Geochemistry of non-traditional stable isotopes:
Saved in:
| Format: | Book |
|---|---|
| Language: | English |
| Published: |
Washington, DC
Mineralogical Soc. of America [u.a.]
2004
|
| Series: | Reviews in mineralogy and geochemistry
55 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XV, 454 S. Ill., graph. Darst. |
| ISBN: | 0939950677 |
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| 245 | 1 | 0 | |a Geochemistry of non-traditional stable isotopes |c ed.: Clark M. Johnson ... |
| 264 | 1 | |a Washington, DC |b Mineralogical Soc. of America [u.a.] |c 2004 | |
| 300 | |a XV, 454 S. |b Ill., graph. Darst. | ||
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| adam_text |
TABLE OF CONTENTS
I Overview and General Concepts
Clark M. Johnson, Brian L. Beard
and Francis Albarède
INTRODUCTION.1
ISOTOPIC ABUNDANCES AND NOMENCLATURE.2
ISOTOPIC FRACTIONATIONS.6
The isotope fractionation factor and mass-dependency of fractionation.7
Predicted and measured isotopic variations.9
Processes that may produce isotopically distinct reservoirs.12
DETERMINATION OF ISOTOPIC FRACTIONATION FACTORS.15
Fluid-mineral fractionation factors.16
Evaluating approach toward isotopic equilibrium in experiments.17
CONCLUSIONS.20
ACKNOWLEDGMENTS.20
REFERENCES.22
Z An Overview of Isotopic Anomalies in
Extraterrestrial Materials and Their Nucleosynthetic Heritage
Jean Louis Birck
INTRODUCTION.25
Historical background.26
The définition of isotopic anomalies.26
THE MEASUREMENT OF ISOTOPIC ANOMALIES.27
Large isotopic variations.27
Two isotope elements and small effects.27
Three isotope elements and small effects.27
Elements having 4 and more isotopes.28
Units.28
STELLAR EVOLUTION AND NUCLEOSYNTHESIS.28
Massive stars.29
p-r-s-processes.30
THE ISOTOPIC HETEROGENEITY IN THE REFRACTORY
COMPONENTS OF THE EARLY SOLAR-SYSTEM.30
Refractory inclusions of the CV3 carbonaceous chondrites (CAIs) .31
Hibonite rich inclusions of the CM2 and oxide grains in carbonaceous chondrites .39
"Presolar" Stardust grains: diamond, graphite, carbides and oxides .40
THE ISOTOPIC HETEROGENEITY IN NON-REFRACTORY EARLY
SOLAR SYSTEM MATERIALS.43
Oxygen.45
vii
Non-Traditional Stable Isotopes - Table of Contents
Chromium.45
Molybdenum .47
EXTINCT RADIOACTIVITIES.47
10-Berylium - 10-Boron (Tm = 1.5 m.y.).49
26-Aluminum - 26-Magnesium (Tin = 0.7 m.y.).49
41-Calcium-41-Potassium(T1/2 = 0.1 m.y.).51
53-Manganese - 53-Chromium (T1/2 = 3.7 m.y.).51
60-Iron - 60-Nickel (T1/2 = 1.5 m.y.) .52
92-Niobium - 92-Zirconium (T1/2 = 36 m.y.).52
107-Palladium - 107-Silver (T1/2 = 6.5 m.y.).52
129-Iodine - 129-Xenon (TI/2 = 16 m.y.).53
146-Samarium - 142-Neodymium (T1/2 = 103 m.y.).53
182-Hafiiium - 182-Tungsten (Jm = 9.4 m.y.).53
244-Plutonium spontaneous fission (Tw = 81 m.y.).54
Other nuclides.54
OPEN QUESTIONS AND FUTURE DIRECTIONS.54
Mass independent fractionation in physico chemical-processes.54
Early proton irradiation within the solar system.54
Presolar silicates.55
Instrumentation.55
CONCLUSION.55
ACKNOWLEDGMENTS.56
REFERENCES.56
«3 Applying Stable Isotope Fractionation Theory to New Systems
Edwin A. Schäuble
INTRODUCTION.65
Overview.66
History.66
General rules governing equilibrium stable isotope fractionations.67
Fractionation factors.68
EQUILIBRIUM FRACTIONATION THEORY.69
Fractionation in molecules.69
Fractionation in crystalline materials and solutions.75
The chemistry of stable isotope fractionation.77
Other causes of equilibrium isotopic fractionation .77
APPLYING STABLE ISOTOPE FRACTIONATION THEORY.78
Estimating unknown vibrational frequencies.78
Vibrational force-field modeling.79
Empirical force fields.81
Transferable empirical force fields (interatomic potentials).86
Ab initio force-field modeling.86
Theoretical applications of Mössbauer spectroscopy.90
Integrating theoretically estimated fractionations with measurements.91
BASIC KINETIC STABLE ISOTOPE FRACTIONATION THEORY.92
viii
Non-Traditional Stable Isotopes - Table of Contents
Effects of isotopic mass on molecular and atomic velocities and diffusivity.93
Effects of isotopic mass on rates of activation.94
MASS-DEPENDENCE OF EQUILIBRIUM AND KINETIC ISOTOPE
FRACTIONAT1ONS.96
CONCLUSIONS.97
ACKNOWLEDGMENTS.97
REFERENCES.97
APPENDIX: ANNOTATED BIBLIOGRAPHY OF THEORETICAL
EQUILIBRIUM FRACTIONATIONS.102
T1 Analytical Methods for Non-Traditional Isotopes
Francis Albarède and Brian L. Beard
INTRODUCTION.113
INSTRUMENTATION USED FOR ISOTOPE RATIO ANALYSIS.113
Gas source machines.114
TIMS.115
MC-ICP-MS.118
A PHENOMENOLOGICAL DESCRIPTION OF THE MASS-DEPENDENT
INSTRUMENTAL BIAS .124
STANDARD BRACKETING METHODS.129
DOUBLE-SPIKE ANALYSIS.130
THE EFFECT OF PEAK SHAPE.132
COUNTING STATISTICS.132
IMPLEMENTATION OF THE MASS BIAS CORRECTION FOR MC-ICP-MS.134
MATRIX EFFECT.136
Spectral (isobaric) effects.136
Non-spectral effects.137
INSTRUMENTAL BIAS: MEMORY EFFECTS.140
ABUNDANCE SENSITIVITY.141
CORRECTION OF THE NON-MASS DEPENDENT INSTRUMENTAL
BIAS IN STATIC MODE.142
CORRECTION OF THE INSTRUMENTAL BIAS IN DYNAMIC MODE.143
A FEW SIMPLE RULES FOR PRECISE AND ACCURATE
MC-ICP-MS MEASUREMENTS.146
ACKNOWLEDGMENTS.147
REFERENCES.147
APPENDIX A: TABLE OF SYMBOLS .151
APPENDIX B: EXAMPLE OF DOUBLE-SPIKE CALCULATION
USING A NE WTON-RAPHSON ITERATION.152
IX
5
Non-Traditional Stable Isotopes - Table of Contents
Developments in the Understanding and
Application of Lithium Isotopes in the Earth and Planetary Sciences
PaulB. Tomascak
INTRODUCTION.153
BACKGROUND: LITHIUM ISOTOPES IN THE SCIENCES.154
Experiments in Li isotope fractionation.154
Lithium isotopes in fields outside geochemistry.154
LITHIUM ISOTOPIC ANALYSIS.155
From early Li isotope measurement to the "modern era" of analysis.155
Plasma-source mass spectrometry.156
Requirements in chemical separation.157
In situ analysis.158
Precision and accuracy.158
INTERNAL-PLANETARY SYSTEMS.159
Mass fractionation in igneous systems.159
Mantle processes.160
Crustal processes.165
PLANETARY SURFACE SYSTEMS.168
Mass fractionation in hydrologie cycle of Li .168
Primarily clastic sediments and sedimentary rocks .169
Lithium isotopic fractionation in the oceans .170
Lithium isotopic fractionation on the continents.180
SIGNIFICANCE OF LITHIUM ISOTOPES IN THE BULK EARTH .185
CONCLUSIONS AND FUTURE DIRECTIONS.187
ACKNOWLEDGMENTS.188
REFERENCES.189
O The Isotope Geochemistry and Cosmochemistry of Magnesium
Edward D. Young and Albert Galy
INTRODUCTION.197
REFERENCE MATERIALS, NOMENCLATURE, AND ANALYTICAL
CONSIDERATIONS.198
Reference material.198
Nomenclature .199
Analytical considerations .200
MAGNESIUM ISOTOPE RESERVOIRS.'.202
RESOLVING MECHANISMS OF ISOTOPE FRACTIONATION WITH THREE
ISOTOPE DIAGRAMS.205
Mass-dependent fractionation laws.206
Mass-fractionation in three-isotope space.208
The definition of A25Mg'.211
Uncertainties in A25Mg' . 211
A' - Ô' Diagrams. 212
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Non-Traditional Stable Isotopes — Table of Contents
TERRESTRIAL MAGNESIUM ISOTOPE RESERVOIRS
IN THREE-ISOTOPE SPACE: IMPLICATIONS FOR
MECHANISMS OF FRACTIONATION.213
EXTRATERRESTRIAL MAGNESIUM ISOTOPE RESERVOIRS IN
THREE-ISOTOPE SPACE.217
ISOTOPIC COSMOBAROMETRY.223
IN SITU LASER ABLATION.225
SUMMARY.228
REFERENCES.229
/ The Stable-Chlorine Isotope Compositions
of Natural and Anthropogenic Materials
Michael A. Stewart and Arthur J. Spivack
INTRODUCTION.231
CHLORINE ISOTOPE NOMENCLATURE.232
STABLE-CHLORINE ISOTOPE ANALYSES.232
CHLORINE ISOTOPE FRACTIONATION.233
RESULTS AND IMPLICATIONS OF THE STABLE-CHLORINE ISOTOPIC
COMPOSITION OF GEOLOGIC AND ANTHROPOGENIC MATERIALS.233
Meteorites.233
Igneous and metamorphic rocks and minerals.235
Fluids.239
Summary of terrestrial chlorine isotope distributions.246
Sea-salt aerosols.247
Environmental chemistry.247
ACKNOWLEDGMENTS.249
REFERENCES.250
8
Calcium Isotopic Variations Produced by Biological,
Kinetic, Radiogenic and Nucleosynthetic Processes
Donald J. DePaolo
INTRODUCTION.255
CALCIUM ISOTOPE ESSENTIALS.256
Analysis methods and issues for radiogenic 40Ca.257
Analysis methods and issues for mass dependent Ca isotope fractionation.258
Ca isotope standards and reference materials.260
CALCIUM ISOTOPES IN METEORITES AND LUNAR SAMPLES.262
TERRESTRIAL STUDIES OF RADIOGENIC CALCIUM.263
Effects of radiogenic calcium 40Ca on measured S^Ca values.266
STUDIES OF TERRESTRIAL CALCIUM STABLE ISOTOPE FRACTIONATION.267
Igneous and metamorphic rocks and petrogenetic processes.267
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Non-Traditional Stable Isotopes - Table of Contents
Biological fractionation through food chains.268
Model for Ca isotope fractionation in vertebrates.270
Ca isotope fractionation in marine shelled organisms.271
Calcium in the weathering cycle.275
Ca isotopic variations in the paleo-oceans.279
Paleoclimatology.281
CONCLUSIONS AND IMPLICATIONS.284
ACKNOWLEDGMENTS.284
REFERENCES.285
9 Mass-Dependent Fractionation of Selenium and
Chromium Isotopes in Low-Temperature Environments
Thomas M. Johnson and Thomas D. Bullen
INTRODUCTION.289
Se geochemistry.
Cr geochemistry.•.
Reduction of sulfate, nitrate, selenate and chromate: Analogous isotopic behavior. 292
ANALYTICAL METHODS.293
?Q3
Selenium mass spectrometry.
Selenium sample preparation.
Chromium mass spectrometry and sample preparation.2"5
Standards currently in use.
NOTATION.296
KINETIC ISOTOPE EFFECTS: THEORETICAL CONSIDERATIONS
AND INSIGHTS FROM THE SULFUR ISOTOPE LITERATURE.297
Dominance of kinetic effects at earth-surface temperatures.29'
Dependence of kinetic isotope effects on reaction mechanisms and rates.297
SELENIUM ISOTOPE SYSTEMATICS.2"
Theoretical estimates of equilibrium isotope fractionation.300
Se(VI) reduction: abiotic.301
Se(IV) reduction: abiotic.302
Se(VT) reduction: microbial.302
Se(IV) reduction: microbial.303
Se oxidation.304
Se(VI) and Se(IV) uptake by algae and plants.304
Volatilization.305
Lack of isotopic fractionation between adsorbed and dissolved species.305
SELENIUM ISOTOPE APPLICATIONS AND DATA FROM NATURAL
MATERIALS.306
Meteorites and igneous rocks.306
Wetlands.306
Hydrothermal Sulfides .306
Marine sediments.306
CHROMIUM ISOTOPE SYSTEMATICS.308
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Non-Traditional Stable Isotopes - Table of Contents
Equilibrium isotope fractionation.308
Fractionation during Cr(VI) reduction.308
Lack of isotopic fractionation between adsorbed and dissolved Cr(VI).309
Other processes.310
Cr isotope data from igneous rocks, reagent Cr, and Cr plating baths .310
Cr isotope data from groundwater systems.311
Need for field calibration.312
FUTURE DIRECTIONS.313
ACKNOWLEDGMENTS.313
REFERENCES.313
10A
Fe Isotope Variations in the Modern and
Ancient Earth and Other Planetary Bodies
Brian L. Beard and Clark M. Johnson
INTRODUCTION .319
NOMENCLATURE AND ANALYTICAL METHODS.321
Nomenclature.321
Analytical methods.323
ORIGIN OF Fe ISOTOPE VARIATIONS.324
Calculated fractionation factors.324
Experimental determination of fractionation factors.326
Composite effects of equilibrium and kinetic fractionations in an experiment.329
Summary observations on Fe isotope fractionation factors.335
IRON ISOTOPE VARIATIONS IN HIGH TEMPERATURE ENVIRONMENTS.336
Fe isotope fractionation produced by vaporization.339
High-temperature inter-mineral Fe isotope fractionation.340
IRON ISOTOPE VARIATIONS IN LOW TEMPERATURE ENVIRONMENTS.344
Fe isotope variations in clastic sediments.344
Fe isotope variations in MOR hydrothermal fluids.347
Iron isotope variations in Fe-Mn nodules.348
Banded iron formations.351
CONCLUSIONS.352
ACKNOWLEDGMENTS.353
REFERENCES.353
1 ÜD Isotopic Constraints on Biogeochemical Cycling of Fe
Clark M. Johnson, Brian L. Beard, Eric E. Roden
Dianne K. Newman and Kenneth H. Nealson
INTRODUCTION.359
Nomenclature.360
BIOLOGICAL PROCESSING OF IRON.361
Fe(II) oxidation.361
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Non-Traditional Stable Isotopes - Table of Contents
Fe(III) reduction.363
Implications for Fe isotope fractionations.364
ISOTOPIC FRACTIONATION DURING DISSOLUTION AND
PRECIPITATION OF MINERALS.365
Congruent dissolution.365
Incongruent dissolution.367
Isotopic fractionations among aqueous species and minerals in abiologic systems .369
ISOTOPIC MASS BALANCE.369
ISOTOPIC FRACTIONATION PRODUCED DURING DISSIMILATORY
Fe(III) REDUCTION.371
Calculation of Fe isotope compositions.374
Temporal changes in reservoir sizes and isotopic compositions.376
Sorption effects.377
Solid products of DIR.379
Summary of Fe isotope fractionations produced during DIR.383
ANAEROBIC PHOTOSYNTHET1C Fe(II) OXIDATION.383
Proportions of reacting species.386
Constraints on isotopic variations.388
The Fe(III)aq-ferrihydrite fractionation factor.390
Comparison with abiologic Fe(II) oxidation.391
ISOTOPIC VARIATIONS PRODUCED DURING BIOGEOCHEMICAL
CYCLING OF IRON.392
Redox cycling of Fe by bacteria.392
Isotopic variations in marine settings.395
CONCLUSIONS.399
ACKNOWLEDGMENTS.401
REFERENCES.402
11
The Stable Isotope Geochemistry of Copper and Zinc
Francis Albarède
INTRODUCTION.409
THE CHEMICAL PROPERTIES OF Cu AND Zn.410
THE GEOCHEMICAL PROPERTIES OF Cu AND Zn.411
THE BIOCHEMICAL USE OF Cu AND Zn.412
ANALYTICAL TECHNIQUES.413
NATURAL ISOTOPIC VARIATIONS.\ZZZZZZZZZZZZZZZZZZZ.415
Meteorites and igneous rocks.416
Sedimentary rocks: zinc.416
Sedimentary rocks: copper.419
Biological products.420
Cu and Zn ores. 420
EXPERIMENTAL PARTITIONING.420
ACKNOWLEDGMENTS. .424
REFERENCES.\ZZZZZZZZZZ.425
xiv
12
Non-Traditional Stable Isotopes - Table of Contents
Molybdenum Stable Isotopes:
Observations, Interpretations and Directions
Ariel D. Anbar
INTRODUCTION.429
MOLYBDENUM IN THE ENVIRONMENT AND IN BIOLOGY:
SETTING THE STAGE.430
Molybdenum environmental geochemistry.430
Molybdenum in biology.433
Isotopic expectations.434
ANALYTICAL CONSIDERATIONS.434
Data reporting conventions.434
Historical perspective.435
Chemical separations.436
Analytical mass fractionation.436
OBSERVATIONS.437
Igneous rocks.438
Marine sediments.439
Waters.440
Laboratory experiments.440
INTERPRETATIONS.441
Mo isotope fractionation in the oceans.442
Mo isotope mass balance in the oceans.446
POTENTIAL APPLICATIONS.447
Mo stable isotopes and global ocean paleoredox.447
Other potential applications.449
CONCLUSIONS.450
ACKNOWLEDGMENTS.450
REFERENCES.450
xv |
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| oclc_num | 249576810 |
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| owner | DE-12 DE-19 DE-BY-UBM DE-20 DE-703 DE-29 DE-83 DE-B16 DE-M490 |
| owner_facet | DE-12 DE-19 DE-BY-UBM DE-20 DE-703 DE-29 DE-83 DE-B16 DE-M490 |
| physical | XV, 454 S. Ill., graph. Darst. |
| publishDate | 2004 |
| publishDateSearch | 2004 |
| publishDateSort | 2004 |
| publisher | Mineralogical Soc. of America [u.a.] |
| record_format | marc |
| series | Reviews in mineralogy and geochemistry |
| series2 | Reviews in mineralogy and geochemistry |
| spelling | Geochemistry of non-traditional stable isotopes ed.: Clark M. Johnson ... Washington, DC Mineralogical Soc. of America [u.a.] 2004 XV, 454 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Reviews in mineralogy and geochemistry 55 Stabiles Isotop - Isotopengeochemie - Aufsatzsammlung Kosmochemie (DE-588)4133733-5 gnd rswk-swf Geochemie (DE-588)4020198-3 gnd rswk-swf Stabiles Isotop (DE-588)4124245-2 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Geochemie (DE-588)4020198-3 s Stabiles Isotop (DE-588)4124245-2 s DE-604 Kosmochemie (DE-588)4133733-5 s b DE-604 Johnson, Clark M. Sonstige oth Reviews in mineralogy and geochemistry 55 (DE-604)BV013377203 55 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=012785625&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Geochemistry of non-traditional stable isotopes Reviews in mineralogy and geochemistry Stabiles Isotop - Isotopengeochemie - Aufsatzsammlung Kosmochemie (DE-588)4133733-5 gnd Geochemie (DE-588)4020198-3 gnd Stabiles Isotop (DE-588)4124245-2 gnd |
| subject_GND | (DE-588)4133733-5 (DE-588)4020198-3 (DE-588)4124245-2 (DE-588)4143413-4 |
| title | Geochemistry of non-traditional stable isotopes |
| title_auth | Geochemistry of non-traditional stable isotopes |
| title_exact_search | Geochemistry of non-traditional stable isotopes |
| title_full | Geochemistry of non-traditional stable isotopes ed.: Clark M. Johnson ... |
| title_fullStr | Geochemistry of non-traditional stable isotopes ed.: Clark M. Johnson ... |
| title_full_unstemmed | Geochemistry of non-traditional stable isotopes ed.: Clark M. Johnson ... |
| title_short | Geochemistry of non-traditional stable isotopes |
| title_sort | geochemistry of non traditional stable isotopes |
| topic | Stabiles Isotop - Isotopengeochemie - Aufsatzsammlung Kosmochemie (DE-588)4133733-5 gnd Geochemie (DE-588)4020198-3 gnd Stabiles Isotop (DE-588)4124245-2 gnd |
| topic_facet | Stabiles Isotop - Isotopengeochemie - Aufsatzsammlung Kosmochemie Geochemie Stabiles Isotop Aufsatzsammlung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=012785625&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV013377203 |
| work_keys_str_mv | AT johnsonclarkm geochemistryofnontraditionalstableisotopes |