High-efficiency multicrystalline silicon solar cells:
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
München
Verl. Dr. Hut
2005
|
| Edition: | 1. Aufl. |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Zugl.: Konstanz, Univ., Diss., 2005 |
| Physical Description: | V, 190 S. Ill., graph. Darst. |
| ISBN: | 3899632605 |
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| adam_text | IMAGE 1
TABLE OF CONTENTS
TABLE OF CONTENTS
ACKNOWLEDGEMENTS I
1 INTRODUCTION 1
1.1 THESIS MOTIVATION 1
1.2 THESIS OUTLINE 3
2 CRYSTALLINE SILICON SOLAR CELLS 5
2.1 INTRODUCTION 5
2.2 OPERATION PRINCIPLE AND BASIC EQUATIONS OF DEVICE PHYSICS 5
2.2.1 CARRIER DENSITY AND THE ELECTROCHEMICAL POTENTIAL 6
2.2.2 MINORITY CARRIER LIFETIME AND RECOMBINATION 9
2.2.3 SOLAR CELLS UNDER OPERATING CONDITIONS 10
2.3 LOSS MECHANISMS 17
2.3.1 OPTICAL LOSSES 17
2.3.2 RECOMBINATION LOSSES 19
2.3.3 RESISTANCE AND SHUNT LOSSES 22
2.4 DESIGN AND PROCESSING OF HIGH-EFFICIENCY SILICON SOLAR CELLS 23
2.5 APPLICATION OF A STANDARD PROCESS SEQUENCE TO MULTICRYSTALLINE
SILICON 25
2.6 CHAPTER SUMMARY 29
3 GETTERING AND THERMAL DEGRADATION OF MULTICRYSTALLINE SILICON 31
3.1 INTRODUCTION 31
3.2 OPTIMISATION OF PROCESS PARAMETERS FOR GETTERING AND OXIDATION 31
3.2.1 PHOSPHORUS GETTERING 32
IMAGE 2
TABLE OF CONTENTS III
3.2.2 ALUMINIUM-PHOSPHORUS CO-GETTERING 34
3.2.3 PLATEAU TEMPERATURE OF OXIDATION 36
3.2.4 HEAT-UP AND COOL-DOWN RAMPS OF OXIDATION PROCESS 38
3.3 REASONS FOR THE CHANGES OF CARRIER LIFETIME BY HIGH-TEMPERATURE
PROCESSES....
41
3.3.1 EXPERIMENTAL PROCEDURE 42
3.3.2 AVERAGE MINORITY CARRIER LIFETIME MEASUREMENTS 44
3.3.3 CORRELATION BETWEEN LOCAL MINORITY CARRIER LIFETIME AND
DISLOCATION DENSITY 49
3.3.4 MICROSCOPIC MODEL 54
3.3.5 CONCLUSIONS FOR THE PRODUCTION OF MULTICRYSTALLINE SILICON SOLAR
CELLS ..61
3.4 CHAPTER SUMMARY 62
4 TEXTURE AND FRONT SURFACE STRUCTURE OF
MULTICRYSTALLINE SILICON SOLAR CELLS 65
4.1 INTRODUCTION 65
4.2 TEXTURING WITH RANDOM AND WITH DEFINED GEOMETRY 66
4.3 HONEYCOMB -TEXTURING 71
4.3.1 THE OPTIMUM STRUCTURE 72
4.3.2 WET CHEMICAL ETCHING 73
4.3.3 PLASMA ETCHING 76
4.3.4 OPTICAL AND ELECTRICAL RESULTS MEASURED IN COMPLETED SOLAR CELLS
82
4.4 CHAPTER SUMMARY 86
5 EMITTER DIFFUSION AND PASSIVATION OF TEXTURED
SURFACES 87
5.1 INTRODUCTION 87
5.2 DOPING PROFILES OF EMITTERS DRIVEN-IN BY WET OXIDATION 87
5.3 EMITTER RECOMBINATION OF PLANAR AND TEXTURED SAMPLES 91
IMAGE 3
IV TABLE OF CONTENTS
5.4 EFFECT OF EMITTER DIFFUSION ON MINORITY CARRIER LIFETIME IN
MULTICRYSTALLINE SILICON 95
5.5 EFFECT OF EMITTER DIFFUSION ON THE FILL FACTOR 96
5.6 CHAPTER SUMMARY 97
6 HIGH-EFFICIENCY MULTICRYSTALLINE SILICON SOLAR CELLS ..
99
6.1 INTRODUCTION 99
6.2 REAR SURFACE STRUCTURE FOR MULTICRYSTALLINE SILICON SOLAR CELLS 99
6.2.1 WET OXIDATION PROCESS 100
6.2.2 SURFACE PASSIVATION USING WET OXIDATION 104
6.2.3 RECOMBINATION VELOCITY OF OXIDISED SURFACES WITH LASER-FIRED
POINT- CONTACTS 107
6.2.4 LASER-FIRED CONTACTS FOR MULTICRYSTALLINE SILICON 110
6.3 CELL STRUCTURE, PROCESS SEQUENCE AND RESULTS 113
6.3.1 CELL STRUCTURE AND MASK DESIGN 113
6.3.2 PROCESS SEQUENCE 117
6.3.3 CELL RESULTS ON DIFFERENT TYPES OF MULTICRYSTALLINE SILICON 119
6.4 CHAPTER SUMMARY 125
7 INFLUENCE OF INHOMOGENEOUS CARRIER LIFETIME ON SOLAR CELL PARAMETERS
127
7.1 INTRODUCTION 127
7.2 SAMPLE PREPARATION FOR LIFETIME MEASUREMENTS 127
7.3 INFLUENCE OF EMITTERS ON CARRIER LIFETIME MEASUREMENTS 131
7.4 EVALUATION OF CDI MEASUREMENTS OF SAMPLES WITH EMITTER 135
7.5 MODELLING OF MULTICRYSTALLINE SILICON SOLAR CELLS 136
IMAGE 4
TABLE OF CONTENTS V
7.5.1 MODELLING OF THE SHORT-CIRCUIT CURRENT DENSITY J S C 138
7.5.2 MODELLING OF THE OPEN-CIRCUIT VOLTAGE V O C 139
7.6 COMPARISON OF EXPERIMENT WITH MODELLING 141
7.6.1 PREDICTION OF SOLAR CELL PARAMETERS FROM SILICON NITRIDE
PASSIVATED SAMPLES 141
7.6.2 PREDICTION OF SOLAR CELL PARAMETERS FROM SAMPLES WITH A SOLAR CELL
STRUCTURE 144
7.6.3 FILL FACTOR 150
7.7 CHAPTER SUMMARY 150
8 SUMMARY 153
DEUTSCHE ZUSAMMENFASSUNG 156
APPENDIX 159
A.I TRANSIENT PHOTOCONDUCTANCE DECAY (PCD) 159
A.2 QUASI-STEADY STATE PHOTOCONDUCTANCE (QSSPC) 160
A.3 DETERMINATION OF THE ABSORPTION FACTOR F ABS 163
A.4 CARRIER DENSITY IMAGING (CDI) 166
LIST OF SYMBOLS, ACRONYMS AND CONSTANTS 168
LIST OF PUBLICATIONS 175
BIBLIOGRAPHY 177
|
| adam_txt |
IMAGE 1
TABLE OF CONTENTS
TABLE OF CONTENTS
ACKNOWLEDGEMENTS I
1 INTRODUCTION 1
1.1 THESIS MOTIVATION 1
1.2 THESIS OUTLINE 3
2 CRYSTALLINE SILICON SOLAR CELLS 5
2.1 INTRODUCTION 5
2.2 OPERATION PRINCIPLE AND BASIC EQUATIONS OF DEVICE PHYSICS 5
2.2.1 CARRIER DENSITY AND THE ELECTROCHEMICAL POTENTIAL 6
2.2.2 MINORITY CARRIER LIFETIME AND RECOMBINATION 9
2.2.3 SOLAR CELLS UNDER OPERATING CONDITIONS 10
2.3 LOSS MECHANISMS 17
2.3.1 OPTICAL LOSSES 17
2.3.2 RECOMBINATION LOSSES 19
2.3.3 RESISTANCE AND SHUNT LOSSES 22
2.4 DESIGN AND PROCESSING OF HIGH-EFFICIENCY SILICON SOLAR CELLS 23
2.5 APPLICATION OF A STANDARD PROCESS SEQUENCE TO MULTICRYSTALLINE
SILICON 25
2.6 CHAPTER SUMMARY 29
3 GETTERING AND THERMAL DEGRADATION OF MULTICRYSTALLINE SILICON 31
3.1 INTRODUCTION 31
3.2 OPTIMISATION OF PROCESS PARAMETERS FOR GETTERING AND OXIDATION 31
3.2.1 PHOSPHORUS GETTERING 32
IMAGE 2
TABLE OF CONTENTS III
3.2.2 ALUMINIUM-PHOSPHORUS CO-GETTERING 34
3.2.3 PLATEAU TEMPERATURE OF OXIDATION 36
3.2.4 HEAT-UP AND COOL-DOWN RAMPS OF OXIDATION PROCESS 38
3.3 REASONS FOR THE CHANGES OF CARRIER LIFETIME BY HIGH-TEMPERATURE
PROCESSES.
41
3.3.1 EXPERIMENTAL PROCEDURE 42
3.3.2 AVERAGE MINORITY CARRIER LIFETIME MEASUREMENTS 44
3.3.3 CORRELATION BETWEEN LOCAL MINORITY CARRIER LIFETIME AND
DISLOCATION DENSITY 49
3.3.4 MICROSCOPIC MODEL 54
3.3.5 CONCLUSIONS FOR THE PRODUCTION OF MULTICRYSTALLINE SILICON SOLAR
CELLS .61
3.4 CHAPTER SUMMARY 62
4 TEXTURE AND FRONT SURFACE STRUCTURE OF
MULTICRYSTALLINE SILICON SOLAR CELLS 65
4.1 INTRODUCTION 65
4.2 TEXTURING WITH RANDOM AND WITH DEFINED GEOMETRY 66
4.3 "HONEYCOMB"-TEXTURING 71
4.3.1 THE OPTIMUM STRUCTURE 72
4.3.2 WET CHEMICAL ETCHING 73
4.3.3 PLASMA ETCHING 76
4.3.4 OPTICAL AND ELECTRICAL RESULTS MEASURED IN COMPLETED SOLAR CELLS
82
4.4 CHAPTER SUMMARY 86
5 EMITTER DIFFUSION AND PASSIVATION OF TEXTURED
SURFACES 87
5.1 INTRODUCTION 87
5.2 DOPING PROFILES OF EMITTERS DRIVEN-IN BY WET OXIDATION 87
5.3 EMITTER RECOMBINATION OF PLANAR AND TEXTURED SAMPLES 91
IMAGE 3
IV TABLE OF CONTENTS
5.4 EFFECT OF EMITTER DIFFUSION ON MINORITY CARRIER LIFETIME IN
MULTICRYSTALLINE SILICON 95
5.5 EFFECT OF EMITTER DIFFUSION ON THE FILL FACTOR 96
5.6 CHAPTER SUMMARY 97
6 HIGH-EFFICIENCY MULTICRYSTALLINE SILICON SOLAR CELLS .
99
6.1 INTRODUCTION 99
6.2 REAR SURFACE STRUCTURE FOR MULTICRYSTALLINE SILICON SOLAR CELLS 99
6.2.1 WET OXIDATION PROCESS 100
6.2.2 SURFACE PASSIVATION USING WET OXIDATION 104
6.2.3 RECOMBINATION VELOCITY OF OXIDISED SURFACES WITH LASER-FIRED
POINT- CONTACTS 107
6.2.4 LASER-FIRED CONTACTS FOR MULTICRYSTALLINE SILICON 110
6.3 CELL STRUCTURE, PROCESS SEQUENCE AND RESULTS 113
6.3.1 CELL STRUCTURE AND MASK DESIGN 113
6.3.2 PROCESS SEQUENCE 117
6.3.3 CELL RESULTS ON DIFFERENT TYPES OF MULTICRYSTALLINE SILICON 119
6.4 CHAPTER SUMMARY 125
7 INFLUENCE OF INHOMOGENEOUS CARRIER LIFETIME ON SOLAR CELL PARAMETERS
127
7.1 INTRODUCTION 127
7.2 SAMPLE PREPARATION FOR LIFETIME MEASUREMENTS 127
7.3 INFLUENCE OF EMITTERS ON CARRIER LIFETIME MEASUREMENTS 131
7.4 EVALUATION OF CDI MEASUREMENTS OF SAMPLES WITH EMITTER 135
7.5 MODELLING OF MULTICRYSTALLINE SILICON SOLAR CELLS 136
IMAGE 4
TABLE OF CONTENTS V
7.5.1 MODELLING OF THE SHORT-CIRCUIT CURRENT DENSITY J S C 138
7.5.2 MODELLING OF THE OPEN-CIRCUIT VOLTAGE V O C 139
7.6 COMPARISON OF EXPERIMENT WITH MODELLING 141
7.6.1 PREDICTION OF SOLAR CELL PARAMETERS FROM SILICON NITRIDE
PASSIVATED SAMPLES 141
7.6.2 PREDICTION OF SOLAR CELL PARAMETERS FROM SAMPLES WITH A SOLAR CELL
STRUCTURE 144
7.6.3 FILL FACTOR 150
7.7 CHAPTER SUMMARY 150
8 SUMMARY 153
DEUTSCHE ZUSAMMENFASSUNG 156
APPENDIX 159
A.I TRANSIENT PHOTOCONDUCTANCE DECAY (PCD) 159
A.2 QUASI-STEADY STATE PHOTOCONDUCTANCE (QSSPC) 160
A.3 DETERMINATION OF THE ABSORPTION FACTOR F ABS 163
A.4 CARRIER DENSITY IMAGING (CDI) 166
LIST OF SYMBOLS, ACRONYMS AND CONSTANTS 168
LIST OF PUBLICATIONS 175
BIBLIOGRAPHY 177 |
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| index_date | 2024-07-02T13:56:51Z |
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| spelling | Schultz, Oliver Verfasser aut High-efficiency multicrystalline silicon solar cells Oliver Schultz 1. Aufl. München Verl. Dr. Hut 2005 V, 190 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Zugl.: Konstanz, Univ., Diss., 2005 Polykristall (DE-588)4188261-1 gnd rswk-swf Lebensdauer (DE-588)4034837-4 gnd rswk-swf Silicium (DE-588)4077445-4 gnd rswk-swf Minoritätsträger (DE-588)4170084-3 gnd rswk-swf Prozessentwicklung Technik (DE-588)4278925-4 gnd rswk-swf Solarzelle (DE-588)4181740-0 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Solarzelle (DE-588)4181740-0 s Silicium (DE-588)4077445-4 s Polykristall (DE-588)4188261-1 s Minoritätsträger (DE-588)4170084-3 s Lebensdauer (DE-588)4034837-4 s Prozessentwicklung Technik (DE-588)4278925-4 s DE-604 SWB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=014634505&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Schultz, Oliver High-efficiency multicrystalline silicon solar cells Polykristall (DE-588)4188261-1 gnd Lebensdauer (DE-588)4034837-4 gnd Silicium (DE-588)4077445-4 gnd Minoritätsträger (DE-588)4170084-3 gnd Prozessentwicklung Technik (DE-588)4278925-4 gnd Solarzelle (DE-588)4181740-0 gnd |
| subject_GND | (DE-588)4188261-1 (DE-588)4034837-4 (DE-588)4077445-4 (DE-588)4170084-3 (DE-588)4278925-4 (DE-588)4181740-0 (DE-588)4113937-9 |
| title | High-efficiency multicrystalline silicon solar cells |
| title_auth | High-efficiency multicrystalline silicon solar cells |
| title_exact_search | High-efficiency multicrystalline silicon solar cells |
| title_exact_search_txtP | High-efficiency multicrystalline silicon solar cells |
| title_full | High-efficiency multicrystalline silicon solar cells Oliver Schultz |
| title_fullStr | High-efficiency multicrystalline silicon solar cells Oliver Schultz |
| title_full_unstemmed | High-efficiency multicrystalline silicon solar cells Oliver Schultz |
| title_short | High-efficiency multicrystalline silicon solar cells |
| title_sort | high efficiency multicrystalline silicon solar cells |
| topic | Polykristall (DE-588)4188261-1 gnd Lebensdauer (DE-588)4034837-4 gnd Silicium (DE-588)4077445-4 gnd Minoritätsträger (DE-588)4170084-3 gnd Prozessentwicklung Technik (DE-588)4278925-4 gnd Solarzelle (DE-588)4181740-0 gnd |
| topic_facet | Polykristall Lebensdauer Silicium Minoritätsträger Prozessentwicklung Technik Solarzelle Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=014634505&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT schultzoliver highefficiencymulticrystallinesiliconsolarcells |