Lithium aluminum hydride in organic chemistry:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | Croatian |
| Veröffentlicht: |
1955
|
| Online-Zugang: | Inhaltsverzeichnis |
Internformat
MARC
| LEADER | 00000nam a2200000zc 4500 | ||
|---|---|---|---|
| 001 | BV018647465 | ||
| 003 | DE-604 | ||
| 005 | 00000000000000.0 | ||
| 007 | t | ||
| 008 | 040418s1955 |||| 00||| srp d | ||
| 035 | |a (OCoLC)636331433 | ||
| 035 | |a (DE-599)BVBBV018647465 | ||
| 040 | |a DE-604 |b ger | ||
| 041 | 0 | |a srp |a scr | |
| 049 | |a DE-12 | ||
| 084 | |a 7,41 |2 ssgn | ||
| 100 | 1 | |a Mićović, Vukić M. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Lithium aluminum hydride in organic chemistry |
| 264 | 1 | |c 1955 | |
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 505 | 0 | |a Red. Kosta V. Petković.<br>Beograd: Naučna knjiga 1955. XI, 193 S.m.Abb. [serbokroat.]<br>([Srpska Akademija nauka. Posebna Izdanja.]<br>Serbian Academy of Sciences. Monographs. 237. = Section for Natural Sciences and Mthematics. 9.) | |
| 700 | 1 | |a Mihailović, Mihailo Lj. |e Sonstige |4 oth | |
| 700 | 1 | |a Petković, Kosta |d 1903-1987 |e Sonstige |0 (DE-588)116128682 |4 oth | |
| 856 | 4 | 2 | |m HEBIS Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=011418202&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 940 | 1 | |n oe | |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-011418202 | ||
| 942 | 1 | 1 | |e 22/bsb |g 4971 |
| 980 | 4 | |a (DE-12)AK14900608 | |
| 980 | 4 | |a (DE-12)AK14930350 | |
| 980 | 4 | |a (DE-12)AK16980710 | |
Datensatz im Suchindex
| _version_ | 1804131263291850752 |
|---|---|
| adam_text | SERBIANACADEMYOFSCIENCES
IMONOGRAPHS
VOLUME cqxxxvii
SECTION FOR NATURAL SCIENCES AND MATHEMATICS
i; A1? 9
!i ;,,, ;! « JT ,1 , •
• VUKlCM:M|(|OVIC:PHI;DMIHA1LQLjMIHAILOVlC,Ph D
ji1 Professor of (chemistry In ttiel • Lecturer in Chemistry in the
j;j University o f Belgrade » University, o f Belgrade;
lj : (Raculty of Sciences) • |! and (Faculty of Sciences)
! • 1 ^ » i • -
i LITHIUM ALUMINUM HYDRIDE
| ij| ORGANIC CHEMISTRY
i • J1-nr-i/*
J -I • ;,i,Redactor
f • ;KOSTAVPETKOVIC
! ;; Member of Academy
Secretary of the Section for Natural Sciences and
: Mathematics
Submitted to the Meetingof the Section for Natural Sciences
and Mathematics on the 23rd of, November, 1954
LZDAVACKOPREDUZECE-
BEOGRAD,1955
CONTENTS
LITHIUM ALUMINUM HYDRIDE AS A REDUCING AGENT IN OR-
: , GANIC CHEMISTRY — _ — — 1
1 Advantages of Lithium Aluminum Hydride — — — •— •— — 1
2 Analogy with Grignard Reagents — — — — — — — — 2
3 Other Complex Metal Hydrides as Reducing Agents — —j — 2
II
FORMATION AND PROPERTIES OF LITHIUM ALUMINUM HYDRIDE 3
1 The Formation of Lithium ; Aluminum Hydride —: — —; — -• 3
2 Properties of Lithium Aluminum Hydride — — — — —; —- — 5
III: r
REACTIONS WITH INORGANIC AND ORGANOMETALLIC- COM
POUNDS: — — — — — — — — — 7
- iv : •
COMPOUNDS CONTAINING ACTIVE HYDROGEN —- — — — 9
V •
EXPERIMENTAL CONDITIONS — — — — ^ — — — — — 11
1 General Procedure — —• — — — — ,— — — — — — 11
2 Solvents — — — — — — — — — — —— — :— — , 11
3 Hydrolysis and Isolation of Reduction Products —— — 12
4 : Special -Procedures and Preparation of Hydride Solutions — 13
• 5ExplosionsandFireHazard — — — — tt- — — — i — • — 1 4
VI p
ALDEHYDES, KETONES AND QUINONES — — — — ; 15
1 Aldehydes, and Ketones — — — — — — — — — — — 15
2 Hydrogenolysis-of ithe Carbonyl Group — — — • — :—• •• 17
3 a, ^-Unsaturated- Aldehydes and Ketones — — — — —, — —• 13
4 Reductions Followed by-Loss of Water, Rearrangement and Jsomer-
• izaticm — — — — •— —: — — —• — — •— — — -20
5 Dialdehydes and Diketones — •— — — — — — — — 23
Jf- -
I
: VIII
6 Steric Course of the Hydride Reduction of Carbonyl Groups — —
, 7 : Keto Steroids — — — — — — — — — — — — — —
8, Asymmetric, Reduction of Ketones — — — — — — — —
9 Reduction of Quinones — — — — — — — — — — —
VII
CARBOXYLIC ACIDS — — — — — — — — — — —
1 Scope arid Limitations — — — — — — —• —:— — — —•
2 Hydrogenolysis of the Carboxyl Group — — — — — — — —
3 Halogen Acids — -— — —• — — — —• — — — — — —
4 Dic^rboxylic Acids — — — — — —: — — — — — —
5 a, /^-Unsaturated, Acids — —• — — — — — — — *— — —
VIII
ESTERS — — — — — — — —
1 Types of Esters Reduced with Lithium Aluminum Hydride — — —
2 Optically, Active ^ Esters — •—• — — — — — — •— — —
3 Halogen Esters — •— — — —•— — — — —• — — —- —
4 Hydrogenolysis of the Ester Function- — —• — — —• — — —
• 5 a, /^-Unsaturated Esters — —• — — —• — — — — •— — —
6 Polyesters — — — —• — — — — — — — — • — — —
7Keto-esters — — — — — • • — — — — — — — —
8 Orthqesters^— — — — — — — — |— — — — —•
9 Enol esters, — — —• — — —r- -—— — •—
IX
ACID CHLORIDES - • — — — — — — — — — — ^
LACTONES — — — — — — — _ —
1 Scope and Limitations — — — — — — ——; — — —
2 Unsaturated Lactones — • — — — — _•—• •— — — — — —•
3 Sugar Lactones •— — — — — — — — — — — — — —
4 Formation of Hydroxy Aldehydes from Lactones — — — — —
I-- • , • - i
X I
ACID ANHYDRIDES — — ,-R-R — _ _ _
1 Scope and Limitations — — —• — ;— — — -— — — — —
2:ReductionofCarbonDioxide — — — — — — — — —
XII
ACID AMIDES, ESTERS OF CARBAMIC ACIDS, IMIDES, LACTAMS
1 Amides — — — — — — — — — — -U — —
2J Rearrangement Reactions and Reductive Cleavage of Amides/ — _ —
3 Secondary Amides — — — — — —- — — • —• — — —
4 Formation of Aldehydes • from : Amides —• *- • —— •— — w —
5 Mechanism of the Reduction of Amides — — — — — — —
6 Carbamic Esters — — — — — — — • — •—? ••— — — — „
IX
1
; 7 Imides — — — — — — — — — — — — — — 61
8 Lactams — — —• — — — — — — — — — — — — 61
(9Applicationsofthe Hydri deReductionofLactamsintheChemdstry
{ of Alkaloids — — — — — — — — — — — — 64
SlO Formation of co-Amirio Aldehydes from Lactams — — — — :— _— 66
11 Aldehyde Ammonias — — —7 — — — — — — — — 67
XIII •
EPOXIDES — -i 1^-1 — I— — -4r -T- —• — — —t — — 68
1 Scope — • — — — — — — —- — — — — — — 68
2 Reduction of Anhydro Sugars — — — — —r- — — — — 68
3 Steroidal •, Epoxides — — — — — — — — — —• —= — 69
4 Mechanism of the Reduction of Epoxides — — — — — •— 70
5 Effect* of Steric and Electronic Factors on the Hydride Reduction of
Epoxides —• —- IV—ri — —s -r- — — — — — —:r — — 71;
6 -Limitations — — — — ___ — — — 74
XIV
OZONIDES AND PEROXIDES — — 75
l i Ozonides — — 1— — — — — — — — — — — — — • 75
2 Peroxides —r — — — — — — — — — — — — — — 75
3 Epidioxides — — — — -—: — — — — — — — 76
XV •
VARIOUS OXYGEN, FUNCTIONS -j- •— — — — — ; 77
1 Hydrogenolysis Reactions — — — — — — — — — — — 77
2 Protection of the Hydroxyl GroupL-Ethers — — — — — — — 79
3 Blocking of the Carbonyl Group — — — — — — — — — 79
4 Hemiacetals and Lactols — — — — — —1 — — —; — 80
,5 Enol Ethers and Ethers of 1,3-Dicarbonyl Compounds — :— — — 81
XVI - -
NITRILES ISONITRILES, CY AN OH YDRINS ACYLCYANIDES — — 83
1 Nitriles — — — — — — — — — —• — — — — — — 83
2 Fonnation of Aldehydes from Nitriles — — — — — — — — 86
3 Dinitriles and Cyanohydrins — — — — — —; ;— — — — 87
4 Isonitriles and Acylcyanides — — — — — — — — — — 87
XVII
NITRO COMPOUNDS — — 88
1 Aliphatic Nitro Compounds — — — — —1 — — — — — 88
2 Reduction of P -Nitrostyrenes —, -4- — — — — — —88
3 Anomalous Reductions — — — -— — — — — — — — ,89
4 Aromatic Nitro Compounds — — — — — — — — — — — 90
XVIII 1 -:*
OXIMES 92
X
XIX
QUATERNARY CYCLIC AMMONIUM; SALTS AND/PYRYLIUM SALTS 94
1 Ammonium Salts — — — — — — — —, — — — — t— 94
2 Mechanism of Reduction — — — — — — — — — — — 95
3 a-Pyrylium and Y-Pyryliurri Salts — — — — — — — — — 96
XX
VARIOUS NITROGEN AND PHOSPHORUS FUNCTIONS — — 97
1 Reduction of Azo and Azoxy Compounds — — — — — — — 97
2; Azines, Nitrosoamines, Hydrazines, Azides, Isocyanates and Isothiio-
• cyanates • — — — — — — — — — — — — — — 98
3 Ami dines, • CarbamiLdes, Guanidineis, Foimazans — — — • — 99
4 Schiff Bases, Imines, Quinone Imines — — — 99
5 Cyclic Imines, Azirines, Hydroxylamdnes, Aminooxides, 2-Phenylhy-
drazono-l,3-dicarbonyl Compounds — — — — — — — 101
6 Esters of Nitric and Nitrous Acid — — — —•• — — — — — 101
7 Compounds Containing Phosphorus Functions — — — — — — 101
XXI „
HALOGEN COMPOUNDS — — — — — — — — — — — — 102
1 Hydrogenolysis of Halogen Atoms — — — — — — — — — 102
2 Selective Reductions — — — — — — — — — —: :— — 103
3 Reactivity of Halogen Compounds — — — — — — — — — 103
4 Di- and Polyhalides — — — — — — — — — — — 106
5 Cyanuric Chloride — — — — — — — — — — — — —• 107
6 Mechanism and Steric Course of the Hydride Reduction of Halides 107
XXII
ORGANIC-SULFUR COMPOUNDS — — — — • ^ — — — 110
1 Dithiois, Disulfides and Pelysulfides — — — — — — — — 110
2 Sulfoxides, Sulfones, Disulfones, Thiocyanates, Epithio Compounds 111
3 Esters of Sulfonic Acids — — — — —, — — — — — — 112
4 Disulfonates — — — — — — — — — — — — — — 113
5: Stereochemical! Course of the Reduction of Sulfonic Esters — •— — 116
6,-, Derivatives of Sulfonic, Sulfinic and Sulfenic Acids — — — — 118
•7; Miscellaneous Sulfur Compounds :— — — — — — — — — 119
XXIII , •
CARBON-CARBON DOUBLE AND TRIPLE BONDS — — — — — 121
1 Ethylenic Bonds — —• — — — — — — — — — — — 121
2 Mechanism of Lithium Aluminum Hydride Addition to the Double
Bonu — — — — — — — — — —• — — — — — — 122
3: Partial Reduction of Conjugated Systems — —i —• — — — — 124
4 Reduction of arOlefins and Cycloolefins — — -4-^ — — — — 125
5 Acetylenic Bonds — — — — — — — —• • — i-— — — 125
XXIV
AROMATIC SYSTEMS —— — — — — h- — — — — — 128
1 Rings Containing Reducible Groups — — — — — — — — 128
XI
2 Unsubstituted Aromatic Hydrocarbons — — — — — — — — 128
3, N- And O-Heterocyclic Rings without Reducible Functions — — — 129
4 Ring Systems Containing Two Heteroatoms — — — — — — 131
XXV _
MECHANISM OF THE HYDRIDE REDUCTION — — — — — — 133
1 Constitution of lithium Aluminum Hydride — — — — — — 133
2 Bimolecular Hydride Ion Transfer — — — — — —: — — 133
3 Homopolar Transfer of Electrons — — — — — — — — — 134
4 Role of Solvent — — — — — — — — — — — — 135
REFERENCES — — _ — — — — — — — — 137
SUBJECT INDEX — 177
|
| any_adam_object | 1 |
| author | Mićović, Vukić M. |
| author_GND | (DE-588)116128682 |
| author_facet | Mićović, Vukić M. |
| author_role | aut |
| author_sort | Mićović, Vukić M. |
| author_variant | v m m vm vmm |
| building | Verbundindex |
| bvnumber | BV018647465 |
| contents | Red. Kosta V. Petković.<br>Beograd: Naučna knjiga 1955. XI, 193 S.m.Abb. [serbokroat.]<br>([Srpska Akademija nauka. Posebna Izdanja.]<br>Serbian Academy of Sciences. Monographs. 237. = Section for Natural Sciences and Mthematics. 9.) |
| ctrlnum | (OCoLC)636331433 (DE-599)BVBBV018647465 |
| format | Book |
| fullrecord | <?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01402nam a2200349zc 4500</leader><controlfield tag="001">BV018647465</controlfield><controlfield tag="003">DE-604</controlfield><controlfield tag="005">00000000000000.0</controlfield><controlfield tag="007">t</controlfield><controlfield tag="008">040418s1955 |||| 00||| srp d</controlfield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(OCoLC)636331433</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)BVBBV018647465</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-604</subfield><subfield code="b">ger</subfield></datafield><datafield tag="041" ind1="0" ind2=" "><subfield code="a">srp</subfield><subfield code="a">scr</subfield></datafield><datafield tag="049" ind1=" " ind2=" "><subfield code="a">DE-12</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">7,41</subfield><subfield code="2">ssgn</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Mićović, Vukić M.</subfield><subfield code="e">Verfasser</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Lithium aluminum hydride in organic chemistry</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">1955</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="505" ind1="0" ind2=" "><subfield code="a">Red. Kosta V. Petković.<br>Beograd: Naučna knjiga 1955. XI, 193 S.m.Abb. [serbokroat.]<br>([Srpska Akademija nauka. Posebna Izdanja.]<br>Serbian Academy of Sciences. Monographs. 237. = Section for Natural Sciences and Mthematics. 9.)</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Mihailović, Mihailo Lj.</subfield><subfield code="e">Sonstige</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Petković, Kosta</subfield><subfield code="d">1903-1987</subfield><subfield code="e">Sonstige</subfield><subfield code="0">(DE-588)116128682</subfield><subfield code="4">oth</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="m">HEBIS Datenaustausch</subfield><subfield code="q">application/pdf</subfield><subfield code="u">http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=011418202&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA</subfield><subfield code="3">Inhaltsverzeichnis</subfield></datafield><datafield tag="940" ind1="1" ind2=" "><subfield code="n">oe</subfield></datafield><datafield tag="999" ind1=" " ind2=" "><subfield code="a">oai:aleph.bib-bvb.de:BVB01-011418202</subfield></datafield><datafield tag="942" ind1="1" ind2="1"><subfield code="e">22/bsb</subfield><subfield code="g">4971</subfield></datafield><datafield tag="980" ind1="4" ind2=" "><subfield code="a">(DE-12)AK14900608</subfield></datafield><datafield tag="980" ind1="4" ind2=" "><subfield code="a">(DE-12)AK14930350</subfield></datafield><datafield tag="980" ind1="4" ind2=" "><subfield code="a">(DE-12)AK16980710</subfield></datafield></record></collection> |
| id | DE-604.BV018647465 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-09T19:34:09Z |
| institution | BVB |
| language | Croatian |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-011418202 |
| oclc_num | 636331433 |
| open_access_boolean | |
| owner | DE-12 |
| owner_facet | DE-12 |
| publishDate | 1955 |
| publishDateSearch | 1955 |
| publishDateSort | 1955 |
| record_format | marc |
| spelling | Mićović, Vukić M. Verfasser aut Lithium aluminum hydride in organic chemistry 1955 txt rdacontent n rdamedia nc rdacarrier Red. Kosta V. Petković.<br>Beograd: Naučna knjiga 1955. XI, 193 S.m.Abb. [serbokroat.]<br>([Srpska Akademija nauka. Posebna Izdanja.]<br>Serbian Academy of Sciences. Monographs. 237. = Section for Natural Sciences and Mthematics. 9.) Mihailović, Mihailo Lj. Sonstige oth Petković, Kosta 1903-1987 Sonstige (DE-588)116128682 oth HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=011418202&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Mićović, Vukić M. Lithium aluminum hydride in organic chemistry Red. Kosta V. Petković.<br>Beograd: Naučna knjiga 1955. XI, 193 S.m.Abb. [serbokroat.]<br>([Srpska Akademija nauka. Posebna Izdanja.]<br>Serbian Academy of Sciences. Monographs. 237. = Section for Natural Sciences and Mthematics. 9.) |
| title | Lithium aluminum hydride in organic chemistry |
| title_auth | Lithium aluminum hydride in organic chemistry |
| title_exact_search | Lithium aluminum hydride in organic chemistry |
| title_full | Lithium aluminum hydride in organic chemistry |
| title_fullStr | Lithium aluminum hydride in organic chemistry |
| title_full_unstemmed | Lithium aluminum hydride in organic chemistry |
| title_short | Lithium aluminum hydride in organic chemistry |
| title_sort | lithium aluminum hydride in organic chemistry |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=011418202&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT micovicvukicm lithiumaluminumhydrideinorganicchemistry AT mihailovicmihailolj lithiumaluminumhydrideinorganicchemistry AT petkovickosta lithiumaluminumhydrideinorganicchemistry |