Structure-property relationships in rubber layered silicate nanocomposites:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Kaiserslautern
Inst. für Verbundwerkstoffe
2005
|
| Ausgabe: | Als Ms. gedr. |
| Schriftenreihe: | IVW-Schriftenreihe
59 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Zugl.: Kaiserslautern, Techn. Univ., Diss., 2005. - Kurzfassung in dt. Sprache |
| Beschreibung: | XV, 121 S. Ill., graph. Darst. |
| ISBN: | 3934930557 |
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Datensatz im Suchindex
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| adam_text | IVW - SCHRIFTENREIHE BAND 59 INSTITUT FUER VERBUNDWERKSTOFFE GMBH -
KAISERSLAUTERN KONSTANTINOS G. GATOS STRUCTURE-PROPERTY RELATIONSHIPS IN
RUBBER/LAYERED SILICATE NANOCOMPOSITES TABLE OF CONTENTS TABLE OF
CONTENTS ACKNOWLEDGEMENTS I TABLE OF CONTENTS III ABSTRACT/KURZFASSUNG
VII LIST OF ABBREVIATIONS AND SYMBOLS XIII 1. INTRODUCTION 1 2.
BACKGROUND 3 2. 1 ELASTOMER SYSTEMS 3 2.2 TYPES OF REINFORCEMENT 4 2.2.1
CARBON BLACK 5 2.2.2 SILICA 6 2.2.3 CLAY 6 2.2.4 SURFACE TREATMENT 8 2.3
RUBBER/LAYERED SILICATE NANOCOMPOSITES 9 2.3.1 EARLY STAGE OF RESEARCH
10 2.3.2 CURRENT STAGE 11 2.4 MODELING OF THE RUBBER NANOCOMPOSITES 12
2.4.1 MECHANICAL PERFORMANCE 13 2.4.2 GAS BARRIER PROPERTIES 15
3.0BJECTIVES 17 4. EXPERIMENTAL 19 4.1 MATERIALS 19 4.1.1 RUBBER MATRIX
19 4.1.1.1 ETHYLENE PROPYLENE DIENE MONOMER RUBBER (EPDM) 19 4.1.1.2
HYDROGENATED ACRYLONITRILE BUTADIENE RUBBER (HNBR) 20 4.1.1.3 NATURAL
RUBBER 21 IV TABLE OF CONTENTS 4.1.2 FILLERS 21 4.1.2.1 CONVENTIONAL
FILLERS 21 4.1.2.2 NATURAL CLAY AND ITS ORGANOPHILIC VERSIONS 21 4.1.2.3
SYNTHETIC CLAY AND ITS ORGANOPHILIC VERSIONS 22 4.1.3VULCANIZATION
ADDITIVESAND CURE RECIPES 23 4.1.3.1 EPDM 23 4.1.3.2 HNBR 23 4.1.3.3 NR
24 4.2 COMPOUNDING 25 4.2.1 INTERNAL MIXER 25 4.2.2 OPEN MILL 25 4.3
VULCANIZATION 25 4.3.1 RHEOMETER 25 4.3.1.1 MONSANTO RHEOMETER 25
4.3.1.2 PLATE-PLATE RHEOMETER 26 4.3.2. HOT PRESS 27 4.4 MECHANICAL
CHARACTERIZATION 27 4.4.1 TENSILE EXPERIMENTS 27 4.4.2 TEAR TEST 27
4.4.3 HARDNESS 27 4.4.4 CYCLIC LOADING 28 4.5 THERMO MECHANICAL
CHARACTERIZATION 28 4.5.1. DYNAMIC MECHANICAL THERMAL ANALYSIS (DMTA) 28
4.5.2. THERMO GRAVIMETRIC ANALYSIS (TGA) 28 4.6 OXYGEN PERMEABILITY
MEASUREMENTS 28 4.7 MICRO- AND NANO-STRUCTURAL CHARACTERIZATION 29 4.7.1
SCANNING ELECTRON MICROSCOPY (SEM) 29 4.7.2 TRANSMISSION ELECTRON
MICROSCOPY (TEM) 29 4.7.3 X-RAY DIFFRACTION (XRD) 29 5. RESULTS AND
DISCUSSION 30 5.1 ESTIMATION OF THE OPTIMUM VULCANIZATION TIME: A NEW
METHOD 30 5.2 MECHANISMS INVOLVED IN RUBBER/ORGANOCLAY NANOCOMPOSITE
FORMATION 38 TABLE OF CONTENTS 5.3 EPDM/ORGANOCIAY NANOCOMPOSITES 39
5.3.1 EFFECT OF MIXING PROCEDURE 39 5.3.2 EFFECT OF POLARITY 46 5.3.3
EFFECT OF VULCANIZATION ACCELERATOR 49 5.3.4 EFFECT OF ORGANOCLAY
INTERCALANT 56 5.3.5 EFFECT OF CLAY LOADING 60 5.4 HNBR/ORGANOCIAY
NANOCOMPOSITES 64 5.4.1 CLAY DISPERSION IN SULFURCURED SYSTEMS 64
5.4.1.1 EFFECT OF TYPE OF ORGANOCLAY INTERCALANT 65 5.4.1.2 EFFECT
OFASPECT RATIO OF CLAY PLATELET 74 5.4.2 CLAY DISPERSION IN PEROXIDE
CURED SYSTEMS AND PROPERTIES 81 1.5 MODELING THE RUBBER/ORGANOCLAY
NANOCOMPOSITE BEHAVIOR 89 5.5.1 MECHANICAL PROPERTIES 89 5.5.2 GAS
PERMEATION 92 J^SUMMARY AND OUTLOOK 95 SNDIX 98 »RATURE 101
TOFPUBLICATIONS FCOF STUDENT SUPPORT WORKS 119 121
|
| adam_txt |
IVW - SCHRIFTENREIHE BAND 59 INSTITUT FUER VERBUNDWERKSTOFFE GMBH -
KAISERSLAUTERN KONSTANTINOS G. GATOS STRUCTURE-PROPERTY RELATIONSHIPS IN
RUBBER/LAYERED SILICATE NANOCOMPOSITES TABLE OF CONTENTS TABLE OF
CONTENTS ACKNOWLEDGEMENTS I TABLE OF CONTENTS III ABSTRACT/KURZFASSUNG
VII LIST OF ABBREVIATIONS AND SYMBOLS XIII 1. INTRODUCTION 1 2.
BACKGROUND 3 2. 1 ELASTOMER SYSTEMS 3 2.2 TYPES OF REINFORCEMENT 4 2.2.1
CARBON BLACK 5 2.2.2 SILICA 6 2.2.3 CLAY 6 2.2.4 SURFACE TREATMENT 8 2.3
RUBBER/LAYERED SILICATE NANOCOMPOSITES 9 2.3.1 EARLY STAGE OF RESEARCH
10 2.3.2 CURRENT STAGE 11 2.4 MODELING OF THE RUBBER NANOCOMPOSITES 12
2.4.1 MECHANICAL PERFORMANCE 13 2.4.2 GAS BARRIER PROPERTIES 15
3.0BJECTIVES 17 4. EXPERIMENTAL 19 4.1 MATERIALS 19 4.1.1 RUBBER MATRIX
19 4.1.1.1 ETHYLENE PROPYLENE DIENE MONOMER RUBBER (EPDM) 19 4.1.1.2
HYDROGENATED ACRYLONITRILE BUTADIENE RUBBER (HNBR) 20 4.1.1.3 NATURAL
RUBBER 21 IV TABLE OF CONTENTS 4.1.2 FILLERS 21 4.1.2.1 CONVENTIONAL
FILLERS 21 4.1.2.2 NATURAL CLAY AND ITS ORGANOPHILIC VERSIONS 21 4.1.2.3
SYNTHETIC CLAY AND ITS ORGANOPHILIC VERSIONS 22 4.1.3VULCANIZATION
ADDITIVESAND CURE RECIPES 23 4.1.3.1 EPDM 23 4.1.3.2 HNBR 23 4.1.3.3 NR
24 4.2 COMPOUNDING 25 4.2.1 INTERNAL MIXER 25 4.2.2 OPEN MILL 25 4.3
VULCANIZATION 25 4.3.1 RHEOMETER 25 4.3.1.1 MONSANTO RHEOMETER 25
4.3.1.2 PLATE-PLATE RHEOMETER 26 4.3.2. HOT PRESS 27 4.4 MECHANICAL
CHARACTERIZATION 27 4.4.1 TENSILE EXPERIMENTS 27 4.4.2 TEAR TEST 27
4.4.3 HARDNESS 27 4.4.4 CYCLIC LOADING 28 4.5 THERMO MECHANICAL
CHARACTERIZATION 28 4.5.1. DYNAMIC MECHANICAL THERMAL ANALYSIS (DMTA) 28
4.5.2. THERMO GRAVIMETRIC ANALYSIS (TGA) 28 4.6 OXYGEN PERMEABILITY
MEASUREMENTS 28 4.7 MICRO- AND NANO-STRUCTURAL CHARACTERIZATION 29 4.7.1
SCANNING ELECTRON MICROSCOPY (SEM) 29 4.7.2 TRANSMISSION ELECTRON
MICROSCOPY (TEM) 29 4.7.3 X-RAY DIFFRACTION (XRD) 29 5. RESULTS AND
DISCUSSION 30 5.1 ESTIMATION OF THE OPTIMUM VULCANIZATION TIME: A NEW
METHOD 30 5.2 MECHANISMS INVOLVED IN RUBBER/ORGANOCLAY NANOCOMPOSITE
FORMATION 38 TABLE OF CONTENTS 5.3 EPDM/ORGANOCIAY NANOCOMPOSITES 39
5.3.1 EFFECT OF MIXING PROCEDURE 39 5.3.2 EFFECT OF POLARITY 46 5.3.3
EFFECT OF VULCANIZATION ACCELERATOR 49 5.3.4 EFFECT OF ORGANOCLAY
INTERCALANT 56 5.3.5 EFFECT OF CLAY LOADING 60 5.4 HNBR/ORGANOCIAY
NANOCOMPOSITES 64 5.4.1 CLAY DISPERSION IN SULFURCURED SYSTEMS 64
5.4.1.1 EFFECT OF TYPE OF ORGANOCLAY INTERCALANT 65 5.4.1.2 EFFECT
OFASPECT RATIO OF CLAY PLATELET 74 5.4.2 CLAY DISPERSION IN PEROXIDE
CURED SYSTEMS AND PROPERTIES 81 1.5 MODELING THE RUBBER/ORGANOCLAY
NANOCOMPOSITE BEHAVIOR 89 5.5.1 MECHANICAL PROPERTIES 89 5.5.2 GAS
PERMEATION 92 J^SUMMARY AND OUTLOOK 95 SNDIX 98 »RATURE 101
TOFPUBLICATIONS FCOF STUDENT SUPPORT WORKS 119 121 |
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| genre_facet | Hochschulschrift |
| id | DE-604.BV021272064 |
| illustrated | Illustrated |
| index_date | 2024-07-02T13:44:46Z |
| indexdate | 2024-07-09T20:34:22Z |
| institution | BVB |
| isbn | 3934930557 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-014593167 |
| oclc_num | 162254570 |
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| owner_facet | DE-91 DE-BY-TUM DE-12 DE-29T DE-703 DE-706 DE-83 |
| physical | XV, 121 S. Ill., graph. Darst. |
| publishDate | 2005 |
| publishDateSearch | 2005 |
| publishDateSort | 2005 |
| publisher | Inst. für Verbundwerkstoffe |
| record_format | marc |
| series | IVW-Schriftenreihe |
| series2 | IVW-Schriftenreihe |
| spelling | Gatos, Konstantinos G. Verfasser aut Structure-property relationships in rubber layered silicate nanocomposites Konstantinos G. Gatos Structure property relationships in rubber layered silicate nanocomposites Als Ms. gedr. Kaiserslautern Inst. für Verbundwerkstoffe 2005 XV, 121 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier IVW-Schriftenreihe 59 Zugl.: Kaiserslautern, Techn. Univ., Diss., 2005. - Kurzfassung in dt. Sprache Gummiverstärkter Kunststoff (DE-588)4277045-2 gnd rswk-swf Nanokomposit (DE-588)4768127-5 gnd rswk-swf Silicate (DE-588)4077444-2 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Nanokomposit (DE-588)4768127-5 s Silicate (DE-588)4077444-2 s Gummiverstärkter Kunststoff (DE-588)4277045-2 s DE-604 IVW-Schriftenreihe 59 (DE-604)BV013248875 59 HEBIS Datenaustausch Darmstadt application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=014593167&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Gatos, Konstantinos G. Structure-property relationships in rubber layered silicate nanocomposites IVW-Schriftenreihe Gummiverstärkter Kunststoff (DE-588)4277045-2 gnd Nanokomposit (DE-588)4768127-5 gnd Silicate (DE-588)4077444-2 gnd |
| subject_GND | (DE-588)4277045-2 (DE-588)4768127-5 (DE-588)4077444-2 (DE-588)4113937-9 |
| title | Structure-property relationships in rubber layered silicate nanocomposites |
| title_alt | Structure property relationships in rubber layered silicate nanocomposites |
| title_auth | Structure-property relationships in rubber layered silicate nanocomposites |
| title_exact_search | Structure-property relationships in rubber layered silicate nanocomposites |
| title_exact_search_txtP | Structure-property relationships in rubber layered silicate nanocomposites |
| title_full | Structure-property relationships in rubber layered silicate nanocomposites Konstantinos G. Gatos |
| title_fullStr | Structure-property relationships in rubber layered silicate nanocomposites Konstantinos G. Gatos |
| title_full_unstemmed | Structure-property relationships in rubber layered silicate nanocomposites Konstantinos G. Gatos |
| title_short | Structure-property relationships in rubber layered silicate nanocomposites |
| title_sort | structure property relationships in rubber layered silicate nanocomposites |
| topic | Gummiverstärkter Kunststoff (DE-588)4277045-2 gnd Nanokomposit (DE-588)4768127-5 gnd Silicate (DE-588)4077444-2 gnd |
| topic_facet | Gummiverstärkter Kunststoff Nanokomposit Silicate Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=014593167&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV013248875 |
| work_keys_str_mv | AT gatoskonstantinosg structurepropertyrelationshipsinrubberlayeredsilicatenanocomposites |