Broadband dielectric spectroscopy in neat and binary molecular glass formers: frequency and time domain spectroscopy, non-resonant spectral hole burning
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Berlin
Logos-Verl.
2003
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Zugl.: Bayreuth, Univ., Diss., 2003 |
| Physical Description: | III, 233 S. graph. Darst. |
| ISBN: | 383250320X |
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MARC
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| 245 | 1 | 0 | |a Broadband dielectric spectroscopy in neat and binary molecular glass formers |b frequency and time domain spectroscopy, non-resonant spectral hole burning |c von Thomas Blochowicz |
| 264 | 1 | |a Berlin |b Logos-Verl. |c 2003 | |
| 300 | |a III, 233 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Zugl.: Bayreuth, Univ., Diss., 2003 | ||
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| adam_text |
CONTENTS
1.
INTRODUCTION
1
2.
DIELECTRIC
SPECTROSCOPY
AND
THE
GLASS
TRANSITION
9
2.1.
THE
GLASS
TRANSITION
.
9
2.2.
MOLECULAR
DYNAMICS
AND
DIELECTRIC
SPECTROSCOPY
.
11
2.2.1.
THE
DIELECTRIC
SUSCEPTIBILITY
.
11
2.2.2.
MOLECULAR
DYNAMICS
AND
AUTOCORRELATION
FUNCTIONS
.
14
3.
MEASUREMENT
TECHNIQUE
17
3.1.
FREQUENCY
DOMAIN
MEASUREMENTS
.
17
3.1.1.
LOW
FREQUENCY
DIELECTRIC
SPECTROSCOPY
.
18
3.1.2.
DIELECTRIC
SPECTROSCOPY
AT
RADIO
FREQUENCIES
.
18
3.2.
TIME
DOMAIN
MEASUREMENTS
.
18
3.2.1.
THE
MODIFIED
SAWYER-TOWER
BRIDGE
.
21
3.2.2.
THE
DIELECTRIC
MODULUS
.
26
3.2.3.
THE
FILON
ALGORITHM
.
32
3.2.4.
SOME
APPLICATIONS
.
35
4.
PHENOMENOLOGICAL
MODEL
FUNCTIONS
43
4.1.
MODEL
FUNCTIONS
AND
DATA
ANALYSIS
.
43
4.1.1.
A-PROCESS
.
44
4.1.2.
/3-PROCESS
.
48
4.2.
YAFF:
YET
ANOTHER
FIT
FUNCTION
.
53
4.2.1.
A
SIMPLE
DISTRIBUTION
FOR
THE
A-PEAK
.
54
4.2.2.
DISTRIBUTION
FOR
THE
A-PEAK
INCLUDING
THE
HF-WING
.
56
4.2.3.
A
DISTRIBUTION
FOR
THE
/^-PROCESS
.
60
4.2.4.
HIGH-FREQUENCY
WING,
/^-RELAXATION
AND
THE
WW-APPROACH
.
63
4.2.5.
NUMERICAL
IMPLEMENTATION
.
66
5.
SOME
EXAMPLES
AND
APPLICATIONS:
CLASSIFYING
SECONDARY
RELAXATIONS
69
5.1.
TYPE-A
GLASS
FORMERS
.
69
5.1.1.
GLYCEROL
.
69
5.1.2.
FOR
COMPARISON:
AN
MCT
ANALYSIS
OF
GLYCEROL
.
72
5.1.3.
TYPE-A:
SOME
UNIVERSAL
FEATURES
.
75
CONTENTS
5.2.
TYPE-B
GLASS
FORMERS
.
78
5.2.1.
TOLUENE
.
78
5.2.2.
3-FLUORO
ANILINE
.
81
5.2.3.
TYPE-B:
SOME
UNIVERSAL
FEATURES
.
83
5.3.
CONCLUSIONS
.
86
6.
DIELECTRIC
RELAXATION
IN
BINARY
GLASS
FORMING
SYSTEMS
89
6.1.
INTRODUCTION:
SOME
PHENOMENA
IN
BINARY
GLASS
FORMERS
.
90
6.2.
PICOLINE
IN
OLIGOSTYRENE
.
96
6.2.1.
THE
SUBSTANCES
.
96
6.2.2.
RESULTS:
2-PICOLINE
IN
TRI-STYRENE
.
99
6.2.3.
SOME
NMR
RESULTS:
2-PICOLINE
IN
TRI-STYRENE
.
114
6.2.4.
RESULTS:
2-PICOLINE
IN
HIGHER
OLIGOMERS
OF
STYRENE
.
115
6.3.
PICOLINE
IN
O-TERPHENYL
.
121
6.3.1.
O-TERPHENYL
.
121
6.3.2.
RESULTS:
2-PICOLINE
IN
O-TERPHENYL
.
122
6.4.
DISCUSSION
AND
CONCLUSIONS
I:
BINARY
SYSTEMS
.
126
6.4.1.
THE
SECONDARY
RELAXATION
.
126
6.4.2.
THE
MAIN
RELAXATION
AND
ITS
POSSIBLE
DECOUPLING
FROM
THE
MATRIX
DYNAMICS
.
128
6.4.3.
THE
MAIN
RELAXATION
IN
VIEW
OF
A
CONCENTRATION
FLUCTUATION
MODEL
.
129
6.5.
FOR
COMPARISON:
THE
SECONDARY
RELAXATION
IN
POLYALCOHOLS
.
131
6.5.1.
RESULTS:
O-PROCESS
.
133
6.5.2.
RESULTS:
/^-PROCESS
.
135
6.6.
DISCUSSION
AND
CONCLUSIONS
II:
/3-PROCESS
AND
HF-WING
.
138
7.
DIELECTRIC
HOLE
BURNING
SPECTROSCOPY
141
7.1.
HOMOGENEOUS
VERSUS
HETEROGENEOUS
DYNAMICS
.
141
7.1.1.
A
DEFINITION
.
141
7.1.2.
EXPERIMENTAL
METHODS:
AN
OVERVIEW
.
143
7.2.
DIELECTRIC
HOLE
BURNING
.
145
7.2.1.
THE
METHOD
.
146
7.2.2.
SOME
THEORETICAL
CONCEPTS
.
150
7.3.
DIELECTRIC
HOLE
BURNING
IN
NEAT
GLASS
FORMERS
.
159
7.3.1.
SOME
ASPECTS
OF
DHB
IN
PREVIOUS
WORKS
.
159
7.3.2.
DHB
IN
GLYCEROL
.
161
7.4.
DIELECTRIC
HOLE
BURNING
IN
BINARY
SYSTEMS
.
163
7.4.1.
SOME
GENERAL
ASPECTS
AND
PROBLEMS
.
163
7.4.2.
DHB
IN
PICOLINE/OLIGOSTYRENE
MIXTURES
.
164
7.5.
SUMMARY
AND
CONCLUSIONS
.
176
SUMMARY
179
II
CONTENTS
BIBLIOGRAPHY
181
APPENDIX
199
A.
MONO
EXPONENTIAL
RELAXATION
AS
A
LIMIT
WITHIN
YAFF
199
A.L.
A-PROCESS
.
199
A.
2.
/3-PROCESS
.
200
B.
ADDITIONAL
DATA
AND
PARAMETERS
201
B.L.
BINARY
GLASS
FORMERS
.
201
B.L.L.
2-PICOLINE
IN
TRI-STYRENE:
THE
DATA
.
201
B.L.
2.
2-PICOLINE
IN
TRI-STYRENE:
FIT
PARAMETERS
.
203
B.1.3.
2-PICOLINE
IN
HIGHER
OLIGOMERES
OF
STYRENE:
DATA
.
212
B.L.
4.
2-PICOLINE
IN
HIGHER
OLIGOMERES
OF
STYRENE:
FIT
PARAMETERS
.
214
B.1.5.
2-PICOLINE
IN
O-TERPHENYL:
DATA
.
216
B.1.6.
2-PICOLINE
IN
ORTHO
TERPHENYL:
PARAMETERS
.
217
B.2.
THE
POLYALCOHOLS
.
222
B.2.1.
THE
POLYALCOHOLS:
FIT
STRATEGY
.
222
B.2.2.
THE
POLYALCOHOLS:
FIT
PARAMETERS
.
226
LIST
OF
PUBLICATIONS
231
DANKSAGUNG
-
ACKNOWLEDGEMENTS
233
III |
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| id | DE-604.BV017478108 |
| illustrated | Illustrated |
| indexdate | 2024-08-23T00:16:09Z |
| institution | BVB |
| isbn | 383250320X |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-010529163 |
| oclc_num | 65427257 |
| open_access_boolean | |
| owner | DE-703 |
| owner_facet | DE-703 |
| physical | III, 233 S. graph. Darst. |
| publishDate | 2003 |
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| spelling | Blochowicz, Thomas Verfasser (DE-588)107766334X aut Broadband dielectric spectroscopy in neat and binary molecular glass formers frequency and time domain spectroscopy, non-resonant spectral hole burning von Thomas Blochowicz Berlin Logos-Verl. 2003 III, 233 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Zugl.: Bayreuth, Univ., Diss., 2003 Impedanzspektroskopie (DE-588)4161400-8 gnd rswk-swf Glasbildner (DE-588)4319818-1 gnd rswk-swf Spektrales Lochbrennen (DE-588)4197390-2 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Glasbildner (DE-588)4319818-1 s Impedanzspektroskopie (DE-588)4161400-8 s Spektrales Lochbrennen (DE-588)4197390-2 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010529163&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Blochowicz, Thomas Broadband dielectric spectroscopy in neat and binary molecular glass formers frequency and time domain spectroscopy, non-resonant spectral hole burning Impedanzspektroskopie (DE-588)4161400-8 gnd Glasbildner (DE-588)4319818-1 gnd Spektrales Lochbrennen (DE-588)4197390-2 gnd |
| subject_GND | (DE-588)4161400-8 (DE-588)4319818-1 (DE-588)4197390-2 (DE-588)4113937-9 |
| title | Broadband dielectric spectroscopy in neat and binary molecular glass formers frequency and time domain spectroscopy, non-resonant spectral hole burning |
| title_auth | Broadband dielectric spectroscopy in neat and binary molecular glass formers frequency and time domain spectroscopy, non-resonant spectral hole burning |
| title_exact_search | Broadband dielectric spectroscopy in neat and binary molecular glass formers frequency and time domain spectroscopy, non-resonant spectral hole burning |
| title_full | Broadband dielectric spectroscopy in neat and binary molecular glass formers frequency and time domain spectroscopy, non-resonant spectral hole burning von Thomas Blochowicz |
| title_fullStr | Broadband dielectric spectroscopy in neat and binary molecular glass formers frequency and time domain spectroscopy, non-resonant spectral hole burning von Thomas Blochowicz |
| title_full_unstemmed | Broadband dielectric spectroscopy in neat and binary molecular glass formers frequency and time domain spectroscopy, non-resonant spectral hole burning von Thomas Blochowicz |
| title_short | Broadband dielectric spectroscopy in neat and binary molecular glass formers |
| title_sort | broadband dielectric spectroscopy in neat and binary molecular glass formers frequency and time domain spectroscopy non resonant spectral hole burning |
| title_sub | frequency and time domain spectroscopy, non-resonant spectral hole burning |
| topic | Impedanzspektroskopie (DE-588)4161400-8 gnd Glasbildner (DE-588)4319818-1 gnd Spektrales Lochbrennen (DE-588)4197390-2 gnd |
| topic_facet | Impedanzspektroskopie Glasbildner Spektrales Lochbrennen Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010529163&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT blochowiczthomas broadbanddielectricspectroscopyinneatandbinarymolecularglassformersfrequencyandtimedomainspectroscopynonresonantspectralholeburning |