Borabenzene derivatives of main group elements:
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Aachen
Shaker
2001
|
| Series: | Berichte aus der Chemie
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Zugl.: Aachen, Techn. Hochsch., Diss., 2001. - Erscheint: 11. Juli 2001 |
| Physical Description: | IV, 98 S. graph. Darst. : 21 cm |
| ISBN: | 3826590279 |
Staff View
MARC
| LEADER | 00000nam a22000008c 4500 | ||
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| 001 | BV013824483 | ||
| 003 | DE-604 | ||
| 005 | 20011214 | ||
| 007 | t| | ||
| 008 | 010710s2001 gw d||| m||| 00||| eng d | ||
| 016 | 7 | |a 961892668 |2 DE-101 | |
| 020 | |a 3826590279 |9 3-8265-9027-9 | ||
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| 044 | |a gw |c DE | ||
| 049 | |a DE-91 | ||
| 084 | |a CHE 330d |2 stub | ||
| 100 | 1 | |a Zheng, Xiaolai |d 1971- |e Verfasser |0 (DE-588)123079772 |4 aut | |
| 245 | 1 | 0 | |a Borabenzene derivatives of main group elements |c Xiaolai Zheng |
| 264 | 1 | |a Aachen |b Shaker |c 2001 | |
| 300 | |a IV, 98 S. |b graph. Darst. : 21 cm | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 0 | |a Berichte aus der Chemie | |
| 500 | |a Zugl.: Aachen, Techn. Hochsch., Diss., 2001. - Erscheint: 11. Juli 2001 | ||
| 650 | 0 | 7 | |a Borinderivate |0 (DE-588)4223693-9 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Hauptgruppenelementkomplexe |0 (DE-588)4227741-3 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Hauptgruppenelement |0 (DE-588)4122190-4 |2 gnd |9 rswk-swf |
| 655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
| 689 | 0 | 0 | |a Hauptgruppenelement |0 (DE-588)4122190-4 |D s |
| 689 | 0 | 1 | |a Borinderivate |0 (DE-588)4223693-9 |D s |
| 689 | 0 | |5 DE-604 | |
| 689 | 1 | 0 | |a Hauptgruppenelementkomplexe |0 (DE-588)4227741-3 |D s |
| 689 | 1 | 1 | |a Borinderivate |0 (DE-588)4223693-9 |D s |
| 689 | 1 | |5 DE-604 | |
| 856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009454490&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-009454490 | |
Record in the Search Index
| _version_ | 1816444282198818816 |
|---|---|
| adam_text |
CONTENTS
1
GENERAL
BACKGROUND
1
2
NEUTRAL
CARBON-BOUND
BORABENZENE
ADDUCTE
4
2.1
INTRODUCTION
4
2.2
FORMATION
OF
CARBON-BOUND
BORABENZENE
ADDUCTS
5
2.2.1
SYNTHESIS
OF
1
-CHLORO-3,5-DIMETHYL-2-TRIMETHYLSILYL-1,2-DIHYDRO-
BORININE
5
2.2.2
ADDITION
WITH
CARBENE
AND
PHOSPHONIUM
YLIDES
6
2.2.3
NMR
SPECTROSCOPIC
PROPERTIES
8
2.3
STRUCTURES
OF
CARBON-BOUND
BORABENZENE
ADDUCTS
10
2.3.1
STRUCTURE
OF
THE
CARBENE
ADDUCT
10
2.3.2
STRUCTURES
OF
YLIDE
ADDUCTS
11
2.4
THEORETICAL
CALCULATIONS
ON
BORABENZENE
ADDUCTS
14
3
BORATABENZENE
COMPLEXES
OF
ALKALI
METALS
16
3.1
INTRODUCTION
16
3.2
SYNTHESIS
OF
ALKALI
METAL
BORATABENZENE
COMPLEXES
18
3.2.1
SYNTHESIS
OF
POTASSIUM
1-METHYLBORATABENZENE
18
3.2.2
SYNTHESIS
OF
AMINOBORATABENZENE
SALTS
19
3.2.3
FORMATION
OF
LEWIS
BASE
ADDUCTS
21
3.3
STRUCTURES
OF
ALKALI
METAL
BORATABENZENE
COMPLEXES
22
3.3.1
CONTACT
ION-PAIR
22
3.3.2
REGULAR
ZIGZAG
STRUCTURE
23
3.3.3
PSEUDO-POLYMORPHS
WITH
UNUSUAL
CHAIN
MOTIFS
24
3.3.4
POLYMERIC
SANDWICH
STRUCTURE
29
4
BIS(BORATABENZENE)
MAGNESIUM
COMPLEXES
31
4.1
INTRODUCTION
31
4.2
SYNTHESIS
OF
BIS(BORATABENZENE)
MAGNESIUM
COMPLEXES
32
4.2.1
2-TRIMETHYLSTANNYL
SUBSTITUTED
DIHYDROBORININES
32
4.2.2
DONOR-FREE
BIS(BORATABENZENE)
MAGNESIUM
COMPLEXES
34
4.2.3
FORMATION
OF
LEWIS
BASE
ADDUCTS
35
4.3
STRUCTURES
OF
BIS(BORATABENZENE)
MAGNESIUM
COMPLEXES
36
4.3.1
STRUCTURE
OF
MG(3,5-ME2CSH3BNME2)2
36
4.3.2
STRUCTURE
OF
MG(3,5-ME2CSH3BNME2)2(THF)2
38
5
BIS(BORATABENZENE)
COMPLEXES
OF
GROUP
14
METALS
41
5.1
INTRODUCTION
41
5.2
SYNTHESIS
OF
BIS(BORATABENZENE)
COMPLEXES
OF
GROUP
14
METALS
42
5.2.1
METATHESIS
REACTION
42
5.2.2
FORMATION
OF
LEWIS
BASE
ADDUCTS
44
5.2.3
SPECTROSCOPIC
DATA
44
5.3
STRUCTURES
OF
BIS(BORATABENZENE)
COMPLEXES
OF
GROUP
14
METALS
45
5.3.1
BIS(1
-METHYLBORATABENZENE)LEAD
AND
ITS
TETRAMERIC
AGGREGATE
45
5.3.2
STRUCTURES
OF
E[3,5-ME2C
6
H
3
BN(SIME3)2]2
(E
=
GE,
SN,
PB)
47
5.3.3
STRUCTURE
OF
PB(C
5
H
5
BME)2(BIPY)
51
6
CONCLUSION
53
7
EXPERIMENTAL
SECTION
57
7.1
GENERAL
PROCEDURES
57
7.1.1
SYNTHETIC
TECHNIQUES
57
7.1.2
ANALYSES
57
7.1.3
VARIABLE-TEMPERATURE
NMR
SPECTROSCOPY
57
7.1.4
COMPUTATIONAL
DETAILS
58
7.1.5
STARTING
MATERIALS
58
7.2
SYNTHETIC
PROCEDURES
AND
EXPERIMENTAL
DATA
60
7.2.1
3,5-DIMETHYL-1
-DIMETHYLAMINO-2-(TRIMETHYLSILYL)-1,2-DIHYDRO
BORININE
(14)
60
7.2.2
1-CHLORO-3,5-DIMETHYL-2-(TRIMETHYLSILYL)-1,2-DIHYDROBORININE
(15)
60
7.2.3
3,5-DIMETHYLBORABENZENE
1,3,4,5-TETRAMETHYLIMIDAZOL-2-YLIDENE
(17)
61
7.2.4
3,5-DIMETHYLBORABENZENE
TRIPHENYLPHOSPHONIUM
METHYLIDE
(18)
AND
3,5-DIMETHYLBORABENZENE
TRIPHENYLPHOSPHONIUM
(TRIMETHYL
SILYLJMETHYLIDE
(19)
62
7.2.5
3,5-DIMETHYLBORABENZENE
TRIMETHYLPHOSPHINE
(20)
64
II
7.2.6
POTASSIUM
1-METHYLBORATABENZENE
[K(22)]
65
7.2.7
18-CROWN-6
ADDUCT
OF
POTASSIUM
1-METHYLBORATABENZENE
(42)
65
7.2.8
SODIUM
3,5-DIMETHYL-1-(DIMETHYLAMINO)BORATABENZENE
[NA(13)]
66
7.2.9
POTASSIUM
3,5-DIMETHYL-1-(DIMETHYLAMINO)BORATABENZENE
[K(13)]
66
7.2.10
POTASSIUM
1
-BIS(TRIMETHYLSILYLAMINO)-3,5-DIMETHYLBORATABENZENE
[K(39)J
67
7.2.11
3,5-DIMETHYL-1-(MORPHOLINO)DIHYDROBORININES
(37A,
B)
68
7.2.12
LITHIUM
3,5-DIMETHYL-1-(MORPHOLINO)BORATABENZENE
[LI(40)]
69
7.2.13
SODIUM
3,
5-DIMETHYL-1
-(MORPHOLINO)BORATABENZENE
[NA(40)]
70
7.2.14
(S)-3,5-DIMETHYL-1-(2-METHOXYMETHYLPYRROLIDIN-1-YL)DIHYDRO
BORININES
(38A,B)
70
7.2.15
LITHIUM
(S)-3,5-DIMETHYL-1-(2-METHOXYMETHYLPYRROLIDIN-1
YL)BORATABEN-ZENE
[LI(41)J
71
7.2.16
3,5-DIMETHYL-1-(DIMETHYLAMINO)-2-(TRIMETHYLSTANNYL)-1,2-DIHYDRO
BORININE
(49)
72
7.2.17
BIS(1-METHYLBORATABENZENE)MAGNESIUM
(46)
73
7.2.18
BIS[3,5-DIMETHYL-1-(DIMETHYLAMINO)BORATABENZENE]MAGNESIUM
(47)
74
7.2.19
THF
SOLVATE
MG(3,5-ME
2
C5H
3
BNME2)2(THF)2
(48)
75
7.2.20
BIS(1-METHYLBORATABENZENE)LEAD
(50C)
75
7.2.21
BIS[3,5-DIMETHYL-1-(DIMETHYLAMINO)BORATABENZENE]LEAD
(51)
76
7.2.22
BIS[1-BIS(TRIMETHYLSILYL)AMINO-3,5-DIMETHYLBORATABENZENE]GER
MANIUM
(53A)
77
7.2.23
BIS[1-BIS(TRIMETHYLSILYL)AMINO-3,5-DIMETHYLBORATABENZENE]TIN
(53B)
77
7.2.24
BIS[1-BIS(TRIMETHYLSILYL)AMINO-3,5-DIMETHYLBORATABENZENE]LEAD
(53C)
78
7.2.25
TMEDA
ADDUCT
OF
BIS(1-METHYLBORATABENZENE)LEAD
(54)
79
7.2.26
2,2'-BIPYRIDINE
ADDUCT
OF
BIS(1-METHYLBORATABENZENE)LEAD
(55)
80
7.3
SINGLE
CRYSTAL
X-RAY
STRUCTURAL
ANALYSIS
81
7.3.1
GENERAL
PROCEDURES
81
7.3.2
X-RAY
STRUCTURAL
DATA
82
REFERENCES
90
III |
| any_adam_object | 1 |
| author | Zheng, Xiaolai 1971- |
| author_GND | (DE-588)123079772 |
| author_facet | Zheng, Xiaolai 1971- |
| author_role | aut |
| author_sort | Zheng, Xiaolai 1971- |
| author_variant | x z xz |
| building | Verbundindex |
| bvnumber | BV013824483 |
| classification_tum | CHE 330d |
| ctrlnum | (OCoLC)50254267 (DE-599)BVBBV013824483 |
| discipline | Chemie |
| format | Book |
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| genre | (DE-588)4113937-9 Hochschulschrift gnd-content |
| genre_facet | Hochschulschrift |
| id | DE-604.BV013824483 |
| illustrated | Illustrated |
| indexdate | 2024-11-22T17:24:17Z |
| institution | BVB |
| isbn | 3826590279 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-009454490 |
| oclc_num | 50254267 |
| open_access_boolean | |
| owner | DE-91 DE-BY-TUM |
| owner_facet | DE-91 DE-BY-TUM |
| physical | IV, 98 S. graph. Darst. : 21 cm |
| publishDate | 2001 |
| publishDateSearch | 2001 |
| publishDateSort | 2001 |
| publisher | Shaker |
| record_format | marc |
| series2 | Berichte aus der Chemie |
| spelling | Zheng, Xiaolai 1971- Verfasser (DE-588)123079772 aut Borabenzene derivatives of main group elements Xiaolai Zheng Aachen Shaker 2001 IV, 98 S. graph. Darst. : 21 cm txt rdacontent n rdamedia nc rdacarrier Berichte aus der Chemie Zugl.: Aachen, Techn. Hochsch., Diss., 2001. - Erscheint: 11. Juli 2001 Borinderivate (DE-588)4223693-9 gnd rswk-swf Hauptgruppenelementkomplexe (DE-588)4227741-3 gnd rswk-swf Hauptgruppenelement (DE-588)4122190-4 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Hauptgruppenelement (DE-588)4122190-4 s Borinderivate (DE-588)4223693-9 s DE-604 Hauptgruppenelementkomplexe (DE-588)4227741-3 s DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009454490&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Zheng, Xiaolai 1971- Borabenzene derivatives of main group elements Borinderivate (DE-588)4223693-9 gnd Hauptgruppenelementkomplexe (DE-588)4227741-3 gnd Hauptgruppenelement (DE-588)4122190-4 gnd |
| subject_GND | (DE-588)4223693-9 (DE-588)4227741-3 (DE-588)4122190-4 (DE-588)4113937-9 |
| title | Borabenzene derivatives of main group elements |
| title_auth | Borabenzene derivatives of main group elements |
| title_exact_search | Borabenzene derivatives of main group elements |
| title_full | Borabenzene derivatives of main group elements Xiaolai Zheng |
| title_fullStr | Borabenzene derivatives of main group elements Xiaolai Zheng |
| title_full_unstemmed | Borabenzene derivatives of main group elements Xiaolai Zheng |
| title_short | Borabenzene derivatives of main group elements |
| title_sort | borabenzene derivatives of main group elements |
| topic | Borinderivate (DE-588)4223693-9 gnd Hauptgruppenelementkomplexe (DE-588)4227741-3 gnd Hauptgruppenelement (DE-588)4122190-4 gnd |
| topic_facet | Borinderivate Hauptgruppenelementkomplexe Hauptgruppenelement Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009454490&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT zhengxiaolai borabenzenederivativesofmaingroupelements |