSION OR IMPREGNATION* (SMAD OR SMAI) . 99* 4.5
PREPARATION OF GOLD CATALYSTS ON SPECIFIC SUPPORTS* 100* 4.5.1* GOLD IN
ZEOLITES . 100* 4.5.2* GOLD IN ORDERED MESOPOROUS SILICA 101* 4.5.3*
GOLD IN TITANOSILICATE ... 103* 4.5.4* GOLD ON CARBON SUPPORTS 104* XI
CONTENTS 4.6 PREPARATION OF SUPPORTED BIMETALLIC CATALYSTS CONTAINING
GOLD . 105* 4.6.1* INTRODUCTION.................... 105* 4.6.2* METHODS
WITHOUT INTERACTION BETWEEN PRECURSORS* IN SOLUTION. . . . . . . . . . .
106* 4.6.2.1* CO-IMPREGNATION . . . . . . 106* 4.6.2.2* CO-ADSORPTION OF
CATIONS . . 106* 4.6.2.3* CO-DEPOSITION-PRECIPITATION 107* 4.6.2.4*
PHOTOREDUCTION . . . . . . . 107* 4.6.3* REDOX METHODS FOR PREPARING
BIMETALLIC CATALYSTS 107* 4.6.4* USE OF ABIMETALLIC PRECURSOR 108*
4.6.4.1* ADSORPTION OF BIMETALLIC MOLECULAR CLUSTERS 108* 4.6.4.2*
DEPOSITION OF BIMETALLIC COLLOIDS 109* 4.6.4.3* DEPOSITION OF
DENDRIMER-STABILISED* BIMETALLIC PARTICLES . . . . . . . . . . . . . . .
110* 4.6.4.4* LOW-ENERGY CLUSTER DEPOSITION. . . . . . . . . 110* 4.7
INFLUENCE OF THE THERMAL TREATMENT ON GOLD PARTICLE SIZE 110* 4.7.1*
NATURE OF THE GAS. . . . . . . . . . . . . . . . . 111* 4.7.2* GAS FLOW
RATE AND SAMPIE WEIGHT . . 111* 4.7.3* EFFECT OF THE TEMPERATURE OF
THERMAL TREATMENT 111* 4.8 EFFECT OF CONDITIONS OF STORAGE ON SIZE OF
GOLD PARTICLES 112* 4.9 CONCLUSION 113* REFERENCES . 113* CHAPTER 5
CHEMISORPTION OF SIMPLE MOLEEULES ON GOLD 121* 5.1 INTRODUCTION:
CHEMISORPTION AND CATALYSIS .* 121* 5.2 INTERACTION OF OXYGEN WITH GOLD
. . . . . .* 122* 5.2.1* INTERACTION WITH GOLD CLUSTERS . . . 122*
5.2.2* CHEMISORPTION OF OXYGEN ON GOLD SURFACES 127* 5.2.3*
FINALE.................... 133* 5.3 CHEMISORPTION OF CARBON MONOXIDE ON
GOLD. . . .* 134* 5.3.1* REACTION OF CARBON MONOXIDE WITH GASEOUS GOLD
CLUSTERS 134* 5.3.2* CHEMISORPTION OF CARBON MONOXIDE ON MASSIVE* GOLD
SURFACES . . . . . . . . . . . . . . . . . . . . . . 136* 5.3.3* THE
BONDING OF CARBON MONOXIDE TO GOLD AND RESULTS OF* DFT CALCULATIONS . .
. . . . . . . . . . . . . . . . 139* 5.3.4* CHEMISORPTION OF CARBON
MONOXIDE ON SUPPORTED* GOLD CATALYSTS . . . . . . . . . . . . . . . . .
. . . 141* 5.4 CHEMISORPTION OF THE OXIDES OF NITROGEN ON GOLD SURFACES
. . .. 149* 5.5 THE CHEMISORPTION OF HYDROGEN AND OF OTHER MOLEEULES ON
GOLD 150* 5.5.1* HYDROGEN................ 150* 5.5.2 OTHER MOLEEULES
153* APPENDIX: INTRODUCTION TO DENSITY FUNCTIONAL THEORY 154*
REFERENCES. . . . . . . . . . . . . . . . . . . . . . . 156* CHAPTER 6
OXIDATION OF CARBON MONOXIDE* 161* 6.1 INTRODUCTION. . . . . . . . . . .
. . . . . . .* . 161* XII* CATALYSIS BY GOLD 6.2* SENSITIVITY OF GOLD
CATALYSTS TOWARDS REACTION CONDITIONS 162* 6.2.1 REPRODUCIBIIITY OF
PREPARATIVE METHOD . 163* 6.2.2 CONDITIONS OF ACTIVATION* . 163* 6.2.3
CONDITIONS OF REACTION AND THE INFLUENCE OF MOISTURE 164* 6.2.4
EXPRESSION OF THE RESULTS .* 167* 6.2.5 KINETICS OF CARBON MONOXIDE
OXIDATION . 167* 6.2.6 DEACTIVATION AND REGENERATION . 170* 6.3*
OXIDATION OF CARBON MONOXIDE ON VARIOUS SUPPORTED* GOLD CATALYSTS . . .
. . . . . . . . . . . . . . . 171* 6.3.1 INTRODUCTION* . 171* 6.3.2
INFLUENCE OF THE NATURE OF THE SUPPORT* 171* 6.3.3 INFLUENCE OF THE
METHOD OF PREPARATION* 175* 6.3.3.1 IRON OXIDES* 176* 6.3.3.2 TITANIA .
. . . . . . . . . . . . . . .* 176* 6.3.3.3 ALUMINA. . . . . . . . . . .
. . . . .* 177* 6.3.3.4 MICROPOROUS AND MESOPOROUS SILICA* 178* 6.3.3.5
ZIRCONIA .* 179* 6.3.3.6 CERIA* 180* 6.3.3.7 MAGNESIA* 182* 6.3.3.8
ACIDIC SUPPORTS.* 183* 6.3.3.9 CONCLUSIONS ...* 184* 6.4* OXIDATION
STATE OF GOLD IN ACTIVE CATALYSTS 185* 6.5* PARTICLE SIZE AND
METAL-SUPPORT INTERACTION 186* 6.6* MECHANISMS OF CARBON MONOXIDE
OXIDATION 189* 6.6.1 INTRODUCTION .* 189* 6.6.2 MECHANISMS ON GOLD
PARTICLE ONLY .* 189* 6.6.3 MECHANISMS INVOLVING THE SUPPORT* 193* 6.7
RETROSPECT AND PROSPECT 197* REFERENCES. . . . . . . . . . . . 198*
CHAPTER 7 THE SELECTIVE OXIDATION OF CARBON MONOXIDE* IN HYDROGEN 204*
7.1* INTRODUCTION: THE NATURE OF THE PROBLEM . 204* 7.1.1 THE CHEMICAL
INDUSTRY S NEED FOR HYDROGEN. 204* 7.1.2 PURE HYDROGEN FOR USE IN FUEL
CELLS . 205* 7.2* THE OXIDATION OF HYDROGEN TO WATER . 206* 7.3*
SELECTIVE OXIDATION OF CARBON MONOXIDE IN HYDROGEN 208* 7.3.1 TOUR
D HORIZON .* 208* 7.3.2 CATALYSIS BY GOLD ON FERRIC OXIDE* 210* 7.3.3
GOLD ON OTHER SUPPORTS* 213* 7.3.4 CONCLUSION 215* REFERENCES . 215*
CHAPTER 8 SELECTIVE OXIDATION* 217* 8.1* INTRODUCTION . . . . . . . . .
. . 217* CONTENTS XIII 8.1.1 A SURVEY OF SELECTIVE OXIDATION . . . . . .
. . . . . . .. 217* 8.1.2 REACTION MECHANISMS AND THE USE OF BIMETALLIC
CATALYSTS 218* 8.2 SELECTIVE OXIDATION OF HYDROCARBONS 220* 8.2.1
OXIDATION OF PROPENE. . . . 220* 8.2.2 OXIDATION OF OTHER ALKENES. 224*
8.2.3 OXIDATION OF CYCLOHEXANE . 225* 8.2.4 OXIDATION OF ALKANES . . . .
226* 8.3 SELECTIVE OXIDATION OF OXYGEN-CONTAINING MOLECULES 226* 8.3.1
LNTRODUCTION......... 226* 8.3.2 OXIDATION OF REDUCING SUGARS . . . . .
. . . 227* 8.3.3 OXIDATION OF OTHER ALDEHYDES . . . . . . . . 229* 8.3.4
OXIDATION OF A C6 POLYHYDRIC ALCOHOL: SORBITOL 229* 8.3.5 OXIDATION OF
DIOLS 230* 8.3.6 OXIDATION OF A TRIOL: GLYCEROL 231* 8.3.7 OXIDATION OF
MONOFUNCTIONAL ALCOHOLS 233* 8.4 SYNTHESIS OF VINYL ACETATE (ETHENYL
ETHANOATE) 23,5 8.5 SYNTHESIS OF HYDROGEN PEROXIDE 237* 8.6 CONCLUSION
238* REFERENCES . 239* CHAPTER 9 REACTIONS INVOLVING HYDROGEN 244* 9.1
LNTRODUCTION: THE INTERACTION OF HYDROGEN WITH GOLD . 244* 9.2 REACTIONS
OF HYDROGEN . . . . . . . . . . . . . . . . . . . . . . . . 245* 9.3
HYDROGENATION OF UNSATURATED MOLECLILES AND RELATED REACTIONS 248* 9.3.1
THE CARBON-CARBON DOUBLE BOND 248* 9.3.2 ALKYNES AND ALKADIENES 2,52
9.3.3 AROMATIC MOLECULES 2,55 9.3.4 RELATED REACTIONS . . . . 2,56 9.4
CHEMOSELECTIVE HYDROGENATION . 2,56 9.5 HYDROGENATION OF CARBON DIOXIDE.
261* 9.6 DEHYDROGENATION... 263* 9.6.1 INTRODUCTION 263* 9.6.2 METHANOL
.. 263* 9.6.3 METHANOIC ACID 264* 9.6.4 OTHER REACTIONS PRODUCING
HYDROGEN 265* REFERENCES . 265* CHAPTER 10 THE WATER-GAS SHIFT 269* 10.1
INTRODUCTION . 269* 10.2 GOLD AS A CATALYST FAR THE WATER-GAS SHIFT 272*
10.2.1 INTRODUCTION . 272* 10.2.2 TITANIA, FERRIC OXIDE AND SIMILAR
SUPPORTS 273* 10.2.3 CERIA AND CERIA-ZIRCONIA AS SUPPORTS ... 276* 10.3
MECHANISM OF THE GOLD-CATALYSED WATER-GAS SHIFT 278* 10.3.1 GOLD ON
CERIA AND CERIA-ZIRCONIA .. . . . 279* XIV CATALYSIS BY GOLD 10.4 GOLD
ON OTHER OXIDES. . . . . . . . . . 281* 10.5 GOLD-CONTAINING BIMETALLIC
CATALYSTS 283* REFERENCES. . . . . .. 283* CHAPTER 11 REACTIONS OF
ENVIRONMENTAL IMPORTANCE 286* 11.1 INTRODUCTION................ 286*
11.2 CATALYTIC TREATMENT OF VEHICLE EXHAUST . . . 286* 11.2.1
INTRODUCTION 286* 11.2.2 THE PROBLEM OF THE NITROGEN OXIDES. 289* 11.2.3
SELECTIVE REDUCTION OF NITROGEN OXIDES WITH PROPENE . 289* 11.2.4
REDUCTION OF NITROGEN OXIDES WITH CARBON MONOXIDE 292* 11.2.5 REDUCTION
OF NITROGEN OXIDES BY HYDROGEN . . . . 293* 11.2.6 REMOVAL OF NITROUS
OXIDE. .. 293* 11.2.7 GOLD-CONTAINING CATALYSTS FOR TREATING VEHICLE
EXHAUST 294* 11.3 DESTRUCTION OF OTHER ATMOSPHERIC POLLUTANTS . . . . .
. . 295* 11.3.1 METHANE.................. .... 295* 11.3.2 REMOVAL OF
VOLATILE ORGANIC COMPOUNDS (VOCS) 296* 11.3.3 OXIDATIVE DECOMPOSITION OF
DIOXINS. . . . . 299* 11.3.4 HYDRODECHLORINATION OF CHLOROFLUOROCARBONS
300* 11.3.5 HYDRODECHLORINATION OF 2,4-DICHLOROPHENOL 301* 11.3.6
REMOVAL OF CHLORINATED HYDROCARBONS. . . . 301* 11.3.7 OZONE
DECOMPOSITION. . . . . . . . . . . . . 302* 11.3.8 REDUCTION OF NITROGEN
OXIDES WITH AMMONIA 303* 11.4 REMOVAL OF SULFUR DIOXIDE. . . . . . .
303* 11.5 CATALYTIC WET AIR OXIDATION (CWAO) 305* REFERENCES. . . . . .
. . . . . . . . . . . . . . 306* CHAPTER 12 CATALYSIS BY SOLUBLE AND
SUPPORTED* GOLD COMPOUNDS 311* 12.1 OVERVIEW OF HOMOGENEOUS CATALYSIS BY
GOLD 311* 12.2 REACTIONS WITH HIGH TURNOVER NUMBERS AND FREQUENCIES 314*
12.3 GOLD COMPOUNDS AS CATALYSTS FOR ORGANIC SYNTHESIS 316* 12.3.1
CARBON-OXYGEN BOND FORMATION. 317* 12.3.2 CARBON-NITROGEN BOND FORMATION
319* 12.3.3 CARBON-CARBON BOND FORMATION. 320* 12.3.4 CATALYTIC
HYDROGENATION . . . . . 325* 12.3.5 POLYMERISATION OF ANILINE BY AURIC
ACID 325* 12.4 SUPPORTED GOLD COMPLEX CATALYSTS . 325* 12.5 FUTURE
PROSPECTS 326* REFERENCES. . . . . . . . . . . . . . . . . . . 327*
CHAPTER 13 MISCELLANEOUS REACTIONS CATALYSED BY GOLD 330* 13.1
INTRODUCTION . . . . . . . . . . 330* 13.2 HYDROCHLORINATION OF ETHYNE .
330* CONTENTS XV 13.3 THE FORMATION OF CARBON-CARBON BONDS 331* 13.4
OTHER REACTIONS CATALYSED BY GOLD . 333* REFERENCES. . . . . . . . . . .
. . . . . . . . 335* CHAPTER 14 COMMERDAL APPLICATIONS 337* 14.1
INTRODUCTION . 337* 14.2 POLLUTION AND EMISSION CONTROL TECHNOLOGIES
338* 14.2.1 AIR CLEANING . 338* 14.2.2 AUTOCATALYSTS . 340* 14.2.3
CATALYTIC WET AIR OXIDATION (CWAO) 342* 14.2.4 MERCURY OXIDATION IN
COAL-FIRED POWER STATIONS. 343* 14.3 CHEMIEAL PROCESSING . 344* 14.3.1
VINYL ACETATE SYNTHESIS . 344* 14.3.2 VINYL CHLORIDE . 345* 14.3.3
PRODUCTION OF NYLON PRECURSORS 345* 14.3.4 METHYL GLYCOLATE . 346*
14.3.5 SELECTIVE OXIDATION OF SUGARS 347* 14.3.6 PROPENE OXIDE . 347*
14.3.7 HYDROGEN PEROXIDE . 349* 14.3.8 HYDROTREATING DISTILLATES 349*
14.3.9 SELECTIVE HYDROGENATION 349* 14.4 FUEL CELLS AND THE HYDROGEN
ECONOMY 350* 14.5 SENSORS . 353* 14.6 SOME ECONOMIC CONSIDERATIONS 354*
14.7 FUTURE PROSPECTS 356* REFERENCES. . . . . . . . 356* INDEX 361*
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C E * V I I * C H A P T E R 1 I N T R O D U C T I O N T O
C A T A L Y S I S * 1 * 1.1 T H E P H E N O M E N O N O F C A T
A L Y S I S . . . . . . . . . . 1 * 1.2 T H E A C T I V A T
I O N E N E R G Y O F C A T A L Y S E D R E A C T I O N S
4 * 1 . 3 W A Y S O F U S I N G H E T E R O G E N E O U S
C A T A L Y S T S 6 * 1.4 U N D E R S T A N D I N G C A T A
L Y S E D R E A C T I O N S . 9 * 1.5 T H E C A T A L Y T
I C A C T I V I T I E S O F M E T A L S 1 7 * 1.6 C A T A
L Y S I S I N B I M E T A L L I C S Y S T E M S 19* R E F E
R E N C E S . . . . . . . . . . . . . . . . 21* C H A P T E R 2
T H E P H Y S I C A L A N D C H E M I C A L P R O P E R T
I E S O F G O L D 2 2 * 2.1* I N T R O D U C T I O N . . . .
. . . . . . . . . . . . . . . 22* 2 . 2 * T H E O R I G I N O F
R E L A T I V I S T I C E F F E C T S . . . . . . . . . . . . . 2
3 * 2 . 3 * C O M P A R I S O N S O F T H E C H E M I S T
R Y O F G O L D W I T H T H A T O F T H E * A D J A
C E N T E L E M E N T S . 2 7 * 2.4* T H E A U R O P H I
L I C B O N D . . . . . . . . . . 29* 2.5* P H Y S I C A
L P R O P E R T I E S O F G O L D A N D A D J A C E N T
E L E M E N T S . 29* 2.5.1 B U L K P R O P E R T I E S * .
29* 2 . 5 . 2 T H E S T R U C T U R E O F S I N G L E - C
R Y S T A L S U R F A C E S . * 31* 2.6 B I M E T A L L I C
S Y S T E M S C O N T A I N I N G G O L D 3 3 * R E F E R E
N C E S . . . . . . . . . . 3 5 * C H A P T E R 3 P
H Y S I C A L P R O P E R T I E S A N D C H A R A C T E R I S A
T I O N O F * S M A L L G O L D P A R T I C L E S 3 7 *
3.1* O V E R V I E W . . . 3 7 * 3 . 2 * W A Y S O
F P R E P A R I N G S M A L L P A R T I C L E S O F G O L
D 40* 3 . 2 . 1 I N T R O D U C T I O N * 40* 3 . 2 . 2 G A
S E O U S C L U S T E R S * 41* 3 . 2 . 3 C O L L O I D A L
G O L D . . * 41* 3 . 2 . 4 O T H E R M E T H O D S . *
44* 3 . 3 * T E C H N I Q U E S F O R T H E S T U D Y
O F S M A L L P A R T I C L E S O F G O L D . 46* 3 . 3 .
1 D E T E R M I N A T I O N O F S I Z E A N D S T R U C T
U R E * 46* 3 . 3 . 2 I N V E S T I G A T I O N O F O P T O
E L E C T R O N I C P A R A M E T E R S * 49* 3 . 3 . 3 O T H E
R M E T H O D S . . . . . . . . . . . . * 51* I X X *
CATALYSIS BY GOLD 3.4 VARIATION OF PHYSICAL PROPERTIES WITH SIZE . . . .
. . . . . . 52* 3.4.1* INTRODUCTION. 52* 3.4.2*
STRUCTURE OF GASEOUS AND IIGAND-STABILISED CLUSTERS 53* 3.4.3* STRUCTURE
OF SMALL SUPPORTED GOLD PARTICLES . 53* 3.4.4* OPTOELECTRONIC
PROPERTIES OF CLUSTERS AND SMALL* SUPPORTED PARTICLES . . . . . . . . .
. . 55* 3.5 METAL-SUPPORT INTERACTIONS . . . . . . . . . . . . .* 59*
3.5.1* PARTICLE SHAPE AND BONDING TO SUPPORT . 59* 3.5.2* INFLUENCE OF
THE SUPPORT ON GOLD PARTICLES 63* 3.5.3 INFLUENCE OF GOLD PARTICLES ON
THE SUPPORT 64* REFERENCES . 65* CHAPTER 4 PREPARATION OF SUPPORTED GOLD
CATALYSTS 72* 4.1 LNTRODUCTION. 72* 4.1.1*
PRINCIPLES OF THE PREPARATION METHODS AND DEFINITIONS 72* 4.1.2* GOLD
SPECIATION . 74* 4.1.3* FULMINATING GOLD . . . . . . . . . . . . . . . .
. 75* 4.2 METHODS OI PREPARATION USING GOLD CHLORIDE PRECURSORS 77*
4.2.1* LMPREGNATION . 77* 4.2.2* COPRECIPITATION . 78* 4.2.3*
DEPOSITION-PRECIPITATION . 79* 4.2.4* DEPOSITION-PRECIPITATION WITH UREA
(DPU) 86* 4.2.5* ANION ADSORPTION . 88* 4.2.6* REMOVAL OF CHLORIDE WHEN
USING GOLD CHLORIDE PRECURSORS 89* 4.3 METHODS OF PREPARATION USING
CHLORIDE-FREE GOLD PRECURSORS 89* 4.3.1* IMPREGNATION IN THE AQUEOUS
PHASE 89* 4.3.2* DEPOSITION OF GOLD-PHOSPHINE COMPLEXES . 90* 4.3.3*
DEPOSITION OI OTHER ORGANOGOLD COMPLEXES 91* 4.3.4* CHEMICAL VAPOUR
DEPOSITION . . . . . . . . 92* 4.3.5* CATION EXCHANGE AND ADSORPTION
. 93* 4.3.6* DEPOSITION OF COLLOIDAL GOLD ONTO SUPPORTS 93* 4.3.7*
DEPOSITION OF DENDRIMER-STABILISED GOLD PARTICLES 95* 4.4 LESS
CONVENTIONAL METHODS . . . .* 95* 4.4.1* SOL-GEL METHOD . . . . . . 95*
4.4.2* PHOTOCHEMICAL DEPOSITION 96* 4.4.3* SONOCHEMICAL TECHNIQUES . 97*
4.4.4* SPRAY TECHNIQUES . . . . . 97* 4.4.5* LOW-ENERGY CLUSTER OR ATOM
BEAM DEPOSITION 98* 4.4.6* DIRECT OXIDATION OF BULK ALLOY . 99* 4.4.7*
SOLVATED METAL ATOM DISPERSION OR IMPREGNATION* (SMAD OR SMAI) . 99* 4.5
PREPARATION OF GOLD CATALYSTS ON SPECIFIC SUPPORTS* 100* 4.5.1* GOLD IN
ZEOLITES . 100* 4.5.2* GOLD IN ORDERED MESOPOROUS SILICA 101* 4.5.3*
GOLD IN TITANOSILICATE . 103* 4.5.4* GOLD ON CARBON SUPPORTS 104* XI
CONTENTS 4.6 PREPARATION OF SUPPORTED BIMETALLIC CATALYSTS CONTAINING
GOLD . 105* 4.6.1* INTRODUCTION. 105* 4.6.2* METHODS
WITHOUT INTERACTION BETWEEN PRECURSORS* IN SOLUTION. . . . . . . . . . .
106* 4.6.2.1* CO-IMPREGNATION . . . . . . 106* 4.6.2.2* CO-ADSORPTION OF
CATIONS . . 106* 4.6.2.3* CO-DEPOSITION-PRECIPITATION 107* 4.6.2.4*
PHOTOREDUCTION . . . . . . . 107* 4.6.3* REDOX METHODS FOR PREPARING
BIMETALLIC CATALYSTS 107* 4.6.4* USE OF ABIMETALLIC PRECURSOR 108*
4.6.4.1* ADSORPTION OF BIMETALLIC MOLECULAR CLUSTERS 108* 4.6.4.2*
DEPOSITION OF BIMETALLIC COLLOIDS 109* 4.6.4.3* DEPOSITION OF
DENDRIMER-STABILISED* BIMETALLIC PARTICLES . . . . . . . . . . . . . . .
110* 4.6.4.4* LOW-ENERGY CLUSTER DEPOSITION. . . . . . . . . 110* 4.7
INFLUENCE OF THE THERMAL TREATMENT ON GOLD PARTICLE SIZE 110* 4.7.1*
NATURE OF THE GAS. . . . . . . . . . . . . . . . . 111* 4.7.2* GAS FLOW
RATE AND SAMPIE WEIGHT . . 111* 4.7.3* EFFECT OF THE TEMPERATURE OF
THERMAL TREATMENT 111* 4.8 EFFECT OF CONDITIONS OF STORAGE ON SIZE OF
GOLD PARTICLES 112* 4.9 CONCLUSION 113* REFERENCES . 113* CHAPTER 5
CHEMISORPTION OF SIMPLE MOLEEULES ON GOLD 121* 5.1 INTRODUCTION:
CHEMISORPTION AND CATALYSIS .* 121* 5.2 INTERACTION OF OXYGEN WITH GOLD
. . . . . .* 122* 5.2.1* INTERACTION WITH GOLD CLUSTERS . . . 122*
5.2.2* CHEMISORPTION OF OXYGEN ON GOLD SURFACES 127* 5.2.3*
FINALE. 133* 5.3 CHEMISORPTION OF CARBON MONOXIDE ON
GOLD. . . .* 134* 5.3.1* REACTION OF CARBON MONOXIDE WITH GASEOUS GOLD
CLUSTERS 134* 5.3.2* CHEMISORPTION OF CARBON MONOXIDE ON MASSIVE* GOLD
SURFACES . . . . . . . . . . . . . . . . . . . . . . " 136* 5.3.3* THE
BONDING OF CARBON MONOXIDE TO GOLD AND RESULTS OF* DFT CALCULATIONS . .
. . . . . . . . . . . . . . . . 139* 5.3.4* CHEMISORPTION OF CARBON
MONOXIDE ON SUPPORTED* GOLD CATALYSTS . . . . . . . . . . . . . . . . .
. . . 141* 5.4 CHEMISORPTION OF THE OXIDES OF NITROGEN ON GOLD SURFACES
. . . 149* 5.5 THE CHEMISORPTION OF HYDROGEN AND OF OTHER MOLEEULES ON
GOLD 150* 5.5.1* HYDROGEN. 150* 5.5.2 OTHER MOLEEULES
153* APPENDIX: INTRODUCTION TO DENSITY FUNCTIONAL THEORY 154*
REFERENCES. . . . . . . . . . . . . . . . . . . . . . . 156* CHAPTER 6
OXIDATION OF CARBON MONOXIDE* 161* 6.1 INTRODUCTION. . . . . . . . . . .
. . . . . . .* . 161* XII* CATALYSIS BY GOLD 6.2* SENSITIVITY OF GOLD
CATALYSTS TOWARDS REACTION CONDITIONS 162* 6.2.1 REPRODUCIBIIITY OF
PREPARATIVE METHOD . 163* 6.2.2 CONDITIONS OF ACTIVATION* . 163* 6.2.3
CONDITIONS OF REACTION AND THE INFLUENCE OF MOISTURE 164* 6.2.4
EXPRESSION OF THE RESULTS .* 167* 6.2.5 KINETICS OF CARBON MONOXIDE
OXIDATION . 167* 6.2.6 DEACTIVATION AND REGENERATION . 170* 6.3*
OXIDATION OF CARBON MONOXIDE ON VARIOUS SUPPORTED* GOLD CATALYSTS . . .
. . . . . . . . . . . . . . . 171* 6.3.1 INTRODUCTION* . 171* 6.3.2
INFLUENCE OF THE NATURE OF THE SUPPORT* 171* 6.3.3 INFLUENCE OF THE
METHOD OF PREPARATION* 175* 6.3.3.1 IRON OXIDES* 176* 6.3.3.2 TITANIA .
. . . . . . . . . . . . . . .* 176* 6.3.3.3 ALUMINA. . . . . . . . . . .
. . . . .* 177* 6.3.3.4 MICROPOROUS AND MESOPOROUS SILICA* 178* 6.3.3.5
ZIRCONIA .* 179* 6.3.3.6 CERIA* 180* 6.3.3.7 MAGNESIA* 182* 6.3.3.8
ACIDIC SUPPORTS.* 183* 6.3.3.9 CONCLUSIONS .* 184* 6.4* OXIDATION
STATE OF GOLD IN ACTIVE CATALYSTS 185* 6.5* PARTICLE SIZE AND
METAL-SUPPORT INTERACTION 186* 6.6* MECHANISMS OF CARBON MONOXIDE
OXIDATION 189* 6.6.1 INTRODUCTION .* 189* 6.6.2 MECHANISMS ON GOLD
PARTICLE ONLY .* 189* 6.6.3 MECHANISMS INVOLVING THE SUPPORT* 193* 6.7
RETROSPECT AND PROSPECT 197* REFERENCES. . . . . . . . . . . . 198*
CHAPTER 7 THE SELECTIVE OXIDATION OF CARBON MONOXIDE* IN HYDROGEN 204*
7.1* INTRODUCTION: THE NATURE OF THE PROBLEM . 204* 7.1.1 THE CHEMICAL
INDUSTRY'S NEED FOR HYDROGEN. 204* 7.1.2 PURE HYDROGEN FOR USE IN FUEL
CELLS . 205* 7.2* THE OXIDATION OF HYDROGEN TO WATER . 206* 7.3*
SELECTIVE OXIDATION OF CARBON MONOXIDE IN HYDROGEN 208* 7.3.1 TOUR
D'HORIZON .* 208* 7.3.2 CATALYSIS BY GOLD ON FERRIC OXIDE* 210* 7.3.3
GOLD ON OTHER SUPPORTS* 213* 7.3.4 CONCLUSION 215* REFERENCES . 215*
CHAPTER 8 SELECTIVE OXIDATION* 217* 8.1* INTRODUCTION . . . . . . . . .
. . 217* CONTENTS XIII 8.1.1 A SURVEY OF SELECTIVE OXIDATION . . . . . .
. . . . . . . 217* 8.1.2 REACTION MECHANISMS AND THE USE OF BIMETALLIC
CATALYSTS 218* 8.2 SELECTIVE OXIDATION OF HYDROCARBONS 220* 8.2.1
OXIDATION OF PROPENE. . . . 220* 8.2.2 OXIDATION OF OTHER ALKENES. 224*
8.2.3 OXIDATION OF CYCLOHEXANE . 225* 8.2.4 OXIDATION OF ALKANES . . . .
226* 8.3 SELECTIVE OXIDATION OF OXYGEN-CONTAINING MOLECULES 226* 8.3.1
LNTRODUCTION. 226* 8.3.2 OXIDATION OF REDUCING SUGARS . . . . .
. . . 227* 8.3.3 OXIDATION OF OTHER ALDEHYDES . . . . . . . . 229* 8.3.4
OXIDATION OF A C6 POLYHYDRIC ALCOHOL: SORBITOL 229* 8.3.5 OXIDATION OF
DIOLS 230* 8.3.6 OXIDATION OF A TRIOL: GLYCEROL 231* 8.3.7 OXIDATION OF
MONOFUNCTIONAL ALCOHOLS 233* 8.4 SYNTHESIS OF VINYL ACETATE (ETHENYL
ETHANOATE) 23,5 8.5 SYNTHESIS OF HYDROGEN PEROXIDE 237* 8.6 CONCLUSION
238* REFERENCES . 239* CHAPTER 9 REACTIONS INVOLVING HYDROGEN 244* 9.1
LNTRODUCTION: THE INTERACTION OF HYDROGEN WITH GOLD . 244* 9.2 REACTIONS
OF HYDROGEN . . . . . . . . . . . . . . . . . . . . . . . . 245* 9.3
HYDROGENATION OF UNSATURATED MOLECLILES AND RELATED REACTIONS 248* 9.3.1
THE CARBON-CARBON DOUBLE BOND 248* 9.3.2 ALKYNES AND ALKADIENES 2,52
9.3.3 AROMATIC MOLECULES 2,55 9.3.4 RELATED REACTIONS . . . . 2,56 9.4
CHEMOSELECTIVE HYDROGENATION . 2,56 9.5 HYDROGENATION OF CARBON DIOXIDE.
261* 9.6 DEHYDROGENATION. 263* 9.6.1 INTRODUCTION 263* 9.6.2 METHANOL
. 263* 9.6.3 METHANOIC ACID 264* 9.6.4 OTHER REACTIONS PRODUCING
HYDROGEN 265* REFERENCES . 265* CHAPTER 10 THE WATER-GAS SHIFT 269* 10.1
INTRODUCTION . 269* 10.2 GOLD AS A CATALYST FAR THE WATER-GAS SHIFT 272*
10.2.1 INTRODUCTION . 272* 10.2.2 TITANIA, FERRIC OXIDE AND SIMILAR
SUPPORTS 273* 10.2.3 CERIA AND CERIA-ZIRCONIA AS SUPPORTS . 276* 10.3
MECHANISM OF THE GOLD-CATALYSED WATER-GAS SHIFT 278* 10.3.1 GOLD ON
CERIA AND CERIA-ZIRCONIA . . . . 279* XIV CATALYSIS BY GOLD 10.4 GOLD
ON OTHER OXIDES. . . . . . . . . . 281* 10.5 GOLD-CONTAINING BIMETALLIC
CATALYSTS 283* REFERENCES. . . . . . 283* CHAPTER 11 REACTIONS OF
ENVIRONMENTAL IMPORTANCE 286* 11.1 INTRODUCTION. 286*
11.2 CATALYTIC TREATMENT OF VEHICLE EXHAUST . . . 286* 11.2.1
INTRODUCTION 286* 11.2.2 THE PROBLEM OF THE NITROGEN OXIDES. 289* 11.2.3
SELECTIVE REDUCTION OF NITROGEN OXIDES WITH PROPENE . 289* 11.2.4
REDUCTION OF NITROGEN OXIDES WITH CARBON MONOXIDE 292* 11.2.5 REDUCTION
OF NITROGEN OXIDES BY HYDROGEN . . . . 293* 11.2.6 REMOVAL OF NITROUS
OXIDE. . 293* 11.2.7 GOLD-CONTAINING CATALYSTS FOR TREATING VEHICLE
EXHAUST 294* 11.3 DESTRUCTION OF OTHER ATMOSPHERIC POLLUTANTS . . . . .
. . 295* 11.3.1 METHANE. . 295* 11.3.2 REMOVAL OF
VOLATILE ORGANIC COMPOUNDS (VOCS) 296* 11.3.3 OXIDATIVE DECOMPOSITION OF
DIOXINS. . . . . 299* 11.3.4 HYDRODECHLORINATION OF CHLOROFLUOROCARBONS
300* 11.3.5 HYDRODECHLORINATION OF 2,4-DICHLOROPHENOL 301* 11.3.6
REMOVAL OF CHLORINATED HYDROCARBONS. . . . 301* 11.3.7 OZONE
DECOMPOSITION. . . . . . . . . . . . . 302* 11.3.8 REDUCTION OF NITROGEN
OXIDES WITH AMMONIA 303* 11.4 REMOVAL OF SULFUR DIOXIDE. . . . . . .
303* 11.5 CATALYTIC WET AIR OXIDATION (CWAO) 305* REFERENCES. . . . . .
. . . . . . . . . . . . . . 306* CHAPTER 12 CATALYSIS BY SOLUBLE AND
SUPPORTED* GOLD COMPOUNDS 311* 12.1 OVERVIEW OF HOMOGENEOUS CATALYSIS BY
GOLD 311* 12.2 REACTIONS WITH HIGH TURNOVER NUMBERS AND FREQUENCIES 314*
12.3 GOLD COMPOUNDS AS CATALYSTS FOR ORGANIC SYNTHESIS 316* 12.3.1
CARBON-OXYGEN BOND FORMATION. 317* 12.3.2 CARBON-NITROGEN BOND FORMATION
319* 12.3.3 CARBON-CARBON BOND FORMATION. 320* 12.3.4 CATALYTIC
HYDROGENATION . . . . . 325* 12.3.5 POLYMERISATION OF ANILINE BY AURIC
ACID 325* 12.4 SUPPORTED GOLD COMPLEX CATALYSTS . 325* 12.5 FUTURE
PROSPECTS 326* REFERENCES. . . . . . . . . . . . . . . . . . . 327*
CHAPTER 13 MISCELLANEOUS REACTIONS CATALYSED BY GOLD 330* 13.1
INTRODUCTION . . . . . . . . . . 330* 13.2 HYDROCHLORINATION OF ETHYNE .
330* CONTENTS XV 13.3 THE FORMATION OF CARBON-CARBON BONDS 331* 13.4
OTHER REACTIONS CATALYSED BY GOLD . 333* REFERENCES. . . . . . . . . . .
. . . . . . . . 335* CHAPTER 14 COMMERDAL APPLICATIONS 337* 14.1
INTRODUCTION . 337* 14.2 POLLUTION AND EMISSION CONTROL TECHNOLOGIES
338* 14.2.1 AIR CLEANING . 338* 14.2.2 AUTOCATALYSTS . 340* 14.2.3
CATALYTIC WET AIR OXIDATION (CWAO) 342* 14.2.4 MERCURY OXIDATION IN
COAL-FIRED POWER STATIONS. 343* 14.3 CHEMIEAL PROCESSING . 344* 14.3.1
VINYL ACETATE SYNTHESIS . 344* 14.3.2 VINYL CHLORIDE . 345* 14.3.3
PRODUCTION OF NYLON PRECURSORS 345* 14.3.4 METHYL GLYCOLATE . 346*
14.3.5 SELECTIVE OXIDATION OF SUGARS 347* 14.3.6 PROPENE OXIDE . 347*
14.3.7 HYDROGEN PEROXIDE . 349* 14.3.8 HYDROTREATING DISTILLATES 349*
14.3.9 SELECTIVE HYDROGENATION 349* 14.4 FUEL CELLS AND THE HYDROGEN
ECONOMY 350* 14.5 SENSORS . 353* 14.6 SOME ECONOMIC CONSIDERATIONS 354*
14.7 FUTURE PROSPECTS 356* REFERENCES. . . . . . . . 356* INDEX 361* |
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| author | Bond, Geoffrey C. 1927- Louis, Catherine Thompson, David T. |
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| callnumber-first | Q - Science |
| callnumber-label | QD505 |
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| callnumber-sort | QD 3505 |
| callnumber-subject | QD - Chemistry |
| classification_rvk | VE 7040 |
| ctrlnum | (OCoLC)75265247 (DE-599)BVBBV022883237 |
| dewey-full | 541.395 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry |
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| dewey-search | 541.395 |
| dewey-sort | 3541.395 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| discipline_str_mv | Chemie / Pharmazie |
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| id | DE-604.BV022883237 |
| illustrated | Illustrated |
| index_date | 2024-07-02T18:51:11Z |
| indexdate | 2024-07-09T21:07:41Z |
| institution | BVB |
| isbn | 1860946585 9781860946585 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-016088189 |
| oclc_num | 75265247 |
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| owner_facet | DE-703 |
| physical | XV, 366 S. Ill., graph. Darst. |
| publishDate | 2006 |
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| publisher | Imperial College Press |
| record_format | marc |
| series | Catalytic science series |
| series2 | Catalytic science series |
| spelling | Bond, Geoffrey C. 1927- Verfasser (DE-588)129582212 aut Catalysis by gold Geoffrey C. Bond; Catherine Louis; David T. Thompson London Imperial College Press 2006 XV, 366 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Catalytic science series 6 Catalysis Gold Metal catalysts Katalyse (DE-588)4029921-1 gnd rswk-swf Gold (DE-588)4157819-3 gnd rswk-swf Katalyse (DE-588)4029921-1 s Gold (DE-588)4157819-3 s DE-604 Louis, Catherine Verfasser aut Thompson, David T. Verfasser aut Catalytic science series 6 (DE-604)BV013477807 6 OEBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016088189&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Bond, Geoffrey C. 1927- Louis, Catherine Thompson, David T. Catalysis by gold Catalytic science series Catalysis Gold Metal catalysts Katalyse (DE-588)4029921-1 gnd Gold (DE-588)4157819-3 gnd |
| subject_GND | (DE-588)4029921-1 (DE-588)4157819-3 |
| title | Catalysis by gold |
| title_auth | Catalysis by gold |
| title_exact_search | Catalysis by gold |
| title_exact_search_txtP | Catalysis by gold |
| title_full | Catalysis by gold Geoffrey C. Bond; Catherine Louis; David T. Thompson |
| title_fullStr | Catalysis by gold Geoffrey C. Bond; Catherine Louis; David T. Thompson |
| title_full_unstemmed | Catalysis by gold Geoffrey C. Bond; Catherine Louis; David T. Thompson |
| title_short | Catalysis by gold |
| title_sort | catalysis by gold |
| topic | Catalysis Gold Metal catalysts Katalyse (DE-588)4029921-1 gnd Gold (DE-588)4157819-3 gnd |
| topic_facet | Catalysis Gold Metal catalysts Katalyse |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016088189&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV013477807 |
| work_keys_str_mv | AT bondgeoffreyc catalysisbygold AT louiscatherine catalysisbygold AT thompsondavidt catalysisbygold |