Inorganic chemistry highlights:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH
2002
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Angekündigt als: Highlights in inorganic chemistry. Hierzu ersch. als Bd. 2 und 3 u.d.T: Inorganic chemistry in focus |
| Beschreibung: | XV, 324 S. Ill., graph. Darst. |
| ISBN: | 3527302654 |
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Datensatz im Suchindex
| _version_ | 1804128859934687232 |
|---|---|
| adam_text | INORGANIC CHEMISTRY HIGHLIGHTS EDITED BY CERD MEYER, DIETER NAUMANN,
LARS WESEMANN WILEY-VCH CONTENTS MOLTEN ZINTL ALLOYS 1 WILLEM VAN DER
LUGT AND PETER VERKERK 1 INTRODUCTION AND SOME TERMINOLOGY 1 2 THE
GRADUAL DEVELOPMENT OF STOICHIOMETRY IN NON-CLUSTERING LIQUID IONIC
ALLOYS 2 3 PHYSICAL PROPERTIES AND DETECTION OF LIQUID ZINTL COMPOUNDS 3
4 NEUTRON DIFFRACTION MEASUREMENTS AND THEIR ANALYSIS: INTRODUCTION 5
NEUTRON DIFFRACTION; ZINTL-KLEMM ALLOYS 8 6 ZINTL-KLEMM ALLOYS:
THEORETICAL CONTRIBUTIONS 11 7 STRUCTURES OF ALKALI-TL AND ALKALI-GA
ALLOYS 12 8 CONCLUSIONS AND FINAL REMARKS 15 STRUCTURE AND BONDING
AROUND THE ZINTL BORDER 21 CORDONJ. MILLER, CHI-SHEN LEE AND WONYOUNG
CHOE 1 INTRODUCTION 21 2 METALS VERSUS NONMETALS: PHYSICAL AND CHEMICAL
PRINCIPLES 23 3 ELEMENTS AT THE ZINTL BORDER 26 4 ELECTRON-COUNTING
RULES 28 5 NEW COMPLEX COMPOUNDS AT THE ZINTL BORDER 35 5.1 LEFT OF THE
ZINTL BORDER FROM HUME-ROTHERY TO ZINTL 35 5.2 RIGHT OF THE ZINTL BORDER
UNSATURATED BONDING AND INTERNAL REDOX PROCESSES 43 6 FURURE DIRECTIONS
AND SUMMARY 50 STRUCTURE PREDICTION AND DETERMINATION OF CRYSTALLINE
COMPOUNDS 55 J. CHRISTIAN SCHOEN AND MARTIN JANSEN 1 INTRODUCTION 55 2
GENERAL APPROACH TO STRUCTURE PREDICTION 56 2.1 FUNDAMENTALS 56 2.2
MODULAR APPROACH 57 2.3 EXAMPLES 58 VI CONTENTS 3.3 INVESTIGATIONS OF
RESTRICTED LANDSCAPES 61 3.3.1 ALTERNATIVE METHODS FOR GENERATION OF
CANDIDATE STRUCTURES 61 3.3.2 MOLECULAR CRYSTALS 62 3.4 STRUCTURE
DETERMINATION 65 3.4.1 RESTRICTED EXPLORATION OF THE ENERGY LANDSCAPE 66
3.4.2 COMBINED OPTIMIZATION 67 3.5 CONCLUDING REMARKS 68 4 MULTIVALENT
CATION CONDUCTORS 71 CIN-YA ADACHI AND NOBUHITO IMANAKA 4.1 INTRODUCTION
71 4.2 DIVALENT CATION CONDUCTORS 72 4.2.1 SS-ALUMINA-TYPE STRUCTURE 72
4.2.2 M 2+ ZR 4 (P0 4 ) 6 76 4.2.3 YP0 4 -BASED COMPOUNDS 84 4.3
TRIVALENT ION CONDUCTORS 85 4.3.1 TRIVALENT CATION CONDUCTORS WITH SS-AL
2 0 3 -TYPE STRUCTURES 85 4.3.2 SS-AL 2 0 3 -RELATED PHASES 89 4.3.3
SS-LANB 3 0 9 90 4.3.4 SC 2 (W0 4 ) 3 -TYPE STRUCTURES 92 4.3.5
PHOSPHATE-BASED TRIVALENT CATION CONDUCTORS 104 4.4 TETRAVALENT CATION
CONDUCTORS 106 4.4.1 SILICON NITRIDE 107 4.4.2 PHOSPHATE-BASED
TETRAVALENT CATION CONDUCTORS 107 4.5 CONCLUSIONS 109 5 THE POTENTIAL OF
PENTAGONAL BUILDING BLOCKS: FROM CIANT RING-SHAPED TO SPHERICAL
POLYOXOMETALATE CLUSTERS 113 LEROY CRONIN 6 MOLYBDENUM PEROXO COMPLEXES
AS CATALYSTS IN OLEFIN EPOXIDATION 123 WERNER R. THIEL 6.1 INTRODUCTION
123 6.2 MECHANISTIC FUNDAMENTALS 126 6.3 PYRAZOLYLPYRIDINE COMPLEXES 127
6.3.1 MECHANISTIC INVESTIGATIONS 128 6.3.2 STRUCTURE/ACTIVITY
RELATIONSHIPS 131 6.3.3 LIGAND FLUXIONALITY 133 7 SYNTHESES OF RARE
EARTH ORGANOMETALIICS, ORGANOAMIDES, AND ARYLOXIDES FROM THE METALS 139
CLEN B. DEACON AND CRAIG M. FORSYTH 7.1 INTRODUCTION 139 7.2 METAL-BASED
SYNTHESES 240 7.2.1 REDOX TRANSMETALATION WITH MERCURY REAGENTS 140
7.2.2 REDOX TRANSMETALATION WITH THALLIUM(I) REAGENTS 142 7.2.3 REDOX
TRANSMETALATION/LIGAND-EXCHANGE 144 7.2.4 SYNTHESIS OF LANTHANOID
TRICHLORIDES 246 7.2.5 THE DIRECT REACTION OF RARE EARTH METALS WITH
WEAK PROTIC REAGENTS AT ELEVATED TEMPERATURES. 247 7.3 CONCLUSIONS 252 8
ENZYME STRUCTURES: ACTIVE SITE STRUCTURAL AND FUNCTIONAL ASPECTS OF
PURPLE ACID PHOSPHATASE AND CATECHOL OXIDASE 255 ANNETTE ROMPEL, CARSTEN
GERDEMANN, ANDREAS VOGEL, AND BERNT KREBS 8.1 INTRODUCTION: AIM AND
PURPOSE OF BIOINORGANIC CHEMISTRY 255 8.2 PURPLE ACID PHOSPHATASES 255
8.2.1 THE CRYSTAL STRUCTURE OF A PLANT PURPLE ACID PHOSPHATASE (KBPAP)
CONTAINING A DINUCLEAR IRON-ZINC CENTER 256 8.2.2 COMPARISONOF MAMMALIAN
AND PLANT PAP STRUCTURE 258 8.2.3 REACTION MECHANISM 259 8.2.4
PHYSIOLOGICAL ROLE 260 8.3 CATECHOL OXIDASE 260 8.3.1 THE CRYSTAL
STRUCTURE OF A PLANT CO (IBCO) CONTAINING A DINUCLEAR COPPER CENTER 262
8.3.2 COMPARISON OF THE CO STRUCTURE WITH DIFFERENT HC STRUCTURES 263
8.3.3 REACTION MECHANISM 264 8.3.4 PHYSIOLOGICAL ROLE 266 9.1
INTRODUCTION 272 9 AMINOTROPONIMINATES AS LIGANDS FOR CROUP 3 AND
LANTHANIDE COMPLEXES - COORDINATION CHEMISTRY AND CATALYSIS 272 PETER W.
ROESKY 9.2 LIGAND SYNTHESIS 272 9.3 METAL COMPLEXES 273 9.3.1 COMPLEXES
OF N,N -DISUBSTITUTED AMINOTROPONIMINATES 273 9.3.2 COMPLEXES OF
MONO-BRIDGED BIS-AMINOTROPONIMINATES 276 9.4 SUMMARY 279 VIII CONTENTS
10 METALLA-CALIX[4]ARENES: HOW THEY ASSIST THE TRANSFORMATIONS OF
HYDROCARBONS INTO METALLA-ALKYLIDENES, OF DINITROGEN INTO
METALLA-NITRIDES, AND OF CARBON MONOXIDE INTO METALLA-CARBIDES 181 CARLO
FLORIANI 10.1 TOPIC OF THIS CHAPTER 181 10.2 INTRODUCTION 182 10.3 THE
SYNTHESIS AND THE CHEMISTRY OF METAL-ALKYLIDENE AND METAL- ALKYLIDYNE
FUNCTIONALITIES 183 10.4 REDUCTIVE CLEAVAGE OF DINITROGEN TO NITRIDES,
AND OF CARBON MONOXIDE TO CARBIDES 188 11 METAL CARBONYL CATIONS AND
THEIR DERIVATIVES - A NEW CLASS OFSUPERELECTROPHILES 195 HELGE WILLNER
AND FRIEDHELM AUBKE 12 BORYLENE COMPLEXES 213 HOLGER BRAUNSCHWEIG 12.1
INTRODUCTION 213 12.2 BRIDGED BORYLENE COMPLEXES 213 12.3 TERMINAL
BORYLENE COMPLEXES 216 13 SILABORANES 219 LARS WESEMANN 14 CARBAALANES -
A NEW CLASS OF COMPOUNDS CONTAINING CLUSTERS OF ALUMINIUM AND CARBON
ATOMS 229 WERNER UHL 14.1 INTRODUCTION 229 14.2 SYNTHESIS OF CARBAALANES
230 14.3 STRUCTURES 233 14.4 SPECTROSCOPIC FINDINGS 237 14.5
QUANTUM-CHEMICAL CALCULATIONS 239 14.6 CHEMICAL REACTIVITY 240 14.7
CONCLUDING REMARKS 242 15 MOLECULAR ALUMINIUM AND GALLIUM SUBHALIDES 245
HANSGEORG SCHNOECKEL AND CHRISTOPH KLEMP 15.1 INTRODUCTION 245 15.2
SYNTHESIS 246 15.3 PRODUCTS 247 15.3.1 [MX] N SPECIES 247 15.3.2 M 2 X4
SPECIES 248 CONTENTS IX 15.3.3 M3X5 SPECIES 250 15.3.4 M4X 6 SPECIES 251
15.3.5 M 5 X 7 SPECIES 251 15.3.6 AL 22 BR 20 AND A1 14 I 6 R 52
SPECIES 254 15.4 CONCLUSION 255 16 RECENT DEVELOPMENTS IN THE CHEMISTRY
OF COVALENT MAIN CROUP AZIDES 259 WOLFGANG FRAENK AND THOMAS M. KTAPOETKE
16.1 INTRODUCTION 259 16.2 GROUP 13 AZIDES 259 16.2.1 BORON AZIDES 259
16.2.2 ALUMINIUM, GALLIUM, AND INDIUM AZIDES 265 16.3 GROUP 14 AZIDES
267 16.3.1 CARBON AZIDES 267 16.3.2 GERMANIUM AZIDES 268 16.4 GROUP 15
AZIDES 271 16.4.1 THE N5 CATION AND HYDROGEN DIAZIDE 271 16.4.2 ARSENIC
AZIDES 272 16.4.3 ANTIMONY AND BISMUTH AZIDES 273 16.5 GROUP 16 AZIDES
273 16.5.1 THE REACTION BETWEEN OF 2 AND CSN 3 273 16.5.2 TELLURIUM
AZIDES 275 16.6 GROUP 17 AZIDES 275 16.7 UPDATE 276 17
SILACALIX-[N]-PHOSPHININES: SP 2 -PHOSPHORUS EQUIVALENTS OF CO MATRICES
279 NICOLAS MAEZAILLES, FRANGOIS MATHEY, AND PASCAL LE FLOCH 18 USING
DINITROGEN AS A RAW MATERIAL: IS THERE A FUTURE? 285 SANDRO CAMBAROTTA
18.1 INTRODUCTION 285 18.2 FORMATION OFNH 3 2 SS 18.3 N 2 REDUCTION 287
18.4 CATALYSIS 288 18.5 COOPERATIVE N 2 REDUCTION 290 18.6 CONCLUSION
293 19 ORGANOXENON COMPOUNDS 297 WIELAND TYRRA AND DIETER NAUMANN 19.1
INTRODUCTION 297 19.2 EVIDENCE FOR XENON-CARBON COMPOUNDS 298 19.3
SYNTHETIC METHODS FOR THE PREPARATION OF ORGANOXENON(II) COMPOUNDS 299 X
I CONTENTS 19.3.1 PREPARATION OF ORGANOXENON(II) FLUOROBORATES FROM
ORGANOBORANES AND XENON DIFLUORIDE 299 19.3.2 SYNTHESIS OF ARYLXENON(II)
TRIFLUOROMETHANESULFONATES THROUGH ELECTROPHILIC AROMATIC SUBSTITUTION
REACTIONS 301 19.3.3 DIRECT ACCESS TO XE(C 6 F 5 ) 2 304 19.3.4 LIGAND
EXCHANGE REACTIONS OF FLUOROPHENYKENON COMPOUNDS 306 19.3.5 SYNTHESIS OF
ALKENYLXENON DERIVATIVES BY FLUORINATION OF ARYLXENON COMPOUNDS 307
19.3.6 XENON(IV)-CARBON COMPOUNDS 308 19.4 CRYSTALLOGRAPHIC AND
SPECTROSCOPIC CHARACTERISTICS OF ORGANOXENON COMPOUNDS 309 19.4.1
CRYSTALLOGRAPHIC DATA 309 19.4.2 NMRSPECTRA 311 19.4.3 VIBRATIONAL
SPECTRA 311 19 AA MASS SPECTRA 311 19.5 REACTIONS OF ORGANOXENON
COMPOUNDS 312 INDEX 317
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| id | DE-604.BV014004861 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T18:55:57Z |
| institution | BVB |
| isbn | 3527302654 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-009587398 |
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| physical | XV, 324 S. Ill., graph. Darst. |
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| spelling | Inorganic chemistry highlights ed. by Gerd Meyer ... Highlights in inorganic chemistry Weinheim Wiley-VCH 2002 XV, 324 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Angekündigt als: Highlights in inorganic chemistry. Hierzu ersch. als Bd. 2 und 3 u.d.T: Inorganic chemistry in focus Chemistry, Inorganic Anorganische Chemie (DE-588)4002145-2 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Aufsatzsammlung - Anorganische Chemie Anorganische Chemie (DE-588)4002145-2 s DE-604 Meyer, Gerd 1949- Sonstige (DE-588)131930915 oth GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009587398&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Inorganic chemistry highlights Chemistry, Inorganic Anorganische Chemie (DE-588)4002145-2 gnd |
| subject_GND | (DE-588)4002145-2 (DE-588)4143413-4 |
| title | Inorganic chemistry highlights |
| title_alt | Highlights in inorganic chemistry |
| title_auth | Inorganic chemistry highlights |
| title_exact_search | Inorganic chemistry highlights |
| title_full | Inorganic chemistry highlights ed. by Gerd Meyer ... |
| title_fullStr | Inorganic chemistry highlights ed. by Gerd Meyer ... |
| title_full_unstemmed | Inorganic chemistry highlights ed. by Gerd Meyer ... |
| title_short | Inorganic chemistry highlights |
| title_sort | inorganic chemistry highlights |
| topic | Chemistry, Inorganic Anorganische Chemie (DE-588)4002145-2 gnd |
| topic_facet | Chemistry, Inorganic Anorganische Chemie Aufsatzsammlung Aufsatzsammlung - Anorganische Chemie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009587398&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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