Chemistry of the environment:
Saved in:
| Format: | Book |
|---|---|
| Language: | English |
| Published: |
San Diego, Calif. [u.a.]
Acad. Press
2002
|
| Edition: | 2. ed. |
| Subjects: | |
| Online Access: | Table of contents Publisher description Inhaltsverzeichnis |
| Item Description: | Includes bibliographical references and index |
| Physical Description: | XXIV, 835 S. Ill., graph. Darst. |
| ISBN: | 0120734613 |
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MARC
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| 245 | 1 | 0 | |a Chemistry of the environment |c Ronald A. Bailey ... |
| 250 | |a 2. ed. | ||
| 264 | 1 | |a San Diego, Calif. [u.a.] |b Acad. Press |c 2002 | |
| 300 | |a XXIV, 835 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Includes bibliographical references and index | ||
| 650 | 7 | |a Química ambiental |2 larpcal | |
| 650 | 4 | |a Environmental chemistry | |
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| 700 | 1 | |a Bailey, Ronald Albert |e Sonstige |4 oth | |
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| _version_ | 1804129323508039680 |
|---|---|
| adam_text | Titel: Chemistry of the environment
Autor: Bailey, Ronald A.
Jahr: 2002
CONTENTS
PREFACE XIX
ABOUT THE AUTHORS XXIII
1
INTRODUCTION
1.1 General 1
1.2 Pollution and Environmental Problems 2
1.3 Waste Disposal 4
1.4 Risk 6
1.5 Energy 7
1.6 Population 7
1.7 The Scope of Chemistry of the Environment 10
Additional Reading 11
2
ATMOSPHERIC COMPOSITION AND BEHAVIOR
2.1 Introduction 13
2.2 Gaseous Constituents of the Atmosphere 15
2.3 History of the Atmosphere 20
VI CONTENTS
2.3.1 Evidence and General Theory 20
2.3.2 Carbon Dioxide 22
2.3.3 Nitrogen 23
2.3.4 Oxygen 23
2.4 Particulate Constituents of the Atmosphere 24
2.5 Extent of the Atmosphere and Its Temperature and
Pressure Profile 26
2.6 General Circulation of the Atmosphere 30
2.7 Conclusion 35
Additional Reading 36
Exercises 36
3
ENERGY AND CLIMATE
3.1 Energy Balance of the Earth 39
3.1.1 Incoming Radiation from the Sun 39
3.1.2 The Greenhouse Effect 44
3.1.3 Other Factors 47
3.2 Climate History of the Earth 49
3.3 Causes of Global Climate Changes 53
3.3.1 General Comments 53
3.3.2 The Milankovitch Theory of Earth s Orbital Variations 55
3.3.3 Greenhouse Effect Changes 56
3.3.4 Albedo Changes 59
3.3.5 Computer Models 61
3.4 Small-Scale Climate 63
3.5 Temperature Inversions 65
3.6 Conclusions 69
Additional Reading 70
Exercises 70
4
PRINCIPLES OF PHOTOCHEMISTRY
4.1 Introduction 73
4.2 Electromagnetic Radiation 75
CONTENTS vjj
4.2.1 Properties of Light 75
4.2.2 Absorption of Light 77
4.3 Kinetics of Thermal Processes 83
4.4 Kinetics of Photochemical Processes 87
Additional Reading 89
Exercises 89
5
ATMOSPHERIC PHOTOCHEMISTRY
5.1 Introduction 91
5.2 Reactions in the Upper Atmosphere 93
5.2.1 Nitrogen 93
5.2.2 Oxygen 95
5.2.3 Ozone 100
5.2.4 Water in the Atmosphere 125
5.3 Photoprocesses in the Troposphere:
Photochemical Smog 126
5.3.1 The General Nature of Smog 126
5.3.2 Nitrogen Oxides (NOX) in the Absence of Volatile Organic
Compounds (VOCs) 129
5.3.3 Reactions in Urban Atmospheres Containing Volatile Organic
Compounds 135
5.3.4 Summary of Photochemical Smog 140
Additional Reading 142
Exercises 143
6
PETROLEUM, HYDROCARBONS, AND COAL
6.1 Introduction 147
6.2 The Nature of Petroleum 148
6.3 Sources of Crude Oil and Hydrocarbons in Marine
Environments 150
6.3.1 Introduction 150
6.3.2 Natural Sources 151
6.3.3 Offshore Wells 152
6.3.4 Industrial and Municipal Waste 153
viii CONTENTS
6.3.5 Transportation 154
6.3.6 Catastrophic Oil Spills 155
6.4 Fate of an Oil Spill 158
6.4.1 Weathering of an Oil Spill 160
6.4.2 Cleaning Up Oil Spills 161
6.5 Effects of Crude Oil on Marine Life 164
6.5.1 Fish 165
6.5.2 Clams, Mussels, and Other Invertebrates 165
6.5.3 Birds 165
6.5.4 Sea Otters and Other Marine Mammals 166
6.5.5 Sea Turtles 167
6.6 Use of Petroleum in the Internal Combustion Engine 168
6.7 Sources of Hydrocarbons and Related Compounds in the
Atmosphere 170
6.7.1 Introduction 170
6.7.2 Hydrocarbons and Other Emissions from Automobiles 171
6.7.3 The Catalytic Converter 175
6.7.4 Gasoline Additives: Tetraalkyllead, Ethanol, and Methyl
tert-Butyl Ether 177
6.8 The Air Pollution Problem in Urban Centers 179
6.8.1 Plans to Reduce Auto Emissions in Urban Centers 180
6.8.2 Low-Emission Automobiles 181
6.9 Coal 182
6.9.1 Coal Formation and Structure 182
6.9.2 Coal Gasification 184
6.9.3 Coal Liquefaction 187
Additional Reading 189
Exercises 190
7
SOAPS, SYNTHETIC SURFACTANTS, AND POLYMERS
7.1 Introduction 193
7.2 Soaps and Synthetic Surfactants 195
7.2.1 Soaps 196
7.2.2 Detergents 197
7.2.3 Surfactants 198
7.2.4 Microbial Metabolism of Hydrocarbons, Soaps, and
Synthetic Surfactants 201
CONTENTS JX
7.2.5 Environmental Effects of Biodegradable Organic Compounds:
Biological Oxygen Demand 206
7.3 Polymers 207
7.3.1 Polymer Synthesis 210
7.3.2 Paper 212
7.3.3 The Fate of Polymers after Use 213
7.3.4 Environmental Degradation of Polymers 214
7.3.5 Biodegradation 217
7.4 Conclusions 218
Additional Reading 219
Exercises 219
8
HALOORGANICS AND PESTICIDES
8.1 Introduction 223
8.2 Environmental Degradation 224
8.3 Chemistry of Chlorinated Organic
Compounds 225
8.3.1 Synthesis 225
8.3.2 Reactions 227
8.4 Microbial Degradation of Organics 231
8.4.1 Reductive Degradation 232
8.4.2 Oxidative Degradation 233
8.4.3 Hydrolytic Degradation 234
8.5 Toxicity 234
8.5.1 Environmental Hormones 235
8.6 Chlorofluorocarbons, Hydrofiuorocarbons, and Perhalogenated
Organics 238
8.6.1 Structural Types 239
8.6.2 Atmospheric Lifetimes 239
8.7 Polychlorinated and Poiybrominated Biphenyls 244
8.7.1 Environmental Problems 245
8.7.2 Toxicity 245
8.7.3 Chemical Synthesis and Reactivity 247
8.7.4 Microbial Degradation 249
8.8 DDT and Its Degradation Products 251
8.8.1 Synthesis 252
8.8.2 Environmental Degradation 253
CONTENTS
8.8.3 Mechanism of Action of DDT and DDT Analogues as
Pesticides 254
8.8.4 Chronic Toxicity of DDT and Related Compounds 255
8.9 Other Chloroorganic Pesticides 258
8.9.1 Lindane 258
8.9.2 Polychlorinated Cyclodienes 260
8.10 Herbicides: 2,4-Dichlorophenoxyacetic Acid and
2,4,5-Trichlorophenoxyacetic Acid 265
8.10.1 Introduction 265
8.10.2 Synthesis 265
8.10.3 Environmental Degradation 266
8.11 Organophosphorus Insecticides 270
8.11.1 Introduction 270
8.11.2 Synthesis 271
8.11.3 Toxicity 273
8.11.4 Environmental Degradation 273
8.12 Resistance: The Bugs Fight Back 274
8.13 Biochemical Methods of Insect Control 276
8.13.1 Pheromones 277
8.13.2 Insect Attractants 280
8.13.3 Hormones 281
8.13.4 Viruses and Bacteria 283
8.14 Integrated Pest Management 285
8.15 Proposed Phaseout of All
Chlorine-Containing Compounds 287
Additional Reading 288
Exercises 291
9
CHEMISTRY IN AQUEOUS MEDIA
9.1 Water in the Environment 295
9.1.1 The Water Cycle 295
9.1.2 Structure and Properties of Water 298
9.1.3 Solubility 304
9.1.4 Acid-Base Behavior 306
9.2 Acid-Base Reactions 307
9.2.1 General Behavior 307
9.2.2 Carbonic Acid 311
CONTENTS xi
9.2.3 pH and Solubility 317
9.3 Effects of Temperature and Pressure Effects on
Equilibrium 319
9.4 Oxidation-Reduction Processes 320
9.5 Coordination Chemistry 324
9.5.1 General Aspects of Coordination Chemistry 324
9.5.2 Coordination Number and Geometry 325
9.5.3 Metal-Ligand Preferences 327
9.5.4 Water as a Ligand 329
9.5.5 Complex Stability and Lability 330
9.5.6 Some Applications of Complexing 333
9.5.7 Complexing in Natural Systems 335
9.6 Colloidal Material 340
9.7 Adsorption and Ion Exchange 341
9.8 Conclusion 343
Additional Reading 344
Exercises 344
10
THE ENVIRONMENTAL CHEMISTRY OF SOME IMPORTANT
ELEMENTS
10.1 Introduction 347
10.2 The Carbon Cycle, C02, and Carbonates 354
10.3 Nitrogen 362
10.4 Sulfur and the Sulfur Cycle 370
10.5 Phosphorus, Fertilizers, and Eutrophication 375
10.6 Biologically Important Metals and Other Elements 379
10.6.1 Introduction 379
10.6.2 Alkaline Earth Metals: Beryllium, Magnesium, Calcium,
Strontium, and Barium 382
10.6.3 Iron 383
10.6.4 Chromium 388
10.6.5 Manganese 389
10.6.6 Copper 389
10.6.7 Zinc, Cadmium, and Mercury 390
10.6.8 Boron 399
10.6.9 Aluminum 399
10.6.10 Tin and Lead 400
Xii CONTENTS
10.6.11 Arsenic 405
10.6.12 Selenium 407
10.6.13 The Halogens 409
10.7 Summary 412
Additional Reading 412
Exercises 413
11
WATER SYSTEMS AND WATER TREATMENT
11.1 Composition of Water Bodies 415
11.2 Model Ocean Systems 417
11.3 Residence Times 421
11.4 Acid Rain 422
11.5 Water Treatment 425
11.5.1 Domestic Water Treatment 427
11.5.2 Wastewater Treatment 432
11.6 Anaerobic Systems 439
11.7 Irrigation Waters 440
Additional Reading 441
Exercises 442
12
THE EARTH S CRUST
12.1 Rocks and Minerals 443
12.2 Recovery of Minerals from Their Ores 449
12.2.1 Sources 449
12.2.2 Ore Treatment 454
12.2.3 Bacterial Mining 456
12.2.4 Iron 457
12.2.5 Aluminum 458
12.2.6 Gold 459
12.3 Soils 460
12.3.1 Soil Formation and Composition 460
12.3.2 Contaminated Soils 469
12.4 Nonmetallic Materials from the Earth 473
CONTENTS Xiii
12.4.1 Stone 473
12.4.2 Clay-Based Materials 474
12.4.3 Glass 475
12.4.4 Cements 476
12.4.5 Asbestos 477
Additional Reading 481
Exercises 482
13
PROPERTIES AND REACTIONS OF ATOMIC NUCLEI,
RADIOACTIVITY, AND IONIZING RADIATION
13.1 Introduction 483
13.2 The Atomic Nucleus 484
13.2.1 Composition, Types, and Selected Properties 484
13.2.2 Physicochemical Effects of Nuclear Mass and Spin 488
13.3 Energetics of Nuclear Reactions 489
13.4 The Kinetics of Nuclear Reactions 494
13.4.1 Radioactive Decay 494
13.4.2 Induced Nuclear Reactions 502
13.5 Modes and Energetics of Radioactive Decay 504
13.5.1 Gamma Ray Emission, Internal Conversion, and
Isomeric Transition 505
13.5.2 Beta Decay 508
13.5.3 Alpha Decay 514
13.5.4 Other Modes of Decay 515
13.6 Selected Induced Nuclear Reactions 516
13.6.1 Charged-Particle Reactions 516
13.6.2 Photonuclear Reactions 517
13.6.3 Nuclear Fission 517
13.6.4 Nonfission Neutron Production 521
13.7 Interaction of Ionizing Radiation with Matter 522
13.7.1 Charged Particles 522
13.7.2 X Rays and Gamma Rays 529
13.7.3 Neutrons 533
13.7.4 Linear Energy Transfer 534
13.8 Effects of Ionizing Radiation on Biological Cells 535
13.9 Classification of Health Effects of Ionizing Radiation 537
13.10 Units of Exposure and Dose for Ionizing Radiation 538
xiv CONTENTS
13.10.1 Exposure 538
13.10.2 Dose 539
13.11 Estimation of Exposure Rate from Gamma-Ray
Sources 544
13.12 Estimation of Dose Rate Based on Source
Characteristics 546
13.12.1 Gamma Radiation 546
13.12.2 Beta Radiation 546
13.12.3 Alpha Radiation 547
13.13 Specific Health Effects 547
13.13.1 External Sources of X and Gamma Radiation 547
13.13.2 Internal Sources 549
13.14 Correlation between Dose and Effect 550
13.14.1 High-Level Dose 550
13.14.2 Low-Level Dose 552
Additional Reading 553
Exercises 554
14
THE NUCLEAR ENVIRONMENT
14.1 Introduction 561
14.2 Cosmic Radiation 562
14.3 Naturally Occurring Sources of Radioactivity in the
Environment 564
14.4 Distribution of Naturally Occurring Radioactivity in the
Environment 565
14.4.1 Rocks and Soils 565
14.4.2 Uranium and Thorium Ores 567
14.4.3 The Atmosphere 568
14.4.4 Water 578
14.4.5 Food 580
14.4.6 Materials Used for Building Construction 581
14.5 Applications of Naturally Occurring Stable Nuclides and
Radionuclides to the Study of Earth and Its
Environment 582
14.5.1 Types of Application 582
14.5.2 Isotope Fractionation 583
CONTENTS XV
14.5.3 Radiometric Methods for Age Determination 585
14.5.4 Summary of Examples of Nuclides Used and
Types of Application 589
14.6 Special-Purpose Sources of Ionizing Radiation in the
Environment: Types and Applications 589
14.6.1 Sources Used for Structural Analysis of Solids, Radiography,
Diagnostic Imaging, and Medical Therapy 593
14.6.2 Sources Used in Nuclear Medicine 595
14.6.3 Multifarious Sources 599
14.7 Nuclear Fission Power Plants BOB
14.7.1 Types of Nuclear Power Reactor 607
14.7.2 Nuclear Fuel 608
14.7.3 Nuclear Fuel Requirements 609
14.7.4 Types of Nuclear Power Plant 611
14.7.5 Safety Features of Nuclear Power Plants 617
14.7.6 Effluents from Nuclear Power Plants 620
14.7.7 Advanced Nuclear Power Plants for the Future 622
14.8 Natural Fission Reactors (The Oklo Phenomenon) 623
14.9 Thermonuclear Power Plants 624
14.10 ColdFusion 626
14.11 Nuclear Weapons 627
14.11.1 Types 627
14.11.2 Production 627
14.11.3 Testing 630
14.11.4 Fallout and Rainout 631
14.11.5 Proliferation 632
14.11.6 A Cold War Heritage: Weapons-Grade Plutonium and
Weapons-Grade Uranium 634
14.12 Radioactive Waste 635
14.12.1 Types and Sources 635
14.12.2 Methods of Disposal 637
14.12.3 The Cold War Mortgage 648
14.13 Pathways for Internal Exposure to Ionizing Radiation 651
14.14 Dose of Ionizing Radiation Received by the U.S.
Population 655
14.14.1 Dose from External Exposure 655
14.14.2 Dose from Internal Exposure 655
14.14.3 Average Annual Dose 657
14.15 Regulatory Limits for Radiation Dose Received by Radiation
Workers and the General Population 659
Xvi COIMTEINTTS
14.16 Examples of Accidents and Incidents Involving the Release of
Radionuclides into the Environment 661
14.16.1 Therapy and Gauging Sources 661
14.16.2 Nuclear Reactors 663
14.16.3 Radioactive Waste 678
14.16.4 Nuclear Fuel Processing Plant 679
Additional Reading 680
Exercises 683
15
ENERGY
15.1 Introduction 687
15.2 Thermodynamic Considerations 689
15.2.1 The First and Second Laws of Thermodynamics 689
15.2.2 Units of Energy and Power 694
15.3 Fossil Fuels 694
15.3.1 Introduction 694
15.3.2 Liquid Hydrocarbon Fuels 696
15.3.3 Coal 697
15.3.4 Natural Gas 698
15.3.5 Synthesis of Methane from Coal 699
15.4 Nuclear Energy 701
15.4.1 Nuclear Power and the Environment 701
15.4.2 Status of Nuclear Power 701
15.4.3 Factors Affecting the Choice of Nuclear Energy for the
Generation of Electricity in the United States 705
15.4.4 Costs 707
15.5 Solar Energy 710
15.5.1 Introduction 710
15.5.2 Biological Utilization of Solar Energy: Biomass 711
15.5.3 Physical Utilization of Solar Energy 713
15.5.4 Photoelectric Utilization of Solar Energy 721
15.5.5 Photoelectrochemical Utilization of Solar Energy 725
15.6 Geothermal Energy 728
15.7 Wind and Water 730
15.7.1 Introduction 730
15.7.2 Wind Energy Conversion 730
15.7.3 Water Energy Conversion 733
CONTENTS XVii
15.8 Energy Storage 737
15.8.1 Introduction 737
15.8.2 Physical Energy Storage 740
15.8.3 Chemical Energy Storage 741
15.9 Direct Generation of Electricity from Fuels 750
15.10 The Energy Future 754
15.10.1 The United States of America 754
15.10.2 The Rest of the World 756
15.10.3 Conclusions 761
Additional Reading 762
Exercises 765
16
SOLID WASTE DISPOSAL AND RECYCLING
16.1 Introduction 769
16.2 Landfills 772
16.3 Composting 775
16.4 Anaerobic Digestion of Biological Wastes 777
16.5 Incineration 777
16.6 The Tire Problem 781
16.7 Recycling 783
16.7.1 Glass 783
16.7.2 Paper 784
16.7.3 Metal 785
16.7.4 Plastics 786
Additional Reading 791
APPENDIX A
DESIGNATION OF SPECTROSCOPE STATES 793
A.1 Introduction 793
A. 2 Atoms 793
A. 3 Diatomic Molecules 796
A. 4 Polyatomic Molecules 799
Additional Reading 800
XVJii CONTENTS
APPENDIX B
THORIUM AND ACTIUM SERIES 801
APPENDIX C
UNITS 805
APPENDIX D
SYMBOLS AND ABBREVIATIONS 807
INDEX 811
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| dewey-ones | 540 - Chemistry and allied sciences 577 - Ecology |
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| discipline | Chemie / Pharmazie Biologie Umwelt |
| edition | 2. ed. |
| format | Book |
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| id | DE-604.BV014534703 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T19:03:19Z |
| institution | BVB |
| isbn | 0120734613 |
| language | English |
| lccn | 2001096794 |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-009890351 |
| oclc_num | 49238333 |
| open_access_boolean | |
| owner | DE-M49 DE-BY-TUM DE-188 |
| owner_facet | DE-M49 DE-BY-TUM DE-188 |
| physical | XXIV, 835 S. Ill., graph. Darst. |
| publishDate | 2002 |
| publishDateSearch | 2002 |
| publishDateSort | 2002 |
| publisher | Acad. Press |
| record_format | marc |
| spelling | Chemistry of the environment Ronald A. Bailey ... 2. ed. San Diego, Calif. [u.a.] Acad. Press 2002 XXIV, 835 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and index Química ambiental larpcal Environmental chemistry Ökologische Chemie (DE-588)4135167-8 gnd rswk-swf Ökologische Chemie (DE-588)4135167-8 s DE-604 Bailey, Ronald Albert Sonstige oth http://www.loc.gov/catdir/toc/els041/2001096794.html Table of contents http://www.loc.gov/catdir/description/els031/2001096794.html Publisher description HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009890351&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Chemistry of the environment Química ambiental larpcal Environmental chemistry Ökologische Chemie (DE-588)4135167-8 gnd |
| subject_GND | (DE-588)4135167-8 |
| title | Chemistry of the environment |
| title_auth | Chemistry of the environment |
| title_exact_search | Chemistry of the environment |
| title_full | Chemistry of the environment Ronald A. Bailey ... |
| title_fullStr | Chemistry of the environment Ronald A. Bailey ... |
| title_full_unstemmed | Chemistry of the environment Ronald A. Bailey ... |
| title_short | Chemistry of the environment |
| title_sort | chemistry of the environment |
| topic | Química ambiental larpcal Environmental chemistry Ökologische Chemie (DE-588)4135167-8 gnd |
| topic_facet | Química ambiental Environmental chemistry Ökologische Chemie |
| url | http://www.loc.gov/catdir/toc/els041/2001096794.html http://www.loc.gov/catdir/description/els031/2001096794.html http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009890351&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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