Physics of ferroelectrics: a modern perspective ; with 24 tables
Gespeichert in:
| Format: | Medienkombination Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Berlin [u.a.]
Springer
2007
|
| Schriftenreihe: | Topics in applied physics
105 |
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | XII, 360 S. zahlr. Ill. und graph. Darst. |
| ISBN: | 9783540345909 3540345906 |
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| 245 | 1 | 0 | |a Physics of ferroelectrics |b a modern perspective ; with 24 tables |c Karin M. Rabe ... (ed.) |
| 264 | 1 | |a Berlin [u.a.] |b Springer |c 2007 | |
| 300 | |a XII, 360 S. |b zahlr. Ill. und graph. Darst. | ||
| 490 | 1 | |a Topics in applied physics |v 105 | |
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Contents
Modern Physics of Ferroelectrics:
Essential Background
Karin M. Rabe, Matthew Dawber, Celine Lichtensteiger, Charles H.
Ahn, and Jean Marc Triscone . 1
1 Introduction. 1
2 Switching and Hysteresis Loops. 2
3 Crystallographic Signature of Ferroelectricity. 6
4 Materials. 8
4.1 Perovskite Oxides. 8
4.2 LiNbO3 . 14
4.3 Layered Oxide Ferroelectrics. 15
4.4 Other Ferroelectric Oxide Families. 17
4.5 Magnetic Ferroelectric Oxides. 18
4.6 Electronic Ferroelectrics. 19
4.7 Nonbulk Ferroelectrics. 19
5 Applications of Ferroelectric Materials. 20
5.1 Pyroelectric and Piezoelectric Devices. 20
5.2 Ferroelectric Memory Technology. 21
5.3 Potential Future Applications . 21
5.3.1 Ferroelectric Nanostructures. 21
5.3.2 Field Effect Devices . 22
5.3.3 Ferroelectric Device Fabrication Using Atomic Force
Microscopy. 22
5.3.4 Ferroelectric Cooling Devices . 23
6 Note from the Editors. 23
References. 23
Index. 29
Theory of Polarization: A Modern Approach
Raffaele Resta and David Vanderbilt . 31
1 Why is a Modern Approach Needed? . 31
1.1 Fallacy of the Clausius Mossotti Picture. 32
1.2 Fallacy of Defining Polarization via the Charge Distribution . . 34
2 Polarization as an Adiabatic Flow of Current. 36
2.1 How is Induced Polarization Measured?. 36
VIII Contents
2.2 How is Ferroelectric Polarization Measured?. 38
2.3 Basic Prescriptions for a Theory of Polarization . 40
3 Formal Description of the Berry Phase Theory. 41
3.1 Formulation in Continuous fc Space. 42
3.2 Formulation in Discrete fc Space. 44
3.3 The Quantum of Polarization . 46
3.4 Formal Polarization as a Multivalued Vector Quantity. 48
3.5 Mapping onto Wannier Centers. 50
4 Implications for Ferroelectrics. 52
4.1 Spontaneous Polarization. 53
4.2 Anomalous Dynamical Charges. 54
4.3 Piezoelectric Properties. 55
5 Further Theoretical Developments. 57
5.1 Polarization in an Applied Electric Field. 57
5.2 Interface Theorem and the Definition of Bound Charge. 58
5.3 Many Body and Noncrystalline Generalizations. 61
5.4 Polarization in Kohn Sham Density Functional Theory. 62
5.5 Localization, Polarization, and Fluctuations. 63
6 Summary. 64
References. 65
Index. 67
A Landau Primer for Ferroelectrics
Premi Chandra, Peter B. Littlewood . 69
1 Introduction. 69
2 Landau Devonshire Theory. 74
2.1 General Phenomenology. 74
2.2 Second Order (Continuous) Transition. 75
2.3 First Order (Discontinuous) Transition. 76
2.4 Coupling to Strain. 79
2.5 Domains. 81
3 Landau Ginzburg Theory. 84
3.1 General Considerations. 84
3.2 The Polarization Correlation Function. 85
3.3 The Levanyuk Ginzburg criterion. 86
3.4 Displacive and Order Disorder Transitions. 88
3.5 Recent Developments in Bulk Ferroelectricity . 91
4 Reduced Size and Other Boundary Effects. 92
4.1 General Discussion. 92
4.2 The Polarization at the Boundary. 93
4.3 Depolarization Effects. 96
4.4 Misfit Epitaxial Strain. 100
4.5 Inhomogeneous Effects . 102
5 Summary and (Some) Open Questions. 104
References . 106
Contents IX
Index. 115
First Principles Studies of Ferroelectric Oxides
Karin M. Rabe and Philippe Ghosez . 117
1 Introduction. 117
2 First Principles Methods. 118
3 Results for Perovskite Oxide Compounds. 123
3.1 Ground State Structure . 124
3.2 Phonons, Lattice Instabilities and Polarization. 127
3.3 Polarization Strain Coupling. 136
3.4 Dielectric and Piezoelectric Responses. 137
3.5 Results at Nonzero Temperature. 140
4 Results for Other Ferroelectric Oxide Compounds. 143
5 Results for Solid Solutions. 146
6 Results for Defects . 150
7 Results for Surfaces, Thin Films, Superlattices, Nanowires and
Nanoparticles. 152
8 Challenges and Prospects. 154
References. 156
Index. 172
Analogies and Differences between Ferroelectrics
and Ferromagnets
Nicola A. Spaldin. 175
1 Fundamentals. 177
1.1 Understanding the Origin of Spontaneous Polarization. 177
1.1.1 What Causes Ferroelectricity? . 177
1.1.2 What Causes Ferromagnetism?. 184
1.2 Domains. 188
2 Applications. 194
2.1 Ferroelectric Random Access Memories. 196
2.2 Magnetoresistive Random Access Memories. 196
3 Multiferroics. 198
3.1 The Scarcity of Ferromagnetic Ferroelectrics . 199
3.2 Magnetoelectric Coupling. 200
3.3 Some Materials Examples. 201
3.3.1 BiFeO3 . 201
3.3.2 BiMnO3. 204
3.3.3 YMnO3. 206
3.3.4 TbMnO3. 209
3.4 Composites. 209
4 Outlook. 210
References. 211
Index. 216
X Contents
Growth and Novel Applications of Epitaxial Oxide
Thin Films
Agham Bayan Posadas, Mikk Lippmaa, Fred J. Walker, Matthew
Dawber, Charles H. Ahn, and Jean Marc Triscone .219
1 Introduction.219
2 Thin Film Growth of Complex Oxides .221
2.1 Vacuum Chamber.221
2.2 Temperature Control and Monitoring .222
2.3 Pulsed Laser Deposition.227
2.3.1 Laser.228
2.3.2 Targets .230
2.3.3 Ablation Process.232
2.3.4 Film Growth Using PLD.235
2.4 Sputter Deposition.238
2.4.1 Sputtering Process .238
2.4.2 The Sputtering of Insulators.239
2.4.3 Process Gas.240
2.4.4 Preferential Sputtering.242
2.4.5 Technical Considerations in Sputter Deposition .242
2.4.6 Reactive Sputtering.244
2.5 Oxide Molecular Beam Epitaxy.244
2.5.1 Hardware .246
2.5.2 RHEED.247
2.5.3 Fundamentals of Growth.249
2.5.4 Alkaline Earth Oxide Growth.253
2.5.5 Perovskite Growth.254
3 Substrates.257
4 Applications of Epitaxial Oxide Thin Films.269
4.1 Strain Engineering and Superlattices.270
4.1.1 Strain Engineering in Epitaxial Thin Films.270
4.1.2 Strain in Superlattices.271
4.1.3 Electrostatic Coupling Between Layers.274
4.1.4 Selected Examples of Material Combinations.274
4.1.5 X Ray Characterization of Superlattices.277
4.2 Crystalline Oxides on Semiconductors (COS).279
4.2.1 Layer Sequenced COS Growth.281
4.2.2 How the Silicide Facilitates Epitaxy .285
4.3 Conclusions.289
References.290
Index.304
Contents XI
Ferroelectric Size Effects
Celine Lichtensteiger, Matthew Dawber, and Jean Marc Triscone .305
1 Size Effects in Ferroelectrics.305
2 Size Effects
in the Ginzburg Landau Devonshire Theory.306
3 Extrinsic Size Effects .307
4 Effect of Screening.308
4.1 Recent Experimental Work: Ultrathin Films on Metallic
Electrodes.310
4.1.1 Results of Combined Experimental and Theoretical
Investigations.316
4.1.2 Other Similar Studies.320
4.2 Scaling of the Coercive Field.321
4.3 Thin Films on Insulating Substrates.322
5 Superlattices.324
6 Other Geometries.326
6.1 Nanoparticles .327
6.2 Areal Size Effects.328
6.3 Self Patterning.328
6.4 Novel Ferroelectric Geometries .329
6.4.1 Nanotubes.329
6.4.2 Nanowires Nanorods.329
References.330
Index.336
Nanoscale Studies of Domain Walls in Epitaxial Ferroelectric
Thin Films
Patrycja Paruch, Thierry Giamarchi, and Jean Marc Triscone .339
1 Introduction.339
2 Ferroelectric Domain Walls
as Elastic Disordered Systems.340
3 Static and Dynamic Behavior
of Elastic Disordered Systems.341
4 Experimental Observation of Domain Wall Creep.344
5 Domain Wall Creep in a Commensurate Potential.347
6 Domain Wall Creep in a Random Potential.351
7 Experimental Observation of Domain Wall Roughness.354
8 Domain Walls in the Presence of Random Bond Disorder and
Dipolar Interactions.357
9 Recent Studies of Ferroelectric Domain Wall Dynamics.358
10 Conclusions.359
References.360
Index.362
XII Contents
APPENDIX A
Landau Free Energy Coefficients
Long Qing Chen.363
1 BaTiO3.364
2 SrTiO3.365
3 PbZr1_xTirrO3 (PZT).366
4 PbTiO3.368
5 LiTaO3 and LiNbO3.368
6 Sro.8Bi2.2Ta209.369
7 SrBi2Nb209.369
References.370
Index.371
Appendix B — Material—Substrate Combinations Tables
Celine Lichtensteiger and Matthew Dawber .373
Index.385 |
| adam_txt |
Contents
Modern Physics of Ferroelectrics:
Essential Background
Karin M. Rabe, Matthew Dawber, Celine Lichtensteiger, Charles H.
Ahn, and Jean Marc Triscone . 1
1 Introduction. 1
2 Switching and Hysteresis Loops. 2
3 Crystallographic Signature of Ferroelectricity. 6
4 Materials. 8
4.1 Perovskite Oxides. 8
4.2 LiNbO3 . 14
4.3 Layered Oxide Ferroelectrics. 15
4.4 Other Ferroelectric Oxide Families. 17
4.5 Magnetic Ferroelectric Oxides. 18
4.6 Electronic Ferroelectrics. 19
4.7 Nonbulk Ferroelectrics. 19
5 Applications of Ferroelectric Materials. 20
5.1 Pyroelectric and Piezoelectric Devices. 20
5.2 Ferroelectric Memory Technology. 21
5.3 Potential Future Applications . 21
5.3.1 Ferroelectric Nanostructures. 21
5.3.2 Field Effect Devices . 22
5.3.3 Ferroelectric Device Fabrication Using Atomic Force
Microscopy. 22
5.3.4 Ferroelectric Cooling Devices . 23
6 Note from the Editors. 23
References. 23
Index. 29
Theory of Polarization: A Modern Approach
Raffaele Resta and David Vanderbilt . 31
1 Why is a Modern Approach Needed? . 31
1.1 Fallacy of the Clausius Mossotti Picture. 32
1.2 Fallacy of Defining Polarization via the Charge Distribution . . 34
2 Polarization as an Adiabatic Flow of Current. 36
2.1 How is Induced Polarization Measured?. 36
VIII Contents
2.2 How is Ferroelectric Polarization Measured?. 38
2.3 Basic Prescriptions for a Theory of Polarization . 40
3 Formal Description of the Berry Phase Theory. 41
3.1 Formulation in Continuous fc Space. 42
3.2 Formulation in Discrete fc Space. 44
3.3 The Quantum of Polarization . 46
3.4 Formal Polarization as a Multivalued Vector Quantity. 48
3.5 Mapping onto Wannier Centers. 50
4 Implications for Ferroelectrics. 52
4.1 Spontaneous Polarization. 53
4.2 Anomalous Dynamical Charges. 54
4.3 Piezoelectric Properties. 55
5 Further Theoretical Developments. 57
5.1 Polarization in an Applied Electric Field. 57
5.2 Interface Theorem and the Definition of Bound Charge. 58
5.3 Many Body and Noncrystalline Generalizations. 61
5.4 Polarization in Kohn Sham Density Functional Theory. 62
5.5 Localization, Polarization, and Fluctuations. 63
6 Summary. 64
References. 65
Index. 67
A Landau Primer for Ferroelectrics
Premi Chandra, Peter B. Littlewood . 69
1 Introduction. 69
2 Landau Devonshire Theory. 74
2.1 General Phenomenology. 74
2.2 Second Order (Continuous) Transition. 75
2.3 First Order (Discontinuous) Transition. 76
2.4 Coupling to Strain. 79
2.5 Domains. 81
3 Landau Ginzburg Theory. 84
3.1 General Considerations. 84
3.2 The Polarization Correlation Function. 85
3.3 The Levanyuk Ginzburg criterion. 86
3.4 Displacive and Order Disorder Transitions. 88
3.5 Recent Developments in Bulk Ferroelectricity . 91
4 Reduced Size and Other Boundary Effects. 92
4.1 General Discussion. 92
4.2 The Polarization at the Boundary. 93
4.3 Depolarization Effects. 96
4.4 Misfit Epitaxial Strain. 100
4.5 Inhomogeneous Effects . 102
5 Summary and (Some) Open Questions. 104
References . 106
Contents IX
Index. 115
First Principles Studies of Ferroelectric Oxides
Karin M. Rabe and Philippe Ghosez . 117
1 Introduction. 117
2 First Principles Methods. 118
3 Results for Perovskite Oxide Compounds. 123
3.1 Ground State Structure . 124
3.2 Phonons, Lattice Instabilities and Polarization. 127
3.3 Polarization Strain Coupling. 136
3.4 Dielectric and Piezoelectric Responses. 137
3.5 Results at Nonzero Temperature. 140
4 Results for Other Ferroelectric Oxide Compounds. 143
5 Results for Solid Solutions. 146
6 Results for Defects . 150
7 Results for Surfaces, Thin Films, Superlattices, Nanowires and
Nanoparticles. 152
8 Challenges and Prospects. 154
References. 156
Index. 172
Analogies and Differences between Ferroelectrics
and Ferromagnets
Nicola A. Spaldin. 175
1 Fundamentals. 177
1.1 Understanding the Origin of Spontaneous Polarization. 177
1.1.1 What Causes Ferroelectricity? . 177
1.1.2 What Causes Ferromagnetism?. 184
1.2 Domains. 188
2 Applications. 194
2.1 Ferroelectric Random Access Memories. 196
2.2 Magnetoresistive Random Access Memories. 196
3 Multiferroics. 198
3.1 The Scarcity of Ferromagnetic Ferroelectrics . 199
3.2 Magnetoelectric Coupling. 200
3.3 Some Materials Examples. 201
3.3.1 BiFeO3 . 201
3.3.2 BiMnO3. 204
3.3.3 YMnO3. 206
3.3.4 TbMnO3. 209
3.4 Composites. 209
4 Outlook. 210
References. 211
Index. 216
X Contents
Growth and Novel Applications of Epitaxial Oxide
Thin Films
Agham Bayan Posadas, Mikk Lippmaa, Fred J. Walker, Matthew
Dawber, Charles H. Ahn, and Jean Marc Triscone .219
1 Introduction.219
2 Thin Film Growth of Complex Oxides .221
2.1 Vacuum Chamber.221
2.2 Temperature Control and Monitoring .222
2.3 Pulsed Laser Deposition.227
2.3.1 Laser.228
2.3.2 Targets .230
2.3.3 Ablation Process.232
2.3.4 Film Growth Using PLD.235
2.4 Sputter Deposition.238
2.4.1 Sputtering Process .238
2.4.2 The Sputtering of Insulators.239
2.4.3 Process Gas.240
2.4.4 Preferential Sputtering.242
2.4.5 Technical Considerations in Sputter Deposition .242
2.4.6 Reactive Sputtering.244
2.5 Oxide Molecular Beam Epitaxy.244
2.5.1 Hardware .246
2.5.2 RHEED.247
2.5.3 Fundamentals of Growth.249
2.5.4 Alkaline Earth Oxide Growth.253
2.5.5 Perovskite Growth.254
3 Substrates.257
4 Applications of Epitaxial Oxide Thin Films.269
4.1 Strain Engineering and Superlattices.270
4.1.1 Strain Engineering in Epitaxial Thin Films.270
4.1.2 Strain in Superlattices.271
4.1.3 Electrostatic Coupling Between Layers.274
4.1.4 Selected Examples of Material Combinations.274
4.1.5 X Ray Characterization of Superlattices.277
4.2 Crystalline Oxides on Semiconductors (COS).279
4.2.1 Layer Sequenced COS Growth.281
4.2.2 How the Silicide Facilitates Epitaxy .285
4.3 Conclusions.289
References.290
Index.304
Contents XI
Ferroelectric Size Effects
Celine Lichtensteiger, Matthew Dawber, and Jean Marc Triscone .305
1 Size Effects in Ferroelectrics.305
2 Size Effects
in the Ginzburg Landau Devonshire Theory.306
3 Extrinsic Size Effects .307
4 Effect of Screening.308
4.1 Recent Experimental Work: Ultrathin Films on Metallic
Electrodes.310
4.1.1 Results of Combined Experimental and Theoretical
Investigations.316
4.1.2 Other Similar Studies.320
4.2 Scaling of the Coercive Field.321
4.3 Thin Films on Insulating Substrates.322
5 Superlattices.324
6 Other Geometries.326
6.1 Nanoparticles .327
6.2 Areal Size Effects.328
6.3 Self Patterning.328
6.4 Novel Ferroelectric Geometries .329
6.4.1 Nanotubes.329
6.4.2 Nanowires Nanorods.329
References.330
Index.336
Nanoscale Studies of Domain Walls in Epitaxial Ferroelectric
Thin Films
Patrycja Paruch, Thierry Giamarchi, and Jean Marc Triscone .339
1 Introduction.339
2 Ferroelectric Domain Walls
as Elastic Disordered Systems.340
3 Static and Dynamic Behavior
of Elastic Disordered Systems.341
4 Experimental Observation of Domain Wall Creep.344
5 Domain Wall Creep in a Commensurate Potential.347
6 Domain Wall Creep in a Random Potential.351
7 Experimental Observation of Domain Wall Roughness.354
8 Domain Walls in the Presence of Random Bond Disorder and
Dipolar Interactions.357
9 Recent Studies of Ferroelectric Domain Wall Dynamics.358
10 Conclusions.359
References.360
Index.362
XII Contents
APPENDIX A
Landau Free Energy Coefficients
Long Qing Chen.363
1 BaTiO3.364
2 SrTiO3.365
3 PbZr1_xTirrO3 (PZT).366
4 PbTiO3.368
5 LiTaO3 and LiNbO3.368
6 Sro.8Bi2.2Ta209.369
7 SrBi2Nb209.369
References.370
Index.371
Appendix B — Material—Substrate Combinations Tables
Celine Lichtensteiger and Matthew Dawber .373
Index.385 |
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| any_adam_object_boolean | 1 |
| building | Verbundindex |
| bvnumber | BV022543392 |
| classification_rvk | UP 4700 |
| ctrlnum | (OCoLC)634886847 (DE-599)BVBBV022543392 |
| dewey-full | 537.2448 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 537 - Electricity and electronics |
| dewey-raw | 537.2448 |
| dewey-search | 537.2448 |
| dewey-sort | 3537.2448 |
| dewey-tens | 530 - Physics |
| discipline | Physik |
| discipline_str_mv | Physik |
| format | Kit Book |
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| id | DE-604.BV022543392 |
| illustrated | Illustrated |
| index_date | 2024-07-02T18:11:04Z |
| indexdate | 2024-07-20T09:21:11Z |
| institution | BVB |
| isbn | 9783540345909 3540345906 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-015749798 |
| oclc_num | 634886847 |
| open_access_boolean | |
| owner | DE-703 DE-83 DE-11 |
| owner_facet | DE-703 DE-83 DE-11 |
| physical | XII, 360 S. zahlr. Ill. und graph. Darst. |
| publishDate | 2007 |
| publishDateSearch | 2007 |
| publishDateSort | 2007 |
| publisher | Springer |
| record_format | marc |
| series | Topics in applied physics |
| series2 | Topics in applied physics |
| spelling | Physics of ferroelectrics a modern perspective ; with 24 tables Karin M. Rabe ... (ed.) Berlin [u.a.] Springer 2007 XII, 360 S. zahlr. Ill. und graph. Darst. Topics in applied physics 105 Ferroelektrikum (DE-588)4154121-2 gnd rswk-swf Ferroelektrikum (DE-588)4154121-2 s DE-604 Rabe, Karin M. Sonstige oth Topics in applied physics 105 (DE-604)BV008007504 105 text/html http://deposit.dnb.de/cgi-bin/dokserv?id=2905038&prov=M&dok_var=1&dok_ext=htm Inhaltstext HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=015749798&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Physics of ferroelectrics a modern perspective ; with 24 tables Topics in applied physics Ferroelektrikum (DE-588)4154121-2 gnd |
| subject_GND | (DE-588)4154121-2 |
| title | Physics of ferroelectrics a modern perspective ; with 24 tables |
| title_auth | Physics of ferroelectrics a modern perspective ; with 24 tables |
| title_exact_search | Physics of ferroelectrics a modern perspective ; with 24 tables |
| title_exact_search_txtP | Physics of ferroelectrics a modern perspective ; with 24 tables |
| title_full | Physics of ferroelectrics a modern perspective ; with 24 tables Karin M. Rabe ... (ed.) |
| title_fullStr | Physics of ferroelectrics a modern perspective ; with 24 tables Karin M. Rabe ... (ed.) |
| title_full_unstemmed | Physics of ferroelectrics a modern perspective ; with 24 tables Karin M. Rabe ... (ed.) |
| title_short | Physics of ferroelectrics |
| title_sort | physics of ferroelectrics a modern perspective with 24 tables |
| title_sub | a modern perspective ; with 24 tables |
| topic | Ferroelektrikum (DE-588)4154121-2 gnd |
| topic_facet | Ferroelektrikum |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=2905038&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=015749798&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV008007504 |
| work_keys_str_mv | AT rabekarinm physicsofferroelectricsamodernperspectivewith24tables |