Semiconductor electrochemistry:
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Weinheim [u.a.]
Wiley-VCH
2002
|
| Edition: | 1. reprint. |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | X, 399 S. Ill., graph. Darst. |
| ISBN: | 352730147X |
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MARC
| LEADER | 00000nam a22000008c 4500 | ||
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| 100 | 1 | |a Memming, Rüdiger |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Semiconductor electrochemistry |c Rüdiger Memming |
| 250 | |a 1. reprint. | ||
| 264 | 1 | |a Weinheim [u.a.] |b Wiley-VCH |c 2002 | |
| 300 | |a X, 399 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 4 | |a Halbleiter - Elektrochemische Eigenschaft | |
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| 650 | 0 | 7 | |a Elektrochemische Eigenschaft |0 (DE-588)4344251-1 |2 gnd |9 rswk-swf |
| 689 | 0 | 0 | |a Halbleiter |0 (DE-588)4022993-2 |D s |
| 689 | 0 | 1 | |a Elektrochemische Eigenschaft |0 (DE-588)4344251-1 |D s |
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| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-012795546 | |
Record in the Search Index
| _version_ | 1809403464820719616 |
|---|---|
| adam_text |
CONTENTS
1
PRINCIPLES
OF
SEMICONDUCTOR
PHYSICS
.
1
1.1
CRYSTAL
STRUCTURE
.
1
1.2
ENERGY
LEVELS
IN
SOLIDS
.
3
1.3
OPTICAL
PROPERTIES
.
7
1.4
DENSITY
OF
STATES
AND
CARRIER
CONCENTRATIONS
.
10
1.4.1
INTRINSIC
SEMICONDUCTORS
.
13
1.4.2
DOPED
SEMICONDUCTORS
.
14
1.5
CARRIER
TRANSPORT
PHENOMENA
.
16
1.6
EXCITATION
AND
RECOMBINATION
OF
CHARGE
CARRIERS
.
18
1.7
FERMI
LEVELS
UNDER
NON-EQUILIBRIUM
CONDITIONS
.
20
2
SEMICONDUCTOR
SURFACES
AND
SOLID
-
SOLID
JUNCTIONS
.
22
2.1
METAL
AND
SEMICONDUCTOR
SURFACES
IN
A
VACUUM
.
22
2.2
METAL-SEMICONDUCTOR
CONTACTS
(SCHOTTKY
JUNCTIONS)
.
24
2.2.1
BARRIER
HEIGHTS
.
25
2.2.2
MAJORITY
CARRIER
TRANSFER
PROCESSES
.
29
2.2.3
MINORITY
CARRIER
TRANSFER
PROCESSES
.
33
2.3
P-N
JUNCTIONS
.
36
2.4
OHMIC
CONTACTS
.
39
2.5
PHOTOVOLTAGES
AND
PHOTOCURRENTS
.
41
2.6
SURFACE
RECOMBINATION
.
44
3
ELECTROCHEMICAL
SYSTEMS
.
46
3.1
ELECTROLYTES
.
46
3.1.1
ION
TRANSPORT
IN
SOLUTIONS
.
46
3.1.2
INTERACTION
BETWEEN
IONS
AND
SOLVENT
.
48
3.2
POTENTIALS
AND
THERMODYNAMICS
OF
ELECTROCHEMICAL
CELLS
.
50
3.2.1
CHEMICAL
AND
ELECTROCHEMICAL
POTENTIALS
.
50
3.2.2
CELL
VOLTAGES
.
53
3.2.3
REFERENCE
POTENTIALS
.
55
3.2.4
STANDARD
POTENTIAL
AND
FERMI
LEVEL
OF
REDOX
SYSTEMS
.
56
4
EXPERIMENTAL
TECHNIQUES
.
61
4.1
ELECTRODE
PREPARATION
.
61
4.2
CURRENT-VOLTAGE
MEASUREMENTS
.
61
4.2.1
VOLTAMETRY
.
61
4.2.2
PHOTOCURRENT
MEASUREMENTS
.
63
4.2.3
ROTATING
RING
DISC
ELECTRODES
.
63
4.2.4
SCANNING
ELECTROCHEMICAL
MICROSCOPY
(SECM)
.
64
4.3
MEASUREMENTS
OF
SURFACE
RECOMBINATION
AND
MINORITY
CARRIER
INJECTION
65
4.4
IMPEDANCE
MEASUREMENTS
.
67
VIII
CONTENTS
4.4.1
BASIC
RULES
AND
TECHNIQUES
.
67
4.4.2
EVALUATION
OF
IMPEDANCE
SPECTRA
.
69
4.5
INTENSITY-MODULATED
PHOTOCURRENT
SPECTROSCOPY
(IMPS)
.
74
4.6
FLASH
PHOTOLYSIS
INVESTIGATIONS
.
75
4.7
SURFACE
SCIENCE
TECHNIQUES
.
76
4.7.1
SPECTROSCOPIC
METHODS
.
76
4.7.2
IN
SITU
SURFACE
MICROSCOPY
(STM
AND
AFM)
.
78
5
SOLID-LIQUID
INTERFACE
.
81
5.1
STRUCTURE
OF
THE
INTERFACE
AND
ADSORPTION
.
81
5.2
CHARGE
AND
POTENTIAL
DISTRIBUTION
AT
THE
INTERFACE
.
83
5.2.1
THE
HELMHOLTZ
DOUBLE
LAYER
.
83
5.2.2
THE
GOUY
LAYER
IN
THE
ELECTROLYTE
.
85
5.2.3
THE
SPACE
CHARGE
LAYER
IN
THE
SEMICONDUCTOR
.
86
5.2.4
CHARGE
DISTRIBUTION
IN
SURFACE
STATES
.
92
5.3
ANALYSIS
OF
THE
POTENTIAL
DISTRIBUTION
.
93
5.3.1
GERMANIUM
ELECTRODES
.
93
5.3.2
SILICON
ELECTRODES
.
99
5.3.3
COMPOUND
SEMICONDUCTOR
ELECTRODES
.
100
5.3.4
FLATBAND
POTENTIAL
AND
POSITION
OF
ENERGY
BANDS
AT
THE
INTERFACE
.
.
.
102
5.3.5
UNPINNING
OF
ENERGY
BANDS
DURING
ILLUMINATION
.
107
6
ELECTRON
TRANSFER
THEORIES
.
112
6.1
THE
THEORY
OF
MARCUS
.
112
6.1.1
ELECTRON
TRANSFER
IN
HOMOGENEOUS
SOLUTIONS
.
112
6.1.2
THE
REORGANIZATION
ENERGY
.
116
6.1.3
ADIABATIC
AND
NON-ADIABATIC
REACTIONS
.
118
6.1.4
ELECTRON
TRANSFER
PROCESSES
AT
ELECTRODES
.
119
6.2
THE
GERISCHER
MODEL
.
122
6.2.1
ENERGY
STATES
IN
SOLUTION
.
122
6.2.2
ELECTRON
TRANSFER
.
127
6.3
QUANTUM
MECHANICAL
TREATMENTS
OF
ELECTRON
TRANSFER
PROCESSES
.
.
.
129
6.3.1
INTRODUCTORY
COMMENTS
.
129
6.3.2
NON-ADIABATIC
REACTIONS
.
133
6.3.3
ADIABATIC
REACTIONS
.
139
6.4
THE
PROBLEM
OF
DERIVING
RATE
CONSTANTS
.
147
6.5
COMPARISON
OF
THEORIES
.
149
7
CHARGE
TRANSFER
PROCESSES
AT
THE
SEMICONDUCTOR-LIQUID
INTERFACE
.
.
.
151
7.1
CHARGE
TRANSFER
PROCESSES
AT
METAL
ELECTRODES
.
151
7.1.1
KINETICS
OF
ELECTRON
TRANSFER
AT
THE
METAL-LIQUID
INTERFACE
.
151
7.1.2
DIFFUSION-CONTROLLED
PROCESSES
.
159
7.1.3
INVESTIGATIONS
OF
REDOX
REACTIONS
BY
LINEAR
SWEEP
VOLTAMETRY
.
163
7.1.4
CRITERIA
FOR
REVERSIBLE
AND
IRREVERSIBLE
REACTIONS
.
164
7.2
QUALITATIVE
DESCRIPTION
OF
CURRENT-POTENTIAL
CURVES
AT
SEMICONDUCTOR
ELECTRODES
.
165
7.3
ONE-STEP
REDOX
REACTIONS
.
167
CONTENTS
IX
7.3.1
THE
ENERGETICS
OF
CHARGE
TRANSFER
PROCESSES
.
167
7.3.2
QUANTITATIVE
DERIVATION
OF
CURRENT-POTENTIAL
CURVES
.
169
7.3.3
LIGHT-INDUCED
PROCESSES
.
174
7.3.4
MAJORITY
CARRIER
REACTIONS
.
178
7.3.5
MINORITY
CARRIER
REACTIONS
.
188
7.3.6
ELECTRON
TRANSFER
IN
THE
'
INVERTED
REGION
'
.
199
7.4
THE
QUASI-FERMI
LEVEL
CONCEPT
.
201
7.4.1
BASIC
MODEL
.
201
7.4.2
APPLICATION
OF
THE
CONCEPT
TO
PHOTOCURRENTS
.
205
7.4.3
CONSEQUENCES
FOR
THE
RELATION
BETWEEN
IMPEDANCE
AND
IMPS
SPECTRA
.
209
7.4.4
QUASI-FERMI
LEVEL
POSITIONS
UNDER
HIGH
LEVEL
INJECTIONS
.
212
7.5
DETERMINATION
OF
THE
REORGANIZATION
ENERGY
.
214
7.6
TWO-STEP
REDOX
PROCESSES
.
220
7.7
PHOTOLUMINESCENCE
AND
ELECTROLUMINESCENCE
.
225
7.7.1
KINETIC
STUDIES
BY
PHOTOLUMINESCENCE
MEASUREMENT
.
226
7.7.2
ELECTROLUMINESCENCE
INDUCED
BY
MINORITY
CARRIER
INJECTION
.
230
7.8
HOT
CARRIER
PROCESSES
.
233
7.9
CATALYSIS
OF
ELECTRODE
REACTIONS
.
236
8
ELECTROCHEMICAL
DECOMPOSITION
OF
SEMICONDUCTORS
.
241
8.1
ANODIC
DISSOLUTION
REACTIONS
.
241
8.1.1
GERMANIUM
.
241
8.1.2
SILICON
.
245
8.1.3
ANODIC
FORMATION
OF
AMORPHOUS
(POROUS)
SILICON
.
251
8.1.4
COMPOUND
SEMICONDUCTORS
.
251
8.2
CATHODIC
DECOMPOSITION
.
255
8.3
DISSOLUTION
UNDER
OPEN
CIRCUIT
CONDITIONS
.
255
8.4
ENERGETICS
AND
THERMODYNAMICS
OF
CORROSION
.
257
8.5
COMPETITION
BETWEEN
REDOX
REACTION
AND
ANODIC
DISSOLUTION
.
259
9
PHOTOREACTIONS
AT
SEMICONDUCTOR
PARTICLES
.
264
9.1
QUANTUM
SIZE
EFFECTS
.
264
9.1.1
QUANTUM
DOTS
.
266
9.1.2
SINGLE
CRYSTALLINE
QUANTUM
FILMS
AND
SUPERLATTICES
.
271
9.1.3
SIZE
QUANTIZED
NANOCRYSTALLINE
FILMS
.
274
9.2
CHARGE
TRANSFER
PROCESSES
AT
SEMICONDUCTOR
PARTICLES
.
274
9.2.1
REACTIONS
IN
SUSPENSIONS
AND
COLLOIDAL
SOLUTIONS
.
274
9.2.2
PHOTOELECTRON
EMISSION
.
281
9.2.3
COMPARISON
BETWEEN
REACTIONS
AT
SEMICONDUCTOR
PARTICLES
AND
AT
COMPACT
ELECTRODES
.
283
9.2.4
THE
ROLE
OF
SURFACE
CHEMISTRY
.
284
9.2.5
ENHANCED
REDOX
CHEMISTRY
IN
QUANTIZED
COLLOIDS
.
285
9.2.6
REACTION
ROUTES
AT
SMALL
AND
BIG
PARTICLES
.
289
9.2.7
SANDWICH
FORMATION
BETWEEN
DIFFERENT
PARTICLES
AND
BETWEEN
PARTICLE
AND
ELECTRODE
.
290
X
CONTENTS
9.3
CHARGE
TRANSFER
PROCESSES
AT
QUANTUM
WELL
ELECTRODES
(MQW,
SQW)
.
294
9.4
PHOTOELECTROCHEMICAL
REACTIONS
AT
NANOCRYSTALLINE
SEMICONDUCTOR
LAYERS
.
297
10
ELECTRON
TRANSFER
PROCESSES
BETWEEN
EXCITED
MOLECULES
AND
SEMICONDUCTOR
ELECTRODES
.
300
10.1
ENERGY
LEVELS
OF
EXCITED
MOLECULES
.
300
10.2
REACTIONS
AT
SEMICONDUCTOR
ELECTRODES
.
305
10.2.1
SPECTRA
OF
SENSITIZED
PHOTOCURRENTS
.
305
10.2.2
DYE
MOLECULES
ADSORBED
ON
THE
ELECTRODE
AND
IN
SOLUTION
.
309
10.2.3
POTENTIAL
DEPENDENCE
OF
SENSITIZATION
CURRENTS
.
311
10.2.4
SENSITIZATION
PROCESSES
AT
SEMICONDUCTOR
SURFACES
MODIFIED
BY
DYE
MONOLAYERS
.
313
10.2.5
QUANTUM
EFFICIENCIES,
REGENERATION
AND
SUPERSENSITIZATION
.
319
10.2.6
KINETICS
OF
ELECTRON
TRANSFER
BETWEEN
DYE
AND
SEMICONDUCTOR
ELECTRODE
.
321
10.2.7
SENSITIZATION
PROCESSES
AT
NANOCRYSTALLINE
SEMICONDUCTOR
ELECTRODES
.
325
10.3
COMPARISON
WITH
REACTIONS
AT
METAL
ELECTRODES
.
329
10.4
PRODUCTION
OF
EXCITED
MOLECULES
BY
ELECTRON
TRANSFER
.
330
11
APPLICATIONS
.
332
11.1
PHOTOELECTROCHEMICAL
SOLAR
ENERGY
CONVERSION
.
332
11.1.1
ELECTROCHEMICAL
PHOTOVOLTAIC
CELLS
.
332
11.1.1.1
ANALYSIS
OF
SYSTEMS
.
336
11.1.1.2
DYE-SENSITIZED
SOLAR
CELLS
.
341
11.1.1.3
CONVERSION
EFFICIENCIES
.
342
11.1.2
PHOTOELECTROLYSIS
.
346
11.1.2.1
TWO-ELECTRODE
CONFIGURATIONS
.
347
11.1.2.2
PHOTOCHEMICAL
DIODES
.
351
11.1.2.3
PHOTOELECTROLYSIS
DRIVEN
BY
PHOTOVOLTAICS
.
353
11.1.2.4
EFFICIENCY
.
355
11.1.3
PRODUCTION
OF
OTHER
FUELS
.
357
11.1.3.1
PHOTOELECTROLYSIS
OF
H2S
.
357
11.1.3.2
PHOTOELECTROLYSIS
OF
HALIDES
.
357
11.1.4
PHOTOREDUCTION
OF
CO
2
.
358
11.2
PHOTOCATALYTIC
REACTIONS
.
360
11.2.1
PHOTODEGRADATION
OF
POLLUTANTS
.
360
11.2.2
LIGHT-INDUCED
CHEMICAL
REACTIONS
.
363
11.3
ETCHING
OF
SEMICONDUCTORS
.
363
11.4
LIGHT-INDUCED
METAL
DEPOSITION
.
366
APPENDICES
.
369
REFERENCES
.
377
SUBJECT
INDEX
.
395 |
| any_adam_object | 1 |
| author | Memming, Rüdiger |
| author_facet | Memming, Rüdiger |
| author_role | aut |
| author_sort | Memming, Rüdiger |
| author_variant | r m rm |
| building | Verbundindex |
| bvnumber | BV019330484 |
| classification_rvk | VE 6300 |
| classification_tum | ELT 072f CHE 140f |
| ctrlnum | (OCoLC)248575205 (DE-599)BVBBV019330484 |
| discipline | Chemie / Pharmazie Physik Chemie Elektrotechnik |
| edition | 1. reprint. |
| format | Book |
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| id | DE-604.BV019330484 |
| illustrated | Illustrated |
| indexdate | 2024-09-06T00:13:32Z |
| institution | BVB |
| isbn | 352730147X |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-012795546 |
| oclc_num | 248575205 |
| open_access_boolean | |
| owner | DE-29T |
| owner_facet | DE-29T |
| physical | X, 399 S. Ill., graph. Darst. |
| publishDate | 2002 |
| publishDateSearch | 2002 |
| publishDateSort | 2002 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Memming, Rüdiger Verfasser aut Semiconductor electrochemistry Rüdiger Memming 1. reprint. Weinheim [u.a.] Wiley-VCH 2002 X, 399 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Halbleiter - Elektrochemische Eigenschaft Halbleiter (DE-588)4022993-2 gnd rswk-swf Elektrochemische Eigenschaft (DE-588)4344251-1 gnd rswk-swf Halbleiter (DE-588)4022993-2 s Elektrochemische Eigenschaft (DE-588)4344251-1 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=012795546&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Memming, Rüdiger Semiconductor electrochemistry Halbleiter - Elektrochemische Eigenschaft Halbleiter (DE-588)4022993-2 gnd Elektrochemische Eigenschaft (DE-588)4344251-1 gnd |
| subject_GND | (DE-588)4022993-2 (DE-588)4344251-1 |
| title | Semiconductor electrochemistry |
| title_auth | Semiconductor electrochemistry |
| title_exact_search | Semiconductor electrochemistry |
| title_full | Semiconductor electrochemistry Rüdiger Memming |
| title_fullStr | Semiconductor electrochemistry Rüdiger Memming |
| title_full_unstemmed | Semiconductor electrochemistry Rüdiger Memming |
| title_short | Semiconductor electrochemistry |
| title_sort | semiconductor electrochemistry |
| topic | Halbleiter - Elektrochemische Eigenschaft Halbleiter (DE-588)4022993-2 gnd Elektrochemische Eigenschaft (DE-588)4344251-1 gnd |
| topic_facet | Halbleiter - Elektrochemische Eigenschaft Halbleiter Elektrochemische Eigenschaft |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=012795546&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT memmingrudiger semiconductorelectrochemistry |