Introduction to polymer physics:
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Oxford
Clarendon Press
2006
|
| Edition: | Reprinted |
| Series: | Oxford science publications
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Aus dem Japan. übers. |
| Physical Description: | IX, 120 S. graph. Darst. |
| ISBN: | 0198517726 9780198517894 0198517890 |
Staff View
MARC
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| 245 | 1 | 0 | |a Introduction to polymer physics |c M. Doi |
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Record in the Search Index
| _version_ | 1804136937124003840 |
|---|---|
| adam_text | Contents
1
Properties of an isolated polymer molecule
1
1.1
The ideal chain
2
1.1.1
The random walk model
2
1.1.2
The effect of short-range interactions
4
1.1.3
Gaussian chains
6
1.2
Distribution of segments in the polymer chain
7
1.2.1
Pair correlation function
7
1.2.2
Radius of gyration
8
1.2.3
Radius of gyration and pair correlation function
of an ideal chain
9
1.3
Non-ideal chains
10
1.3.1
The excluded volume effect
10
1.3.2
Effect of the solvent
12
1.3.3
The
θ
temperature and coil-globule transition
14
1.4
Scaling laws
16
2
Concentrated solutions and melts
20
2.1
Thermodynamic properties of polymer solutions
21
2.1.1
Flory-Huggins theory
21
2.1.2
Chemical potential and osmotic pressure
23
2.1.3
Phase separation
26
2.2
Concentration fluctuation in polymer solutions
29
2.2.1
Correlation function and response function
29
2.2.2
Random phase approximation
32
2.2.3
Concentration fluctuations in concentrated polymer
solutions
34
2.2.4
Scaling theory
35
2.3
Polymer blends
38
2.3.1
Phase diagrams of polymer-polymer mixtures
38
2.3.2
Correlation function in
miscible
systems
39
2.4
Block copolymers
40
2.4.1
Block copolymers and microscopic phase separation
40
2.4.2
Correlation function in the uniform phase
41
2.4.3
Domain size
43
viii Contents
3 Polymer
gels
45
3.1
Elasticity of
rubber
46
3.1.1
Polymer thermal motion and the elasticity of rubber
46
3.1.2
Elastic free energy of rubber
47
3.1.3
Relationship between stress and strain
48
3.2
The stress optical law
51
3.2.1
Orientation of bonds of a stretched chain
51
3.2.2
Stress tensor and orientational order parameter tensor
54
3.3
Interactions between partial chains
56
3.3.1
Excluded volume interactions
56
3.3.2
Nematic interactions
57
3.3.3
Entanglement interactions
59
3.4
Swelling of gels
62
4
Molecular motion of polymers in dilute solution
65
4.1
General theory of Brownian motion
66
4.1.1
Brownian motion of spherical particles
66
4.1.2
The effect of a potential field
67
4.1.3
Einstein s relation
68
4.1.4
The Brownian motion of a harmonic oscillator
70
4.2
The bead-spring model
71
4.2.1
Rouse theory
71
4.2.2
Features of Brownian motion of the polymer
73
4.2.3
Comparison with experiments
75
4.3
Hydrodynamic interactions
76
4.3.1
The mobility matrix for a many-particle system
76
4.3.2
Zimm theory
78
4.3.3
The dynamic scaling law
81
4.4
Dynamic light scattering
82
4.4.1
Dynamic structure factor
82
4.4.2
Initial decay rate of g(q,l)
83
4.5
Appendix
86
4.5.1
Derivation of the diffusion equation
86
4.5.2
Initial decay rate of the time correlation function
87
5
Molecular motion in entangled polymer systems
89
5.1
Dynamics of concentration fluctuations
89
5.1.1
Time correlation function of concentration fluctuations
89
5.1.2
Cooperative diffusion constant
90
5.1.3
Initial decay rate of g(q,
ή
92
Contents ix
5.2
Reptation
93
5.2.1
Entanglement effects and the tube model
93
5.2.2
Lattice model of
reptation
94
5.2.3
Motion of the centre of mass
96
5.2.4
Rotational motion
97
5.2.5
Shape memory function
99
5.2.6
Fluctuations of the tube contour length
101
5.3
Viscoelasticity of polymers
103
5.3.1
Phenomenological theory of viscoelasticity
103
5.3.2
Microscopic description of stress
105
5.3.3
The Rouse model
107
5.3.4
The
reptation
model
109
Bibliography
114
Index
117
|
| adam_txt |
Contents
1
Properties of an isolated polymer molecule
1
1.1
The ideal chain
2
1.1.1
The random walk model
2
1.1.2
The effect of short-range interactions
4
1.1.3
Gaussian chains
6
1.2
Distribution of segments in the polymer chain
7
1.2.1
Pair correlation function
7
1.2.2
Radius of gyration
8
1.2.3
Radius of gyration and pair correlation function
of an ideal chain
9
1.3
Non-ideal chains
10
1.3.1
The excluded volume effect
10
1.3.2
Effect of the solvent
12
1.3.3
The
θ
temperature and coil-globule transition
14
1.4
Scaling laws
16
2
Concentrated solutions and melts
20
2.1
Thermodynamic properties of polymer solutions
21
2.1.1
Flory-Huggins theory
21
2.1.2
Chemical potential and osmotic pressure
23
2.1.3
Phase separation
26
2.2
Concentration fluctuation in polymer solutions
29
2.2.1
Correlation function and response function
29
2.2.2
Random phase approximation
32
2.2.3
Concentration fluctuations in concentrated polymer
solutions
34
2.2.4
Scaling theory
35
2.3
Polymer blends
38
2.3.1
Phase diagrams of polymer-polymer mixtures
38
2.3.2
Correlation function in
miscible
systems
39
2.4
Block copolymers
40
2.4.1
Block copolymers and microscopic phase separation
40
2.4.2
Correlation function in the uniform phase
41
2.4.3
Domain size
43
viii Contents
3 Polymer
gels
45
3.1
Elasticity of
rubber
46
3.1.1
Polymer thermal motion and the elasticity of rubber
46
3.1.2
Elastic free energy of rubber
47
3.1.3
Relationship between stress and strain
48
3.2
The stress optical law
51
3.2.1
Orientation of bonds of a stretched chain
51
3.2.2
Stress tensor and orientational order parameter tensor
54
3.3
Interactions between partial chains
56
3.3.1
Excluded volume interactions
56
3.3.2
Nematic interactions
57
3.3.3
Entanglement interactions
59
3.4
Swelling of gels
62
4
Molecular motion of polymers in dilute solution
65
4.1
General theory of Brownian motion
66
4.1.1
Brownian motion of spherical particles
66
4.1.2
The effect of a potential field
67
4.1.3
Einstein's relation
68
4.1.4
The Brownian motion of a harmonic oscillator
70
4.2
The bead-spring model
71
4.2.1
Rouse theory
71
4.2.2
Features of Brownian motion of the polymer
73
4.2.3
Comparison with experiments
75
4.3
Hydrodynamic interactions
76
4.3.1
The mobility matrix for a many-particle system
76
4.3.2
Zimm theory
78
4.3.3
The dynamic scaling law
81
4.4
Dynamic light scattering
82
4.4.1
Dynamic structure factor
82
4.4.2
Initial decay rate of g(q,l)
83
4.5
Appendix
86
4.5.1
Derivation of the diffusion equation
86
4.5.2
Initial decay rate of the time correlation function
87
5
Molecular motion in entangled polymer systems
89
5.1
Dynamics of concentration fluctuations
89
5.1.1
Time correlation function of concentration fluctuations
89
5.1.2
Cooperative diffusion constant
90
5.1.3
Initial decay rate of g(q,
ή
92
Contents ix
5.2
Reptation
93
5.2.1
Entanglement effects and the tube model
93
5.2.2
Lattice model of
reptation
94
5.2.3
Motion of the centre of mass
96
5.2.4
Rotational motion
97
5.2.5
Shape memory function
99
5.2.6
Fluctuations of the tube contour length
101
5.3
Viscoelasticity of polymers
103
5.3.1
Phenomenological theory of viscoelasticity
103
5.3.2
Microscopic description of stress
105
5.3.3
The Rouse model
107
5.3.4
The
reptation
model
109
Bibliography
114
Index
117 |
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| edition | Reprinted |
| format | Book |
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| index_date | 2024-07-02T18:27:53Z |
| indexdate | 2024-07-09T21:04:20Z |
| institution | BVB |
| isbn | 0198517726 9780198517894 0198517890 |
| language | English |
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| spelling | Doi, Masao 1948- Verfasser (DE-588)1052280056 aut Kōbunshi butsuri Introduction to polymer physics M. Doi Reprinted Oxford Clarendon Press 2006 IX, 120 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Oxford science publications Aus dem Japan. übers. Polymere (DE-588)4046699-1 gnd rswk-swf Physik (DE-588)4045956-1 gnd rswk-swf 1\p (DE-588)4151278-9 Einführung gnd-content Polymere (DE-588)4046699-1 s Physik (DE-588)4045956-1 s DE-604 Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=015920440&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Doi, Masao 1948- Introduction to polymer physics Polymere (DE-588)4046699-1 gnd Physik (DE-588)4045956-1 gnd |
| subject_GND | (DE-588)4046699-1 (DE-588)4045956-1 (DE-588)4151278-9 |
| title | Introduction to polymer physics |
| title_alt | Kōbunshi butsuri |
| title_auth | Introduction to polymer physics |
| title_exact_search | Introduction to polymer physics |
| title_exact_search_txtP | Introduction to polymer physics |
| title_full | Introduction to polymer physics M. Doi |
| title_fullStr | Introduction to polymer physics M. Doi |
| title_full_unstemmed | Introduction to polymer physics M. Doi |
| title_short | Introduction to polymer physics |
| title_sort | introduction to polymer physics |
| topic | Polymere (DE-588)4046699-1 gnd Physik (DE-588)4045956-1 gnd |
| topic_facet | Polymere Physik Einführung |
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