Synthetic methods of organometallic and inorganic chemistry: 9 Transition metals ; Pt. 3
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| Format: | Book |
|---|---|
| Language: | German |
| Published: |
Stuttgart [u.a.]
Thieme
2000
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XI, 221 S. Ill. |
| ISBN: | 3131151412 0865779716 |
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| 245 | 1 | 0 | |a Synthetic methods of organometallic and inorganic chemistry |n 9 |p Transition metals ; Pt. 3 |c [ed.] Herrmann ... |
| 264 | 1 | |a Stuttgart [u.a.] |b Thieme |c 2000 | |
| 300 | |a XI, 221 S. |b Ill. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 7 | |a Composés inorganiques - Synthèse |2 ram | |
| 650 | 7 | |a Composés organométalliques - Synthèse |2 ram | |
| 650 | 7 | |a Métaux de transition - Composés organiques |2 ram | |
| 700 | 1 | |a Herrmann, Wolfgang A. |d 1948- |e Sonstige |0 (DE-588)123397472 |4 oth | |
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| _version_ | 1807504721544478720 |
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CONTENTS
CHAPTER
1
ALKENYL,
ALLYL,
AND
DIENYL
COMPLEXES
OF
MAIN
GROUP
ELEMENTS
AND
TRANSITION
METALS
RUEDIGER
BECKHAUS
.
1
1.1
INTRODUCTION
.
2
1.2
1-AIKENYL
COMPOUNDS
.
3
1.2.1
GENERAL
SYNTHESES
OF
TRANSITION
METAL-VINYL
COMPLEXES
.
4
1.2.2
MAIN
GROUP
ELEMENTS
.
7
1.2.3
TRANSITION
METAL
COMPOUNDS
.
9
1.3
ALLYL
COMPOUNDS
.
13
1.3.1
MAIN
GROUP
COMPOUNDS
.
13
1.3.2
TRANSITION
METAL
COMPOUNDS
.
19
1.4
DIENYL
COMPOUNDS
.
43
1.5
POLYENYL
COMPOUNDS
.
50
CHAPTER
2
TT-COMPLEXES
WITH
HETEROCYCLIC
LIGANDS
NORBERT
KUHN
.
53
2.1
INTRODUCTION
.
54
2.2
PENTAMETHYLPYRROLE
COMPLEXES
.
57
2.3
(P
5
-PYRROLYL)TRICARBONYLMANGANESE
(AZACYMANTRENE)
.
59
2.4
(R]
5
-CYCLOPENTADIENYL)(R|
5
-L/F-PYRROL-L-YL)IRON
(AZAFERROCENE)
.
60
2.5
2,5-DI-/ERT.-BUTYI-L-AZACYCLOPENTADIENYL
COMPLEXES
.
62
2.6
R]
5
-PHOSPHOLYL
COMPLEXES
OF
EARLY TRANSITION
METALS
.
64
2.6.1
SYNTHESIS
OFPHOSPHOLYL
PRECURSORS
.
65
2.6.2
SYNTHESIS
OFPHOSPHOLYL
COMPLEXES
.
68
2.7
4,5DIPHENYL-L,3-DIPHOSPHOLIDE
ANION
AND
(R|
5
-DIPHENYL-L,3-DIPHOSPHOLYL)
(R]
5
-CYCLOPENTADIENYL)IRON
.
72
2.8
2,2
'
,5,5
'
-TETRAKIS(TRIMETHYLSILYL)-3,3
'
,4,4
'
-TERAETHYL-L,L
'
-DISTIBAFERROCENE
.
76
2.9
BIS(L-ZERT.-BUTYL-2-METHYL-LAE-L,2-AZABOROLYL)IRON
AND
(L-ZERT.-BUTYL-2-METHYL
LAE-L,2-AZABOROLYL)(DICARBONYL)COBALT
.
80
CHAPTER
3
COMPLEXES
OF
7V-HETEROCYCLIC
CARBENES
WOLFGANG
A.
HERRMANN,
FLORIAN
J.
KOHL,
JUERGEN
SCHWARZ
.
84
3.1
INTRODUCTION
.
85
3.2
HIGH-YIELDING
SYNTHESIS
OF
FUNCTIONALIZED
N-HETEROCYCLIC
CARBENES
IN
LIQUID
AMMONIA
.
85
X
CONTENTS
3.3
SYNTHESIS
OF
NHC
COMPLEXES
BY
A
METALLA-LGZ
REACTION
.
87
3.4
NICKEI(II)
COMPLEXES
.
88
3.5
NICKEL(0)
COMPLEXES
.
90
3.6
PALIADIUM(II)
COMPLEXES
.
92
3.7
IMMOBILIZATION
OFPD(II)-NHC
COMPLEXES
.
97
3.8
PALLADIUM(O)
COMPLEXES
.
101
3.9
IRIDIUM(III)
COMPLEXES
.
R
.
104
3.10
RUTHENIUM(II)
COMPLEXES
.
106
CHAPTER
4
OXO
AND
ALKOXY-COMPLEXES
FRITZ
E.
KUEHN,
WOLFGANG
A.
HERRMANN,
JOERG
FRIDGEN,
ANAM.
SANTOS
.
113
4.1
ALKYLTRIOXOMETAL
COMPLEXES
.
114
4.2
OXOHALIDES
OF
MOLYBDENUM
AND
TUNGSTEN
.
117
4.2.1
TETRACHLOROOXOMOLYBDENUM
AND
-TUNGSTEN
.
117
4.2.2
DICHLORODIOXOMOLYBDENUM
AND-TUNGSTEN
.
118
4.2.3
DICHLORODIOXOBIS(TRIPHENYLPHOSPHANE
OXIDE)MOLYBDENUM
AND
-TUNGSTEN,
DIOXOTUNGSTENACETYLACETONATE
.
119
4.3
TRICHLOROOXOTUNGSTEN
COMPOUNDS
WITH
PYRIDYL
ALCOHOLATE
LIGANDS
.
121
4.4
DIOXOMOLYBDENUM
AND
-TUNGSTEN
COMPOUNDS
WITH
PYRIDYL
ALCOHOLATE
LIGANDS
123
4.5
VARIOUS
COMPOUNDS
WITH
PYRIDYL
ALCOHOLATE
LIGANDS
.
127
4.5.1
RHENIUM(V)
COMPOUNDS
.
127
4.5.2
PALLADIUM
AND
COPPER
COMPLEXES
.
130
4.6
SOLVENT
ADDUCTS
OF
DIBROMODIOXOMOLYBDENUM
.
131
4.7
LEWIS
BASE
ADDUCTS
OF
DIHALODIOXOMOLYBDENUM(VI)
.
133
4.7.1
DIHALO(
1
,4-DI-P-TOLYL
1
,4-DIAZABUTA
1
,3-DIENE)DIOXOMOLYBDENUM(VI)
.
133
4.7.2
(L,4-DI-ZERT.-BUTYL-L,4-DIAZABUTA-L,3-DIENE)DIHALODIOXOMOLYBDENUM(VI)
.
135
4.8
TRIGONAL
BIPYRAMIDAL
LEWIS
BASE
ADDUCTS
OF
METHYLTRIOXORHENIUM(VII)
.
137
4.8.1
PYRIDINE ADDUCTS
OF
METHYITRIOXORHENIUM
.
137
4.7.2
BIPYRIDINE
ADDUCTS
OF
METHYLTRIOXORHENIUM
.
138
CHAPTER
5
HIGHLY
REDUCED
TANTALUM
CARBONYLS
DERIVED
FROM
THE
HEXACARBONYLTANTALUM
ANION
JOHNE.
ELLIS,
GARRY
F.
WARNOCK.
.
141
5.1
HEXACARBONYLTANTALATES(L-)
.
142
5.2
PENTACARBONYLTANTALATES(3-)
.
145
5.3
PENTACARBONYLHYDRIDOTANTALATES(2-)
.
147
5.4
(AMMINE)(PENTACARBONYL)TANTALATES(L-)
.
148
CONTENTS
XI
5.5
(TERT.-BUTYL
ISOCYANIDE)(PENTACARBONYL)TANTALATES(L-)
.
149
5.6
(CYANO)(PENTACARBONYL)TANTALATES(2-)
.
150
CHAPTER
6
WATER-SOLUBLE
METAL
COMPLEXES
OF
SULFONATED
TRIPHENYLPHOSPHANE
(TPPTS)
WOLFGANG
A.
HERRMANN
.
153
6.1
INTRODUCTION
.
154
6.2
GENERAL
REMARKS
.
155
6.3
GEL
PERMEATION
CHROMATOGRAPHY
.
155
6.3.1
APPARATES
.
155
6.3.2
COLUMN
PACKING
.
157
6.4
SULFONATED
PHOSPHANES
.
158
6.5
TPPTS-METAL
COMPLEXES
.
160
CHAPTER
7
MISCELLANEOUS
COMPLEXES
WOLFGANG
A.
HERRMANN,
FLORIAN
J.
KOHL
.
178
7.1
(PENTAMETHYLCYCLOPENTADIENYL)(PHOSPHANE)RUTHENIUM
COMPLEXS
.
179
7.2
ALLYL
AND
PHOSPHANE
COMPLEXES
OF
PALLADIUM
.
182
7.3
A
SELECTION
OF
IMPORTANT
ALKYLIDENE-METAL
COMPLEXES
.
185
7.3.1
INTRODUCTION
.
185
7.3.2
RUTHENIUM-ALKYLIDENE
COMPLEXES
.
185
7.3.3
TUNGSTEN-ALKYLIDENE
COMPLEXES
.
187
7.3.4
RUTHENIUM-VINYLIDENE
AND-ALLENYLIDENE
COMPLEXES
.
188
7.4
BISIMINO
SYSTEMS
(BROOKHART-GIBSON
SYSTEMS)
.
194
INDEX
.
203
LIST
OF
TRANSITION
METAL
COMPLEXES
IN
OTHER
VOLUMES
OF
THIS
SERIES
.
219 |
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| isbn | 3131151412 0865779716 |
| language | German |
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| physical | XI, 221 S. Ill. |
| publishDate | 2000 |
| publishDateSearch | 2000 |
| publishDateSort | 2000 |
| publisher | Thieme |
| record_format | marc |
| spelling | Synthetic methods of organometallic and inorganic chemistry 9 Transition metals ; Pt. 3 [ed.] Herrmann ... Stuttgart [u.a.] Thieme 2000 XI, 221 S. Ill. txt rdacontent n rdamedia nc rdacarrier Composés inorganiques - Synthèse ram Composés organométalliques - Synthèse ram Métaux de transition - Composés organiques ram Herrmann, Wolfgang A. 1948- Sonstige (DE-588)123397472 oth (DE-604)BV010664136 9 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008907553&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Synthetic methods of organometallic and inorganic chemistry Composés inorganiques - Synthèse ram Composés organométalliques - Synthèse ram Métaux de transition - Composés organiques ram |
| title | Synthetic methods of organometallic and inorganic chemistry |
| title_auth | Synthetic methods of organometallic and inorganic chemistry |
| title_exact_search | Synthetic methods of organometallic and inorganic chemistry |
| title_full | Synthetic methods of organometallic and inorganic chemistry 9 Transition metals ; Pt. 3 [ed.] Herrmann ... |
| title_fullStr | Synthetic methods of organometallic and inorganic chemistry 9 Transition metals ; Pt. 3 [ed.] Herrmann ... |
| title_full_unstemmed | Synthetic methods of organometallic and inorganic chemistry 9 Transition metals ; Pt. 3 [ed.] Herrmann ... |
| title_short | Synthetic methods of organometallic and inorganic chemistry |
| title_sort | synthetic methods of organometallic and inorganic chemistry transition metals pt 3 |
| topic | Composés inorganiques - Synthèse ram Composés organométalliques - Synthèse ram Métaux de transition - Composés organiques ram |
| topic_facet | Composés inorganiques - Synthèse Composés organométalliques - Synthèse Métaux de transition - Composés organiques |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008907553&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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