Molecular theory of capillarity:
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Mineola, NY
Dover Publications
2002
|
| Edition: | 1. publ., [Nachdr. der Ausg.] Oxford 1989 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XI, 327 S. graph. Darst. |
| ISBN: | 0486425444 |
Staff View
MARC
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| 245 | 1 | 0 | |a Molecular theory of capillarity |c by J. S. Rowlinson and B. Widom |
| 250 | |a 1. publ., [Nachdr. der Ausg.] Oxford 1989 | ||
| 264 | 1 | |a Mineola, NY |b Dover Publications |c 2002 | |
| 300 | |a XI, 327 S. |b graph. Darst. | ||
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| 650 | 4 | |a Capillarity | |
| 650 | 4 | |a Molecular theory | |
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| 650 | 0 | 7 | |a Kapillarität |0 (DE-588)4029556-4 |2 gnd |9 rswk-swf |
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Record in the Search Index
| _version_ | 1804129402053722112 |
|---|---|
| adam_text | CONTENTS
Principal
symbols
ix
1
MECHANICAL MOLECULAR MODELS
1.1
Introduction
1
1.2
Molecular mechanics
2
1.3
Capillary phenomena
7
1.4
The internal energy of a liquid
13
1.5
The continuous surface profile
16
1.6
The mean molecular field
17
2
THERMODYNAMICS
2.1
Thermodynamics and kinetic theory
25
2.2
The thermodynamics of the surface
26
2.3
Surface functions
31
2.4
The spherical surface
38
2.5
Quasi-thermodynamics
—
a first look
43
3
THE THEORY OF VAN
DER WAALS
3.1
Introduction
50
3.2
The surface tension
56
3.3
Independently variable densities
57
3.4
Gibbs adsorption equation in the van
der Waals
theory
62
3.5
Constraints on the range of fluctuations
64
4
STATISTICAL MECHANICS OF THE LIQUID-GAS
SURFACE
4.1
Introduction
69
4.2
Distribution and correlation functions
69
4.3
The pressure tensor
85
4.4
The virial route to the surface tension
89
4.5
Functionals of the distribution functions
93
4.6
The surface tension from the direct correlation function
98
4.7
Equivalence of the two expressions for the surface tension
104
4.8
The spherical surface
109
4.9
Density fluctuations and their correlation
115
4.10
Local thermodynamic functions
122
5
MODEL FLUIDS IN THE MEAN-FIELD
APPROXIMATION
5.1
Introduction: mean-field theory of a homogeneous fluid of attract¬
ing hard spheres
129
5.2
Liquid-gas interface in the model of attracting hard spheres
133
5.3
Lattice-gas model: one component
135
ji
CONTENTS
5.4
Lattice-gas model: two components
140
5.5
Penetrable-sphere model: theory
151
5.6
Penetrable-sphere model: applications 159
5.7
Penetrable-sphere model: spherical surfaces
167
ι
COMPUTER SIMULATION OF THE LIQUID-GAS
SURFACE
6.1
The experimental background
1 3
6.2
The methods of computer simulation
175
6.3
The density profile I78
6.4
The surface tension
181
6.5
Further work
185
7
CALCULATION OF THE DENSITY PROFILE
7.1
Introduction I90
7.2
Solution of the YBG equation I90
7.3
Approximations for the direct correlation function
195
7.4
Modified van
der Waals
theories
198
7.5
Perturbation theories
200
7.6
Surface tension
202
8
THREE-PHASE EQUILIBRIUM
8.1
Introduction
207
8.2
Contact angles and Neumann s triangle
209
8.3
Spreading and Antonow s rule
212
8.4
The
αγ
interface
221
8.5
Phase transitions in interfaces. The Cahn transition
225
8.6
Three-phase line and line tension
232
9
INTERFACES NEAR CRITICAL POINTS
9.1
Introduction: mean-field approximation
249
9.2
Digression on the Ornstein-Zernike theory of the pair-correlation
function
255
9.3
Digression on critical-point exponents
261
9.4
Van
der Waals
theory with non-classical exponents
270
9.5
Tricritical points
276
9.6
Non-critical interface near a critical endpoint
285
9.7
Renormalization-group theory; field-theoretical models
296
APPENDIX
1
Thermodynamics
307
APPENDIX
2
Dirac s delta-function
314
NAME INDEX
316
SUBJECT INDEX
321
|
| any_adam_object | 1 |
| author | Rowlinson, John S. Widom, Benjamin |
| author_facet | Rowlinson, John S. Widom, Benjamin |
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| dewey-full | 541.3/3 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry |
| dewey-raw | 541.3/3 |
| dewey-search | 541.3/3 |
| dewey-sort | 3541.3 13 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| edition | 1. publ., [Nachdr. der Ausg.] Oxford 1989 |
| format | Book |
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| indexdate | 2024-07-09T19:04:34Z |
| institution | BVB |
| isbn | 0486425444 |
| language | English |
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| physical | XI, 327 S. graph. Darst. |
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| spelling | Rowlinson, John S. Verfasser aut Molecular theory of capillarity by J. S. Rowlinson and B. Widom 1. publ., [Nachdr. der Ausg.] Oxford 1989 Mineola, NY Dover Publications 2002 XI, 327 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Capillarity Molecular theory Statistische Mechanik (DE-588)4056999-8 gnd rswk-swf Kapillarität (DE-588)4029556-4 gnd rswk-swf Oberflächenspannung (DE-588)4139720-4 gnd rswk-swf Zwischenmolekulare Kraft (DE-588)4191346-2 gnd rswk-swf Kapillarität (DE-588)4029556-4 s Zwischenmolekulare Kraft (DE-588)4191346-2 s Statistische Mechanik (DE-588)4056999-8 s 1\p DE-604 Oberflächenspannung (DE-588)4139720-4 s 2\p DE-604 Widom, Benjamin Verfasser aut Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009940610&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Rowlinson, John S. Widom, Benjamin Molecular theory of capillarity Capillarity Molecular theory Statistische Mechanik (DE-588)4056999-8 gnd Kapillarität (DE-588)4029556-4 gnd Oberflächenspannung (DE-588)4139720-4 gnd Zwischenmolekulare Kraft (DE-588)4191346-2 gnd |
| subject_GND | (DE-588)4056999-8 (DE-588)4029556-4 (DE-588)4139720-4 (DE-588)4191346-2 |
| title | Molecular theory of capillarity |
| title_auth | Molecular theory of capillarity |
| title_exact_search | Molecular theory of capillarity |
| title_full | Molecular theory of capillarity by J. S. Rowlinson and B. Widom |
| title_fullStr | Molecular theory of capillarity by J. S. Rowlinson and B. Widom |
| title_full_unstemmed | Molecular theory of capillarity by J. S. Rowlinson and B. Widom |
| title_short | Molecular theory of capillarity |
| title_sort | molecular theory of capillarity |
| topic | Capillarity Molecular theory Statistische Mechanik (DE-588)4056999-8 gnd Kapillarität (DE-588)4029556-4 gnd Oberflächenspannung (DE-588)4139720-4 gnd Zwischenmolekulare Kraft (DE-588)4191346-2 gnd |
| topic_facet | Capillarity Molecular theory Statistische Mechanik Kapillarität Oberflächenspannung Zwischenmolekulare Kraft |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009940610&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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