Nanoparticles: from theory to application
Saved in:
| Format: | Book |
|---|---|
| Language: | English |
| Published: |
Weinheim
Wiley-VCH
2005
|
| Edition: | 1. ed., 3. reprint |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | X, 434 S. Ill., graph. Darst. |
| ISBN: | 3527305076 |
Staff View
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Record in the Search Index
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| adam_text | Contents
1 General Introduction 1
Cunter Schmid
2 Quantum Dots 4
WolfgangJohann Parak, Liberato Manna, Friedrich Christian Simmel,
Daniele Gerion, and Paul Alivisatos
2.1 Introduction and Outline 4
2.2 Nanoscale Materials and Quantum Mechanics 6
2.2.1 Nanoscale Materials as Intermediate between Atomic and Bulk
Matter 6
2.2.2 Quantum Mechanics 7
2.3 From Atoms to Molecules and Quantum Dots 8
2.4 Shrinking Bulk Material to a Quantum Dot 10
2.4.1 Three Dimensional Systems (Bulk Material) 10
2.4.2 Two Dimensional Systems 14
2.4.3 One Dimensional Systems (Quantum Wires) 18
2.4.4 Zero Dimensional Systems (Quantum Dots) 20
2.5 Energy Levels of a (Semiconductor) Quantum Dot 21
2.6 Varieties of Quantum Dots 24
2.6.1 Lithographically Denned Quantum Dots 25
2.6.2 Epitaxially Self Assembled Quantum Dots 27
2.6.3 Colloidal Quantum Dots 28
2.7 Optical Properties of Quantum Dots 29
2.7.1 Absorption and Emission Spectra 29
2.7.2 Spectral Diffusion and Blinking 31
2.7.3 Metal Nanoparticles 33
2.7.4 Overview of Some Selected Applications 33
2.8 Some (Electrical) Transport Properties of Quantum Dots 34
2.8.1 Coulomb Blockade: Basic Theory and Historical Sketch 35
2.8.2 Single Electron Tunneling 37
2.8.3 Tunneling Transport Line Shape of Conductance Peaks 41
2.8.4 Some Applications 42
References 44
vi Contents
3 Syntheses and Characterizations 50
3.1 Semiconductor Nanopartides 50
3.1.1 Synthesis and Characterization of II—VI Nanopartides 50
Alexander Eychmuller
3.1.1.1 Historical Review 50
3.1.1.2 Thiol Stabilized Nanopartides 57
3.1.1.3 The TOP/TOPO Synthesis 61
3.1.1.4 Core Shell Nanocrystals 63
3.1.1.5 Quantum Dot Quantum Wells 65
References 71
3.1.2 Synthesis and Characterization of III—V Semiconductor
Nanopartides 79
Uri Banin
3.1.2.1 Introduction 79
3.1.2.2 Synthetic Strategy 8]
3.1.2.3 InAs and InP Nanocrystals 84
3.1.2.4 III—V Core/Shell Nanocrystals Synthesis and Characterization 89
Acknowledgement 105
References 105
3.1.3 Synthesis and Characterization of Ib VI Nanoclusters 107
Stefanie Dehnen, Andreas Eichhb fer, John F. Corrigan, and Dieter Fenske
3.1.3.1 Introduction 107
3.1.3.2 Chalcogen Bridged Copper Clusters 108
3.1.3.3 Chalcogen Bridged Silver Clusters 158
3.1.3.4 Selenium Bridged Gold Clusters 281
References 183
3.2 Synthesis of Metal Nanopartides 185
3.2.1 Noble Metal Nanopartides 186
John S. Bradley and Giinter Schmid
3.2.1.1 Introduction 186
3.2.1.2 History and Background 186
3.2.1.3 Generation of Metal Particles 187
3.2.1.4 Stabilization of Colloidal Metal Particles in Liquids 189
3.2.1.5 Synthetic Methods for the Preparation of Colloidal Transition
Metals 191
3.2.2 Synthesis and Characterization of Magnetic Nanopartides 199
Dmitri V. Talapin, Elena V. Shevchenko, Horst Weller
3.2.2.1 Introduction 199
3.2.2.2 Organometallic Synthesis of Magnetic Nanopartides 202
3.2.2.3 Size and Shape Dependent Magnetic Properties of Ferromagnetic Metal
Nanopartides 220
References 230
4 Organization of Nanopartides 239
4.1 Semiconductor Nanopartides 239
Alexander Eychmuller
Contents vii
4.1.1 Molecular Crystals 239
4.1.2 Superlattices of Semiconductor Nanoparticles 242
4.1.3 Layers of Semiconductor Nanocrystals 244
4.1.4 Coupling of Semiconductor Nanocrystals 249
4.2 Metal Nanoparticles 251
Giinter Schmid, Dmitri V. Talapin, and Elena V. Shevchenko
4.2.1 Three dimensional Organization of Metal Nanoparticles 251
4.2.2 Ordered Monolayers of Metal Nanoparticles 260
4.2.2.1 Self Assembly 261
4.2.2.2 Guided Self Assembly 268
4.2.2.3 Aimed Structures 277
4.2.3 One dimensional Arrangements 280
References 298
5 Properties 305
5.1 Semiconductor Nanoparticles 305
5.1.1 Optical and Electronic Properties of III Vand II—VI Nanoparticles 305
Uri Banin and Oded Millo
5.1.1.1 Introduction 305
5.1.1.2 Semiconductor Nanocrystals as Artificial Atoms 306
5.1.1.3 Theoretical Descriptions of the Electronic Structure 313
5.1.1.4 Atomic like States in Core/Shell Nanocrystals Spectroscopy and
Imaging 314
5.1.1.5 Level Structure of CdSe Quantum Rods 319
5.1.1.6 Optical Gain and Lasing in Semiconductor Nanocrystals 320
Acknowledgements 322
5.1.2 Optical and Thermal Properties of Ib VI Nanoparticles 322
Stefanie Dehnen, Andreas Eichhofer, John F. Corrigan, and Dieter Fenske
5.1.2.1 Optical Spectra and Thermal Behavior 322
5.1.2.2 Optical Spectra in the Solid State 326
5.2 Electrical Properties of Metal Nanoparticles 328
Ulrich Simon
5.2.1 Introduction 328
5.2.2 Physical Background and Quantum Size Effect 329
5.2.3 Single Electron Tunneling 331
5.2.3.1 Working Principles of Metal Based Single Electron Tunneling
Devices 333
5.2.4 Single Electron Tunneling in Nanoparticles 338
5.2.4.1 Thin Film Structures and STM Single Electron Systems 340
5.2.4.2 SET on Single Chemically Tailored Nanoparticles 342
5.2.4.3 Metal Nanoparticles in Single Electron Devices 345
5.2.4.4 Mesoscopic Arrays with Nanoelectrodes 347
5.2.4.5 Chemical Switching and Gating of Current through Nanoparticles 352
5.2.5 From Single Particle Properties to Collective Charge Transport 353
5.2.5.1 One Dimensional Arrangements 356
5.2.5.2 Two Dimensional Arrangements 358
viii Contents
5.2.5.3 Three Dimensional Arrangements 359
References 362
6 Biomaterial Nanoparticle Hybrid Systems: Synthesis, Properties, and
Applications 368
Eugenii Katz, Andrew N. Shipway, and Itamar Willner
6.1 Introduction 368
6.2 The Synthesis and Properties of Biomaterial Functionalized
Nanoparticles 371
6.2.1 Functionalization by Electrostatic Adsorption 371
6.2.2 Functionalization by Chemisorption of Thiol Derivatized
Biomaterials 372
6.2.3 Functionalization by Specific Interactions 373
6.2.4 Properties of Nanoparticle Biomaterial Composites 374
6.3 Biomaterial Functionalized Nanoparticles for Controlled Chemical
Reactivity 376
6.3.1 Controlling DNA Reactivity 376
6.3.2 Reporting on DNA Reactivity 377
6.4 The Aggregation of Biomaterial Functionalized Nanoparticles 377
6.4.1 Receptor Induced Aggregation of Guest Functionalized
Nanoparticles 379
6.4.2 Nucleic Acid Functionalized Nanoparticles for Controlled
Aggregation 382
6.4.3 Composite Assemblies of Nucleic Acids, Proteins, and
Nanoparticles 385
6.5 Assembly of Biomaterial Nanoparticle Architectures on Surfaces 390
6.5.1 Assembly of Layered Nanoparticle Protein Assemblies 391
6.5.2 Nucleic Acid Nanoparticle Architectures on Surfaces 392
6.6 Functional Biomaterial Nanoparticle Structures on Surfaces for Sensoric
and Electronic Applications 397
6.6.1 Nanoparticle Biomaterial Conjugates for Optical Sensing and
Analysis 398
6.6.2 Electronic Transduction of Biosensing Events by Nanoparticle Biomaterial
Functionalized Arrays 400
6.6.3 Biomaterial Nanoparticle Arrays for Electronic Circuitry 407
6.7 Biomaterial Functionalized Magnetic Particles 409
Acknowledgment 415
References 415
7 Conclusions and Perspectives 422
All Authors
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| title | Nanoparticles from theory to application |
| title_auth | Nanoparticles from theory to application |
| title_exact_search | Nanoparticles from theory to application |
| title_full | Nanoparticles from theory to application ed. by Günter Schmid |
| title_fullStr | Nanoparticles from theory to application ed. by Günter Schmid |
| title_full_unstemmed | Nanoparticles from theory to application ed. by Günter Schmid |
| title_short | Nanoparticles |
| title_sort | nanoparticles from theory to application |
| title_sub | from theory to application |
| topic | Nanopartikel Nanotechnologie (DE-588)4327470-5 gnd Nanopartikel (DE-588)4333369-2 gnd |
| topic_facet | Nanopartikel Nanotechnologie |
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