Valency and bonding: a natural bond orbital donor-acceptor perspective
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| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Cambridge, UK [u.a.]
Cambridge University Press
2005
|
| Edition: | 1. publ. |
| Subjects: | |
| Online Access: | Table of contents Inhaltsverzeichnis |
| Item Description: | Includes bibliographical references and indexes |
| Physical Description: | IX, 749 S. Ill., graph. Darst. |
| ISBN: | 0521831288 9780521831284 |
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Record in the Search Index
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| adam_text | VALENCY AND BONDING A NATURAL BOND ORBITAL DONOR-ACCEPTOR PERSPECTIVE
FRANK WEINHOLD AND CLARK R. LANDIS DEPARTMENT OF CHEMISTRY, UNIVERSITY
OF WISCONSIN-MADISON, WISCONSIN 53706 CAMBRIDGE UNIVERSITY PRESS
CONTENTS PREFACE PAGE VII 1 INTRODUCTION AND THEORETICAL BACKGROUND 1
1.1 THE SCHRODINGER EQUATION AND MODELS OF CHEMISTRY 1 1.2 HYDROGEN-ATOM
ORBITALS 8 1.3 MANY-ELECTRON SYSTEMS: HARTREE-FOCK AND CORRELATED
TREATMENTS 13 1.4 PERTURBATION THEORY FOR ORBITALS IN THE HARTREE-FOCK
FRAMEWORK: THE DONOR-ACCEPTOR PARADIGM 16 1.5 DENSITY MATRICES, NATURAL
LOCALIZED AND DELOCALIZED ORBITALS, AND THE LEWIS-STRUCTURE PICTURE 21
1.6 NATURAL RESONANCE STRUCTURES AND WEIGHTINGS 32 1.7 PAULI-EXCHANGE
ANTISYMMETRY AND STERIC REPULSIONS 36 1.8 SUMMARY 40 NOTES FOR CHAPTER 1
41 2 ELECTROSTATIC AND IONIC BONDING 45 2.1 INTRODUCTION 45 2.2 ATOMIC
AND IONIC ORBITALS 47 2.3 CHARGE TRANSFER AND HYBRIDIZATION IN IONIC
BONDING 49 2.4 DONOR-ACCEPTOR THEORY OF HYBRIDIZATION IN IONIC BONDING
55 2.5 IONIC-COVALENT TRANSITIONS 60 2.6 ION-DIPOLE AND DIPOLE-DIPOLE
BONDING 64 2.7 BENT IONIC COMPOUNDS OF HEAVY ALKALINE EARTHS 73 2.8
IONIC BONDING IN D-BLOCK ELEMENTS 76 2.9 SUMMARY 86 NOTES FOR CHAPTER 2
87 VI CONTENTS 3 MOLECULAR BONDING IN S/P-BLOCK ELEMENTS 89 3.1
INTRODUCTION 89 3.2 COVALENT AND POLAR COVALENT BONDING 90 3.3
CONJUGATION AND AROMATICITY 182 3.4 HYPERCONJUGATION 215 3.5
HYPERVALENCY: 3C/4E TU BONDS 275 3.6 HYPOVALENCY: 3C/2E BRIDGE BONDS
306 3.7 SUMMARY 351 NOTES FOR CHAPTER 3 353 4 MOLECULAR BONDING IN THE
D-BLOCK ELEMENTS 363 4.1 INTRODUCTION 363 4.2 LEWIS-LIKE STRUCTURES FOR
THE D-BLOCK ELEMENTS 365 4.3 HYBRIDIZATION AND MOLECULAR SHAPE 372 4.4
COVALENT AND POLAR-COVALENT BONDING 387 4.5 COORDINATIVE METAL-LIGAND
BONDING 434 4.6 BEYOND SIGMA BONDING: TRANSITION-METAL HYPERBONDING AND
PI BACK/FRONTBONDING 447 4.7 HYPOVALENCY, AGOSTIC INTERACTIONS, AND
RELATED ASPECTS OF CATALYTIC ACTIVATION AT METAL CENTERS 479 4.8
HYPERCONJUGATIVE EFFECTS 519 4.9 MULTIELECTRON COORDINATION 522 4.10
VERTICAL TRENDS IN TRANSITION-METAL BONDING 545 4.11 LOCALIZED VERSUS
DELOCALIZED DESCRIPTIONS OF TRANSITION-METAL BONDING AND HYPERBONDING
563 4.12 SUMMARY 573 NOTES FOR CHAPTER 4 575 5 SUPRAMOLECULAR BONDING
579 5.1 AN INTRODUCTORY OVERVIEW OF INTERMOLECULAR FORCES 579 5.2
HYDROGEN BONDING 593 5.3 CHARGE-TRANSFER COMPLEXES 661 5.4
TRANSITION-STATE SPECIES 678 5.5 COUPLING OF INTRAMOLECULAR AND
INTERMOLECULAR INTERACTIONS 693 5.6 SUMMARY 702 NOTES FOR CHAPTER 5 704
APPENDIX A. METHODS AND BASIS SETS 710 APPENDIX B. CHEMICAL PERIODICITY
715 APPENDIX C. UNITS 723 CHEMICAL-SPECIES INDEX 727 AUTHOR INDEX 732
SUBJECT INDEX 740
|
| adam_txt |
VALENCY AND BONDING A NATURAL BOND ORBITAL DONOR-ACCEPTOR PERSPECTIVE
FRANK WEINHOLD AND CLARK R. LANDIS DEPARTMENT OF CHEMISTRY, UNIVERSITY
OF WISCONSIN-MADISON, WISCONSIN 53706 CAMBRIDGE UNIVERSITY PRESS
CONTENTS PREFACE PAGE VII 1 INTRODUCTION AND THEORETICAL BACKGROUND 1
1.1 THE SCHRODINGER EQUATION AND MODELS OF CHEMISTRY 1 1.2 HYDROGEN-ATOM
ORBITALS 8 1.3 MANY-ELECTRON SYSTEMS: HARTREE-FOCK AND CORRELATED
TREATMENTS 13 1.4 PERTURBATION THEORY FOR ORBITALS IN THE HARTREE-FOCK
FRAMEWORK: THE DONOR-ACCEPTOR PARADIGM 16 1.5 DENSITY MATRICES, NATURAL
LOCALIZED AND DELOCALIZED ORBITALS, AND THE LEWIS-STRUCTURE PICTURE 21
1.6 NATURAL RESONANCE STRUCTURES AND WEIGHTINGS 32 1.7 PAULI-EXCHANGE
ANTISYMMETRY AND STERIC REPULSIONS 36 1.8 SUMMARY 40 NOTES FOR CHAPTER 1
41 2 ELECTROSTATIC AND IONIC BONDING 45 2.1 INTRODUCTION 45 2.2 ATOMIC
AND IONIC ORBITALS 47 2.3 CHARGE TRANSFER AND HYBRIDIZATION IN IONIC
BONDING 49 2.4 DONOR-ACCEPTOR THEORY OF HYBRIDIZATION IN IONIC BONDING
55 2.5 IONIC-COVALENT TRANSITIONS 60 2.6 ION-DIPOLE AND DIPOLE-DIPOLE
BONDING 64 2.7 BENT IONIC COMPOUNDS OF HEAVY ALKALINE EARTHS 73 2.8
IONIC BONDING IN D-BLOCK ELEMENTS 76 2.9 SUMMARY 86 NOTES FOR CHAPTER 2
87 VI CONTENTS 3 MOLECULAR BONDING IN S/P-BLOCK ELEMENTS 89 3.1
INTRODUCTION 89 3.2 COVALENT AND POLAR COVALENT BONDING 90 3.3
CONJUGATION AND AROMATICITY 182 3.4 HYPERCONJUGATION 215 3.5
HYPERVALENCY: 3C/4E "TU BONDS" 275 3.6 HYPOVALENCY: 3C/2E BRIDGE BONDS
306 3.7 SUMMARY 351 NOTES FOR CHAPTER 3 353 4 MOLECULAR BONDING IN THE
D-BLOCK ELEMENTS 363 4.1 INTRODUCTION 363 4.2 LEWIS-LIKE STRUCTURES FOR
THE D-BLOCK ELEMENTS 365 4.3 HYBRIDIZATION AND MOLECULAR SHAPE 372 4.4
COVALENT AND POLAR-COVALENT BONDING 387 4.5 COORDINATIVE METAL-LIGAND
BONDING 434 4.6 BEYOND SIGMA BONDING: TRANSITION-METAL HYPERBONDING AND
PI BACK/FRONTBONDING 447 4.7 HYPOVALENCY, AGOSTIC INTERACTIONS, AND
RELATED ASPECTS OF CATALYTIC ACTIVATION AT METAL CENTERS 479 4.8
HYPERCONJUGATIVE EFFECTS 519 4.9 MULTIELECTRON COORDINATION 522 4.10
VERTICAL TRENDS IN TRANSITION-METAL BONDING 545 4.11 LOCALIZED VERSUS
DELOCALIZED DESCRIPTIONS OF TRANSITION-METAL BONDING AND HYPERBONDING
563 4.12 SUMMARY 573 NOTES FOR CHAPTER 4 575 5 SUPRAMOLECULAR BONDING
579 5.1 AN INTRODUCTORY OVERVIEW OF INTERMOLECULAR FORCES 579 5.2
HYDROGEN BONDING 593 5.3 CHARGE-TRANSFER COMPLEXES 661 5.4
TRANSITION-STATE SPECIES 678 5.5 COUPLING OF INTRAMOLECULAR AND
INTERMOLECULAR INTERACTIONS 693 5.6 SUMMARY 702 NOTES FOR CHAPTER 5 704
APPENDIX A. METHODS AND BASIS SETS 710 APPENDIX B. CHEMICAL PERIODICITY
715 APPENDIX C. UNITS 723 CHEMICAL-SPECIES INDEX 727 AUTHOR INDEX 732
SUBJECT INDEX 740 |
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| spelling | Weinhold, Frank Verfasser aut Valency and bonding a natural bond orbital donor-acceptor perspective Frank Weinhold and Clark R. Landis 1. publ. Cambridge, UK [u.a.] Cambridge University Press 2005 IX, 749 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and indexes Liaisons chimiques Structure moléculaire Valence (Chimie théorique) Valence (Theoretical chemistry) Chemical bonds Molecular structure Valenz Chemie (DE-588)4187347-6 gnd rswk-swf Chemische Bindung (DE-588)4009843-6 gnd rswk-swf (DE-588)4123623-3 Lehrbuch gnd-content Chemische Bindung (DE-588)4009843-6 s Valenz Chemie (DE-588)4187347-6 s DE-604 Landis, Clark R. Verfasser aut http://www.loc.gov/catdir/toc/fy0602/2005047076.html Table of contents HEBIS Datenaustausch Darmstadt application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=014758751&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Weinhold, Frank Landis, Clark R. Valency and bonding a natural bond orbital donor-acceptor perspective Liaisons chimiques Structure moléculaire Valence (Chimie théorique) Valence (Theoretical chemistry) Chemical bonds Molecular structure Valenz Chemie (DE-588)4187347-6 gnd Chemische Bindung (DE-588)4009843-6 gnd |
| subject_GND | (DE-588)4187347-6 (DE-588)4009843-6 (DE-588)4123623-3 |
| title | Valency and bonding a natural bond orbital donor-acceptor perspective |
| title_auth | Valency and bonding a natural bond orbital donor-acceptor perspective |
| title_exact_search | Valency and bonding a natural bond orbital donor-acceptor perspective |
| title_exact_search_txtP | Valency and bonding a natural bond orbital donor-acceptor perspective |
| title_full | Valency and bonding a natural bond orbital donor-acceptor perspective Frank Weinhold and Clark R. Landis |
| title_fullStr | Valency and bonding a natural bond orbital donor-acceptor perspective Frank Weinhold and Clark R. Landis |
| title_full_unstemmed | Valency and bonding a natural bond orbital donor-acceptor perspective Frank Weinhold and Clark R. Landis |
| title_short | Valency and bonding |
| title_sort | valency and bonding a natural bond orbital donor acceptor perspective |
| title_sub | a natural bond orbital donor-acceptor perspective |
| topic | Liaisons chimiques Structure moléculaire Valence (Chimie théorique) Valence (Theoretical chemistry) Chemical bonds Molecular structure Valenz Chemie (DE-588)4187347-6 gnd Chemische Bindung (DE-588)4009843-6 gnd |
| topic_facet | Liaisons chimiques Structure moléculaire Valence (Chimie théorique) Valence (Theoretical chemistry) Chemical bonds Molecular structure Valenz Chemie Chemische Bindung Lehrbuch |
| url | http://www.loc.gov/catdir/toc/fy0602/2005047076.html http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=014758751&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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