Electrochemistry of glasses and glass melts, including glass electrodes:
Saved in:
| Format: | Book |
|---|---|
| Language: | English |
| Published: |
Berlin [u.a.]
Springer
2001
|
| Series: | Schott series on glass and glass ceramics
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XVI, 451 S. graph. Darst. |
| ISBN: | 3540586083 |
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MARC
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| 245 | 1 | 0 | |a Electrochemistry of glasses and glass melts, including glass electrodes |c Hans Bach ... (eds.) |
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Record in the Search Index
| _version_ | 1804128144944267264 |
|---|---|
| adam_text | HANS BACH FRIEDRICH G.K. BAUCKE DIETER KRAUSE EDITORS ELECTROCHEMISTRY
OF GLASSES AND GLASS MELTS, INCLUDING GLASS ELECTRODES WITH 146 FIGURES
AND 22 TABLES FFLTI SPRINGER CONTENTS 0. ABOUT TERMINOLOGY 1 DIETER
KRAUSE 1. OVERVIEW 5 FRIEDRICH G.K. BAUCKE 1.1 SOLID GLASSES 6 1.1.1
GLASS ELECTRODES 6 1.1.2 GLASS ELECTROLYSIS 9 1.1.3 IONIC TRANSPORT:
CONDUCTIVITY 12 1.1.4 MIXED-ALKALI EFFECT 13 1.1.5 GLASS CORROSION,
GLASS DURABILITY 16 1.1.6 ACTIVE THIN-LAYER SYSTEMS 18 1.1.7
ELECTROMETRIC PH MEASUREMENT 21 1.2 ISOTHERMAL GLASS-FORMING MELTS 24
1.2.1 REDOX STATE AND BASICITY 24 1.2.2 TRANSPORT PROPERTIES: ELECTRICAL
CONDUCTIVITY 27 1.3 NON-ISOTHERMAL OXIDIC GLASS-FORMING MELTS 28
REFERENCES 29 2. ELECTROCHEMISTRY OF SOLID GLASSES 35 FRIEDRICH G.K.
BAUCKE 2.1 INTRODUCTION 35 2.2 OPERATIONAL BASIS AND RESPONSE OF GLASS
ELECTRODES 39 2.3 HISTORICAL NOTES 46 2.4 EXPERIMENTAL METHODS FOR THE
INVESTIGATION OF GLASS-SOLUTION INTERFACES 54 2.5 GLASS IN CONTACT WITH
SOLUTIONS - INTERFACIAL EQUILIBRIA 58 2.5.1 QUALITATIVE DESCRIPTION 59
2.5.2 QUANTITATIVE TREATMENT 66 2.5.3 RIGOROUS EXAMINATION OF
INTERFACIAL EQUILIBRIA - THE SUB-NERNSTIAN RESPONSE 71 2.5.4 THE
TRANSITION RANGE BETWEEN THE PH AND THE PM RESPONSE OF GLASS ELECTRODES
81 2.5.5 KINETICS OF INTERFACIAL EQUILIBRIA 89 XIV CONTENTS 2.6
FIELD-DRIVEN TRANSPORT OF IONS INTO AND WITHIN GLASSES 96 2.6.1 ELECTRIC
CONTACTS 96 2.6.2 ELECTROMIGRATION OF GUEST PROTONS AND GUEST
DEUTERONS 100 2.6.3 INTERFACIAL EQUILIBRIA IN ELECTRIC FIELDS -
TRANSFER OF DIFFERENT CATIONS ACROSS GLASS-SOLUTION INTERFACES 109 2.6.4
STERICAL EFFECTS 117 2.6.5 SINMLTANEOUS ELECTROMIGRATION OF IONS AND
GUEST IONS 121 2.6.6 THE MOVING BOUNDARY BETWEEN DIFFERENT ELECTRO-
MIGRATING IONS 135 2.6.7 PROTON TRAPS AND HEAT TREATMENT-INDUCED NETWORK
CHANGES 145 2.6.8 A DIFFERENT SITUATION: ELECTROLYSIS OF BORATE GLASSES.
. 151 2.7 INTERFACIAL EQUILIBRIA UNDER THE INFLUENCE OF SUBSURFACE
CONCENTRATION GRADIENTS 156 2.7.1 PROTON/ALKALI ION INTERDIFFUSION:
GLASS LEACHING 159 2.7.2 INTERACTION OF GLASSES WITH HUMID ATMOSPHERES
169 2.7.3 ALKALI/ALKALI ION INTERDIFFUSION 171 2.7.4 DIFFUSION
POTENTIALS IN SUBSURFACE GLASS LAYERS 173 2.7.5 ADDITIONAL SURFACE
REACTIONS 182 2.7.6 SIGMFICANCE OF INTERFACIAL EQUILIBRIA FOR GLASS
CORROSION 186 2.8 HYDROGEN-SENSITIVE PLATINUM-COVERED GLASS ELECTRODE
MEMBRANES 190 2.9 THE DISSOCIATION MECHANISM OF GLASS ELECTRODES -
DISCUSSION 196 2.9.1 INTERFACIAL EQUILIBRIUM 196 2.9.2 SUBSURFACE
INTERDIFFUSION 209 2.9.3 PD RESPONSE OF GLASS MEMBRANES 217 2.9.4
POTENTIALTMPAIRING REACTIONS 219 2.10 ELECTROMETRIC PH MEASUREMENTS 220
2.10.1 DEFINITION OF PH . . 221 2.10.2 PRINCIPLES OF PH MEASUREMENT 223
2.10.3 PRIMARY STANDARD BUFFER SOLUTIONS - ASSIGNMENT OF PH(PS) 224
2.10.4 SECONDARY STANDARD BIIFFER SOLUTIONS - ASSIGNMENT OF PH(SS) 227
2.10.5 CALIBRATION OF PH METER-ELECTRODE ASSEMBLIES 228 2.10.6
BRACKETING PROCEDURE 229 2.10.7 MULTIPLE-POINT CALIBRATION WITH LINEAR
REGRESSION . . . 229 2.10.8 THE SLOPE OF CELLS WITH TRANSFERENCE
CONTAINING STANDARD BUFFER SOLUTIONS 230 CONTENTS XV 2.10.9 PAST
PROPOSAL OF AN ALTERNATIVE PH SCALE BY BSI 234 2.10.10 INTERNATIONAL
RECOMMENDATIONS OF PH MEASUREMENT . 235 2.10.11 MEASUREMENT OF HYDROGEN
ION CONCENTRATIONS 237 2.10.12 REFERENCE ELECTRODES 238 2.10.13 THE
MEANING OF THE UNCERTAINTY OF PH VALUES 242 2.11 APPLICATION OF GLASS
ELECTRODES IN HEAVY WATER 242 2.11.1 MECHANISM OF PD RESPONSE 243 2.11.2
DEUTERON EFFECT 245 2.11.3 DEUTERIUM OXIDE EFFECT 250 REFERENCES 253 3.
ELECTROCHEMISTRY OF GLASS-FORMING MELTS 269 3.1 INTRODUCTION FRIEDRICH
G.K. BAUCKE 269 3.2 ELECTROCHEMICAL CHARACTERIZATION FRIEDRICH G.K.
BAUCKE . . 272 3.3 BASICITY OF GLASS-FORMING MELTS JOHN DUFFY 275 3.3.1
DEVELOPMENT OF BASICITY CONCEPTS 275 3.3.2 OPTICAL BASICITY 278 3.3.3
REDOX REACTIONS IN MELTS 289 3.4 OXYGEN IN GLASS-FORMING MELTS FRIEDRICH
G.K. BAUCKE. . . . 301 3.4.1 ELECTROCHEMICAL CELLS FOR ON-LINE
MEASUREMENT OF OXYGEN PARTIAL PRESSURES 304 3.4.2 MEASURING ELECTRODES
306 3.4.3 REFERENCE ELECTRODES 308 3.4.4 VERIFICATION OF THE
THERMODYNAMICALLY CORRECT RESPONSE OF OXYGEN SENSORS 313 3.4.5
ALTERNATIVE REFERENCE ELECTRODES 317 3.5 APPLICATION OF OXYGEN SENSORS
FRIEDRICH G.K. BAUCKE 322 3.5.1 (REDOX) FINING OF OXIDIC GLASS-FORMING
MELTS FRIEDRICH G.K. BAUCKE 323 3.5.2 THERMODYNAMIC STANDARD DATA OF
REDOX EQUILIBRIA FRIEDRICH G.K. BAUCKE 330 3.5.3 SULPHATE FINING DETLEF
KAPSEL 346 3.5.4 TEST OF TECHNICAL OXYGEN SENSORS FRIEDRICH G.K. BAUCKE
353 3.5.5 ELECTROLYTIC FINING FRIEDRICH G.K. BAUCKE 359 3.6
NON-ISOTHERMAL GLASS-FORMING MELTS FRIEDRICH G.K. BAUCKE 367 3.6.1
MEASUREMENT OF THERMOELECTRIC VOLTAGES - STANDARD SEEBECK COEFFICIENTS
369 3.6.2 APPLICATION OF OXYGEN SENSORS IN NON-ISOTHERMAL MELTS 374
3.6.3 SHORT-CIRCUITED PLATINUM PARTS IN NON-ISOTHERMAL MELTS 376 3.6.4
DECOMPOSITION OF OXIDIC GLASS MELTS BY SHORT- CIRCUITED NON-ISOTHERMAL
METAL ELECTRODES 383 XVI CONTENTS 3.7 ARRANGEMENT FOR DISPLACING
ELECTROCHEMICAL REACTIONS FRIEDRICH G.K. BAUCKE 385 3.8 OXYGEN BUBBLE
FORMATION AT MELT/REFRACTORY INTERFACES FRIEDRICH G.K. BAUCKE 391 3.8.1
THE REACTION MECHANISM 392 3.8.2 A SUBSURFACE ELECTROCHEMICAL CELL 394
3.8.3 GENERAL REACTION MECHANISM, TECHNICAL APPLICATION . 405 3.9 THE
CONDUCTIVITY OF GLASS-FORMING MELTS FRIEDRICH G.K. BAUCKE 408 3.9.1 A
CRITICAL ANALYSIS OF REPORTED CONDUCTIVITY CELLS . . 409 3.9.2
CONDUCTANCE CELL DESIGNED AT SCHOTT GLAS 412 3.9.3 APPLICATION OF THE
SCHOTT CELL TO MIXED-ALKALI GLASS MELTS 416 REFERENCES 420 LIST OF
CONTRIBUTING AUTHORS 437 SOURCES OF FIGURES AND TABLES 439
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| illustrated | Illustrated |
| indexdate | 2024-07-09T18:44:35Z |
| institution | BVB |
| isbn | 3540586083 |
| language | English |
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| physical | XVI, 451 S. graph. Darst. |
| publishDate | 2001 |
| publishDateSearch | 2001 |
| publishDateSort | 2001 |
| publisher | Springer |
| record_format | marc |
| series2 | Schott series on glass and glass ceramics |
| spelling | Electrochemistry of glasses and glass melts, including glass electrodes Hans Bach ... (eds.) Berlin [u.a.] Springer 2001 XVI, 451 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Schott series on glass and glass ceramics Eletroquímica larpcal Vidro larpcal Electrochemistry Electrodes, Glass Glass Glasschmelze (DE-588)4122177-1 gnd rswk-swf Elektrochemie (DE-588)4014241-3 gnd rswk-swf Glas (DE-588)4021142-3 gnd rswk-swf Glasschmelze (DE-588)4122177-1 s Elektrochemie (DE-588)4014241-3 s DE-604 Glas (DE-588)4021142-3 s Bach, Hans 1930- Sonstige (DE-588)115540245 oth GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009117552&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Electrochemistry of glasses and glass melts, including glass electrodes Eletroquímica larpcal Vidro larpcal Electrochemistry Electrodes, Glass Glass Glasschmelze (DE-588)4122177-1 gnd Elektrochemie (DE-588)4014241-3 gnd Glas (DE-588)4021142-3 gnd |
| subject_GND | (DE-588)4122177-1 (DE-588)4014241-3 (DE-588)4021142-3 |
| title | Electrochemistry of glasses and glass melts, including glass electrodes |
| title_auth | Electrochemistry of glasses and glass melts, including glass electrodes |
| title_exact_search | Electrochemistry of glasses and glass melts, including glass electrodes |
| title_full | Electrochemistry of glasses and glass melts, including glass electrodes Hans Bach ... (eds.) |
| title_fullStr | Electrochemistry of glasses and glass melts, including glass electrodes Hans Bach ... (eds.) |
| title_full_unstemmed | Electrochemistry of glasses and glass melts, including glass electrodes Hans Bach ... (eds.) |
| title_short | Electrochemistry of glasses and glass melts, including glass electrodes |
| title_sort | electrochemistry of glasses and glass melts including glass electrodes |
| topic | Eletroquímica larpcal Vidro larpcal Electrochemistry Electrodes, Glass Glass Glasschmelze (DE-588)4122177-1 gnd Elektrochemie (DE-588)4014241-3 gnd Glas (DE-588)4021142-3 gnd |
| topic_facet | Eletroquímica Vidro Electrochemistry Electrodes, Glass Glass Glasschmelze Elektrochemie Glas |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009117552&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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