Elemental speciation: new approaches for trace element analysis
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| Format: | Book |
|---|---|
| Language: | English |
| Published: |
Amsterdam [u.a.]
Elsevier
2000
|
| Edition: | 1. ed. |
| Series: | Wilson and Wilson's Comprehensive analytical chemistry
33 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XVII, 581 S. Ill., graph. Darst. |
| ISBN: | 0444500472 |
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| 245 | 1 | 0 | |a Elemental speciation |b new approaches for trace element analysis |c ed. by Joseph A. Caruso... |
| 250 | |a 1. ed. | ||
| 264 | 1 | |a Amsterdam [u.a.] |b Elsevier |c 2000 | |
| 300 | |a XVII, 581 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 1 | |a Wilson and Wilson's Comprehensive analytical chemistry |v 33 | |
| 650 | 4 | |a Chimie de l'environnement - Méthodologie | |
| 650 | 4 | |a Eser analiz - Metodoloji | |
| 650 | 4 | |a Spéciation (Chimie) | |
| 650 | 4 | |a Ultramicrométhodes - Méthodologie | |
| 650 | 4 | |a Çevre kimyası - Metedoloji | |
| 650 | 4 | |a Environmental chemistry |x Methodology | |
| 650 | 4 | |a Speciation (Chemistry) | |
| 650 | 4 | |a Trace analysis |x Methodology | |
| 650 | 0 | 7 | |a Spurenelement |0 (DE-588)4056595-6 |2 gnd |9 rswk-swf |
| 689 | 0 | 0 | |a Spurenelement |0 (DE-588)4056595-6 |D s |
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| 700 | 1 | |a Caruso, Joseph A. |e Sonstige |4 oth | |
| 830 | 0 | |a Wilson and Wilson's Comprehensive analytical chemistry |v 33 |w (DE-604)BV000900805 |9 33 | |
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| _version_ | 1804128453237145600 |
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| adam_text | Titel: Elemental speciation
Autor: Caruso, Joseph A
Jahr: 2000
Contents
Series Editor s Preface............................xxiii
Editors Preface...............................xxiv
Chapter 1. Introduction...........................................1
1.1 Sampling and sample preparation..................2
1.2 Highly selective chromatographic methods.............3
1.3 Plasma mass spectrometry......................3
1.4 Information rich plasma detectors..................5
References..................................6
Chapter 2. Sample preparation techniques for elemental speciation studies. . 7
2.1 Introduction..............................7
2.2 Sample collection, pretreatment and storage...........10
2.2.1 Atmospheric and gas samples...............10
2.2.2 Water samples........................11
2.2.3 Sediments and soils.....................13
2.2.4 Biological materials.....................14
2.3 Sample handling prior to GC chromatographic analysis.....15
2.3.1 Aqueous samples......................16
2.3.1.1 Sorption (solid-phase extraction)........16
2.3.1.2 Solid phase micro-extraction...........16
2.3.1.3 Solvent extraction................17
2.3.1.4 Steam distillation.................18
2.3.1.5 Liquid-gas extraction (purge and trap).....18
2.3.2 Solid samples........................19
2.3.2.1 Leaching methods................19
2.3.2.2 Solubilization of biological samples prior to
speciation analysis................20
2.3.2.3 Enhanced techniques: supercritical fluid
extraction and accelerated solvent extraction. . 20
2.3.2.4 Microwave-assisted processes..........21
2.3.3 Organic samples (gas condensates, shale oils, gasoline) . 22
2.3.4 Derivatization techniques in speciation analysis.....23
2.3.4.1 Derivatization by hydride generation......24
xi
2.3.4.2 Derivatization with tetraalkyl(aryl)borates... 24
2.3.4.3 Derivatization with Grignard reagents.....25
2.3.4.4 Other derivatization techniques.........26
2.3.5 Preconcentration and cleanup...............26
2.3.6 Automation of sample preparation and GC sample
introduction.........................27
2.4 Handling of biomaterials prior to HPLC..............29
2.4.1 Organometalloid compounds................29
2.4.2 Coordination complexes of metals with bio-ligands . ... 31
2.4.2.1 Biological fluids (full blood, plasma, synovial
fluid, breast milk).................31
2.4.2.2 Plant and animal tissues.............31
2.5 Conclusions—trends and perspectives...............32
References.................................^
Chapter 3. The use of biological substrates for preconcentration and
element speciation............................................41
3.1 Introduction.............................41
3.2 Accumulation mechanisms.....................44
3.2.1 Biosorption.........................44
3.2.2 Interactions between metal species and biological
substrates..........................46
3.2.3 Toxicity of heavy metals to biological substrates.....46
3.2.3.1 Microorganism strategies for avoiding metal
toxicity......................48
3.2.3.2 Use of dead biomass for metal removal and
recovery......................49
3.2.4 Phytoremediation......................49
3.2.5 Hyperaccumulation.....................50
3.3 Experimental accumulation procedures..............52
3.3.1 Batch processes.......................52
3.3.2 Immobilization techniques.................55
3.4 Primary analytical applications of biological substrates.....57
3.4.1 Algae.............................57
3.4.2 Yeast and fungi.......................60
3.4.3 Bacteria...........................64
3.4.4 Plant-derived materials...................68
3.4.5 Use of biological substrates for speciation.........72
References....................................^7
Chapter 4. Liquid chromatographic techniques for trace element
speciation analysis..................................
4.1 Introduction.......................
4.2 The tools of the trade..................
4.3 Liquid chromatography as the separation technique in
trace element speciation analysis...........
xii
4.3.1 Reversed phase partition liquid chromatography (HPLC). 87
4.3.2 Ion exchange chromatography (IEC)............89
4.3.3 Reversed phase ion pair chromatography (RP-IPC).... 91
4.3.4 Size exclusion liquid chromatography (SEC).......92
4.3.5 Micelle and vesicle-mediated chromatography......94
4.4 Interfacing liquid chromatography to atomic spectrometry. ... 96
4.4.1 Flame atomic absorption spectrometry (FAAS) detection. 97
4.4.2 Hydride generation-AAS detection.............98
4.4.3 Inductively coupled plasma-optical emission
spectrometry (ICP-OES)..................99
4.4.4 Inductively coupled plasma-mass spectrometry
(ICP-MS) detection.....................100
4.5 Applications to particular trace elements.............103
4.5.1 Arsenic...........................103
4.5.2 Lead............................106
4.5.3 Tin.............................106
4.5.4 Mercury..........................109
4.5.5 Selenium..........................109
4.5.6 Chromium.........................112
4.5.7 Aluminum.........................113
References.................................115
Chapter 5. Gas chromatographic and supercritical fluid chromatographic
techniques for elemental speciation.............................123
5.1 Introduction............................123
5.2 Atomic plasma emission gas chromatographic detectors (AED). 124
5.2.1 Microwave induced plasmas as gas chromatographic
detectors..........................125
5.2.2 Other plasma systems for GC detection.........127
5.3 Plasma interfacing with capillary GC...............128
5.4 Analytical information and speciation by GC-AED.......128
5.4.1 GC-AED detection of non-metallic elements.......133
5.4.2 GC-AED detection of metallic elements.........139
5.4.2.1 GC-AED of main group metallic compounds. . 139
5.4.2.2 GC-AED of transition metal compounds . . . . 142
5.5 Plasma detectors for supercritical fluid chromatography .... 143
5.6 Atomic plasma mass spectral gas chromatographic detectors. . 144
5.7 The future of atomic emission chromatographic detection. . . . 147
References.................................147
Chapter 6. Capillary electrophoresis for elemental speciation studies.....151
6.1 Introduction............................151
6.2 Principles and instruments for elemental speciation using
capillary electrophoresis......................153
6.2.1 Influence of experimental parameters on migration time 154
xm
. . . .. .......158
6.2.2 Sample injection............ •. •. ¦ .
6.2.2.1 Hydrodynamic or hydrostatic injection.....xoo
6 2.2.2 Electrokinetic injection.............
6.2.3 Influence of experimental parameters on band
dispersion and resolution.................
6.2.3.1 Longitudinal diffusion.............
6.2.3.2 Injected sample plug..............
6.2.3.3 Joule heating..................
6.2.3.4 Concentration overload.............1°*
6.2.3.5 Laminar flow..................
6.2.3.6 Sample-wall interactions............lb*
6.2.4 Selection of experimental parameters..........163
6.2.4.1 Applied voltage.................l°3
6.2.4.2 Capillary inner diameter............164
6.2.4.3 Capillary length ... ................164
6.2.4.4 Capillary material and coating.........164
6.2.4.5 Electrolyte/bufTer...............166
6.2.4.6 Injection volume ................166
6.2.4.7 Optimizing injection volume, capillary
diameter and electrolyte/buffer conductivity. . 166
6.3 Detectors for elemental speciation by CE.............166
6.3.1 On-capillary detection . . ...............166
6.3.1.1 Indirect UV detection..............168
6.3.1.2 Direct on-capillary detection by
electrochemical detection............168
6.3.1.3 Direct on-capillary detection by laser induced
fluorescence...................169
6.3.1.4 UV absorption detection following
complexation...................169
6.3.2 Post-capillary detectors..................169
6.3.2.1 Interface considerations.............170
6.3.2.2 Inductively coupled plasma optical emission
and mass spectrometry.............170
6.3.2.3 Electrospray and ion spray mass
spectrometry...................179
6.3.2.4 Proton induced X-ray emission (PIXE).....180
6.4 Applications of capillary electrophoresis for elemental speciation . 181
6.4.1 Charge (oxidation) state speciation............181
6.4.2 Arsenic and selenium speciation ............182
6.4.2.1 Arsenic and selenium speciation using
nonspecific detection..............183
6.4.2.2 Arsenic and selenium speciation using
element selective detection...........186
6.4.2.3 Arsenic and selenium speciation using
electrospray mass spectrometry detection . . . 190
xiv
6.4.3 Anion speciation......................190
6.4.4 Metal binding with organic ligands and biomolecules . . 193
6.4.4.1 Effect of complexation on migration times and
CE separations.................193
6.4.4.2 CE of metal-ligand complexes.........194
6.4.4.3 Determination of metal-ligand complexation
constants.....................196
6.4.4.4 Metal complexation with humic and other
polyhydroxy substances.............199
6.4.4.5 Metal binding to biological molecules.....200
6.4.5 Other applications.....................202
6.5 Conclusions: advantages and limitations of capillary
electrophoresis for elemental speciation.............203
References.................................204
Chapter 7. Nebulizer sample introduction for elemental speciation.......213
7.1 Introduction............................213
7.2 High performance liquid chromatography inductively coupled
plasma-mass spectrometry....................214
7.2.1 Conventional nebulizers..................216
7.2.2 Low flow nebulizers....................216
7.2.3 Less conventional nebulizer techniques.........219
7.3 Capillary electrophoresis inductively coupled plasma-mass
spectrometry............................220
7.4 Conclusions and future trends..................223
References.................................224
Chapter 8. The use oflCP-AES as a detector for elemental speciation
studies....................................................227
8.1 Introduction............................227
8.2 Liquid chromatography......................229
8.2.1 Mobile phases.......................231
8.2.1.1 Inorganic mobile phases............231
8.2.1.2 Organic mobile phases.............232
8.2.2 Micro-HPLC and specialized nebulizers.........234
8.2.3 Applications........................237
8.2.4 Liquid chromatography-hydride generation-ICP-AES . 238
8.2.4.1 Instrumentation.................238
8.2.4.2 Formation of reducible species.........239
8.3 Capillary zone electrophoresis..................240
8.4 Gas chromatography........................241
8.5 Supercritical fluid chromatography................244
8.6 Flow injection analysis......................244
8.7 Interferences............................244
8.8 Conclusions.............................245
References.................................246
xv
Chapter 9. The use oflCP-MS as a detector for elemental speciation ^
studies....................................................249
9.1 Introduction...............................
9.2 Components of an ICP-MS....................
9.2.1 Sample introduction....................
9.2.2 The inductively coupled plasma..............*55
9.2.3 The mass spectrometer..................256
9.3 Elements of interest........................
9.3.1 Chromium.........................
9.3.2 Gold and platinum.....................257
9.3.3 Lead............................^58
9.3.4 Mercury..........................258
9.3.5 Tin.............................259
9.3.6 Vanadium........................259
9.3.7 Cadmium.........................259
9.3.8 Selenium.........................260
9.3.9 Arsenic..........................2^9
9.3.10 Antimony.........................260
9.3.11 Aluminum........................261
9.3.12 Iodine...........................261
9.4 Interferences...........................261
9.4.1 Spectroscopic interferences...............261
9.4.2 Non-spectroscopic interferences.............263
9.5 Improving sample transport efficiency..............264
9.6 Coupling chromatographic techniques with ICP-MS.......266
9.6.1 Liquid chromatography.................266
9.6.2 Gas chromatography....................267
9.6.3 Supercritical fluid chromatography............268
9.7 Alternative mass analyzers....... ............268
9.8 Conclusions.............................270
References.................................271
Chapter 10. Application of isotope dilution in elemental speciation:
speciated isotope dilution mass spectrometry (SIDMS)..............27/
10.1 Introduction............................277
10.1.1 Inaccuracy of speciation analysis due to species
transformations......................277
10.1.2 Stable isotopic ratio concepts and measurements .... 279
10.2 Conventional isotope dilution mass spectrometry (IDMS).... 281
10.3 Isotope dilution mass spectrometry in elemental speciation. . • 282
10.3.1 Application of isotope dilution in speciation analysis
based on conventional concepts..............282
10.3.2 Principle of speciated isotope dilution mass spectrometry
(SIDMS) and its comparison to other IDMS protocols . . 283
xvi
10.3.3 Calculations in speciated isotope dilution mass
spectrometry........................285
10.4 Relationship between SIDMS and IDMS.............289
10.5 Preparation and calibration of isotopic spikes..........290
10.6 Measurement of isotope ratios in species.............292
10.7 Error propagation in SIDMS...................294
10.7.1 A model for SIDMS....................295
10.7.2 Monte Carlo simulation for evaluating error
propagation..........................295
10.8 Standard SIDMS method, EPA method 6800 .......... 298
10.9 Demonstration and application of SIDMS in correcting for
species transformation.......................299
10.9.1 Analysis of a synthesized water sample.........299
10.9.2 Analysis of environmental water samples........301
10.9.3 Analysis of extracts of chromite ore processing residue
(COPR)...........................302
10.9.4 Analysis of soil extracts..................302
10.10 Application of sidms in correcting for incomplete species
separation.............................303
10.11 Application of SIDMS as A diagnostic tool in identifying species
altering procedures in more conventional speciation methods . 305
10.12 Application of sidms in the analysis of challenging and difficult
environmental solid samples...................308
References.................................310
Chapter 11. Plasma sources as alternatives to the atmospheric pressure ICP
for speciation studies.........................................315
11.1 Introduction............................315
11.2 Microwave plasmas........................316
11.2.1 Microwave plasma formation...............317
11.2.1.1 Microwave induced plasma (MIP).......317
11.2.1.2 Capacitively coupled microwave plasma (CMP) 320
11.2.1.3 Suface wave plasma or surfatron (SWP). . . . 320
11.2.1.4 Microwave plasma torch (MPT)........320
11.2.1.5 Strip-line microwave plasma (SMP)......320
11.2.2 Atomic emission spectrometry..............321
11.2.2.1 Instrumentation.................321
11.2.2.2 Gas chromatography..............323
11.2.2.3 Supercritical fluid chromatography......333
11.2.2.4 Liquid chromatography.............334
11.2.2.5 Other methods..................336
11.2.3 Mass spectrometry.....................339
11.2.3.1 Instrumentation.................340
11.2.3.2 Gas chromatography..............341
11.2.3.3 Supercritical fluid chromatography......345
xvii
11.2.3.4 Liquid chromatography..........
11.3 Low pressure microwave plasmas..............
11.3.1 Atomic mass spectrometry..............
11.3.2 Molecular mass spectrometry............
11.4 Low pressure inductively coupled plasmas.........
11.4.1 Low pressure plasma formation...........
11.4.2 Atomic emission spectrometry...........
11.4.3 Mass spectrometry..................
11.4.3.1 Instrumentation..............
11.4.3.2 Gas chromatography...........
11.4.3.3 Liquid sample introduction........
11.5 Glow discharge plasmas................ . . .
11.5.1 Glow discharge plasma formation..........
11.5.1.1 Grimm type glow discharge........
11.5.1.2 Hollow-cathode glow discharge......
11.5.1.3 Radio frequency glow discharge.....
11.5.2 Atomic emission spectrometry...........
11.5.2.1 Gas chromatography...........
11.5.2.2 Hydride generation............
11.5.2.3 Liquid chromatography..........
11.5.3 Mass spectrometry..................
11.5.3.1 Instrumentation..............
11.5.3.2 Gas chromatography...........
11.5.3.3 Liquid sample introduction........
11.5.4 Other sample introduction methods........
11.6 On-column micro-plasma..................
References..............................
Chapter 12. Elcctrospray ionization mass spectrometry................383
12.1 Elcctrospray as an elemental ion source.............383
12.1.1 A brief historical account.................383
12.1.2 Current trends in elemental analysis...........383
12.1.3 Present status of elcctrospray ionization (ESI)......384
12.1.4 Application of ESI to inorganic analytes.........385
12.1.5 Other atmospheric pressure ion sources.........386
12.2 ESI operating principles......................388
12.2.1 The clectrospray mechanism...............388
12.2.2 Taylor cone and spray morphology............391
12.2.3 Corona discharge......................391
12.2.4 Electrospray current....................393
12.2.5 Droplet formation and ion liberation mechanisms .... 395
12.3 ESI-MS hardware.........................398
12.3.1 Sample delivery......................398
12.3.2 Integration of separation technology...........401
12.3.3 Atmospheric pressure interface technology........406
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xviii
12.3.4 Mass spectrometry.....................408
12.4 Gas phase chemistry of metallic species.............408
12.4.1 Metallic species (mono-, di-, and tri-valent cations) . . . 408
12.4.2 Non-metallic anions and oxo-anionic metal species . . . 414
12.4.3 Organometallics......................420
12.4.4 Metal-Iigand complexes..................425
12.5 Quantitative analysis.......................431
12.5.1 Analytical response curves................431
12.5.2 The role of an ESI stabilizer................433
12.5.3 Internal standardization and analyte suppression. . . . 433
12.5.4 Analytical performance and figures of merit.......434
12.6 Applications............................435
12.6.1 Fluoride in mouthwash..................435
12.6.2 Towards the analysis of disinfection by-products in
municipal water supplies by ESI-FAIMS-MS......437
12.6.3 Literature review.....................437
12.7 Conclusions.............................438
References.................................439
Chapter 13. Trends in speciation analysis for routine and new
environmental issues.........................................451
13.1 Introduction............................451
13.2 Determination of redox species..................455
13.2.1 Non-chromatographic methods..............455
13.2.2 Separation by microbore HPLC..............456
13.2.3 Separation by capillary zone electrophoresis.......458
13.3 Determination of organometallic species (Sn, Hg, Pb)......461
13.3.1 Trends in sample preparation procedures........461
13.3.2 Cost-effective methods...................464
13.3.2.1 Interferences...................466
13.3.2.2 Field techniques and on-site sampling.....467
13.3.3 Mercury speciation.....................468
13.3.3.1 Simple approaches using purge-and-trap
methods.....................468
13.3.3.2 Evolution of methods using gas
chromatography separation...........469
13.3.3.3 Development of liquid separation methods . . 471
13.3.4 Determination of Sn and Pb compounds by gas
chromatographic methods.................474
13.3.4.1 Derivatization of organotin compounds .... 474
13.3.4.2 Derivatization of organolead compounds. . . . 477
13.3.4.3 Cost-effective detectors for routine
determination..................477
13.4 Multielement-multispecies determination using plasma
source detection..........................480
xix
13.5 New trends for the detection mode for organometal species. . . 487
13.6 Mass spectrometric detection and perspectives.........
13.6.1 Isotopic precision......................
13.6.2 Species-specific stable isotope dilution..........
Acknowledgements........................^
References.................................
Chapter 14. Speciation analysis of biological, clinical and nutritional
samples using plasma spectrometry.............................
14.1 Introduction............................
14.2 Sample collection, storage, preparation and pretreatment . . . 5U4
14.2.1 General guidelines....................^04
14.2.2 Clinical samples.....................507
14.2.3 Biological samples....................^09
14.2.4 Nutritional samples...................510
14.3 Example applications......................512
14.3.1 Clinical applications...................512
14.3.1.1 Aluminum...................513
14.3.1.2 Arsenic....................513
14.3.1.3 Chromium...................514
14.3.1.4 Iodine......................515
14.3.1.5 Lead......................516
14.3.1.6 Mercury.....................516
14.3.1.7 Platinum.....................516
14.3.1.8 Selenium.....................517
14.3.1.9 Zinc........................518
14.3.2 Biological applications...................519
14.3.2.1 Arsenic......................519
14.3.2.2 Chromium....................519
14.3.2.3 Selenium.....................520
14.3.3 Nutritional applications..................520
14.3.3.1 Arsenic......................521
14.3.3.2 Cadmium....................522
14.3.3.3 Chromium............ .... 523
14.3.3.4 Lead................................523
14.3.3.5 Selenium................, 523
14.3.3.6 Tin..................525
14.3.3.7 Bromine.....................525
14.4 Conclusions....................................525
References....................................526
Chapter 15. Certified reference materials: a tool for quality control of
elemental speciation analysis....................................531
15.1 Introduction....................................531
15.2 Ways to achieve accuracy in elemental speciation studies .... 533
xx
15.3 Sources of errors in speciation analysis..............534
15.4 Calibration.............................536
15.5 The interlaboratory approach...................537
15.6 Certified reference materials—definitions............540
15.7 Requirements for the preparation of reference materials .... 541
15.7.1 Collection and pre-treatment...............542
15.7.2 Stabilization........................543
15.7.3 Homogenization......................546
15.7.4 Homogeneity control....................548
15.7.5 Stability control......................550
15.7.6 Storage and transport...................553
15.8 Procedures to certify and assign values..............555
15.8.1 Certification of reference materials............555
15.8.2 Assigned values......................558
15.9 Evaluation of results and data collection.............558
15.9.1 Description of the methods................559
15.9.2 Technical evaluation....................559
15.9.3 Statistical evaluation...................561
15.10 Availability of CRMs for quality control of speciation analysis . 563
15.11 Conclusions.............................565
Acknowledgements........................565
References.................................566
Index.....................................571
xxi
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| id | DE-604.BV013643729 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T18:49:29Z |
| institution | BVB |
| isbn | 0444500472 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-009321853 |
| oclc_num | 47002569 |
| open_access_boolean | |
| owner | DE-703 DE-Aug7 |
| owner_facet | DE-703 DE-Aug7 |
| physical | XVII, 581 S. Ill., graph. Darst. |
| publishDate | 2000 |
| publishDateSearch | 2000 |
| publishDateSort | 2000 |
| publisher | Elsevier |
| record_format | marc |
| series | Wilson and Wilson's Comprehensive analytical chemistry |
| series2 | Wilson and Wilson's Comprehensive analytical chemistry |
| spelling | Elemental speciation new approaches for trace element analysis ed. by Joseph A. Caruso... 1. ed. Amsterdam [u.a.] Elsevier 2000 XVII, 581 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Wilson and Wilson's Comprehensive analytical chemistry 33 Chimie de l'environnement - Méthodologie Eser analiz - Metodoloji Spéciation (Chimie) Ultramicrométhodes - Méthodologie Çevre kimyası - Metedoloji Environmental chemistry Methodology Speciation (Chemistry) Trace analysis Methodology Spurenelement (DE-588)4056595-6 gnd rswk-swf Spurenelement (DE-588)4056595-6 s DE-604 Caruso, Joseph A. Sonstige oth Wilson and Wilson's Comprehensive analytical chemistry 33 (DE-604)BV000900805 33 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009321853&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Elemental speciation new approaches for trace element analysis Wilson and Wilson's Comprehensive analytical chemistry Chimie de l'environnement - Méthodologie Eser analiz - Metodoloji Spéciation (Chimie) Ultramicrométhodes - Méthodologie Çevre kimyası - Metedoloji Environmental chemistry Methodology Speciation (Chemistry) Trace analysis Methodology Spurenelement (DE-588)4056595-6 gnd |
| subject_GND | (DE-588)4056595-6 |
| title | Elemental speciation new approaches for trace element analysis |
| title_auth | Elemental speciation new approaches for trace element analysis |
| title_exact_search | Elemental speciation new approaches for trace element analysis |
| title_full | Elemental speciation new approaches for trace element analysis ed. by Joseph A. Caruso... |
| title_fullStr | Elemental speciation new approaches for trace element analysis ed. by Joseph A. Caruso... |
| title_full_unstemmed | Elemental speciation new approaches for trace element analysis ed. by Joseph A. Caruso... |
| title_short | Elemental speciation |
| title_sort | elemental speciation new approaches for trace element analysis |
| title_sub | new approaches for trace element analysis |
| topic | Chimie de l'environnement - Méthodologie Eser analiz - Metodoloji Spéciation (Chimie) Ultramicrométhodes - Méthodologie Çevre kimyası - Metedoloji Environmental chemistry Methodology Speciation (Chemistry) Trace analysis Methodology Spurenelement (DE-588)4056595-6 gnd |
| topic_facet | Chimie de l'environnement - Méthodologie Eser analiz - Metodoloji Spéciation (Chimie) Ultramicrométhodes - Méthodologie Çevre kimyası - Metedoloji Environmental chemistry Methodology Speciation (Chemistry) Trace analysis Methodology Spurenelement |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009321853&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV000900805 |
| work_keys_str_mv | AT carusojosepha elementalspeciationnewapproachesfortraceelementanalysis |