Surface-enhanced vibrational spectroscopy:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Chichester [u.a.]
Wiley
2006
|
| Schlagworte: | |
| Online-Zugang: | Table of contents Inhaltsverzeichnis |
| Beschreibung: | Includes bibliographical references and index |
| Beschreibung: | XXV, 233 S. Ill., graph. Darst. |
| ISBN: | 9780471607311 0471607312 |
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| 100 | 1 | |a Aroca, Ricardo |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Surface-enhanced vibrational spectroscopy |c Ricardo Aroca |
| 246 | 1 | 3 | |a Surface enhanced vibrational spectroscopy |
| 264 | 1 | |a Chichester [u.a.] |b Wiley |c 2006 | |
| 300 | |a XXV, 233 S. |b Ill., graph. Darst. | ||
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| 500 | |a Includes bibliographical references and index | ||
| 650 | 4 | |a Raman, Effet exalté de surface | |
| 650 | 4 | |a Spectre de vibration | |
| 650 | 4 | |a Spectroscopie moléculaire | |
| 650 | 4 | |a Molecular spectroscopy | |
| 650 | 4 | |a Raman effect, Surface enhanced | |
| 650 | 4 | |a Vibrational spectra | |
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Datensatz im Suchindex
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| adam_text | SURFACE-ENHANCED VIBRATIONAL SPECTROSCOPY RICARDO AROCA UNIVERSITY OF
WINDSOR, ONTARIO, CANADA JOHN WILEY & SONS, LTD CONTENTS PREFACE XI
ACKNOWLEDGMENTS XVII GLOSSARY XIX 1 THEORY OF MOLECULAR VIBRATIONS. THE
ORIGIN OF INFRARED AND RAMAN SPECTRA 1 1.1 ELECTRONIC, VIBRATIONAL,
ROTATIONAL AND TRANSLATIONAL ENERGY 1 1.1.1 ELECTRONIC STRUCTURE OF
MOLECULES 2 1.2 SEPARATION OF NUCLEAR AND ELECTRONIC MOTIONS 4 1.2.1
EXAMPLE. THE POTENTIAL ENERGY FUNCTION OF DIATOMIC MOLECULES 6 1.3
VIBRATIONS IN POLYATOMIC MOLECULES 7 1.4 EQUILIBRIUM PROPERTIES. DIPOLE
MOMENT AND POLARIZABILITY 10 1.5 FUNDAMENTAL VIBRATIONAL TRANSITIONS IN
THE INFRARED AND RAMAN REGIONS 12 1.6 SYMMETRY OF NORMAL MODES AND
VIBRATIONAL STATES 13 1.7 SELECTION RULES 18 1.8 THE EXAMPLE OF AB
INITIO COMPUTATION OF THE RAMAN AND INFRARED SPECTRA 20 1.8.1
CONVENTIONS FOR MOLECULAR AXES 24 1.9 VIBRATIONAL INTENSITIES 24 1.9.1
RAMAN INTENSITIES 29 1.10 DEFINITION OF CROSS-SECTION 29 1.11 THE UNITS
OF ENERGY AND FORCE CONSTANTS 31 REFERENCES 32 CONTENTS THE INTERACTION
OF LIGHT WITH NANOSCOPIC METAL PARTICLES AND MOLECULES ON SMOOTH
REFLECTING SURFACES 35 2.1 ELECTRIC PERMITTIVITY AND REFRACTIVE INDEX 38
2.2 PROPAGATION OF ELECTROMAGNETIC WAVES AND THE OPTICAL PROPERTIES OF
MATERIALS 41 2.2.1 FREQUENCY DISPERSION IN SOLIDS 45 2.2.2 METALS 48 2.3
SCATTERING AND ABSORPTION BY NANOSCOPIC PARTICLES 50 2.3.1 SCATTERING
AND ABSORPTION COMPUTATIONS 53 2.3.2 MIE COMPUTATIONS 57 2.4
REFLECTION-ABSORPTION INFRARED SPECTROSCOPY ON SMOOTH METAL SURFACES 59
2.4.1 REFLECTION COEFFICIENTS AND REFLECTANCE 60 2.4.2
REFLECTION-ABSORPTION INFRARED SPECTROSCOPY (RAIRS) 64 2.4.3 RAIRS
EXAMPLE 65 REFERENCES 69 SURFACE-ENHANCED RAMAN SCATTERING (SERS) 73 3.1
ELECTROMAGNETIC ENHANCEMENT MECHANISM 76 3.1.1 DEFINITION OF SERS 76
3.1.2 SINGLE PARTICLE SERS MODEL SYSTEMS 77 3.1.3 SPHERICAL MODEL 79
3.1.4 THE SPHEROIDAL MODEL 85 3.1.5 THE SHAPE FACTOR, AGGREGATES AND
FRACTALS 89 3.1.6 DISTANCE DEPENDENCE 92 3.1.7 COVERAGE DEPENDENCE OF
SERS 96 REFERENCES 101 CHEMICAL EFFECTS AND THE SERS SPECTRUM 107 4.1
PHYSICAL AND CHEMICAL ADSORPTION 107 4.2 SERS/SERRS OF PHYSICALLY
ADSORBED MOLECULES 112 4.3 SERS OF CHEMICALLY ADSORBED MOLECULES WITHOUT
ELECTRONIC RESONANCE EXCITATION 113 4.4 SERS OF CHEMICALLY ADSORBED
MOLECULES WITH CHARGE TRANSFER EXCITATION 122 CONTENTS IX 4.5
METAL-MOLECULE OR MOLECULE-METAL CHARGE TRANSFER 124 4.6 SERRS FROM A
SURFACE COMPLEX 127 REFERENCES 129 5 IS SERS MOLECULE SPECIFIC? 133
REFERENCES 138 6 SERS/SERRS, THE ANALYTICAL TOOL 141 6.1 AVERAGE SERS ON
METAL COLLOIDS. PREPARATION AND PROPERTIES 143 6.1.1 SILVER COLLOIDS 144
6.1.2 GOLD COLLOID 146 6.1.3 COPPER COLLOID 148 6.2 METAL COLLOIDS. THE
BACKGROUND SERS 149 6.3 METAL COLLOIDS. MAXIMIZING THE AVERAGE SERS IN
SOLUTION 152 6.4 AVERAGE SERS ON METAL ISLAND FILMS 156 6.5 AVERAGE SERS
ON ROUGH ELECTRODES 162 6.6 ULTRASENSITIVE SERS ANALYSIS AND SINGLE
MOLECULE DETECTION 164 6.7 UNIQUENESS OF ULTRASENSITIVE CHEMICAL
ANALYSIS. THE MOVING TARGET 171 6.8 APPLICATIONS AND OUTLOOK 174
REFERENCES 176 7 SURFACE-ENHANCED INFRARED SPECTROSCOPY 185 7.1 OVERVIEW
185 7.2 THEORETICAL MODELS FOR SEIRA 192 7.3 SEIRA-ACTIVE SUBSTRATES 198
7.4 INTERPRETATION OF THE OBSERVED SEIRA SPECTRA 203 7.5 APPLICATIONS OF
SEIRA 210 7.5.1 SEIRA OF ULTRATHIN FILMS 210 7.5.2 SURFACE
PHOTOCHEMISTRY AND CATALYTIC REACTIONS 211 7.5.3 ELECTROCHEMISTRY 211
7.5.4 ANALYTICAL APPLICATIONS 212 REFERENCES 214 INDEX 223
|
| adam_txt |
SURFACE-ENHANCED VIBRATIONAL SPECTROSCOPY RICARDO AROCA UNIVERSITY OF
WINDSOR, ONTARIO, CANADA JOHN WILEY & SONS, LTD CONTENTS PREFACE XI
ACKNOWLEDGMENTS XVII GLOSSARY XIX 1 THEORY OF MOLECULAR VIBRATIONS. THE
ORIGIN OF INFRARED AND RAMAN SPECTRA 1 1.1 ELECTRONIC, VIBRATIONAL,
ROTATIONAL AND TRANSLATIONAL ENERGY 1 1.1.1 ELECTRONIC STRUCTURE OF
MOLECULES 2 1.2 SEPARATION OF NUCLEAR AND ELECTRONIC MOTIONS 4 1.2.1
EXAMPLE. THE POTENTIAL ENERGY FUNCTION OF DIATOMIC MOLECULES 6 1.3
VIBRATIONS IN POLYATOMIC MOLECULES 7 1.4 EQUILIBRIUM PROPERTIES. DIPOLE
MOMENT AND POLARIZABILITY 10 1.5 FUNDAMENTAL VIBRATIONAL TRANSITIONS IN
THE INFRARED AND RAMAN REGIONS 12 1.6 SYMMETRY OF NORMAL MODES AND
VIBRATIONAL STATES 13 1.7 SELECTION RULES 18 1.8 THE EXAMPLE OF AB
INITIO COMPUTATION OF THE RAMAN AND INFRARED SPECTRA 20 1.8.1
CONVENTIONS FOR MOLECULAR AXES 24 1.9 VIBRATIONAL INTENSITIES 24 1.9.1
RAMAN INTENSITIES 29 1.10 DEFINITION OF CROSS-SECTION 29 1.11 THE UNITS
OF ENERGY AND FORCE CONSTANTS 31 REFERENCES 32 CONTENTS THE INTERACTION
OF LIGHT WITH NANOSCOPIC METAL PARTICLES AND MOLECULES ON SMOOTH
REFLECTING SURFACES 35 2.1 ELECTRIC PERMITTIVITY AND REFRACTIVE INDEX 38
2.2 PROPAGATION OF ELECTROMAGNETIC WAVES AND THE OPTICAL PROPERTIES OF
MATERIALS 41 2.2.1 FREQUENCY DISPERSION IN SOLIDS 45 2.2.2 METALS 48 2.3
SCATTERING AND ABSORPTION BY NANOSCOPIC PARTICLES 50 2.3.1 SCATTERING
AND ABSORPTION COMPUTATIONS 53 2.3.2 MIE COMPUTATIONS 57 2.4
REFLECTION-ABSORPTION INFRARED SPECTROSCOPY ON SMOOTH METAL SURFACES 59
2.4.1 REFLECTION COEFFICIENTS AND REFLECTANCE 60 2.4.2
REFLECTION-ABSORPTION INFRARED SPECTROSCOPY (RAIRS) 64 2.4.3 RAIRS
EXAMPLE 65 REFERENCES 69 SURFACE-ENHANCED RAMAN SCATTERING (SERS) 73 3.1
ELECTROMAGNETIC ENHANCEMENT MECHANISM 76 3.1.1 DEFINITION OF SERS 76
3.1.2 SINGLE PARTICLE SERS MODEL SYSTEMS 77 3.1.3 SPHERICAL MODEL 79
3.1.4 THE SPHEROIDAL MODEL 85 3.1.5 THE SHAPE FACTOR, AGGREGATES AND
FRACTALS 89 3.1.6 DISTANCE DEPENDENCE 92 3.1.7 COVERAGE DEPENDENCE OF
SERS 96 REFERENCES 101 CHEMICAL EFFECTS AND THE SERS SPECTRUM 107 4.1
PHYSICAL AND CHEMICAL ADSORPTION 107 4.2 SERS/SERRS OF PHYSICALLY
ADSORBED MOLECULES 112 4.3 SERS OF CHEMICALLY ADSORBED MOLECULES WITHOUT
ELECTRONIC RESONANCE EXCITATION 113 4.4 SERS OF CHEMICALLY ADSORBED
MOLECULES WITH CHARGE TRANSFER EXCITATION 122 CONTENTS IX 4.5
METAL-MOLECULE OR MOLECULE-METAL CHARGE TRANSFER 124 4.6 SERRS FROM A
SURFACE COMPLEX 127 REFERENCES 129 5 IS SERS MOLECULE SPECIFIC? 133
REFERENCES 138 6 SERS/SERRS, THE ANALYTICAL TOOL 141 6.1 AVERAGE SERS ON
METAL COLLOIDS. PREPARATION AND PROPERTIES 143 6.1.1 SILVER COLLOIDS 144
6.1.2 GOLD COLLOID 146 6.1.3 COPPER COLLOID 148 6.2 METAL COLLOIDS. THE
BACKGROUND SERS 149 6.3 METAL COLLOIDS. MAXIMIZING THE AVERAGE SERS IN
SOLUTION 152 6.4 AVERAGE SERS ON METAL ISLAND FILMS 156 6.5 AVERAGE SERS
ON ROUGH ELECTRODES 162 6.6 ULTRASENSITIVE SERS ANALYSIS AND SINGLE
MOLECULE DETECTION 164 6.7 UNIQUENESS OF ULTRASENSITIVE CHEMICAL
ANALYSIS. THE MOVING TARGET 171 6.8 APPLICATIONS AND OUTLOOK 174
REFERENCES 176 7 SURFACE-ENHANCED INFRARED SPECTROSCOPY 185 7.1 OVERVIEW
185 7.2 THEORETICAL MODELS FOR SEIRA 192 7.3 SEIRA-ACTIVE SUBSTRATES 198
7.4 INTERPRETATION OF THE OBSERVED SEIRA SPECTRA 203 7.5 APPLICATIONS OF
SEIRA 210 7.5.1 SEIRA OF ULTRATHIN FILMS 210 7.5.2 SURFACE
PHOTOCHEMISTRY AND CATALYTIC REACTIONS 211 7.5.3 ELECTROCHEMISTRY 211
7.5.4 ANALYTICAL APPLICATIONS 212 REFERENCES 214 INDEX 223 |
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| id | DE-604.BV021515033 |
| illustrated | Illustrated |
| index_date | 2024-07-02T14:20:17Z |
| indexdate | 2024-07-09T20:37:34Z |
| institution | BVB |
| isbn | 9780471607311 0471607312 |
| language | English |
| lccn | 2005036662 |
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| physical | XXV, 233 S. Ill., graph. Darst. |
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| spelling | Aroca, Ricardo Verfasser aut Surface-enhanced vibrational spectroscopy Ricardo Aroca Surface enhanced vibrational spectroscopy Chichester [u.a.] Wiley 2006 XXV, 233 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and index Raman, Effet exalté de surface Spectre de vibration Spectroscopie moléculaire Molecular spectroscopy Raman effect, Surface enhanced Vibrational spectra Oberflächenverstärkter Raman-Effekt (DE-588)4172264-4 gnd rswk-swf Oberflächenverstärkter Raman-Effekt (DE-588)4172264-4 s DE-604 http://www.loc.gov/catdir/toc/ecip065/2005036662.html Table of contents HEBIS Datenaustausch Darmstadt application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=014731603&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Aroca, Ricardo Surface-enhanced vibrational spectroscopy Raman, Effet exalté de surface Spectre de vibration Spectroscopie moléculaire Molecular spectroscopy Raman effect, Surface enhanced Vibrational spectra Oberflächenverstärkter Raman-Effekt (DE-588)4172264-4 gnd |
| subject_GND | (DE-588)4172264-4 |
| title | Surface-enhanced vibrational spectroscopy |
| title_alt | Surface enhanced vibrational spectroscopy |
| title_auth | Surface-enhanced vibrational spectroscopy |
| title_exact_search | Surface-enhanced vibrational spectroscopy |
| title_exact_search_txtP | Surface-enhanced vibrational spectroscopy |
| title_full | Surface-enhanced vibrational spectroscopy Ricardo Aroca |
| title_fullStr | Surface-enhanced vibrational spectroscopy Ricardo Aroca |
| title_full_unstemmed | Surface-enhanced vibrational spectroscopy Ricardo Aroca |
| title_short | Surface-enhanced vibrational spectroscopy |
| title_sort | surface enhanced vibrational spectroscopy |
| topic | Raman, Effet exalté de surface Spectre de vibration Spectroscopie moléculaire Molecular spectroscopy Raman effect, Surface enhanced Vibrational spectra Oberflächenverstärkter Raman-Effekt (DE-588)4172264-4 gnd |
| topic_facet | Raman, Effet exalté de surface Spectre de vibration Spectroscopie moléculaire Molecular spectroscopy Raman effect, Surface enhanced Vibrational spectra Oberflächenverstärkter Raman-Effekt |
| url | http://www.loc.gov/catdir/toc/ecip065/2005036662.html http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=014731603&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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