A novel route to deoxyazasugars:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | German |
| Veröffentlicht: |
Berlin
Köster
2001
|
| Ausgabe: | 1. Aufl. |
| Schriftenreihe: | Wissenschaftliche Schriftenreihe Chemie
45 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Zugl.: Berlin, Humboldt-Univ., Diss., 2001 |
| Beschreibung: | 156 S. 21 cm |
| ISBN: | 3895744239 |
Internformat
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| 250 | |a 1. Aufl. | ||
| 264 | 1 | |a Berlin |b Köster |c 2001 | |
| 300 | |a 156 S. |b 21 cm | ||
| 336 | |b txt |2 rdacontent | ||
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Datensatz im Suchindex
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|---|---|
| adam_text |
CONTENT
1.
INTRODUCTION
AND
AIM
OF
THE
PROJECT
.
1
2.
RESULTS
AND
DISCUSSION
.
14
2.1
SYNTHESIS
OF
AZOLES
.
14
2.2
SYNTHESIS
OF
5-BROMO-4-BROMOMETHYLAZOLES
.
15
2.3
N-ALKYLATION
OF
A-AMINO
ESTERS
.
16
2.3.1
N-ALKYLATION
OF
BIOGENIC
A-AMINO
ESTERS
WITH
5-BROMO-4-BROMOMETHYL
AZOLES
.
16
2.3.2
N-ALKYLATION
OF
N-MONOPROTECTED
A-AMINO
ACID ESTERS WITH
DIBROMOALKYL
AND
DIBROMOALKENYL
COMPOUNDS
.
23
2.4
HALOGEN-LITHIUM
EXCHANGE
REACTIONS
.
24
2.4.1
CYCLISATION
OF
O-BROMO-HETEROARYLAMINO
ESTERS
BY
BR-LI
EXCHANGE
REACTIONS
.
24
2.4.2
REACTION
OF
BROMOALKYL
AND
BROMOALKENYLAMINO
ESTERS
WITH
ALKYLLITHIUM
REAGENTS
AND
LITHIUM
METAL
.
33
2.5
STEREOSELECTIVE
REDUCTION
OF
CONDENSED
DIHYDROPYRIDIN-3-ONE
AND
INDOLIZIN-9-ONE
DERIVATIVES
.
40
2.6
MANIPULATION
OF
THE
ALCOHOL
FUNCTION AT
THE
PIPERIDINE
RING
.
43
2.6.1
O-ALKYLATION
OF
DIHYDROPYRIDIN-3-OL
AND
INDOLIZIN-9-OL
DERIVATIVES
.
43
2.6.2
MITSUNOBU
REACTION
.
45
2.7
EXCHANGE
OF
PROTECTIVE
GROUP
.
48
2.8
DESTRUCTION
OF
THE
FUSED
AZOLE
RING
.
50
2.8.1
KNOWN
METHODS
OF
DESTRUCTION
OF
AZOLES
.
50
2.8.2
ATTEMPTS
TO
OPEN
OXAZOLOPYRIDINES
BY
REDUCTION
METHODS
.
60
2.8.3
ALKYLATION
OF
THE
RING
NITROGEN
ATOM
.
61
2.8.4
DESTRUCTION
OF
THE
OXAZOLIUM
RING
.
66
2.8.4.1
RING
OPENING
OF
THE
OXAZOLIUM
SALTS
.
66
2.8.4.2
REDUCTION
OF
THE
KETO
GROUP
EMANATING
FROM
THE
OXAZOLE RING
CLEAVAGE
.
70
2.8.5
RING OPENING
AND
REDUCTION
OF
THE THIAZOLIUM
RING
.
73
3.
CONCLUSION
.
76
4.
EXPERIMENTAL
RESULTS
.
84
4.1
PREPARATION
OF
5-BROMO-4-BROMOMETHYL
AZOLES
.
85
4.2
PREPARATION
OF
O-BROMO-HETEROARYL
AMINO
ESTERS
.
87
4.3
REACTION
OF
DIBROMOPROPANE/
PROPENE
WITH
N-MONOPROTECTED
ALANINE
METHYL
ESTER
.
95
4.4
HALOGEN-LITHIUM
EXCHANGE
REACTIONS
.
97
4.5
REDUCTION
OF
CONDENSED
PYRIDONE
RING
.
105
4.6
O-ALKYLATION
OF
DIHYDROPYRIDIN-3-OL
AND
INDOLIZIN-9-OL
DERIVATIVES
.
108
4.7
PREPARATION
OF
BENZOESTER
182
.
112
4.8
PREPARATION
OF
THE
DESULFONYLATED
PRODUCT
184
.
113
4.9
PREPARATION
OF
CARBAMATE
186
.
114
4.10
N-ALKYLATION
OF
THE
RING
N-ATOM
OF
THE AZOLOPYRIDINES
160
AND
161
.
114
4.11
CLEAVAGE
OF
OXAZOLIUM
SALTS
.
120
4.12
REDUCTION
OF
CLEAVED
PRODUCTS
TO
291
.
123
4.13
PREPARATION
OF
THIAZOLIDINE
COMPOUNDS
.
126
5.
REFERENCES
.
129
6.
ZUSAMMENFASSUNG
.
137 |
| any_adam_object | 1 |
| author | Swaleh, Sauda M. |
| author_facet | Swaleh, Sauda M. |
| author_role | aut |
| author_sort | Swaleh, Sauda M. |
| author_variant | s m s sm sms |
| building | Verbundindex |
| bvnumber | BV013746771 |
| classification_rvk | VK 5507 |
| ctrlnum | (OCoLC)635069454 (DE-599)BVBBV013746771 |
| discipline | Chemie / Pharmazie |
| edition | 1. Aufl. |
| format | Book |
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| genre | (DE-588)4113937-9 Hochschulschrift gnd-content |
| genre_facet | Hochschulschrift |
| id | DE-604.BV013746771 |
| illustrated | Not Illustrated |
| indexdate | 2024-11-22T17:22:41Z |
| institution | BVB |
| isbn | 3895744239 |
| language | German |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-009397498 |
| oclc_num | 635069454 |
| open_access_boolean | |
| owner | DE-29T DE-11 |
| owner_facet | DE-29T DE-11 |
| physical | 156 S. 21 cm |
| publishDate | 2001 |
| publishDateSearch | 2001 |
| publishDateSort | 2001 |
| publisher | Köster |
| record_format | marc |
| series | Wissenschaftliche Schriftenreihe Chemie |
| series2 | Wissenschaftliche Schriftenreihe Chemie |
| spelling | Swaleh, Sauda M. Verfasser aut A novel route to deoxyazasugars Sauda M. Swaleh 1. Aufl. Berlin Köster 2001 156 S. 21 cm txt rdacontent n rdamedia nc rdacarrier Wissenschaftliche Schriftenreihe Chemie 45 Zugl.: Berlin, Humboldt-Univ., Diss., 2001 Chemische Synthese (DE-588)4133806-6 gnd rswk-swf Desoxyzucker (DE-588)4149204-3 gnd rswk-swf Azazucker (DE-588)4319843-0 gnd rswk-swf Chirale Verbindungen (DE-588)4348527-3 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Azazucker (DE-588)4319843-0 s Desoxyzucker (DE-588)4149204-3 s Chirale Verbindungen (DE-588)4348527-3 s Chemische Synthese (DE-588)4133806-6 s DE-604 Wissenschaftliche Schriftenreihe Chemie 45 (DE-604)BV008378173 45 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009397498&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Swaleh, Sauda M. A novel route to deoxyazasugars Wissenschaftliche Schriftenreihe Chemie Chemische Synthese (DE-588)4133806-6 gnd Desoxyzucker (DE-588)4149204-3 gnd Azazucker (DE-588)4319843-0 gnd Chirale Verbindungen (DE-588)4348527-3 gnd |
| subject_GND | (DE-588)4133806-6 (DE-588)4149204-3 (DE-588)4319843-0 (DE-588)4348527-3 (DE-588)4113937-9 |
| title | A novel route to deoxyazasugars |
| title_auth | A novel route to deoxyazasugars |
| title_exact_search | A novel route to deoxyazasugars |
| title_full | A novel route to deoxyazasugars Sauda M. Swaleh |
| title_fullStr | A novel route to deoxyazasugars Sauda M. Swaleh |
| title_full_unstemmed | A novel route to deoxyazasugars Sauda M. Swaleh |
| title_short | A novel route to deoxyazasugars |
| title_sort | a novel route to deoxyazasugars |
| topic | Chemische Synthese (DE-588)4133806-6 gnd Desoxyzucker (DE-588)4149204-3 gnd Azazucker (DE-588)4319843-0 gnd Chirale Verbindungen (DE-588)4348527-3 gnd |
| topic_facet | Chemische Synthese Desoxyzucker Azazucker Chirale Verbindungen Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009397498&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV008378173 |
| work_keys_str_mv | AT swalehsaudam anovelroutetodeoxyazasugars |