Reactive polymer blending:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
München [u.a.]
Hanser
2001
|
| Schriftenreihe: | Progress in polymer processing
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XVI, 289 S. Ill., graph. Darst. |
| ISBN: | 3446210687 1569903123 |
Internformat
MARC
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| 020 | |a 3446210687 |9 3-446-21068-7 | ||
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| 245 | 1 | 0 | |a Reactive polymer blending |c W. E. Baker ... |
| 264 | 1 | |a München [u.a.] |b Hanser |c 2001 | |
| 300 | |a XVI, 289 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 0 | |a Progress in polymer processing | |
| 650 | 4 | |a Polymer-Blend - Reaktive Polymere | |
| 650 | 0 | 7 | |a Reaktive Polymere |0 (DE-588)4403842-2 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Polymer-Blend |0 (DE-588)4200547-4 |2 gnd |9 rswk-swf |
| 689 | 0 | 0 | |a Polymer-Blend |0 (DE-588)4200547-4 |D s |
| 689 | 0 | 1 | |a Reaktive Polymere |0 (DE-588)4403842-2 |D s |
| 689 | 0 | |5 DE-604 | |
| 700 | 1 | |a Baker, Warren E. |e Sonstige |4 oth | |
| 856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009365914&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-009365914 | |
Datensatz im Suchindex
| _version_ | 1807229237837430784 |
|---|---|
| adam_text |
CONTENTS
1
INTRODUCTION
.
1
1.1
BACKGROUND
.
2
1.2
IMPORTANT
BLENDING
PRINCIPLES
.
3
1.3
A
HISTORICAL
PERSPECTIVE
ON
REACTIVE
BLENDING
.
7
1.4
THE
EVOLUTION
OF
COMMERCIAL
PRACTICE
.
9
1.4.1
PATENTS
AND
PRODUCTS
.
9
1.4.2
PROCESSING
.
10
1.5
SUMMARY
.
11
REFERENCES
.
.
.
.
11
2
TYPES
OF
REACTIVE
POLYMERS
USED
IN
BLENDING
.
13
2.1
INTRODUCTION
.
14
2.2
COMPATIBILITY
IN
POLYMER
BLENDS
.
15
2.2.1
BASIC
CONCEPTS
.
15
2.2.2
STRATEGIES
FOR
BLEND
COMPATIBILIZATION
.
15
2.2.2.1
ADDITION
OF
BLOCK
AND
GRAFT
COPOLYMERS
.
15
2.2.2.2
UTILIZATION
OF
NON-BONDING
SPECIFIC
INTERACTIONS
.
16
2.2.2.3
ADDITION
OF
LOW
MOLECULAR
WEIGHT
COUPLING
AGENTS
.
16
2.2.2.4
REACTIVE
COMPATIBILIZATION
.
17
2.3
PREPARATION
OF
REACTIVE
POLYMERS
.
17
2.4 TYPES
OF
COMPATIBILIZING
REACTIONS
.
19
2.5
TYPES
OF
REACTIVE
POLYMERS
AND
THEIR
APPLICATIONS
.
19
2.5.1
REACTIVE
POLYMERS
HAVING
MAN
FUNCTIONALITY
.
20
2.5.2
REACTIVE
POLYMERS
WITH
CARBOXYLIC
ACID
FUNCTIONALITY
.
22
2.5.3
REACTIVE
POLYMERS CAPABLE
OF
INTERCHANGE
REACTIONS
.
24
2.5.4
REACTIVE
POLYMERS
CONTAINING
PRIMARY
AND
SECONDARY
AMINES
.
26
2.5.5
REACTIVE
POLYMERS
CONTAINING
HYDROXYL
GROUPS
.
26
2.5.6
REACTIVE
POLYMERS CONTAINING
HETEROCYCLIC
GROUPS
.
29
2.5.7
REACTIVE
POLYMERS CAPABLE
OF
IONIC
INTERACTIONS
.
31
2.5.8
MISCELLANEOUS
REACTIVE
POLYMERS
.
31
2.6
CONCLUDING
REMARKS
.
32
LIST
OF
ABBREVIATIONS
.
34
REFERENCES
.
35
3
REACTIVE
BLENDING
WITH
IMMISCIBLE
FUNCTIONAL
POLYMERS:
MOLECULAR,
MORPHOLOGICAL,
AND
INTERFACIAL
ASPECTS
.
43
3.1
INTRODUCTION
.
44
3.2
REACTIVE
VERSUS
PHYSICAL
BLENDING
WITH
RESPECT
TO
COMPATIBILIZATION
.
44
3.2.1
SIMILARITIES
AND
DIFFERENCES
.
44
3.2.2
INDUSTRIAL
FEASIBILITY
AND
CURRENT
TRENDS
.
46
X
CONTENTS
3.3
IN
SITU
INTERFACIAL
CHEMICAL
REACTIONS
OF
FUNCTIONAL
POLYMERS
.
47
3.3.1
TYPES
OF
IN
SITU
CHEMICAL
REACTIONS
INVOLVED
.
47
3.3.2
KINETICS
OF
INTERFACIAL
REACTIONS
AND
MOLECULAR
CHARACTERIZATION
.
49
3.4
EFFECTS
OF
REACTIVE
BLENDING
ON
PHASE
MORPHOLOGY
.
53
3.4.1
EFFECT
OF
REACTIVE
BLENDING
ON
PHASE
MORPHOLOGY
GENERATION
.
53
3.4.1.1
GENERAL
ASPECTS
OF
PHASE
MORPHOLOGY
DEVELOPMENT
.
53
3.4.1.2
PHASE
MORPHOLOGY
DEVELOPMENT
IN
NON-REACTIVE
BLENDING
.
.
54
3.4.1.3
PHASE
MORPHOLOGY
DEVELOPMENT
IN
REACTIVE
BLENDING
.
56
3.4.2
EFFECT
OF
REACTIVE
BLENDING
ON
PHASE
STABILISATION
IN
THE
MELT
.
63
3.4.3
EFFECT
OF
REACTIVE
BLENDING
ON
PHASE
CO-CONTINUITY
.
64
3.4.4
INTERFACIAL
STABILITY
OF
THE
IN
SITU
FORMED
COPOLYMER
.
67
3.5
EFFECT
OF
REACTIVE
BLENDING
ON
CRYSTALLIZATION
OF
BLENDS
CONTAINING
CRYSTALLIZABLE
COMPONENTS
.
67
3.6
BLEND
INTERFACE
CHARACTERIZATION
.
69
3.6.1
GENERAL
ASPECTS
CONCERNING
POLYMER/POLYMER
INTERFACES
.
69
3.6.2
DETERMINATION
OF
THE
INTERFACIAL
TENSION
IN
REACTIVELY
COMPATIBILIZED
BLENDS
.
72
3.6.2.1
BLEND
RHEOLOGY
USING
THE
PALIEME
MODEL
.
72
3.6.2.2
THE
BREAKING
THREAD
METHOD
.
73
3.6.3
DETERMINATION
OF
THE
INTERFACIAL
THICKNESS
IN
REACTIVE
BLENDS
.
74
3.6.3.1
ELLIPSOMETRY
.
74
3.6.3.2
NEUTRON
REFLECTOMETRY
.
75
3.6.3.3
TRANSMISSION
ELECTRON
MICROSCOPY
.
77
3.7
GENERAL
CONCLUSIONS
.
78
REFERENCES
.
79
4
KEY
ROLE
OF
STRUCTURAL
FEATURES
OF
COMPATIBILIZING
POLYMER
ADDITIVES
IN
REACTIVE
BLENDING
.
82
4.1
INTRODUCTION
.
83
4.2
GENERAL
PRINCIPLES
.
85
4.3
MOLECULAR
ARCHITECTURE
OF
THE
COMPATIBILIZER
.
85
4.3.1
ALTERNATIVE
1
.
86
4.3.2
ALTERNATIVE
2
.
86
4.3.3
ALTERNATIVE
3
.
87
4.4
PHASE
MORPHOLOGY
DEVELOPMENT
.
87
4.5
EFFECT
OF
THE
INTERFACIAL
REACTION
ON
THE
PHASE
MORPHOLOGY
DEVELOPMENT
.
89
4.6
EFFECT
OF
THE
MOLECULAR
CHARACTERISTIC FEATURES
OF
THE
REACTIVE
POLYMERS
.
90
4.6.1
KINETICS
OF
THE
INTERFACIAL
REACTION
.
90
4.6.2
MOLECULAR
WEIGHT
OF
THE
COMPATIBILIZER
PRECURSORS
.
95
4.6.3
REACTIVE
GROUP
CONTENT
OF
THE
REACTING
POLYMERS
.
98
4.6.4
DISTRIBUTION
OF
THE
REACTIVE
GROUPS
ALONG
THE
CHAINS
.
104
4.7
EFFECT
OF
PROCESSING
CONDITIONS
.
105
4.7.1
MELTING
ORDER
OF
THE
CONSTITUTIVE
COMPONENTS
OF
REACTIVE
POLYBLENDS
.
105
4.7.2
EFFECT
OF
SHEARING
.
106
4.7.3
INITIAL
STATE
OF
DISPERSION
.
107
4.7.4
MIXING
TEMPERATURE
.
107
4.8
CONCLUSIONS
.
108
REFERENCES
.
109
CONTENTS
XI
5
MORPHOLOGICAL
AND
RHEOLOGICAL
ASPECTS
OF
REACTIVE
POLYMER
BLENDING
.
113
5.1
MORPHOLOGY
DEVELOPMENT
DURING
BLENDING
OF
IMMISCIBLE
POLYMERS
.
114
5.1.1
THE
MELTING
REGIME
.
116
5.1.2
THE
MELT
FLOW
REGIME
.
120
5.1.3
FINAL
MORPHOLOGY
OF
REACTIVE
BLENDS
.
127
5.1.4
MISCIBLE
REACTIVE
POLYMER
BLENDS
.
132
5.2
RHEOLOGICAL
ASPECTS
OF
REACTIVE
POLYMER
BLENDING
.
132
5.2.1
RHEOLOGICAL
CHANGES
DURING
BLENDING
.
132
5.2.2
RHEOLOGY
OF
REACTIVELY
COMPATIBILIZED
POLYMER
BLENDS
.
134
5.3
CONCLUSIONS
.
138
5.4
FUTURE
CHALLENGES
.
139
REFERENCES
.
139
6
REACTIVE
BLENDING
IN
SCREW
EXTRUDERS
.
142
6.1
INTRODUCTION
.
143
6.2
REACTIVE
BLENDING
IN
MIXERS
.
144
6.2.1
COPOLYMER
FORMATION
AT
POLYMER/POLYMER
INTERFACES
.
145
6.2.1.1
CHEMICAL
CONSIDERATIONS
.
145
6.2.1.2
COPOLYMER
ARCHITECTURE
CONSIDERATIONS
.
145
6.2.1.3
KINETICS
CONSIDERATIONS
.
145
6.2.1.4
EXPERIMENTAL
ASSESSMENT
OF
REACTION
KINETICS
AT
POLYMER-POLYMER
INTERFACES
.
151
6.2.2
BATCH
MIXERS
FOR
REACTIVE
BLENDING
.
154
6.2.2.1
REACTIVE
COMPATIBILIZATION
VS.
PHYSICAL
COMPATIBILIZATION
.
.
.
154
6.2.2.2
MORPHOLOGY
DEVELOPMENT
.
155
6.2.3
REACTIVE
BLENDING
IN
SCREW
EXTRUDERS
.
158
6.2.3.1
NON-REACTIVE
VS.
REACTIVE
PP/PA6
BLENDS
.
163
6.2.3.2
INFLUENCE
OF
SCREW
CONFIGURATION
.
164
6.2.3.3
INFLUENCES
OF
FEED
RATE
AND
SCREW
SPEED
.
165
6.2.3.4
INFLUENCE
OF
THE
MALEIC
ANHYDRIDE
MODIFIED
PP
CONTENT
.
166
6.2.3.5
CORRELATION
BETWEEN
MORPHOLOGY
AND
MECHANICAL
PROPERTIES
.
.
167
6.4
ONE-STEP
AND
TWO-STEP
REACTIVE
BLENDING
PROCESSES
.
170
6.4.1
PP/PA6
BLENDS
.
171
6.4.2
PP/PBT
BLENDS
.
174
6.5
CONCLUDING
REMARKS
.
177
REFERENCES
.
178
7
EXTRUSION
EQUIPMENT
FOR
REACTIVE
BLENDING
.
180
7.1
EXTRUDERS
USED
FOR
REACTIVE
BLENDING
.
181
7.2
MIXING
MECHANISM
.
185
7.2.1
DISTRIBUTIVE
AND
DISPERSIVE
MIXING
.
186
7.2.1.1
DISTRIBUTIVE
MIXING
.
186
7.2.1.2
DISPERSIVE
MIXING
.
187
7.2.1.3
VISCOSITY
RATIO
AND
SURFACE
TENSION
.
187
7.2.1.4
EXTENSIONAL
FLOW
.
188
7.2.2
DISSIPATIVE
MELTING
.
188
7.3
RESIDENCE
TIME
AND
RESIDENCE
TIME
DISTRIBUTION
.
193
XII
CONTENTS
7.4
DEVOLATILIZATION
.
194
7.5
MICROSTRUCTURE
DEVELOPMENT
AND
MONITORING
IN
REACTIVE
BLENDING
.
197
7.6
HYBRIDIZED
POLYMER
PROCESSING
SYSTEMS
.
201
7.7
CONCLUSIONS
.
204
REFERENCES
.
205
8
RUBBER
TOUGHENING
OF
POLYAMIDES
BY
REACTIVE
BLENDING
.
207
8.1
INTRODUCTION
.
208
8.2
EVOLUTION
OF
POLYAMIDE
IMPACT
MODIFICATION
TECHNOLOGY
.
211
8.3
COMPARISON
OF
REACTIVITY
VS.
TOUGHENING
EFFICIENCY
OF
VARIOUS
FUNCTIONAL
RUBBERS
.
216
8.4
TOUGHENING
EFFICIENCY
OF
MALEATED
EP
RUBBERS
.
224
8.4.1
EFFECT
OF
MALEIC
ANHYDRIDE
CONTENT
.
224
8.4.2
EFFECT
OF
POLYAMIDE
END
GROUPS
.
226
8.5
TOUGHENING
EFFICIENCY
OF
MALEATED
STYRENE-ETHYLENE/BUTYLENE-STYRENE
(M-SEBS)
BLOCK
COPOLYMER
RUBBERS
.
231
8.6
EFFECT
OF
MIXTURES
OF
REACTIVE
AND
NON-REACTIVE
(MALEATED
AND
UNMALEATED)
RUBBERS
.
236
8.7
REACTIVE
TOUGHENING
OF
PA6
WITH
ACYLLACTAM-GRAFTED
EP
RUBBERS
.
237
8.8
TOUGHENING
OF
POLYAMIDES
WITH
MALEATED
LDPE
.
239
8.9
HIGH
IMPACT
POLYAMIDE/ABS
BLEND
.
241
8.10
TOUGHENING
MECHANISMS
IN
RUBBER
MODIFIED
POLYAMIDES
.
243
8.10.1
ROLE
OF
RUBBER
PARTICLE
SIZE
ON
POLYAMIDE
TOUGHNESS
.
243
8.10.2
ROLE
OF
RUBBER
PARTICLE
CAVITATION
ON
THE
PA
MATRIX
TOUGHENING
.
.
.
245
8.11
RUBBER
TOUGHENING
OF
REINFORCED
POLYAMIDES
.
246
8.12
APPLICATIONS
OF
RUBBER
TOUGHENED
POLYAMIDE
.
247
8.13
HIGH
RUBBER/POLYAMIDE
BLENDS
.
248
8.14
POLYAMIDE/REACTIVE
RUBBER
BLENDING
PROCESS
.
250
8.16
FUTURE
DIRECTIONS
IN
RUBBER
TOUGHENED
POLYAMIDES
.
251
REFERENCES
.
252
9
COMPATIBILIZATION
USING
LOW
MOLECULAR
WEIGHT
REACTIVE
ADDITIVES
.
254
9.1
INTRODUCTION
.
255
9.2
FREE
RADICAL
REACTIVITY
AND
COMPATIBILIZATION
OF
POLYOLEFINS
.
256
9.3
POLYETHYLENE/POLYSTYRENE
COMPATIBILIZATION
.
259
9.4
COMPATIBILIZATION
OF
POLYOLEFIN/POLYAMIDE
BLENDS
.
263
9.5
DEVELOPMENT
OF
THE
VECTOR
FLUID
COMPATIBILIZATION
CONCEPT
.
266
9.6
SPECIAL
PEROXIDE
.
272
9.7
INORGANIC
CATALYST
FOR
PE/PS
COMPATIBILIZATION
.
273
9.8
A
RECENT
EXAMPLE
.
277
9.9
SUMMARY
.
279
REFERENCES
.
279
INDEX
281 |
| any_adam_object | 1 |
| building | Verbundindex |
| bvnumber | BV013703559 |
| classification_rvk | UV 9240 |
| classification_tum | WER 590f CIT 710f |
| ctrlnum | (OCoLC)248357069 (DE-599)BVBBV013703559 |
| discipline | Physik Werkstoffwissenschaften Chemie-Ingenieurwesen |
| format | Book |
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| id | DE-604.BV013703559 |
| illustrated | Illustrated |
| indexdate | 2024-08-13T00:15:06Z |
| institution | BVB |
| isbn | 3446210687 1569903123 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-009365914 |
| oclc_num | 248357069 |
| open_access_boolean | |
| owner | DE-91G DE-BY-TUM DE-210 DE-703 DE-12 DE-526 |
| owner_facet | DE-91G DE-BY-TUM DE-210 DE-703 DE-12 DE-526 |
| physical | XVI, 289 S. Ill., graph. Darst. |
| publishDate | 2001 |
| publishDateSearch | 2001 |
| publishDateSort | 2001 |
| publisher | Hanser |
| record_format | marc |
| series2 | Progress in polymer processing |
| spelling | Reactive polymer blending W. E. Baker ... München [u.a.] Hanser 2001 XVI, 289 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Progress in polymer processing Polymer-Blend - Reaktive Polymere Reaktive Polymere (DE-588)4403842-2 gnd rswk-swf Polymer-Blend (DE-588)4200547-4 gnd rswk-swf Polymer-Blend (DE-588)4200547-4 s Reaktive Polymere (DE-588)4403842-2 s DE-604 Baker, Warren E. Sonstige oth DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009365914&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Reactive polymer blending Polymer-Blend - Reaktive Polymere Reaktive Polymere (DE-588)4403842-2 gnd Polymer-Blend (DE-588)4200547-4 gnd |
| subject_GND | (DE-588)4403842-2 (DE-588)4200547-4 |
| title | Reactive polymer blending |
| title_auth | Reactive polymer blending |
| title_exact_search | Reactive polymer blending |
| title_full | Reactive polymer blending W. E. Baker ... |
| title_fullStr | Reactive polymer blending W. E. Baker ... |
| title_full_unstemmed | Reactive polymer blending W. E. Baker ... |
| title_short | Reactive polymer blending |
| title_sort | reactive polymer blending |
| topic | Polymer-Blend - Reaktive Polymere Reaktive Polymere (DE-588)4403842-2 gnd Polymer-Blend (DE-588)4200547-4 gnd |
| topic_facet | Polymer-Blend - Reaktive Polymere Reaktive Polymere Polymer-Blend |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009365914&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT bakerwarrene reactivepolymerblending |