Surface science: an introduction
Saved in:
| Format: | Book |
|---|---|
| Language: | English |
| Published: |
Berlin [u.a.]
Springer
2003
|
| Series: | Advanced texts in physics
Physics and astronomy online library |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Hier auch später erschienene, unveränderte Nachdrucke |
| Physical Description: | XII, 440 S. Ill., graph. Darst. |
| ISBN: | 3540005455 9783540005452 9783642056062 |
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| 245 | 1 | 0 | |a Surface science |b an introduction |c K. Oura ... |
| 264 | 1 | |a Berlin [u.a.] |b Springer |c 2003 | |
| 300 | |a XII, 440 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 0 | |a Advanced texts in physics | |
| 490 | 0 | |a Physics and astronomy online library | |
| 500 | |a Hier auch später erschienene, unveränderte Nachdrucke | ||
| 650 | 4 | |a Oberflächenphysik | |
| 650 | 4 | |a Surfaces (Physics) | |
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Record in the Search Index
| _version_ | 1804129891689431040 |
|---|---|
| adam_text | Contents
1.
Introduction
.............................................. 1
2. Basics
of Two-Dimensional Crystallography
...............
З
2.1
Two-Dimensional Lattices
...............................
З
2.1.1
Lattice, Basis, and Crystal Structure
(3D
Case)
...... 3
2.1.2
Concept of a 2D Lattice
........................... 3
2.1.3
2D
Bravais
Lattices
............................... 4
2.2
Miller Indices for Crystal Planes
.......................... 6
2.2.1
Definition of Miller Indices
........................ 6
2.2.2
Low-Miller-Index Planes of Some Important Crystals
. 8
2.2.3
High-Miller-Index Stepped Surfaces
................. 8
2.3
Indices of Directions
.................................... 11
2.4
Notation for Surface Structures
.......................... 11
2.4.1
Matrix Notation
.................................. 11
2.4.2
Wood s Notation
................................. 12
2.4.3
Some Examples
.................................. 13
2.5
2D Reciprocal Lattice
................................... 14
2.6
Brillouin Zone
......................................... 16
Problems
.................................................. 17
Further Reading
............................................ 18
3.
Experimental Background
................................ 19
3.1
Why Ultra-High Vacuum?
............................... 19
3.2
Vacuum Concepts
...................................... 20
3.3
Ultra-High-Vacuum Technology
.......................... 23
3.3.1
UHV Materials
................................... 23
3.3.2
UHV Pumping System
............................ 24
3.3.3
UHV Hardware
.................................. 32
3.4
Preparation of Atomically Clean Surfaces
.................. 35
3.4.1
Cleavage
........................................ 35
3.4.2
Heating
......................................... 37
3.4.3
Chemical Treatment
.............................. 37
3.4.4
Ion Sputtering and Annealing
...................... 37
3.5
UHV Deposition Technology
............................. 38
VIII Contents
3.5.1
Deposition Concepts
.............................. 38
3.5.2
Deposition Sources
............................... 39
3.5.3
Deposition Monitors
.............................. 43
3.5.4
Exposure to Gases
................................ 44
Problems
.................................................. 45
Further Reading
............................................ 46
4.
Surface Analysis I.
Diffraction
Methods
.................. 47
4.1
Low-Energy Electron Diffraction
(LEED)
.................. 47
4.1.1 Ewald
Construction in
LEED
Conditions
............ 47
4.1.2
LEED
Experimental Set-Up
....................... 49
4.1.3
Interpretation of
a LEED
Pattern
.................. 51
4.2
Reflection High-Energy Electron Diffraction (RHEED)
...... 59
4.2.1 Ewald
Construction in RHEED Conditions
.......... 59
4.2.2
RHEED Set-Up
.................................. 60
4.2.3
RHEED Analysis
................................. 61
4.3
Grazing Incidence
Х
-Ray Diffraction (GIXRD)
............. 66
4.3.1
Refraction of
Х
-Rays at Grazing Incidence
........... 66
4.3.2 Ewald
Construction in GIXRD Conditions
and Basics of the Kinematic Approximation
......... 67
4.3.3
GIXRD Experimental Set-Up
...................... 69
4.3.4
Structural Analysis by GIXRD
..................... 69
4.4
Other Diffraction Techniques
............................. 73
4.4.1
Transmission Electron Diffraction (TED)
............ 73
4.4.2
Atom Scattering
................................. 73
4.4.3
Photoelectron Diffraction (PED)
and Auger Electron Diffraction
(AED)
.............. 74
Problems
.................................................. 74
Further Reading
............................................ 75
5.
Surface Analysis II. Electron Spectroscopy Methods
...... 77
5.1
General Remarks
....................................... 77
5.1.1
Surface Specificity
................................ 77
5.1.2
Spectrum of Secondary Electrons
................... 77
5.1.3
Electron Energy Analyzers
........................ 78
5.2
Auger Electron Spectroscopy
............................. 82
5.2.1
Physical Principles
............................... 82
5.2.2
AES Experimental Set-Up
......................... 84
5.2.3
AES Analysis
.................................... 86
5.3
Electron Energy Loss Spectroscopy
....................... 89
5.3.1
Core Level Electron Energy Loss Spectroscopy
....... 90
5.3.2
Electron Energy Loss Spectroscopy
................. 92
5.3.3
High-Resolution Electron Energy Loss Spectroscopy
.. 95
5.4
Photoelectron Spectroscopy
.............................. 98
5.4.1
Photoelectric Effect
............................... 98
Contents
IX
5.4.2
PES
Experimental Set-Up
......................... 99
5.4.3
PES
Analysis
....................................101
Problems
..................................................107
Further Reading
............................................108
6.
Surface Analysis III. Probing Surfaces with Ions
..........109
6.1
General Principles
......................................109
6.1.1
Classical Binary Collisions
.........................109
6.1.2
Scattering Cross-Section
...........................113
6.1.3
Shadowing and Blocking
..........................114
6.1.4
Channeling
......................................117
6.1.5
Sputtering
.......................................118
6.1.6
Ion-Induced Electronic Processes
...................120
6.2
Low-Energy Ion Scattering Spectroscopy
..................123
6.2.1
General Remarks: Merits and Problems
.............123
6.2.2
Alkali Ion Scattering and Time-of-Flight Techniques
.. 124
6.2.3
Quantitative Structural Analysis
in Impact-Collision Geometry
......................126
6.3
Rutherford Backscattering
and Medium-Energy Ion Scattering Spectroscopy
...........129
6.3.1
General Remarks
.................................129
6.3.2
Surface Peak
.....................................131
6.3.3
Thin Film Analysis
...............................136
6.4
Elastic Recoil Detection Analysis
.........................137
6.5
Secondary Ion Mass Spectroscopy
........................138
Problems
..................................................142
Further Reading
............................................143
7.
Surface Analysis IV. Microscopy
..........................145
7.1
Field Emission Microscopy
...............................145
7.2
Field Ion Microscopy
....................................147
7.3
Transmission Electron Microscopy
........................149
7.4
Reflection Electron Microscopy
...........................152
7.5
Low-Energy Electron Microscopy
.........................154
7.6
Scanning Electron Microscopy
............................156
7.7
Scanning Tunneling Microscopy
..........................159
7.8
Atomic Force Microscopy
................................164
Problems
..................................................168
Further Reading
............................................168
8.
Atomic Structure of Clean Surfaces
.......................171
8.1
Relaxation and Reconstruction
...........................171
8.2
Relaxed Surfaces of Metals
..............................173
8.2.1
Al(llO)
.........................................173
8.2.2
Fe(211)
.........................................174
X
Contents
8.3
Reconstructed
Surfaces
of Metals
.........................176
8.3.1
Pt(lOO)
.........................................176
8.3.2
Pt(llO)
.........................................178
8.3.3
W(100)
.........................................178
8.4
Graphite Surface
.......................................179
8.5
Surfaces of Elemental Semiconductors
.....................180
8.5.1
Si(100)
.......................................... 181
8.5.2
Si(lll)
.......................................... 183
8.5.3
Ge(lll)
......................................... 187
8.6
Surfaces of
ПІ
-V
Compound Semiconductors
............... 188
8.6.1
GaAs(llO)
.........._._._.......................... 188
8.6.2
GaAsìlll)
and GaAs(lll)
........................ 189
Problems
.................................................. 192
Further Reading
............................................ 194
9.
Atomic Structure of Surfaces with Adsorbates
............195
9.1
Surface Phases
in Submonolayer Adsorbate/Substrate Systems
.............195
9.2
Surface Phase Composition
..............................196
9.2.1
Coverage of
Adsórbate
............................197
9.2.2
Coverage of Substrate Atoms
......................199
9.2.3
Experimental Determination of Composition
.........200
9.3
Formation Phase Diagram
...............................205
9.4
Metal Surfaces with Adsorbates
..........................210
9.4.1
Family of
уДх
VŠ
Structures
on (111) fee Metal Surfaces
........................210
9.4.2 №(110)2x1-00..................................213
9.4.3
nxl Structures in
Pb/Cu(H0), Bi/CufllO),
Li/CufllO), and S/Ni(110) Systems
................214
9.5
Semiconductor Surfaces with Adsorbates
..................217
9.5.1
Family of
>Дх Д
Structures on Si(lll) and GeClll)
. 217
9.5.2 2x1, 1x1,
and
3x1
Phases in the H/Si(100) System
.. 224
Problems
..................................................226
Further Reading
............................................227
10.
Structural Defects at Surfaces
............................229
10.1
General Consideration Using the TSK Model
..............229
10.1.1
Point Defects
....................................229
10.1.2
Steps, Singular and Vicinal Surfaces, Facets
.........232
10.2
Selected Realistic Examples
..............................237
10.2.1 Adatoms........................................237
10.2.2
Vacancies
.......................................239
10.2.3
Anti-Site Defects
.................................243
10.2.4
Dislocations
.....................................245
10.2.5
Domain Boundaries
...............................247
Contents
XI
10.2.6 Steps...........................................252
10.2.7
Facetting........................................
257
Problems..................................................260
Further Reading
............................................260
11. Electronic
Structure of Surfaces
..........................261
11.1 Basics
of Density Functional Theory
......................261
11.2
Jellium Model
..........................................263
11.3
Surface States
..........................................266
11.4
Electronic Structure of Selected Surfaces
..................272
11.4.1
Si(lll)2xl
......................................272
11.4.2
Si(lll)7x7
......................................273
11.4.3
SiCllljlxl-As
...................................275
11.4.4
Si(lll) /3x /3-In
................................277
11.5
Surface Conductivity
....................................277
11.6
Work Function
.........................................282
11.6.1
Work Function of Metals
..........................282
11.6.2
Work Function of Semiconductors
..................286
11.6.3
Work Function Measurements
......................286
Problems
..................................................293
Further Reading
............................................293
12.
Elementary Processes at Surfaces I.
Adsorption and Desorption
...............................295
12.1
Adsorption Kinetics
....................................295
12.1.1
Coverage Dependence
.............................296
12.1.2
Temperature Dependence
..........................301
12.1.3
Angular and Kinetic Energy Dependence
............305
12.2
Thermal Desorption
....................................305
12.2.1
Desorption Kinetics
...............................305
12.2.2
Thermal Desorption Spectroscopy
..................308
12.3
Adsorption Isotherms
...................................315
12.4
Non-Thermal Desorption
................................319
Problems
..................................................322
Further Reading
............................................323
13.
Elementary Processes at Surfaces II. Surface Diffusion
.... 325
13.1
Basic Equations
........................................325
13.1.1
Random-Walk Motion
............................325
13.1.2
Fick s Laws
......................................327
13.2
Tracer and Chemical Diffusion
...........................330
13.3
Intrinsic and Mass Transfer Diffusion
.....................331
13.4
Anisotropy of Surface Diffusion
...........................333
13.5
Atomistic Mechanisms of Surface Diffusion
................335
13.5.1
Hopping Mechanism
..............................336
XII Contents
13.5.2
Atomic
Exchange
Mechanism
......................338
13.5.3
Tunneling Mechanism
.............................338
13.5.4
Vacancy Mechanism
..............................340
13.6
Surface Diffusion of Clusters
.............................341
13.7
Surface Diffusion and Phase Formation
....................345
13.8
Surface Electromigration
................................348
13.9
Experimental Study of Surface Diffusion
...................349
13.9.1
Direct Observation of Diffusing Atoms
..............349
13.9.2
Profile Evolution Method
..........................350
13.9.3
Capillarity Techniques
............................353
13.9.4
Island Growth Technique
..........................354
Problems
..................................................356
Further Reading
............................................356
14.
Growth of Thin Films
....................................357
14.1
Growth Modes
.........................................357
14.2
Nucleation and Growth of Islands
........................359
14.2.1
Island Number Density
............................359
14.2.2
Island Shape
.....................................365
14.2.3
Island Size Distribution
...........................368
14.2.4
Vacancy Islands
..................................374
14.3
Kinetic Effects in Homoepitaxial Growth
..................374
14.4
Strain Effects in Heteroepitaxy
...........................377
14.5
Thm Film Growth Techniques
...........................379
14.5.1
Molecular Beam Epitaxy
..........................379
14.5.2
Solid Phase Epitaxy
..............................381
14.5.3
Chemical Beam Epitaxy
...........................382
14.6
Surfactant-Mediated Growth
.............................383
Problems
..................................................386
Further Reading
............................................387
15.
Atomic Manipulations
and Nanostructure Formation
............................389
15.1
Nano-Size and Low-Dimensional Objects
..................389
15.2
Atomic Manipulation with STM
..........................393
15.2.1
Lateral Atomic Displacement
......................394
15.2.2
Atom Extraction
.................................399
15.2.3
Atom Deposition
.................................403
15.3
Self-Organization of Nanostructures
.......................404
15.4
Fullerenes
and Carbon Nanotubes
........................408
Further Reading
............................................415
References
....................................................417
Index
.........................................................433
|
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| id | DE-604.BV016972363 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T19:12:21Z |
| institution | BVB |
| isbn | 3540005455 9783540005452 9783642056062 |
| language | English |
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| owner | DE-20 DE-703 DE-1046 DE-29T DE-355 DE-BY-UBR DE-91G DE-BY-TUM DE-634 DE-83 DE-19 DE-BY-UBM DE-11 DE-92 DE-384 |
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| physical | XII, 440 S. Ill., graph. Darst. |
| publishDate | 2003 |
| publishDateSearch | 2003 |
| publishDateSort | 2003 |
| publisher | Springer |
| record_format | marc |
| series2 | Advanced texts in physics Physics and astronomy online library |
| spelling | Surface science an introduction K. Oura ... Berlin [u.a.] Springer 2003 XII, 440 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Advanced texts in physics Physics and astronomy online library Hier auch später erschienene, unveränderte Nachdrucke Oberflächenphysik Surfaces (Physics) Oberflächenphysik (DE-588)4134881-3 gnd rswk-swf Oberflächenphysik (DE-588)4134881-3 s DE-604 Oura, Kenjiro 1941- Sonstige (DE-588)124782981 oth Digitalisierung UB Regensburg application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010250061&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Surface science an introduction Oberflächenphysik Surfaces (Physics) Oberflächenphysik (DE-588)4134881-3 gnd |
| subject_GND | (DE-588)4134881-3 |
| title | Surface science an introduction |
| title_auth | Surface science an introduction |
| title_exact_search | Surface science an introduction |
| title_full | Surface science an introduction K. Oura ... |
| title_fullStr | Surface science an introduction K. Oura ... |
| title_full_unstemmed | Surface science an introduction K. Oura ... |
| title_short | Surface science |
| title_sort | surface science an introduction |
| title_sub | an introduction |
| topic | Oberflächenphysik Surfaces (Physics) Oberflächenphysik (DE-588)4134881-3 gnd |
| topic_facet | Oberflächenphysik Surfaces (Physics) |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010250061&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT ourakenjiro surfacescienceanintroduction |