Mutual interaction effects between electronic defect states and molecular ions in alkali halides:
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| Main Author: | |
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| Format: | Book |
| Language: | English |
| Published: |
2000
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| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Paderborn, Univ., Habil.-Schr., 2001 |
| Physical Description: | VIII, 229 S. graph. Darst. : 31 cm |
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| 245 | 1 | 0 | |a Mutual interaction effects between electronic defect states and molecular ions in alkali halides |c vorgelegt von Volkmar Dierolf |
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| 300 | |a VIII, 229 S. |b graph. Darst. : 31 cm | ||
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| 337 | |b n |2 rdamedia | ||
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| 500 | |a Paderborn, Univ., Habil.-Schr., 2001 | ||
| 650 | 4 | |a Alkalihalogenide - Gitterbaufehler - Elektronenzustand - Molekülion - Wechselwirkung | |
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Record in the Search Index
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| adam_text |
CONTENTS
1 INTRODUCTION AND HISTORICAL OVERVIEW 1
1.1
THE INITIAL IDEA.
1
1.2
THE UNEXPECTED NEW RESULTS. 2
1.3 THE DREAM COMES TRUE.
3
1.4 WHAT TO EXPECT? .
3
2
PROPERTIES OF MOLECULAR DEFECTS 7
2.1 TRANSITION ENERGIES.
7
2.2
ABSORPTION INTENSITY AND OSCILLATOR STRENGTHS. .
10
2.3 MOLECULES IN ALKALI HALIDES. 15
3
THEORETICAL MODELS FOR THE E-V TRANSFER 17
3.1 FORSTER-DEXTER TYPE MODELS . 20
3.2 ELECTRONIC-VIBRATIONAL COUPLING MODELS. 23
3.3 COMPARISON. 30
3.4 POTENTIAL ENERGY SURFACES. 32
4
F CENTER RELATED DEFECTS: OVERVIEW 35
5
FJJ(CN") CENTERS 37
5.1 REVIEW OF PREVIOUS STUDIES.
37
5.2 DETERMINATION OF THE E-V TRANSFER RATES. 41
5.3 V-E ENERGY TRANSFER. 48
5.4 VIBRATIONAL COUPLING OF F CENTERS TO THE CN" STRETCH-MODE . 48
5.5 THE NATURE OF THE RELAXED EXCITED STATE.
53
5.6 PUTTING ALL TOGETHER: COMPARING E-V TRANSFER RATES WITH THEORETICAL
MODELS.
54
V
BIBLIOGRAFISCHE INFORMATIONEN
HTTP://D-NB.INFO/962271799
CONTENTS
6 CN
- NEXT TO AN ANION VACANCY OCCUPIED BY NONE OR TWO ELECTRONS 59
6.1 BACKGROUND. 59
6.2 EXPERIMENTAL RESULTS. 60
6.3 CREATION KINETICS . 63
6.4 SHIFT IN SPECTRAL POSITION. 64
6.5 CHANGES IN ABSORPTION CROSS-SECTION. 64
7 F
H(OH-) CENTERS 67
7.1 CS HALIDES. 67
7.2 FJJ
2 CENTER. 72
7.3 K AND RB-HALIDES: OPTICAL BISTABILITY. 72
7.4 E-V ENERGY TRANSFER. 83
7.5 DYNAMIC PROPERTIES. 84
8 INTERACTION BETWEEN F ELECTRONS AND DISTANT OH" MOLECULES 87
8.1 THE MAIN IDEA. 87
8.2 OH
- DEFECTS WITH A CAPTURED EXTRA ELECTRON . 89
8.3 VIBRATIONAL PROPERTIES OF MOLECULAR ELECTRON TRAPS. 93
8.4 ELECTRON TRAPPING BY OH~-PAIRS . 98
8.5 ELECTRON TUNNELING FROM F CENTERS TO OH
- RELATED DEFECTS.100
8.6
E-V TRANSFER BETWEEN DISTANT F-CENTERS AND OH_DEFECTS.102
8.7 CONCLUSIONS AND OUTLOOK.103
8.8
VIBRATIONAL LUMINESCENCE OF OH- TYPE CENTERS IN CSL.104
9 YTTERBIUM AND CN" MOLECULES 107
9.1 CRYSTAL GROWTH AND SAMPLE CHARACTERIZATION.108
9.2 THE ISOLATED YB
2+ ION IN ALKALI HALIDES.109
9.3 ELECTRONIC TRANSITIONS OF YB
2+ IONS WITHIN YB2+:(CN-)YY DEFECT COM
PLEXES .113
9.4 POSSIBLE APPLICATION AS A PHOSPHOR.119
9.5 VIBRATIONAL TRANSITIONS OF CN" MOLECULES WITHIN YB
2+:(CN")N COM
PLEXES .122
9.6 OPTICALLY INDUCED BISTABILITY.129
9.7 INTERPRETATION OF THE SPECTRAL SHIFTS.133
9.8 CENTER MODEL.139
9.9 VIBRATIONAL LUMINESCENCE AND E-V ENERGY TRANSFER.142
VI
CONTENTS
9.10 DYNAMIC OF THE E-V TRANSFER.147
9.11 PROPERTIES OF YB2+ IONS WITH EXCITED CN" NEIGHBORS.156
9.12 PUTTING ALL TOGETHER: COMPARING E-V TRANSFER RATES WITH THEORETICAL
MODELS. .162
10 EUROPIUM AND CN
- MOLECULES 167
10.1 ISOLATED EU
2+ DEFECTS. .168
10.2 EU2+:(CN_)N -COMPLEXES.168
10.3 POSSIBLE APPLICATION AS PHOSPHOR.171
10.4 SUMMARY AND INTERPRETATION OF EXPERIMENTAL RESULTS.171
11 SAMARIUM AND CN
- MOLECULES _ 175
11.1
ISOLATED SM2+-DEFECTS. 176
11.2
(SM2+)N-COMPLEXES.179
11.3 COMPLEXES INVOLVING A SINGLE CN~ MOLECULE .181
11.4 COMPLEXES INVOLVING SEVERAL CN- MOLECULES.186
11.5 E-V ENERGY TRANSFER.188
12 OTHER DEFECT COMPLEXES 193
12.1 NS
2 -IONS (TL+, PB2+) AND CN- MOLECULES.193
12.2 CU
+ AND OH- MOLECULES.195
13 SUMMARY 197
BIBLIOGRAPHY 203
LIST OF FIGURES 217
LIST OF TABLES 223
225
VII
INDEX |
| any_adam_object | 1 |
| author | Dierolf, Volkmar |
| author_facet | Dierolf, Volkmar |
| author_role | aut |
| author_sort | Dierolf, Volkmar |
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| bvnumber | BV013983233 |
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| genre_facet | Hochschulschrift |
| id | DE-604.BV013983233 |
| illustrated | Illustrated |
| indexdate | 2024-10-09T18:08:33Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-009572154 |
| oclc_num | 248561775 |
| open_access_boolean | |
| owner | DE-703 DE-706 |
| owner_facet | DE-703 DE-706 |
| physical | VIII, 229 S. graph. Darst. : 31 cm |
| publishDate | 2000 |
| publishDateSearch | 2000 |
| publishDateSort | 2000 |
| record_format | marc |
| spelling | Dierolf, Volkmar Verfasser aut Mutual interaction effects between electronic defect states and molecular ions in alkali halides vorgelegt von Volkmar Dierolf 2000 VIII, 229 S. graph. Darst. : 31 cm txt rdacontent n rdamedia nc rdacarrier Paderborn, Univ., Habil.-Schr., 2001 Alkalihalogenide - Gitterbaufehler - Elektronenzustand - Molekülion - Wechselwirkung Molekülion (DE-588)4039973-4 gnd rswk-swf Alkalihalogenide (DE-588)4226772-9 gnd rswk-swf Wechselwirkung (DE-588)4064937-4 gnd rswk-swf Elektronenzustand (DE-588)4263453-2 gnd rswk-swf Gitterbaufehler (DE-588)4125030-8 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Alkalihalogenide (DE-588)4226772-9 s Gitterbaufehler (DE-588)4125030-8 s Elektronenzustand (DE-588)4263453-2 s Molekülion (DE-588)4039973-4 s Wechselwirkung (DE-588)4064937-4 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009572154&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Dierolf, Volkmar Mutual interaction effects between electronic defect states and molecular ions in alkali halides Alkalihalogenide - Gitterbaufehler - Elektronenzustand - Molekülion - Wechselwirkung Molekülion (DE-588)4039973-4 gnd Alkalihalogenide (DE-588)4226772-9 gnd Wechselwirkung (DE-588)4064937-4 gnd Elektronenzustand (DE-588)4263453-2 gnd Gitterbaufehler (DE-588)4125030-8 gnd |
| subject_GND | (DE-588)4039973-4 (DE-588)4226772-9 (DE-588)4064937-4 (DE-588)4263453-2 (DE-588)4125030-8 (DE-588)4113937-9 |
| title | Mutual interaction effects between electronic defect states and molecular ions in alkali halides |
| title_auth | Mutual interaction effects between electronic defect states and molecular ions in alkali halides |
| title_exact_search | Mutual interaction effects between electronic defect states and molecular ions in alkali halides |
| title_full | Mutual interaction effects between electronic defect states and molecular ions in alkali halides vorgelegt von Volkmar Dierolf |
| title_fullStr | Mutual interaction effects between electronic defect states and molecular ions in alkali halides vorgelegt von Volkmar Dierolf |
| title_full_unstemmed | Mutual interaction effects between electronic defect states and molecular ions in alkali halides vorgelegt von Volkmar Dierolf |
| title_short | Mutual interaction effects between electronic defect states and molecular ions in alkali halides |
| title_sort | mutual interaction effects between electronic defect states and molecular ions in alkali halides |
| topic | Alkalihalogenide - Gitterbaufehler - Elektronenzustand - Molekülion - Wechselwirkung Molekülion (DE-588)4039973-4 gnd Alkalihalogenide (DE-588)4226772-9 gnd Wechselwirkung (DE-588)4064937-4 gnd Elektronenzustand (DE-588)4263453-2 gnd Gitterbaufehler (DE-588)4125030-8 gnd |
| topic_facet | Alkalihalogenide - Gitterbaufehler - Elektronenzustand - Molekülion - Wechselwirkung Molekülion Alkalihalogenide Wechselwirkung Elektronenzustand Gitterbaufehler Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009572154&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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