Evaluation of synthetic pathways for the heterofullerene C58N2 and introduction of the first concept for a completely regioselective control of multiple adduct formation of C60:
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| Main Author: | |
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| Format: | Thesis Book |
| Language: | English German |
| Published: |
2001
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| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Erlangen-Nürnberg, Univ., Diss., 2001. - Enth. Zsfassung in dt. Sprache |
| Physical Description: | III, 237 S. Ill., graph. Darst. |
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| adam_text | EVALUATION OF SYNTHETIC PATHWAYS FOR THE HETEROFUUERENE C 58 N 2 AND
INTRODUCTION OF THE FIRST CONCEPT FOR A COMPLETELY REGIOSELECTIVE
CONTROL OF MULTIPLE ADDUCT FORMATION OF C 6 O DEN
NATURWISSENSCHAFTLICHEN FAKULTAETEN DER FRIEDRICH-ALEXANDER-UNIVERSITAET
ERLANGEN-NUERNBERG ZUR ERLANGUNG DES DOKTORGRADES VORGELEGT VON UWE
REUTHER AUS FRANKFURT/MAIN TABLE OF CONTENTS 1 INTRODUCTION 1 1.1 THE
DISCOVERY OF THE FULLERENES 1 1.1.1 THE FULLERENE C 60 1 1.1.2 THE
FULLERENE C 70 3 1.1.3 THE HIGHER FULLERENES 5 1.2 PHYSICAL PROPERTIES
OF FULLERENES 6 1.2.1 SOLUBILITY 6 1.2.2 IR AND UV SPECTROSCOPY 7 1.2.3
MAGNETIC RING CURRENTS IN C 60 AND C 70 10 1.3 CHEMICAL PROPERTIES OF
FULLERENES 12 1.3.1 OVERVIEW OF FULLERENE REACTIVITY 12 1.3.1.1 GENERAL
PROPERTIES GOVERNING FULLERENE CHEMISTRY 12 1.3.1.2 REDOX CHEMISTRY 13
1.3.1.3 NUCLEOPHILIC ADDITIONS 16 1.3.1.4 CYCLOADDITIONS 19 1.3.2
NOMENCLATURE CONVENTIONS FOR FULLERENE ADDUCTS 23 1.3.2.1 CONVENTIONS
FOR [60]FULLERENE ADDUCTS 23 1.3.2.2 CONVENTIONS FOR [70]FULLERENE
ADDUCTS 24 1.3.3 SPACER-CONTROUED REMOTE FUNCTIONALIZATION OF FULLERENES
26 1.4 AN INTRODUCTION TO HETEROFULLERENES 29 1.4.1 PRELIMINARY REMARKS
29 1.4.2 SYNTHESIS OF AZA[60|FULLERENE 31 1.4.2.1 THE METHOD OF WUDL 31
1.4.2.2 THE METHOD OF HIRSCH 33 1.4.3 PHYSICAL PROPERTIES OF AZA
[60]FULLERENE 35 1 TABLE OF CONTENTS 1.4.3.1 THE STRUCTURE OF THE
AZA[60]FULLERENE DIMER 35 1.4.3.2 EXAMINATION OF THE DIMER BOND 36
1.4.3.3 THE ELECTRONIC STRUCTURE OF AZA[60]FULLERENE 37 1.4.3.4
PROPERTIES OF THE AZA[60]FULLERENE SOLID 38 1.4.4 DERIVATIZATION OF
AZA[60]FULLERENE 38 1.4.4.1 THEORETICAL ASPECTS OF AZA[60]FULLERENE
DERIVATIZATION 38 1.4.4.2 REACTIONS AT THE RADICAL OR CATIONIC CENTER OF
AZA[60]FULLERENYL 40 1.4.4.3 REACTIONS AT THE HETEROFULLERENE CORE 43 2
PROPOSAL 46 3 RESULTS AND DISCUSSION 47 3.1 HIGH PURITY SYNTHESIS AND
INVESTIGATIONS OF (C 59 N) 2 47 3.1.1 OPTIMIZATION OF THE (C 59 N) 2
SYNTHESIS 47 3.1.2 FILM GROWTH OF (C 59 N) 2 ON LAYERED MATERIALS 48
3.1.3 PHOTOLYSIS OF (C 59 N) 2 STUDIED BY TIME RESOLVED VIS
SPECTROSCOPY. 49 3.1.4 FLUORINATION OF (C 59 N) 2 52 3.1.5 GENERATION OF
C 59 N + IN THE MASS SPECTROMETER 54 3.2 A STRATEGY FOR THE SYNTHESIS OF
C S8 N2 56 3.2.1 PREREQUISITES FOR A SUCCESSFUL SYNTHESIS OF C 58 N 2 56
3.2.2 THE *FIXED SPACER METHOD 59 3.2.2.1 INTRODUCTORY REMARKS 59
3.2.2.2 THE SYNTHESIS OF MODEL ADDUCTS 64 3.2.2.3 SYNTHESIS OF (C 59 N)
2 DERIVATIVES WITH THE FIXED SPACER METHOD 77 3.2.3 THE *TWEEZERS
METHOD 80 3.2.2.1 INTRODUCTORY REMARKS 80 3.2.2.2 SYNTHESIS OF THE
BISAZIDES 81 3.2.2.3 SYNTHESIS OF C 60 ADDUCTS WITH BISAZIDES 83 II
TABLE OF CONTENTS 3.3 TETHER FUNCTIONALIZATION OF C 70 AND C 6 O WITH
MALONATES 94 3.3.1 TETHER DIRECTED BISFUNCTIONALIZATION OF C 70 94 3.3.2
TETHER DIRECTED BISFUNCTIONALIZATION OF C 60 98 3.3.3 A NEW METHOD FOR
TETHER FUNCTIONALIZATION OF C 60 101 3.3.3.1 INTRODUCTORY REMARKS 101
3.3.3.2 THE CONCEPT - MACROCYCLIC MALONATES 102 3.3.3.4 SYNTHESIS OF
MACROCYCLIC MALONATES 104 3.3.3.5 SYNTHESIS OF C 60 BISADDUCTS 112
3.3.3.6 SYNTHESIS OF C 60 TRISADDUCTS 115 3.3.3.7 SYNTHESIS OF C 60
TETRAADDUCTS 120 3.3.3.8 SYNTHESIS OF A C 60 PENTAADDUCT 124 3.3.3.9
SYNTHESIS OF MIXED ADDUCTS 125 3.3.3.10 CONCLUDING REMARKS AND OUTLOOK
132 4 SUMMARY 134 4 ZUSAMMENFASSUNG 138 5 EXPERIMENTAL PART 142 5.1
INSTRUMENTS AND METHODS 142 5.2 CHEMICALS 144 5.3 EXPERIMENTAL DETAILS
144 6 REFERENCES 212 7 APPENDIX X RAY STRUCTURES 221 IN
|
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| discipline | Chemie / Pharmazie |
| format | Thesis Book |
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| id | DE-604.BV014117433 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T18:57:57Z |
| institution | BVB |
| language | English German |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-009672986 |
| oclc_num | 248750592 |
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| physical | III, 237 S. Ill., graph. Darst. |
| publishDate | 2001 |
| publishDateSearch | 2001 |
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| spelling | Reuther, Uwe Verfasser aut Evaluation of synthetic pathways for the heterofullerene C58N2 and introduction of the first concept for a completely regioselective control of multiple adduct formation of C60 von Uwe Reuther 2001 III, 237 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Erlangen-Nürnberg, Univ., Diss., 2001. - Enth. Zsfassung in dt. Sprache Erlangen-Nürnberg, Univ., Diss., 2001 Stickstoff-substituierte Verbindungen (DE-588)4346068-9 gnd rswk-swf Heterofullerene (DE-588)4381788-9 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Heterofullerene (DE-588)4381788-9 s Stickstoff-substituierte Verbindungen (DE-588)4346068-9 s DE-604 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009672986&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Reuther, Uwe Evaluation of synthetic pathways for the heterofullerene C58N2 and introduction of the first concept for a completely regioselective control of multiple adduct formation of C60 Stickstoff-substituierte Verbindungen (DE-588)4346068-9 gnd Heterofullerene (DE-588)4381788-9 gnd |
| subject_GND | (DE-588)4346068-9 (DE-588)4381788-9 (DE-588)4113937-9 |
| title | Evaluation of synthetic pathways for the heterofullerene C58N2 and introduction of the first concept for a completely regioselective control of multiple adduct formation of C60 |
| title_auth | Evaluation of synthetic pathways for the heterofullerene C58N2 and introduction of the first concept for a completely regioselective control of multiple adduct formation of C60 |
| title_exact_search | Evaluation of synthetic pathways for the heterofullerene C58N2 and introduction of the first concept for a completely regioselective control of multiple adduct formation of C60 |
| title_full | Evaluation of synthetic pathways for the heterofullerene C58N2 and introduction of the first concept for a completely regioselective control of multiple adduct formation of C60 von Uwe Reuther |
| title_fullStr | Evaluation of synthetic pathways for the heterofullerene C58N2 and introduction of the first concept for a completely regioselective control of multiple adduct formation of C60 von Uwe Reuther |
| title_full_unstemmed | Evaluation of synthetic pathways for the heterofullerene C58N2 and introduction of the first concept for a completely regioselective control of multiple adduct formation of C60 von Uwe Reuther |
| title_short | Evaluation of synthetic pathways for the heterofullerene C58N2 and introduction of the first concept for a completely regioselective control of multiple adduct formation of C60 |
| title_sort | evaluation of synthetic pathways for the heterofullerene c58n2 and introduction of the first concept for a completely regioselective control of multiple adduct formation of c60 |
| topic | Stickstoff-substituierte Verbindungen (DE-588)4346068-9 gnd Heterofullerene (DE-588)4381788-9 gnd |
| topic_facet | Stickstoff-substituierte Verbindungen Heterofullerene Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009672986&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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