Measurement of crystal growth and nucleation rates:
Saved in:
| Format: | Book |
|---|---|
| Language: | English |
| Published: |
Rugby
Inst. of Chemical Engineers
2002
|
| Edition: | 2. ed. |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XI, 202 S. graph. Darst. |
| ISBN: | 0852954492 |
Staff View
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| 245 | 1 | 0 | |a Measurement of crystal growth and nucleation rates |c [ed. by John Garside ...] |
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Record in the Search Index
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| adam_text | Titel: Measurement of crystal growth and nucleation rates
Autor: Garside, John
Jahr: 2002
Contents
Contributors iii
Preface to the first edition v
Preface to the second edition vii
1 Introduction 1
2 Fundamentals of kinetics 3
2.1 Concentration 3
2.1.1 Concentration units 3
2.1.2 Concentration measurements 5
2.2 Supersaturation 12
2.3 Crystal growth and nucleation rates 14
2.3.1 Growth 14
2.3.2 Nucleation 16
2.4 Growth rate expressions 17
2.4.1 Empirical expressions 17
2.4.2 Diffusion and integration control 19
2.4.3 Fundamental growth rate expressions 23
2.4.4 Effect of temperature 23
2.5 Size dependent growth and growth rate dispersion 26
2.5.1 Size dependent growth 26
2.5.2 Growth rate dispersion 27
2.6 Shape factors 28
2.6.1 Definition 28
2.6.2 Determination of shape factors 31
2.7 Size distributions 34
2.7.1 Introduction 34
2.7.2 Definition of size distributions 35
2.7.3 Graphical presentation of size distribution 38
2.7.4 Measurement of crystal size 40
ix
CRYSTAL GROWTH AND NUCLEATION RATES
: 48
2.7.5 Sample preparation
2.8 Nucleation rate expressions 49
2.8.1 Primary nucleation 49
2.8.2 Secondary nucleation 50
3 Methods of growth rate measurement 51
3.1 Introduction 51
3.2 Fixed single crystals 52
3.2.1 Solubility, supersaturation and the creation of supersaturation 53
3.2.2 Fluid dynamics 58
3.2.3 Layout of equipment 58
3.2.4 Problems 64
3.2.5 Example 65
3.3 Rotating disc 68
3.3.1 Introduction 88
3.3.2 Principles 88
3.3.3 Equipment 70
3.3.4 Measurement procedure 73
3.3.5 Examples of measured data 74
3.3.6 Comparison with other data ; 78
3.4 Batch multipartide systems 78
3.4.1 Fluidized bed measurement (weighing method) 79
3.4.2 Fluidized single crystals (video camera) - 85
3.4.3 Batch differential growth 90
3.4.4 Desupersaturation of solution 92
3.4.5 Quasi-isothermal model crystallization 95
3.4.6 Polythermal model crystallization 100
3.4.7 Simultaneous determination of G and B0jrff from batch experiments 102
3.5 Continuous MSMPR crystallizer 105
3.5.1 MSMPR model 105
3.5.2 Measuring technique and analysis procedure 110
3.5.3 Estimation of the effective rate of attrition controlled secondary
nucleation, B0_eff 125
3.5.4 Comparison of crystal growth rates obtained for single crystals,
for crystals in fluidized beds and from MSMPR crystallizers 129
3.5.5 Deviations from the idealized MSMPR model 131
3.6 Mechanical material properties relevant for attrition 138
3.6.1 Elasticity 139
3.6.2 Plastic flow and fracture 139
3.6.3 Problems in the determination of the material
properties relevant for attrition 147
x
CONTENTS
4 Methods of nudeation rate measurement 151
4.1 Introduction 151
4.2 Metastable zone width measurement 156
4.2.1 Isothermal measurements 160
4.2.2 Polythermal methods 162
4.3 Rates of primary nucleation 169
4.3.1 Fundamentals 169
4.3.2 General requirements for an experimental technique 172
4.3.3 Integral determination with T- or Y-mixers 174
4.3.4 Desupersaturation experiments at constant volume 183
4.3.5 MSMPR experiments 185
References and bibliography 187
Notation 195
xi
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| illustrated | Illustrated |
| indexdate | 2024-07-09T18:59:21Z |
| institution | BVB |
| isbn | 0852954492 |
| language | English |
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| physical | XI, 202 S. graph. Darst. |
| publishDate | 2002 |
| publishDateSearch | 2002 |
| publishDateSort | 2002 |
| publisher | Inst. of Chemical Engineers |
| record_format | marc |
| spelling | Measurement of crystal growth and nucleation rates [ed. by John Garside ...] 2. ed. Rugby Inst. of Chemical Engineers 2002 XI, 202 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Dynamica gtt Groeisnelheid gtt Kristalfysica gtt Kristalgroei gtt Crystal growth Crystallization Kristallwachstum (DE-588)4123579-4 gnd rswk-swf Kristallwachstum (DE-588)4123579-4 s DE-604 Garside, John Sonstige oth HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009729913&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Measurement of crystal growth and nucleation rates Dynamica gtt Groeisnelheid gtt Kristalfysica gtt Kristalgroei gtt Crystal growth Crystallization Kristallwachstum (DE-588)4123579-4 gnd |
| subject_GND | (DE-588)4123579-4 |
| title | Measurement of crystal growth and nucleation rates |
| title_auth | Measurement of crystal growth and nucleation rates |
| title_exact_search | Measurement of crystal growth and nucleation rates |
| title_full | Measurement of crystal growth and nucleation rates [ed. by John Garside ...] |
| title_fullStr | Measurement of crystal growth and nucleation rates [ed. by John Garside ...] |
| title_full_unstemmed | Measurement of crystal growth and nucleation rates [ed. by John Garside ...] |
| title_short | Measurement of crystal growth and nucleation rates |
| title_sort | measurement of crystal growth and nucleation rates |
| topic | Dynamica gtt Groeisnelheid gtt Kristalfysica gtt Kristalgroei gtt Crystal growth Crystallization Kristallwachstum (DE-588)4123579-4 gnd |
| topic_facet | Dynamica Groeisnelheid Kristalfysica Kristalgroei Crystal growth Crystallization Kristallwachstum |
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| work_keys_str_mv | AT garsidejohn measurementofcrystalgrowthandnucleationrates |