Electron spin resonance spectroscopy of organic radicals:
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH
2003
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XV, 464 S. graph. Darst. |
| ISBN: | 3527302751 |
Internformat
MARC
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| 100 | 1 | |a Gerson, Fabian |d 1928-2011 |e Verfasser |0 (DE-588)108164737X |4 aut | |
| 245 | 1 | 0 | |a Electron spin resonance spectroscopy of organic radicals |c Fabian Gerson ; Walter Huber |
| 264 | 1 | |a Weinheim |b Wiley-VCH |c 2003 | |
| 300 | |a XV, 464 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
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Datensatz im Suchindex
| _version_ | 1808135770672726016 |
|---|---|
| adam_text |
CONTENTS
PREFACE
IX
ABBREVIATIONS
AND
SYMBOLS
XI
A
GENERAL
PART
1
1
PHYSICAL
FUNDAMENTALS
OF
ELECTRON
SPIN
RESONANCE
3
1.1
SPIN
AND
MAGNETIC
MOMENT
OF
ELECTRON
3
1.2
ZEEMAN
SPLITTING
AND
RESONANCE
CONDITION
4
1.3
SPIN-LATTICE
RELAXATION
6
1.4
LINE-WIDTH
AND
LINE-FORM
8
2
PARAMAGNETIC
ORGANIC
SPECIES
AND
THEIR
GENERATION
10
2.1
SPIN
MULTIPLICITY
10
2.2
NEUTRAL
RADICALS
13
2.3
RADICAL
IONS
19
2.4
TRIPLETS:
ELECTRON-ELECTRON
MAGNETIC
INTERACTION
27
3
ELECTRON-NUCLEAR
MAGNETIC
INTERACTION
37
3.1
NUCLEAR
MAGNETISM
37
3.2
HYPERFINE
SPLITTING
OF
ESR
SIGNAL
39
4
SPIN
DENSITY,
SPIN
POPULATION,
SPIN
POLARIZATION,
AND
SPIN
DELOCALIZATION
49
4.1
CONCEPTS
49
4.2
N
RADICALS
56
4.3
T
RADICALS
75
4.4
TRIPLET
STATES
79
4.5
CALCULATIONS
OF
SPIN
POPULATIONS
80
5
MULTIRESONANCE
83
5.1
HISTORICAL
NOTE
83
5.2
ENDOR
84
VI
I
CONTENTS
5.3
TRIPLE
RESONANCE
94
5.4
ELDOR
96
6
TAKING
AND
ANALYZING
ESR
SPECTRA
97
6.1
INSTRUMENTATION
97
6.2
G
E
FACTOR
99
6.3
OPTIMAL
CONDITIONS
102
6.4
UNRAVELLING
HYPERFINE
PATTERN
109
6.5
ASSIGNMENT
AND
SIGN
OF
COUPLING
CONSTANTS
127
6.6
ION
PAIRING
141
6.7
INTRAMOLECULAR
DYNAMIC
PROCESSES
153
B
SPECIAL
PART
167
7
ORGANIC
RADICALS
CENTERED
ON
ONE,
TWO,
OR
THREE
ATOMS
169
7.1
C-,
N-,
AND
O-CENTERED
RADICALS
169
7.2
SI-,
P-,
AND
S-CENTERED
RADICALS
186
7.3
CC-,
NN-,
AND
OO-CENTERED
RADICALS
189
7.4
NO
AND
NO
2
-CENTERED
RADICALS
200
7.5
PO-,
PP-,
SO-,
SS-,
AND
SCH-CENTERED
RADICALS
208
8
CONJUGATED
HYDROCARBON
RADICALS
210
8.1
THEORETICAL
INTRODUCTION
210
8.2
ODD
ALTERNANT
RADICALS
217
8.3
ODD
NONALTERNANT
RADICALS
AND
RADICAL
DIANIONS
224
8.4
EVEN
ALTERNANT
RADICAL
IONS
229
8.5
EVEN
NONALTERNANT
RADICAL
IONS
254
8.6
RADICALS
AND
RADICAL
IONS
WITH
A
PERTURBED
N
PERIMETER
261
8.7
RADICAL
IONS
OF
PHANES
278
8.8
RADICAL
IONS
OF
RADIALENES
287
9
CONJUGATED
RADICALS
WITH
HETEROATOMS
290
9.1
NEUTRAL
RADICALS
290
9.2
RADICAL
ANIONS
OF
ELECTRON
ACCEPTORS
302
9.3
RADICAL
CATIONS
OF
ELECTRON
DONORS
346
9.4
RADICAL
CATIONS
WITH
SPECIAL
STRUCTURES
366
9.5
RADICAL
IONS
OF
MULTI-REDOX
SYSTEMS
372
10
SATURATED
HYDROCARBON
RADICALS
375
10.1
RADICAL
CATIONS
OF
ALKANES
375
10.2
STRUCTURALLY
MODIFIED
RADICAL
CATIONS
380
11
BIRADICALS
AND
TRIPLET-STATE
MOLECULES
386
11.1
BIRADICALS
386
CONTENTS
|
VII
11.2
MOLECULES
IN
PHOTOEXCITED
TRIPLET
STATE
389
11.3
MOLECULES
IN
GROUND
OR
THERMALLY
ACCESSIBLE
TRIPLET
STATE
393
APPENDICES
405
A.L
NITROXYLS
AS
SPIN
LABELS
AND
SPIN
ADDUCTS
405
A.2
HYPERFINE
SPLITTING
BY
ALKALI-METAL
NUCLEI
IN
COUNTERIONS
OF
RADICAL
ANIONS
409
REFERENCES
415
INDEX
447 |
| any_adam_object | 1 |
| author | Gerson, Fabian 1928-2011 Huber, Walter |
| author_GND | (DE-588)108164737X |
| author_facet | Gerson, Fabian 1928-2011 Huber, Walter |
| author_role | aut aut |
| author_sort | Gerson, Fabian 1928-2011 |
| author_variant | f g fg w h wh |
| building | Verbundindex |
| bvnumber | BV015736182 |
| classification_rvk | VG 9700 VK 6000 |
| classification_tum | CHE 610f CHE 615f CHE 248f |
| ctrlnum | (OCoLC)249558037 (DE-599)BVBBV015736182 |
| dewey-full | 538.364 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 538 - Magnetism |
| dewey-raw | 538.364 |
| dewey-search | 538.364 |
| dewey-sort | 3538.364 |
| dewey-tens | 530 - Physics |
| discipline | Chemie / Pharmazie Physik Chemie |
| format | Book |
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| id | DE-604.BV015736182 |
| illustrated | Illustrated |
| indexdate | 2024-08-23T00:24:04Z |
| institution | BVB |
| isbn | 3527302751 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-010121912 |
| oclc_num | 249558037 |
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| physical | XV, 464 S. graph. Darst. |
| publishDate | 2003 |
| publishDateSearch | 2003 |
| publishDateSort | 2003 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Gerson, Fabian 1928-2011 Verfasser (DE-588)108164737X aut Electron spin resonance spectroscopy of organic radicals Fabian Gerson ; Walter Huber Weinheim Wiley-VCH 2003 XV, 464 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Radikal Chemie (DE-588)4076475-8 gnd rswk-swf Organische Verbindungen (DE-588)4043816-8 gnd rswk-swf Elektronenspinresonanzspektroskopie (DE-588)4151888-3 gnd rswk-swf Radikal Chemie (DE-588)4076475-8 s Elektronenspinresonanzspektroskopie (DE-588)4151888-3 s DE-604 Organische Verbindungen (DE-588)4043816-8 s Huber, Walter Verfasser aut DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010121912&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Gerson, Fabian 1928-2011 Huber, Walter Electron spin resonance spectroscopy of organic radicals Radikal Chemie (DE-588)4076475-8 gnd Organische Verbindungen (DE-588)4043816-8 gnd Elektronenspinresonanzspektroskopie (DE-588)4151888-3 gnd |
| subject_GND | (DE-588)4076475-8 (DE-588)4043816-8 (DE-588)4151888-3 |
| title | Electron spin resonance spectroscopy of organic radicals |
| title_auth | Electron spin resonance spectroscopy of organic radicals |
| title_exact_search | Electron spin resonance spectroscopy of organic radicals |
| title_full | Electron spin resonance spectroscopy of organic radicals Fabian Gerson ; Walter Huber |
| title_fullStr | Electron spin resonance spectroscopy of organic radicals Fabian Gerson ; Walter Huber |
| title_full_unstemmed | Electron spin resonance spectroscopy of organic radicals Fabian Gerson ; Walter Huber |
| title_short | Electron spin resonance spectroscopy of organic radicals |
| title_sort | electron spin resonance spectroscopy of organic radicals |
| topic | Radikal Chemie (DE-588)4076475-8 gnd Organische Verbindungen (DE-588)4043816-8 gnd Elektronenspinresonanzspektroskopie (DE-588)4151888-3 gnd |
| topic_facet | Radikal Chemie Organische Verbindungen Elektronenspinresonanzspektroskopie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010121912&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT gersonfabian electronspinresonancespectroscopyoforganicradicals AT huberwalter electronspinresonancespectroscopyoforganicradicals |