The absorption spectra of solutions of comparatively rare salts, including those of Gadolinium, Dysprosium, and Samarium: the spectrophotography of certain chemical reactions and the effect of high temperature on the absorption spectra of non-aqueous solutions
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| Main Authors: | , |
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| Format: | Book |
| Language: | English |
| Published: |
Washington, DC
Carnegie Institution
1911
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| Series: | Publication / Carnegie Institution of Washington
160 |
| Subjects: | |
| Online Access: | Volltext // Exemplar mit der Signatur: München, Bayerische Staatsbibliothek -- 4 Acad. 157 tg-160 Inhaltsverzeichnis |
| Physical Description: | VIII, 112 S. Ill. |
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| 245 | 1 | 0 | |a The absorption spectra of solutions of comparatively rare salts, including those of Gadolinium, Dysprosium, and Samarium |b the spectrophotography of certain chemical reactions and the effect of high temperature on the absorption spectra of non-aqueous solutions |c by Harry C. Jones ; W. W. Strong |
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| 650 | 4 | |a Absorption spectra | |
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| 700 | 1 | |a Strong, W. W. |d 1883-1955 |e Verfasser |0 (DE-588)1027579213 |4 aut | |
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| adam_text |
THE
ABSORPTION SPECTRA OF SOLUTIONS
OF COMPARATIVELY RARE SALTS
INCLUDING THOSE OP GADOLINIUM, DYSPROSIUM, AND SAMARIUM
THE SPECTROPHOTOGRAPHY OF CERTAIN CHEMICAL REACTIONS
AND THE EFFECT OF HIGH TEMPERATURE ON THE ABSORPTION SPECTRA
OF NON-AQUEOUS SOLUTIONS
BY
HARRY C JOKES AND \V W STRONG
WASHINGTON, D C
PUBLISHED BY THE CARNEGIE INSTITUTION' OF WASHINGTON
CONTENTS
CHAPTER I THE ABSORPTION AND EMISSION CENTERS OF LIGHT AND HEAT:
Atomic Structure and Spectra
The Ionization Theory and Absorption and Emission Centers
Sulphur Bands
The Carriers of Canal-Ray Spectra
The Carriers of Spark Spectra
The Emission Centers of Flames and Arcs
Schumann Waves
The Possible Catalytic Action of Light
Emission Spectra of Organic Compounds
The Absorption Spectra of Organic Compounds
The Unit of this Absorption
The Theory of Chromophores
Influence of the Solvent
The Absorption Spectra of Benzene and Its Derivatives
Theory of Dynamic Isomerism
Theory of Stark
Other Benzene Theories
CHAPTER II EXPERIMENTAL METHODS AND APPABATDS:
CHAPTER III MAPPING THE ABSORPTION SPECTRA OF VARIOUS SALTS IN SOLUTION:
The Absorption of Certain Cyanides and Chromates 31
Calcium Ferrocyanide and Calcium Ferricyanide 32
The Chromate and Bichromate of Lithium 33
Aluminium and Calcium Chromates 33
Potassium Nickel Chromate and Copper Bichromate 33
The Absorption of Solutions of Certain Erbium Salts 33
The Absorption of Solutions of Certain Neodymium Salts 34
Neodymium Chloride in Water • 35
Neodymium Chloride as a Methyl Alcoholate 35
Neodymium Chloride in Propyl Alcohol 36
Neodymium Chloride in Isopropyl Alcohol 36
Neodymium Chloride in Butyl Alcohol 36
Neodymium Chloride in Isobutyl Alcohol 37
Neodymium Chloride in Ether 37
Neodymium Nitrate in Propyl Alcohol 3S
Neodymium Nitrate in Isopropyl Alcohol 38
Neodymium Nitrate in Butyl Alcohol 38
Neodymium Nitrate in Isobutyl Alcohol 39
Neodymium Nitrate in Acetone 39
Neodymium Nitrate in Ethyl Ester 39
Neodymium Acetate in Acetone 40
Neodymium Acetate in Formamide 40
Summary of Neodymium Spectra 40
The Absorption Spectrum of Solutions of Certain Salts of Uranium 43
Uranyl Chloride in Propyl Alcohol 43
Uranyl Chloride in Isopropyl Alcohol 43
Uranyl Chloride in Butyl Alcohol 43
Uranyl Chloride in Isobutyl Alcohol 43
Uranyl Chloride in Ether 43
Uranyl Chloride in Methyl Ester 44
Uranyl Chloride in Ethyl Ester 44
Uranyl Chloride in Formamide 44
Uranyl Nitrate in Propjd Alcohol 44
i Uranyl Nitrate in Acetone 44
I Uranyl Nitrate in Methyl Ester 44
I Uranous Chloride in Propyl Alcohol 44
' Uranous Chloride in Isobutyl Alcohol 45
Uranous Chloride in Methyl Ester 45
The Absorption Centers of Uranium Spectra 45
The Absorption Spectrum of Gadolinium 46
Gadolinium Chloride in Water 46
Gadolinium Chloride in Ethyl Alcohol 46
vii
viii CONTENTS
CHAPTER III—continued PAGE
The Absorption Spectrum of Dysprosium 46
Dysprosium Chloride in Water 47
Dysprosium Chloride in Methyl Alcohol 47
Dysprosium Chloride in Ethyl Alcohol 47
Dysprosium Acetate in Water 48
The Absorption Spectrum of Samarium 48
Samarium Chloride in Water 48
Samarium Nitrate in Water • 49
Samarium Chloride in Methyl and Ethyl Alcohols 49
Samarium Chloride in Water and Ethyl Alcohol 50
CHAPTER IV THE SPECTROPHOTOGRAPHY OF CHEMICAL REACTIONS:
Introduction 51
Phosphorescence of Praseodymium in Calcium Oxide 54
Phosphorescence of Neodymium in Calcium Oxide 54
Phosphorescence of Erbium in Calcium Oxide 54
Phosphorescence of Praseodymium in Calcium Sulphate 54
Phosphorescence of Erbium in Calcium Sulphate 54
Phosphorescence of Erbium in Calcium Fluoride 54
Neodymium Chloride in Ethyl Acetate and Anthracene 56
The Uranyl and Uranous Bands 57
The Oxidization of Uranous to Uranyl Salts in Solution 58
The Oxidization of Uranous Chloride by Hydrogen Peroxide 58
Oxidization of Uranous Chloride in Hydrochloric Acid by Hydrogen Peroxide 60
The Oxidization of Uranous Sulphate 61
The Oxidization of Uranous Bromide by Hydrogen Peroxide 61
A Possible Method of Measuring the S1 rengths of Acids 62
Are the Ions Factors in the Absorption of Light ? 62
The Oxidization of Uranous Salts by Nitric Acid 64
Uranous Acetate and the Effect of the Addition of Nitric Acid 65
The Selective Action of Chemical Reagents on Solvates 66
The Reduction of Uranyl Salts in Solution 69
Reduction of Uranyl Chloride in Methyl Ester 69
Selective Reduction of Uranyl Aggregaies 70
Direct Spectroscopic Evidence for the Effect of Mass 71
CHAPTER V THE EFFECT OF TEMPERATURE ON ABSORPTION SPECTRA:
Solvates and the Effect of Change in Temperature on the Relative Intensity of
Solvate Bands 74
Neodymium Chloride in Water and Ethyl Alcohol 77
Neodymium Bromide in Water and Methyl Alcohol 77
Neodymium Chloride, Bromide, arid Nitrate in Water 77
Neodymium Chloride in Methyl Alcohol 78
Neodymium Bromide in Methyl Alcohol 79
Neodymium Nitrate in Isobutyl Alcohol 79
Neodymium Nitrate in Acetone 80
Erbium Chloride in Water 80'
Uranyl Chloride in Acetone 81
Uranyl Nitrate in Propyl Alcohol 81
• Uranyl Chloride and Nitrate jn Isobutyl Alcohol 81
Uranyl Chloride and Nitrate in Methyl Ester 81
Uranous Chloride in Water and Methyl Alcohol 82
Uranous Chloride in Acetone 82
The Existence of Aggregates and Their Properties, and the Effect of Rise in Tem
perature on the Aggregates 83
Neodymium Salts in Acid Solutions 84
Uranous Sulphate in Sulphuric Acid 85
Uranyl Nitrate in Nitric Acid, Uranyl Chloride in Hydrochloric Acid, and
Uranyl Sulphate in Sulphuric Acid 86
CHAPTER VI SUMMARY AND GENERAL DISCUSSION:
Mapping of Spectra 87
A Theory of Absorption Spectra 89
Solvation 92
The Uranyl and Uranous Bands 94
Aggregates and Their Properties 95
The Effect of Temperature on Absorption Spectra 98
DESCRIPTION OF PLATES 101
INDEX 102 |
| adam_txt |
THE
ABSORPTION SPECTRA OF SOLUTIONS
OF COMPARATIVELY RARE SALTS
INCLUDING THOSE OP GADOLINIUM, DYSPROSIUM, AND SAMARIUM
THE SPECTROPHOTOGRAPHY OF CERTAIN CHEMICAL REACTIONS
AND THE EFFECT OF HIGH TEMPERATURE ON THE ABSORPTION SPECTRA
OF NON-AQUEOUS SOLUTIONS
BY
HARRY C JOKES AND \V W STRONG
WASHINGTON, D C
PUBLISHED BY THE CARNEGIE INSTITUTION' OF WASHINGTON
CONTENTS
CHAPTER I THE ABSORPTION AND EMISSION CENTERS OF LIGHT AND HEAT:
Atomic Structure and Spectra
The Ionization Theory and Absorption and Emission Centers
Sulphur Bands
The Carriers of Canal-Ray Spectra
The Carriers of Spark Spectra
The Emission Centers of Flames and Arcs
Schumann Waves
The Possible Catalytic Action of Light
Emission Spectra of Organic Compounds
The Absorption Spectra of Organic Compounds
The Unit of this Absorption
The Theory of Chromophores
Influence of the Solvent
The Absorption Spectra of Benzene and Its Derivatives
Theory of Dynamic Isomerism
Theory of Stark
Other Benzene Theories
CHAPTER II EXPERIMENTAL METHODS AND APPABATDS:
CHAPTER III MAPPING THE ABSORPTION SPECTRA OF VARIOUS SALTS IN SOLUTION:
The Absorption of Certain Cyanides and Chromates 31
Calcium Ferrocyanide and Calcium Ferricyanide 32
The Chromate and Bichromate of Lithium 33
Aluminium and Calcium Chromates 33
Potassium Nickel Chromate and Copper Bichromate 33
The Absorption of Solutions of Certain Erbium Salts 33
The Absorption of Solutions of Certain Neodymium Salts 34
Neodymium Chloride in Water • 35
Neodymium Chloride as a Methyl Alcoholate 35
Neodymium Chloride in Propyl Alcohol 36
Neodymium Chloride in Isopropyl Alcohol 36
Neodymium Chloride in Butyl Alcohol 36
Neodymium Chloride in Isobutyl Alcohol 37
Neodymium Chloride in Ether 37
Neodymium Nitrate in Propyl Alcohol 3S
Neodymium Nitrate in Isopropyl Alcohol 38
Neodymium Nitrate in Butyl Alcohol 38
Neodymium Nitrate in Isobutyl Alcohol 39
Neodymium Nitrate in Acetone 39
Neodymium Nitrate in Ethyl Ester 39
Neodymium Acetate in Acetone 40
Neodymium Acetate in Formamide 40
Summary of Neodymium Spectra 40
The Absorption Spectrum of Solutions of Certain Salts of Uranium 43
Uranyl Chloride in Propyl Alcohol 43
Uranyl Chloride in Isopropyl Alcohol 43
Uranyl Chloride in Butyl Alcohol 43
Uranyl Chloride in Isobutyl Alcohol 43
Uranyl Chloride in Ether 43
Uranyl Chloride in Methyl Ester 44
Uranyl Chloride in Ethyl Ester 44
Uranyl Chloride in Formamide 44
Uranyl Nitrate in Propjd Alcohol 44
i Uranyl Nitrate in Acetone 44
I Uranyl Nitrate in Methyl Ester 44
I Uranous Chloride in Propyl Alcohol 44
' Uranous Chloride in Isobutyl Alcohol 45
Uranous Chloride in Methyl Ester 45
The Absorption Centers of Uranium Spectra 45
The Absorption Spectrum of Gadolinium 46
Gadolinium Chloride in Water 46
Gadolinium Chloride in Ethyl Alcohol 46
vii
viii CONTENTS
CHAPTER III—continued PAGE
The Absorption Spectrum of Dysprosium 46
Dysprosium Chloride in Water 47
Dysprosium Chloride in Methyl Alcohol 47
Dysprosium Chloride in Ethyl Alcohol 47
Dysprosium Acetate in Water 48
The Absorption Spectrum of Samarium 48
Samarium Chloride in Water 48
Samarium Nitrate in Water • 49
Samarium Chloride in Methyl and Ethyl Alcohols 49
Samarium Chloride in Water and Ethyl Alcohol 50
CHAPTER IV THE SPECTROPHOTOGRAPHY OF CHEMICAL REACTIONS:
Introduction 51
Phosphorescence of Praseodymium in Calcium Oxide 54
Phosphorescence of Neodymium in Calcium Oxide 54
Phosphorescence of Erbium in Calcium Oxide 54
Phosphorescence of Praseodymium in Calcium Sulphate 54
Phosphorescence of Erbium in Calcium Sulphate 54
Phosphorescence of Erbium in Calcium Fluoride 54
Neodymium Chloride in Ethyl Acetate and Anthracene 56
The Uranyl and Uranous Bands 57
The Oxidization of Uranous to Uranyl Salts in Solution 58
The Oxidization of Uranous Chloride by Hydrogen Peroxide 58
Oxidization of Uranous Chloride in Hydrochloric Acid by Hydrogen Peroxide 60
The Oxidization of Uranous Sulphate 61
The Oxidization of Uranous Bromide by Hydrogen Peroxide 61
A Possible Method of Measuring the S1 rengths of Acids 62
Are the Ions Factors in the Absorption of Light ? 62
The Oxidization of Uranous Salts by Nitric Acid 64
Uranous Acetate and the Effect of the Addition of Nitric Acid 65
The Selective Action of Chemical Reagents on Solvates 66
The Reduction of Uranyl Salts in Solution 69
Reduction of Uranyl Chloride in Methyl Ester 69
Selective Reduction of Uranyl Aggregaies 70
Direct Spectroscopic Evidence for the Effect of Mass 71
CHAPTER V THE EFFECT OF TEMPERATURE ON ABSORPTION SPECTRA:
Solvates and the Effect of Change in Temperature on the Relative Intensity of
Solvate Bands 74
Neodymium Chloride in Water and Ethyl Alcohol 77
Neodymium Bromide in Water and Methyl Alcohol 77
Neodymium Chloride, Bromide, arid Nitrate in Water 77
Neodymium Chloride in Methyl Alcohol 78
Neodymium Bromide in Methyl Alcohol 79
Neodymium Nitrate in Isobutyl Alcohol 79
Neodymium Nitrate in Acetone 80
Erbium Chloride in Water 80'
Uranyl Chloride in Acetone 81
Uranyl Nitrate in Propyl Alcohol 81
• Uranyl Chloride and Nitrate jn Isobutyl Alcohol 81
Uranyl Chloride and Nitrate in Methyl Ester 81
Uranous Chloride in Water and Methyl Alcohol 82
Uranous Chloride in Acetone 82
The Existence of Aggregates and Their Properties, and the Effect of Rise in Tem
perature on the Aggregates 83
Neodymium Salts in Acid Solutions 84
Uranous Sulphate in Sulphuric Acid 85
Uranyl Nitrate in Nitric Acid, Uranyl Chloride in Hydrochloric Acid, and
Uranyl Sulphate in Sulphuric Acid 86
CHAPTER VI SUMMARY AND GENERAL DISCUSSION:
Mapping of Spectra 87
A Theory of Absorption Spectra 89
Solvation 92
The Uranyl and Uranous Bands 94
Aggregates and Their Properties 95
The Effect of Temperature on Absorption Spectra 98
DESCRIPTION OF PLATES 101
INDEX 102 |
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| spelling | Jones, Harry Clary 1865-1916 Verfasser (DE-588)117655600 aut The absorption spectra of solutions of comparatively rare salts, including those of Gadolinium, Dysprosium, and Samarium the spectrophotography of certain chemical reactions and the effect of high temperature on the absorption spectra of non-aqueous solutions by Harry C. Jones ; W. W. Strong Washington, DC Carnegie Institution 1911 VIII, 112 S. Ill. txt rdacontent n rdamedia nc rdacarrier Publication / Carnegie Institution of Washington 160 Absorption spectra Solution (Chemistry) Strong, W. W. 1883-1955 Verfasser (DE-588)1027579213 aut Elektronische Reproduktion München : Bayerische Staatsbibliothek, 2012 urn:nbn:de:bvb:12-bsb00067497-0 Carnegie Institution of Washington Publication 160 (DE-604)BV035415500 160 http://mdz-nbn-resolving.de/urn:nbn:de:bvb:12-bsb00067497-0 Resolving-System kostenfrei Volltext // Exemplar mit der Signatur: München, Bayerische Staatsbibliothek -- 4 Acad. 157 tg-160 HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=015756540&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Jones, Harry Clary 1865-1916 Strong, W. W. 1883-1955 The absorption spectra of solutions of comparatively rare salts, including those of Gadolinium, Dysprosium, and Samarium the spectrophotography of certain chemical reactions and the effect of high temperature on the absorption spectra of non-aqueous solutions Absorption spectra Solution (Chemistry) |
| title | The absorption spectra of solutions of comparatively rare salts, including those of Gadolinium, Dysprosium, and Samarium the spectrophotography of certain chemical reactions and the effect of high temperature on the absorption spectra of non-aqueous solutions |
| title_auth | The absorption spectra of solutions of comparatively rare salts, including those of Gadolinium, Dysprosium, and Samarium the spectrophotography of certain chemical reactions and the effect of high temperature on the absorption spectra of non-aqueous solutions |
| title_exact_search | The absorption spectra of solutions of comparatively rare salts, including those of Gadolinium, Dysprosium, and Samarium the spectrophotography of certain chemical reactions and the effect of high temperature on the absorption spectra of non-aqueous solutions |
| title_exact_search_txtP | The absorption spectra of solutions of comparatively rare salts, including those of Gadolinium, Dysprosium, and Samarium the spectrophotography of certain chemical reactions and the effect of high temperature on the absorption spectra of non-aqueous solutions |
| title_full | The absorption spectra of solutions of comparatively rare salts, including those of Gadolinium, Dysprosium, and Samarium the spectrophotography of certain chemical reactions and the effect of high temperature on the absorption spectra of non-aqueous solutions by Harry C. Jones ; W. W. Strong |
| title_fullStr | The absorption spectra of solutions of comparatively rare salts, including those of Gadolinium, Dysprosium, and Samarium the spectrophotography of certain chemical reactions and the effect of high temperature on the absorption spectra of non-aqueous solutions by Harry C. Jones ; W. W. Strong |
| title_full_unstemmed | The absorption spectra of solutions of comparatively rare salts, including those of Gadolinium, Dysprosium, and Samarium the spectrophotography of certain chemical reactions and the effect of high temperature on the absorption spectra of non-aqueous solutions by Harry C. Jones ; W. W. Strong |
| title_short | The absorption spectra of solutions of comparatively rare salts, including those of Gadolinium, Dysprosium, and Samarium |
| title_sort | the absorption spectra of solutions of comparatively rare salts including those of gadolinium dysprosium and samarium the spectrophotography of certain chemical reactions and the effect of high temperature on the absorption spectra of non aqueous solutions |
| title_sub | the spectrophotography of certain chemical reactions and the effect of high temperature on the absorption spectra of non-aqueous solutions |
| topic | Absorption spectra Solution (Chemistry) |
| topic_facet | Absorption spectra Solution (Chemistry) |
| url | http://mdz-nbn-resolving.de/urn:nbn:de:bvb:12-bsb00067497-0 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=015756540&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV035415500 |
| work_keys_str_mv | AT jonesharryclary theabsorptionspectraofsolutionsofcomparativelyraresaltsincludingthoseofgadoliniumdysprosiumandsamariumthespectrophotographyofcertainchemicalreactionsandtheeffectofhightemperatureontheabsorptionspectraofnonaqueoussolutions AT strongww theabsorptionspectraofsolutionsofcomparativelyraresaltsincludingthoseofgadoliniumdysprosiumandsamariumthespectrophotographyofcertainchemicalreactionsandtheeffectofhightemperatureontheabsorptionspectraofnonaqueoussolutions |