Synthesis and characterisation of substituted lithium lanthanum titanates, with possible applications in electrochromic systems:
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| Format: | Book |
| Language: | English |
| Published: |
2002
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| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Kiel, Univ., Diss., 2002 |
| Physical Description: | 170 S. Ill., graph. Darst. : 30 cm |
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| 245 | 1 | 0 | |a Synthesis and characterisation of substituted lithium lanthanum titanates, with possible applications in electrochromic systems |c Sonia Stramare |
| 264 | 1 | |c 2002 | |
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| 500 | |a Kiel, Univ., Diss., 2002 | ||
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Record in the Search Index
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CONTENTS
I INTRODUCTION
AND
STATE OF THE ART 9
1 INTRODUCTION 11
1.1 HISTORICAL AND GENERAL ASPECTS. 11
1.2 AIM OF THE WORK. 12
2 STATE OF THE ART 15
2.1 ELECTROCHROMIC MATERIALS AND THEIR CHARACTERISATION. 15
2.2 EXISTING ELECTROCHROMIC DEVICES . 20
2.2.1 ELECTROCHROMIC WINDOWS . 21
2.2.2 ELECTROCHEMICAL DISPLAY. 22
2.2.3 ALL-SOL-GEL DEVICES. 23
2.2.4 TESTING AND PERFORMANCE ISSUES. 24
2.3 LITHIUM LANTHANUM TITANATE (LLT):
LI
XLAYTI03. 27
2.3.1 STRUCTURE. 27
2.3.2 STABILITY AND PHASE TTANSITIONS. 34
2.3.3 ELECTRICAL PROPERTIES. 37
2.4 SUMMARY OF CHAPTER 2. 49
II DEVELOPMENT OF MATERIALS 53
3 MATERIALS SELECTION CONSIDERATIONS 55
3.1 IDEA OF SUBSTITUTIONS. 55
3.2 STRUCTURAL CONSIDERATIONS (TOLERANCE FACTORS). 55
3.3 THERMODYNAMICAL CONSIDERATIONS. 57
3.4 ELECTROCHEMICAL SERIES. 65
3.5 SUMMARY OF CHAPTER 3. 69
7
BIBLIOGRAFISCHE INFORMATIONEN
HTTP://D-NB.INFO/964766051
8
CONTENTS
4 EXPERIMENTAL ASPECTS 71
4.1 PREPARATION OF THE SAMPLES. 71
4.1.1 LITHIUM LANTHANUM TITANATE. 71
4.1.2 SUBSTITUTED TITANATES. 72
4.1.3 CHEMICAL LITHIATION AND DE-LITHIATION. 76
4.1.4 SOL-GEL SYNTHESIS AND DIP-COATING TECHNIQUE. 76
4.1.5 THIN FILMS DEPOSITION. 77
4.1.6 CONSTRUCTION OF MONOLITHIC CELLS. 78
4.2 EXPERIMENTAL SETUPS. 81
4.3 EQUATIONS FOR THE EVALUATION OF THE RESULTS. 87
4.3.1 X-RAY DIFFRACTION (XRD). 87
4.3.2 AC IMPEDANCE SPECTROSCOPY. 88
4.3.3 DC POLARISATION TECHNIQUE.S. . 91
4.3.4 GALVANOSTATIC INTERMITTENT TITRATION TECHNIQUE
(G.I.T.T.). 93
4.4 SUMMARY OF CHAPTER 4. 96
5 RESULTS 97
5.1 X-RAY DIFFRACTION (XRD). 97
5.2 DIFFERENTIAL THERMAL ANALYSIS (DTA) -
THERMOGRAVIMETRIC ANALYSIS (TGA).108
5.3 AC - IMPEDANCE SPECTROSCOPY / ELECTROCHEMICAL IMPEDANCE SPEC
TROSCOPY (EIS) .110
5.4 DC - POLARISATION.118
5.5 G.I.T.T.124
5.6 SCANNING ELECTRON MICROSCOPE (SEM) .132
5.7 PROTOTYPE OF ELECTROCHROMIC WINDOW . . .134
5.8 SUMMARY OF CHAPTER 5.135
6 DISCUSSION 137
7 SUMMARY AND OUTLOOK 145
7.1 SUMMARY.145
7.2 OUTLOOK.146
8 APPENDIX 147
8.1 STEADY STATE DC POLARISATION TECHNIQUE.147
8.2 GALVANOSTATIC INTERMITTENT TITRATION TECHNIQUE.152 |
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| illustrated | Illustrated |
| indexdate | 2024-10-09T18:04:26Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-010046631 |
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| physical | 170 S. Ill., graph. Darst. : 30 cm |
| publishDate | 2002 |
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| spelling | Stramare, Sonia Verfasser aut Synthesis and characterisation of substituted lithium lanthanum titanates, with possible applications in electrochromic systems Sonia Stramare 2002 170 S. Ill., graph. Darst. : 30 cm txt rdacontent n rdamedia nc rdacarrier Kiel, Univ., Diss., 2002 Titanate (DE-588)4371102-9 gnd rswk-swf Elektrochromes Material (DE-588)4292130-2 gnd rswk-swf Lithiumverbindungen (DE-588)4322206-7 gnd rswk-swf Lanthanverbindungen (DE-588)4166759-1 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Lithiumverbindungen (DE-588)4322206-7 s Lanthanverbindungen (DE-588)4166759-1 s Titanate (DE-588)4371102-9 s Elektrochromes Material (DE-588)4292130-2 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010046631&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Stramare, Sonia Synthesis and characterisation of substituted lithium lanthanum titanates, with possible applications in electrochromic systems Titanate (DE-588)4371102-9 gnd Elektrochromes Material (DE-588)4292130-2 gnd Lithiumverbindungen (DE-588)4322206-7 gnd Lanthanverbindungen (DE-588)4166759-1 gnd |
| subject_GND | (DE-588)4371102-9 (DE-588)4292130-2 (DE-588)4322206-7 (DE-588)4166759-1 (DE-588)4113937-9 |
| title | Synthesis and characterisation of substituted lithium lanthanum titanates, with possible applications in electrochromic systems |
| title_auth | Synthesis and characterisation of substituted lithium lanthanum titanates, with possible applications in electrochromic systems |
| title_exact_search | Synthesis and characterisation of substituted lithium lanthanum titanates, with possible applications in electrochromic systems |
| title_full | Synthesis and characterisation of substituted lithium lanthanum titanates, with possible applications in electrochromic systems Sonia Stramare |
| title_fullStr | Synthesis and characterisation of substituted lithium lanthanum titanates, with possible applications in electrochromic systems Sonia Stramare |
| title_full_unstemmed | Synthesis and characterisation of substituted lithium lanthanum titanates, with possible applications in electrochromic systems Sonia Stramare |
| title_short | Synthesis and characterisation of substituted lithium lanthanum titanates, with possible applications in electrochromic systems |
| title_sort | synthesis and characterisation of substituted lithium lanthanum titanates with possible applications in electrochromic systems |
| topic | Titanate (DE-588)4371102-9 gnd Elektrochromes Material (DE-588)4292130-2 gnd Lithiumverbindungen (DE-588)4322206-7 gnd Lanthanverbindungen (DE-588)4166759-1 gnd |
| topic_facet | Titanate Elektrochromes Material Lithiumverbindungen Lanthanverbindungen Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010046631&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT stramaresonia synthesisandcharacterisationofsubstitutedlithiumlanthanumtitanateswithpossibleapplicationsinelectrochromicsystems |