Basic physical chemistry for the atmospheric sciences: a companion text to "Introduction to atmospheric chemistry"
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Cambridge [u.a.]
Cambridge Univ. Press
2000
|
| Edition: | 2. ed. |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XI, 209 S. graph. Darst. |
| ISBN: | 0521780837 0521785677 |
Staff View
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| 245 | 1 | 0 | |a Basic physical chemistry for the atmospheric sciences |b a companion text to "Introduction to atmospheric chemistry" |c Peter V. Hobbs |
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Record in the Search Index
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| adam_text | Contents
Preface to first edition ix
Preface to second edition xi
1 Chemical equilibrium 1
1.1 Some introductory concepts 1
1.2 Equilibrium constants 3
1.3 Reaction quotient 8
1.4 LeChatelier s principle 10
Exercises 12
2 Chemical thermodynamics 17
2.1 The first law of thermodynamics; enthalpy 17
2.2 Enthalpies of reaction and formation 21
2.3 Entropy and the second law of thermodynamics 22
2.4 The third law of thermodynamics; absolute entropies 26
2.5 Criteria for equilibrium and spontaneous
transformation 27
2.6 Standard free energy changes 29
2.7 Free energy change and the equilibrium constant 31
2.8 Chemical potential; homogeneous nucleation of
water-vapor condensation 34
Exercises 38
3 Chemical kinetics 43
3.1 Reaction rates 43
3.2 Reaction mechanisms 46
3.3 Reaction rates and equilibria 50
3.4 Collision theory of gaseous reactions 52
vi Contents
3.5 The effect of temperature on reaction rates:
the Arrhenius relation 55
3.6 Catalysis 57
3.7 Half-life, residence time, and renewal time 58
Exercises 61
4 Solution chemistry and aqueous equilibria 68
4.1 Definitions and types of solutions 68
4.2 Solution concentrations 68
4.3 Factors affecting solubility 70
4.4 Colligative properties 71
4.5 Aqueous solutions; electrolytes 72
4.6 Aqueous equilibria 73
4.7 Strong and weak electrolytes; ion-product constant
for water 78
Exercises 80
5 Acids and bases 83
5.1 Some definitions and concepts 83
5.2 The nature of H~(aq) 86
5.3 The Br0nsted-Lowry theory; conjugate acid-base pairs 86
5.4 Strengths of acids and bases; acid-dissociation
(or ionization) constant 87
5.5 The Lewis theory 88
5.6 The pH scale 88
5.7 Polyprotic acids 90
5.8 Hydrolysis 90
5.9 Buffers 93
5.10 Complex ions 96
5.11 Mass balance and charge balance relations 97
5.12 The pH of rainwater 98
Exercises 101
6 Oxidation-reduction reactions 104
6.1 Some definitions 104
6.2 Oxidation numbers 105
6.3 Balancing oxidation-reduction reactions 108
6.4 Half-reactions in electrochemical cells 115
6.5 Strengths of oxidants and reductants; standard cell
and half-cell potentials 116
Contents
vu
6.6 Standard cell potentials and free-energy change 124
6.7 The Nernst equation 126
6.8 Redox potentials; Eh-pH diagrams 128
6.9 Gram-equivalent weight and normality 130
Exercises 132
7 Photochemistry 137
7.1 Some properties of electromagnetic waves 137
7.2 Some photochemical terminology and principles 139
7.3 Quantum yields 141
7.4 Rate coefficients for photolysis 143
7.5 Photostationary states 145
7.6 Stratospheric ozone and photochemistry; depletion
of stratospheric ozone 146
Exercises 154
Appendix I International system of units (SI) 159
Appendix II Some useful numerical values 160
Appendix III Atomic weights 161
Appendix IV Equilibrium (or dissociation) constants for some
chemical reactions 164
Appendix V Some molar standard Gibbs free energies of
formation, molar standard enthalpies (or heats)
of formation, and molar absolute entropies
at 25°C and 1 atmosphere 169
Appendix VI Names, formulas, and charges of some
common ions 172
Appendix VII Answers to exercises and hints and solutions
to selected exercises 173
Index 187
|
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| dewey-full | 551.511 551.51/1 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 551 - Geology, hydrology, meteorology |
| dewey-raw | 551.511 551.51/1 |
| dewey-search | 551.511 551.51/1 |
| dewey-sort | 3551.511 |
| dewey-tens | 550 - Earth sciences |
| discipline | Geowissenschaften Geologie / Paläontologie Physik Chemie Geographie |
| edition | 2. ed. |
| format | Book |
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| id | DE-604.BV013515875 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T18:47:09Z |
| institution | BVB |
| isbn | 0521780837 0521785677 |
| language | English |
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| physical | XI, 209 S. graph. Darst. |
| publishDate | 2000 |
| publishDateSearch | 2000 |
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| publisher | Cambridge Univ. Press |
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| spelling | Hobbs, Peter Victor 1936-2005 Verfasser (DE-588)123310660 aut Basic physical chemistry for the atmospheric sciences a companion text to "Introduction to atmospheric chemistry" Peter V. Hobbs 2. ed. Cambridge [u.a.] Cambridge Univ. Press 2000 XI, 209 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Atmospheric chemistry Atmospheric physics Chemistry, Physical and theoretical Physikalische Chemie (DE-588)4045959-7 gnd rswk-swf Meteorologie (DE-588)4038953-4 gnd rswk-swf Physikalische Chemie (DE-588)4045959-7 s Meteorologie (DE-588)4038953-4 s DE-604 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009224673&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Hobbs, Peter Victor 1936-2005 Basic physical chemistry for the atmospheric sciences a companion text to "Introduction to atmospheric chemistry" Atmospheric chemistry Atmospheric physics Chemistry, Physical and theoretical Physikalische Chemie (DE-588)4045959-7 gnd Meteorologie (DE-588)4038953-4 gnd |
| subject_GND | (DE-588)4045959-7 (DE-588)4038953-4 |
| title | Basic physical chemistry for the atmospheric sciences a companion text to "Introduction to atmospheric chemistry" |
| title_auth | Basic physical chemistry for the atmospheric sciences a companion text to "Introduction to atmospheric chemistry" |
| title_exact_search | Basic physical chemistry for the atmospheric sciences a companion text to "Introduction to atmospheric chemistry" |
| title_full | Basic physical chemistry for the atmospheric sciences a companion text to "Introduction to atmospheric chemistry" Peter V. Hobbs |
| title_fullStr | Basic physical chemistry for the atmospheric sciences a companion text to "Introduction to atmospheric chemistry" Peter V. Hobbs |
| title_full_unstemmed | Basic physical chemistry for the atmospheric sciences a companion text to "Introduction to atmospheric chemistry" Peter V. Hobbs |
| title_short | Basic physical chemistry for the atmospheric sciences |
| title_sort | basic physical chemistry for the atmospheric sciences a companion text to introduction to atmospheric chemistry |
| title_sub | a companion text to "Introduction to atmospheric chemistry" |
| topic | Atmospheric chemistry Atmospheric physics Chemistry, Physical and theoretical Physikalische Chemie (DE-588)4045959-7 gnd Meteorologie (DE-588)4038953-4 gnd |
| topic_facet | Atmospheric chemistry Atmospheric physics Chemistry, Physical and theoretical Physikalische Chemie Meteorologie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009224673&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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