The physical basis of thermodynamics: with applications to chemistry
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| Format: | Book |
| Language: | English |
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New York [u.a.]
Kluwer Acad./Plenum Publ.
2001
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| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XXVII, 442 S. graph. Darst. |
| ISBN: | 0306465841 |
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| 245 | 1 | 0 | |a The physical basis of thermodynamics |b with applications to chemistry |c Pascal Richet |
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| adam_text | THE PHYSICAL BASIS OF THERMODYNAMICS WITH APPLICATIONS TO CHEMISTRY
PASCAL RICHET INSTITUT DE PHYSIQUE DU GLOBE PARIS, FRANCE KLUWER
ACADEMIC/PLENUM PUBLISHERS NEW YORK, BOSTON, DORDRECHT, LONDON, MOSCOW
CONTENTS S.I. UNITS AND PHYSICAL CONSTANTS: 1998 CODATA RECOMMENDED
VALUES XXIII ELEMENTS: ATOMIC NUMBERS AND 1995 STANDARD ATOMIC WEIGHTS
... XXV GREEK LETTERS XXVII 1. ENTROPY AND PRINCIPLES 1 1.1 PREAMBLE 1
1.1A SYSTEMS, PROPERTIES, PHASES 1 1.1B STATE, STATE FUNCTIONS,
TRANSFORMATIONS, ADVANCEMENT OF REACTION 3 1.1C STATE CHARACTERIZATION,
DUHEM POSTULATE 3 1.2 INTERNAL ENERGY AND FIRST PRINCIPLE 4 1.2A
TEMPERATURE AND HEAT 4 1.2B HEAT CAPACITY AND LATENT HEAT 5 1.2C HEAT AS
AN ENERGY: FIRST PRINCIPLE 6 1.2D INTERNAL ENERGY 7 1.3 TENSIONS AND
EXTENSITIES 8 1.3A GRAVITATIONAL ENERGY 8 1.3B ELECTRICAL ENERGY 9 XI
XII CONTENTS 1.3C KINETIC ENERGY 10 1.3D MECHANICAL ENERGY 10 1.3E
CONJUGATE VARIABLES 11 1.4 ENTROPY AND SECOND PRINCIPLE 12 1.4A
REVERSIBILITY AND IRREVERSIBILITY 12 1.4B ENTROPY AND THERMODYANAMIC
TEMPERATURE 13 1.4C SECOND PRINCIPLE 15 1.4D HEAT AND ENTROPY: TWO
EXAMPLES 16 1.5 ENTROPY AND THERMAL ENERGY 18 1.5A ENTROPY AS A
NON-CONSERVATIVE EXTENSITY 18 1.5B CONVERSION OF HEAT INTO WORK 19 1.5C
THERMAL ENERGY AS A DEGRADED FORM OF ENERGY 21 1.5D MICROSCOPIC STRETCH
22 2. ENERGIES AND EVOLUTION CRITERIA 25 2.1 INTERNAL ENERGY OF AN OPEN
SYSTEM 25 2.1A INTERNAL ENERGY AND COMPOSITION 25 2.1B COMPONENTS OF A
SYSTEM 26 2.1C CHEMICAL POTENTIALS 26 2.1D INTERNAL ENERGY 27 2.1E
GIBBS-DUHEM EQUATION 28 2.2 ENERGIES 29 2.2A HEATS OF TRANFORMATION,
ENTHALPY 29 2.2B HELMHOLTZ FREE ENERGY 30 2.2C GIBBS FREE ENERGY 31 2.3
EVOLUTION CRITERIA AND THERMODYNAMIC POTENTIALS 32 2.3A INTERNAL ENERGY
CRITERION 32 2.3B FUNDAMENTAL REPRESENTATIONS 34 2.3C ENTHALPY CRITERION
34 2.3D GIBBS FREE ENERGY CRITERION 35 2.3E HELMHOLTZ FREE ENERGY
CRITERION 36 2.3F LEGENDRE TRANSFORMATIONS AND EVOLUTION CRITERIA ....
36 2.4 STABILITIES AND INTERNAL EQUILIBRIUM 39 2.4A INTERNAL EQUILIBRIUM
39 2.4B STABILITY 39 2.4C STATES OF MATTER 41 3. AUXILIARY RELATIONS 45
3.1 DIFFERENTIAL EXPRESSIONS 45 3.1A OPEN SYSTEMS 45 CONTENTS XIII 3.1B
GIBBS-HELMHOLTZ EQUATIONS 46 3.1C MAXWELL RELATIONS 47 3.1D ORDER OF
VARIABLES 48 3.2 PARTIAL MOLAR PROPERTIES 48 3.2A DEFINITION 48 3.2B
INTEGRATION OF PARTIAL MOLAR PROPERTIES 50 3.2C DETERMINATION OF PARTIAL
MOLAR PROPERTIES 50 3.3 THERMODYNAMIC EQUATIONS OF STATE 52 3.3A
INTERNAL ENERGY AND VOLUME 52 3.3B ENTHALPY AND PRESSURE 52 3.3C
EQUATIONS OF STATE .^ 53 3.4 SUMMARY OF THERMODYNAMIC RELATIONSHIPS 54
3.4A PARTIAL DERIVATIVES 54 3.4B JACOBIANS AND PARTIAL DERIVATIVES 56 4.
OBSERVABLE PROPERTIES 57 4.1 INTENSIVE PROPERTIES 57 4.1A CHEMICAL
COMPOSITION 57 4.1B TEMPERATURE 59 4.1C PRESSURE 61 4.2 VOLUME
PROPERTIES 63 4.2A VOLUME AND DENSITY 63 4.2B THERMAL EXPANSION
COEFFICIENT 65 4.2C COMPRESSIBILITIES 66 4.2D THERMAL EXPANSION
COEFFICIENT VS. COMPRESSIBILITY .. 67 4.2E GRIINEISEN PARAMATER AND
ADIABATIC PROCESSES 68 4.3 HEAT CAPACITY AND ENTHALPY 69 4.3A HEAT
CAPACITY 69 4.3B RELATIVE ENTHALPY 73 4.4 ENTROPY AND NERNST S LAW 74
4.4A RELATIVE ENTROPY 74 4.4B NERNST S LAW 75 4.4C RESIDUAL ENTROPY OF
GLASSES AND DISORDERED CRYSTALS 76 4.5 HEATS OF TRANSFOMATION 77 4.5A
HEAT OF REACTION, CYCLE 77 4.5B ENTHALPY OF FORMATION 79 4.5C STANDARD
STATE OF THE ELEMENTS 80 4.6 GIBBS FREE ENERGY 81 4.6A GIBBS FREE ENERGY
AT 1 BAR 81 4.6B GIBBS FREE ENERGY OF FORMATION 81 4.6C GIBBS FREE
ENERGY AT HIGH PRESSURE AND TEMPERATURE 81 XIV CONTENTS 4.7
THERMODYNAMIC DATA 83 4.7A THERMODYNAMIC TABLES 83 4.7B EMPIRICAL
ESTIMATIONS OF THERMODYNAMIC PROPERTIES 83 5. EQUATIONS OF STATE 87 5.1
IDEAL GASES 87 5.1A IDEAL GAS LAW AND ABSOLUTE TEMPERATURE 88 5.1B
VALIDITY OF THE IDEAL GAS LAW 90 5.2 PROPERTIES AND TRANSFORMATIONS OF
AN IDEAL GAS 91 5.2A COEFFICIENTS 92 5.2B INTERNAL ENERGY AND ENTHALPY
92 5.2C REVERSIBLE ISOTHERMAL EXPANSION 92 5.2D IRREVERSIBLE ISOTHERMAL
EXPANSION 93 5.2E REVERSIBLE ADIABATIC EXPANSION 93 5.2F IRREVERSIBLE
ADIABATIC EXPANSION 94 5.2G CARNOT CYCLES 94 5.3 REAL FLUIDS 97 5.3A
VAPOR AND LIQUID PHASES 97 5.3B CRITICAL POINT 98 5.3C VAN DER WAALS
EQUATION 101 5.3D PRINCIPLES OF CORRESPONDING STATES 103 5.3E
CONDENSATION 104 5.4 REAL GASES 106 5.4A SOME OTHER PROPERTIES 106 5.4B
A FEW EQUATIONS OF STATE 107 5.4C MIXING LAWS 110 5.4D JOULE-THOMSON
EXPANSION ILL - 5.5 CONDENSED PHASES 112 5.5A EMPIRICAL EQUATIONS 113
5.5B FINITE STRAIN EQUATIONS 115 5.5C TEMPERATURE EFFECTS 118 5.5D
CONVECTION AND ADIABATIC GRADIENT 120 6. CONFIGURATIONAL CHANGES 123 6.1
CONFIGURATIONS 123 6.1A TEMPERATURE AND PRESSURE EFFECTS 123 6.1B A FEW
EXAMPLES 124 6.1C ENERGIES OF TRANSFORMATION 128 6.ID CONFIGURATIONAL
HEAT CAPACITY 129 CONTENTS XV 6.1E CONFIGURATIONAL VS. VIBRATIONAL
CONTRIBUTIONS 130 6.2 EQUILIBRIUM PHASE TRANSITIONS 130 6.2A FIRST-ORDER
AND CONTINUOUS TRANSITIONS 130 6.2B CRITICAL EXPONENTS OF FLUIDS 133
6.2C ORDER PARAMETERS 136 6.2D RENORMALIZATION GROUP THEORY 137 6.2E
LANDAU THEORY 138 6.3 KINETIC TRANSITIONS 143 6.3A NERNST S LAW AND
INTERNAL DISEQUILIBRIUM 143 6.3B RELAXATION TIMES 144 6.3C VIBRATIONAL
VS. CONFIGURATIONAL RELAXATION 145 6.4 GLASS TRANSITION 147 6.4A A
SCHEMATIC DESCRIPTION 147 6.4B GLASS TRANSITION TEMPERATURE 149 6.4C
KAUZMANN PARADOX 150 6.4D FICTIVE TEMPERATURE 152 6.4E PERMANENT
COMPACTION OF GLASSES 154 6.4F GLASS-LIKE TRANSITIONS 155 7. CRITERIA
FOR CHEMICAL EQUILIBRIUM 159 7.1 CHEMICAL REACTIONS 159 7.1A ADVANCEMENT
OF A REACTION 159 7.1B AFFINITY 160 7.2 EQUILIBRIA 162 7.2A STABILITY OF
EQUILIBRIA 162 7.2B EQUILIBRIUM CRITERIA 162 7.2C EQUIVALENCE OF THE
CRITERIA FOR CHEMICAL EQUILIBRIUM 164 7.3 PHASE SEPARATION 166 7.3A
GIBBS FREE ENERGY AND UNMIXING 166 7.3B SOLVUS AND SPINODAL 169 7.3C
PHASE SEPARATION MECHANISMS 170 7.3D UNMIXING AS A CRITICAL PHENOMENON
171 8. EQUILIBRIUM AND CHEMICAL POTENTIALS 173 8.1 PREAMBLE 173 8.1A
INTEGRATION PATHS OF CHEMICAL POTENTIALS 173 8.1B STANDARD STATE AND
CHEMICAL POTENTIAL 175 8.1C STANDARD AFFINITY REACTION 175 8.2 IDEAL GAS
176 XVI CONTENTS 8.2A CHEMICAL POTENTIAL OF AN IDEAL GAS 176 8.2B IDEAL
GAS MIXTURES 176 8.2C ENTROPY OF MIXING 178 8.3 MASS ACTION LAW 179 8.3A
CHEMICAL EQUILIBRIA BETWEEN IDEAL GASES 179 8.3B TEMPERATURE DEPENDENCE
OF EQUILIBRIUM CONSTANTS .. 180 8.3C THE AFFINITY AS A DRIVING FORCE OF
REACTIONS 181 8.4 REAL GASES 182 8.4A FUGACITY OF A REAL GAS 182 8.4B
FUGACITIES IN A GAS MIXTURE 184 8.4C EQUILIBRIUM BETWEEN REAL GASES 185
8.5 CONDENSED PHASES 186 8.5A ACTIVITY 186 8.5B ACTIVITY IN SOLID OR
LIQUID SOLUTIONS 187 8.5C ACTIVITY MEASUREMENTS: AN EXAMPLE 188 8.5D
INTEGRATION OF THE GIBBS-DUHEM EQUATION 189 8.6 GENERAL EQUILIBRIUM 191
8.6A ACTIVITIES AND,STANDARD CHEMICAL POTENTIALS 191 8.6B IDEAL
SOLUTIONS 192 8.6C GENERAL EXPRESSION FOR AN EQUILIBRIUM CONSTANT 193
8.6D GIBBS FREE ENERGY MINIMIZATIONS 193 9. PHASE RULE AND SIMPLE
UNIVARIANT EQUILIBRIA .. 197 9.1 PHASE RULE 197 9.1A VARIANCE 197 9.1B
INDEPENDENT COMPONENTS 198 9.1C REPRESENTATIONS OF COMPOSITION 199 9.1D
LEVER RULE 200 9.2 UNARY SYSTEMS 201 9.2A EQUILIBRIUM CURVES AND TRIPLE
POINTS 201 9.2B POLYMORPHISM 202 9.2C VAPOR PRESSURE 203 9.2D EFFECT OF
AN INERT GAS ON VAPOR PRESSURE 205 9.3 SIMPLE UNIVARIANT EQUILIBRIA 206
9.3A CLAPEYRON EQUATION 206 9.3B LE CMTELIER S LAWS 207 9.3C ENTHALPIES
AND ENTROPIES OF TRANSFORMATION 208 9.3D EQUILIBRIUM BETWEEN SOLIDS 209
9.3E GENERAL CALCULATION OF AN EQUILIBRIUM CURVE 209 9.3F EXPERIMENTAL
TEST OF NERNST S LAW 211 9.3G TEMPERATURE-FUGACITY DIAGRAMS 212 CONTENTS
XVII 10. BINARY PHASE DIAGRAMS 215 10.1 SOLUBILITY ...- 215 10.1A
PRELIMINARY REMARKS 215 10.1B SOLIDS, LIQUIDS AND GASES 216 10.2
EUTECTIC DIAGRAMS 218 10.2A GRAPHICAL REPRESENTATION 218 10.2B
CALCULATION 221 10.3 SPINDLE-LIKE DIAGRAMS 223 10.3A GRAPHICAL
REPRESENTATION 223 10.3B CALCULATION 224 10.3C LIQUID-VAPOR EQUILIBRIA
225 10.4 PARTIAL SOLUBILITIES 227 10.4A GIBBS FREE ENERGY OF MIXING 227
10.4B SPINODAL, CRITICAL POINT AND SOLVUS CALCULATIONS .. 228 10.4C
CRITICAL MIXING TEMPERATURES 231 10.5 AZEOTROPES, FRACTIONATION 232
10.5A AZEOTROPES 232 10.5B PARTITION COEFFICIENTS, CHEMICAL
FRACTIONATION .... 234 10.5C NERNST PARTITION LAW 236 10.6 VARIATIONS ON
BINARY THEMES 236 10.6A FROM EUTECTICS TO SPINDLE-LIKE DIAGRAMS, THE
RABBIT EARS 236 10.6B FORMATION OF INTERMEDIATE COMPOUNDS 239 10.6C
CONGRUENCY, INCONGRUENCY 240 10.6D MULTICOMPONENT SYSTEMS 241 10.7
PRESSURE EFFECTS 242 10.7A COMPOSITION AND TEMPERATURE OF CRITICAL
MIXING 242 10.7B EUTECTIC EQUILIBRIUM 243 11. SOLUTIONS AND SOLUTION
MODELS 245 11.1 ENTROPY IN IDEAL SOLUTIONS 245 11.1A CONFIGURATIONAL
ENTROPY IN A CRYSTAL 245 11.1B CONFIGURATIONAL ENTROPY IN GASES AND
LIQUIDS ... 248 11.2 MIXING AND EXCESS PROPERTIES 249 11.2A MIXING
PROPERTIES 249 11.2B PARTIAL MOLAR MIXING PROPERTIES 250 11.2C EXCESS
PROPERTIES 251 11.2D A FAMILY OF ACTIVITY COEFFICIENTS 252 11.2E
STANDARD STATES: SOLUTES VS. SOLVENTS 253 11.2F A NEW LOOK AT
EQUILIBRIUM CONSTANTS 256 XVIII CONTENTS 11.3 COLLIGATIVE PROPERTIES 257
11.3A OSMOTIC PRESSURE 257 11.3B RAOULT S LAWS 259 11.4 GENERAL SOLUTION
MODELS 260 11.4A HENRY S LAW 260 11.4B REGULAR SOLUTIONS 262 11.4C
SERIES EXPANSIONS 263 11.4D EXTENSION TO MULTICOMPONENT SYSTEMS 264 11.5
OTHER SOLUTION MODELS 265 11.5A TEMKIN MODEL 266 11.5B RECIPROCAL AND
MULTISITE SOLUTIONS 266 11.5C ACTIVITY IN A MULTISITE SOLUTION 268 11.5D
FLORY-HUGGINS MODEL 270 11.5E ATHERMAL SOLUTIONS 270 11.6 ELECTROLYTES
271 11.6A IONIC DISSOCIATION AND SPECIATION 271 11.6B IONIC ACTIVITIES
273 11.6C IONIC ACTIVITY COEFFICIENTS 274 11.6D OSMOTIC COEFFICIENT 275
11.6E DEBYE-HUCKEL MODEL 277 11.6F PITZER MODEL 279 12. EQUILIBRIA IN
ELECTROLYTE SOLUTIONS 285 12.1 ACIDS AND BASES 285 12.1A CONJUGATE
SPECIES 285 12.1B HYDROGEN POTENTIAL (PH) 286 12.1C WATER IONIZATION 287
12. ID ACTIVE AND INACTIVE SPECIES 288 12.1E EQUILIBRIUM CONSTANTS 289
12.2 PH CALCULATIONS 290 12.2A PRINCIPLE 290 12.2B SILLEN DIAGRAMS 290
12.2C MULTIPLE ACID-BASE FUNCTIONS 293 12.3 IONS: STANDARD PROPERTIES
AND INTERACTIONS IN SOLUTION ... 294 12.3A STANDARD STATE OF IONS : 294
12.3B STANDARD PROPERTIES OF IONS: THE EXAMPLE OF THE HYDROXYL ION 295
12.3C COMPLEXATION REACTIONS 296 12.3D SOLUBILITY PRODUCT 298 12.4 REDOX
REACTIONS 299 12.4A OXIDANTS AND REDUCTANTS 299 12.4B HALF REACTIONS 300
CONTENTS XIX 12.4C ELECTROCHEMICAL CELLS 301 12.4D GIBBS FREE ENERGY OF
REACTION AND NERNST S EQUATION 304 12.4E RELATIVE ELECTRODE POTENTIALS
305 12.4F POTENTIAL-PH DIAGRAMS 307 12.4G ON THE MISUSE OF MATHEMATICS
IN CHEMICAL THERMODYNAMICS 309 13. BASICS OF STATISTICAL MECHANICS 313
13.1 A PRIMER WITH IDEAL GASES 313 13.1A PREAMBLE 313 13.1B KINETIC
MODEL OF AN IDEAL MONOTONIC GAS 314 13.1C VELOCITY DISTRIBUTION IN AN
IDEAL GAS 317 13. ID EQUIPARTITION OF ENERGY 320 13.2 STATE OF A
MICROSCOPIC SYSTEM 321 13.2A PHASE SPACE, ERGODICITY 321 13.2B WAVE
FUNCTION 321 13.2C SCHRODINGER EQUATION 322 13.2D WAVE FUNCTION
CALCULATION: PARTICLE IN TRANSLATION 323 13.2E FACTORIZATION OF THE WAVE
FUNCTION 324 13.3 COUNTING OF STATES 325 13.3A LOCALIZED AND
NONLOCALIZED PARTICLES 325 13.3B DISTINGUISHABILITY,
INDISTINGUISHABILITY 325 13.3C DENSITY OF STATES 326 13.4
MAXWELL-BOLTZMANN STATISTICS 327 13.4A ENSEMBLES 328 13.4B ANALOG OF
ENTROPY 329 13.4C MAXWELL-BOLTZMANN DISTRIBUTION LAW 330 13.4D ANALOG OF
HELMHOLTZ FREE ENERGY 331 13.4E TEMPERATURE AND ENTROPY 332 13.4F
NEGATIVE TEMPERATURES 333 13.4G ENTROPY AND INFORMATION 334 13.5
APPLICATIONS OF THE MAXWELL-BOLTZMANN STATISTICS 335 13.5A PARTITION
FUNCTION 335 13.5B THERMODYNAMIC PROPERTIES 336 13.5C FACTORIZATION OF
PARTITION FUNCTIONS 337 13.5D HEAT CAPACITY OF TWO-LEVEL SYSTEMS 338
13.5E EQUILIBRIUM BETWEEN IDEAL GASES 339 13.6 QUANTUM STATISTICS *. 341
13.6A PROBABILITY LAWS 341 13.6B FERMI-DIRAC STATISTICS 341 13.6C
BOSE-EINSTEIN STATISTICS 343 XX CONTENTS 13.6D COMPARISON WITH
MAXWELL-BOLTZMANN STATISTICS .. 343 13.6E BLACK-BODY RADIATION 345 13.6F
PLANCK S DISTRIBUTION LAW 346 14. THEORETICAL CALCULATIONS OF
THERMODYNAMIC PROPERTIES 351 14.1 ENERGIES AND PARTITION FUNCTIONS 351
14.1A PREAMBLE 351 14.1B TRANSLATIONS 353 14.1C RIGID ROTATOR 354 14.1D
HARMONIC OSCILLATOR 356 14.2 IDEAL GASES 358 14.2A INTERNAL AND
ELECTRONIC DEGREES OF FREEDOM 358 14.2B MONOATOMIC GASES 358 14.2C
DIATOMIC GASES 359 14.2D POLYATOMIC GASES 362 14.3 CRYSTALS 365 14.3A
VIBRATIONAL DENSITY OF STATES 365 14.3B EINSTEIN S MODEL 367 14.3C
DULONG AND PETIT S LAW 368 14.3D DEBYE S MODEL 369 14.3E DEBYE-EINSTEIN
MODELS 374 14.3F LATTICE DYNAMICS 374 14.4 NUMERICAL SIMULATIONS 376
14.4A POTENTIALS, STRUCTURE AND PROPERTIES 376 14.4B COMPRESSIBILITY OF
CRYSTALS 377 14.4C INTERATOMIC POTENTIALS 378 14.4D MONTE CARLO
SIMULATIONS 380 14.4E MOLECULAR DYNAMICS SIMULATIONS 381 14.4F AB INITIO
CALCULATIONS 384 15. ISOTOPIC EQUILIBRIA 387 15.1 ISOTOPIC REACTIONS 387
15.1A PREAMBLE 387 15.1B INTERNAL ISOTOPIC EQUILIBRIUM 389 15.1C
EXTERNAL ISOTOPIC EQUILIBRIUM 390 15. ID PARTITIONS FUNCTIONS AND
EQUILIBRIUM CONSTANTS .. 391 15.2 REDUCED PARTITION FUNCTION RATIOS 392
15.2A ELEMENT-SPECIES EQUILIBRIA 392 15.2B DIATOMIC GASEOUS MOLECULES
392 15.2C POLYATOMIC GASEOUS MOLECUES 393 CONTENTS XXI 15.2D CONDENSED
PHASES 394 15.3 ISOTOPIC EQUILIBRIA 394 15.3A ISOTOPE FRACTIONATION AND
ZERO POINT ENERGY 394 15.3B ISOTOPIC EQUILIBRIUM CONSTANTS 395 15.3C
SERIES EXPANSIONS 396 15.4 ISOTOPE FRACTIONATION 398 15.4A ISOTOPE
PARTITIONING 398 15.4B ENVIRONMENTAL APPLICATION OF ISOTOPIC EQUILIBRIA
400 APPENDICES 403 A. MATHEMATICAL COMPLEMENTS 403 A.I STATE FUNCTIONS
AND EXACT DIFFERENTIALS 403 A.2 RELATIONS BETWEEN PARTIAL DERIVATIVES
404 A.3 HOMOGENEOUS FUNCTIONS 406 B. ADIABATIC COMPRESSIBILITIES 409 B.I
ACOUSTIC WAVES 409 B.2 FLUIDS 410 B.3 SOLIDS 412 C. SHOCK WAVES AND
EQUATIONS OF STATE 413 C.I SHOCK WAVES 413 C.2 EQUATIONS OF
RANKINE-HUGONIOT AND HUGONIOT 414 C.3 PRESSURE AND VOLUME 415 C.4
PRESSURE, TEMPERATURE AND VOLUME 416 D. MULTICOMPONENT REGULAR AND
SUBREGULAR MODELS 419 D.I REGULAR MODEL 419 D.2 SUBREGULAR MODEL 419 E.
MOLECULAR ENERGIES 421 E.I INTERNAL AND TRANSLATIONAL ENERGY 421 E.2
BORN-OPPENHEIMER APPROXIMATION 421 E.3 VIBRATIONAL AND ROTATIONAL
ENERGIES 422 REFERENCES 427 INDEX 435
|
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| discipline | Physik |
| format | Book |
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| id | DE-604.BV014031256 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T18:56:24Z |
| institution | BVB |
| isbn | 0306465841 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-009606741 |
| oclc_num | 46240337 |
| open_access_boolean | |
| owner | DE-703 DE-634 |
| owner_facet | DE-703 DE-634 |
| physical | XXVII, 442 S. graph. Darst. |
| publishDate | 2001 |
| publishDateSearch | 2001 |
| publishDateSort | 2001 |
| publisher | Kluwer Acad./Plenum Publ. |
| record_format | marc |
| spelling | Richet, Pascal Verfasser aut The physical basis of thermodynamics with applications to chemistry Pascal Richet New York [u.a.] Kluwer Acad./Plenum Publ. 2001 XXVII, 442 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Termodinâmica larpcal Thermodynamics Thermodynamik (DE-588)4059827-5 gnd rswk-swf Thermodynamik (DE-588)4059827-5 s DE-604 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009606741&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Richet, Pascal The physical basis of thermodynamics with applications to chemistry Termodinâmica larpcal Thermodynamics Thermodynamik (DE-588)4059827-5 gnd |
| subject_GND | (DE-588)4059827-5 |
| title | The physical basis of thermodynamics with applications to chemistry |
| title_auth | The physical basis of thermodynamics with applications to chemistry |
| title_exact_search | The physical basis of thermodynamics with applications to chemistry |
| title_full | The physical basis of thermodynamics with applications to chemistry Pascal Richet |
| title_fullStr | The physical basis of thermodynamics with applications to chemistry Pascal Richet |
| title_full_unstemmed | The physical basis of thermodynamics with applications to chemistry Pascal Richet |
| title_short | The physical basis of thermodynamics |
| title_sort | the physical basis of thermodynamics with applications to chemistry |
| title_sub | with applications to chemistry |
| topic | Termodinâmica larpcal Thermodynamics Thermodynamik (DE-588)4059827-5 gnd |
| topic_facet | Termodinâmica Thermodynamics Thermodynamik |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009606741&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT richetpascal thephysicalbasisofthermodynamicswithapplicationstochemistry |