Modified cyclodextrins: scaffolds and templates for supramolecular chemistry
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| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
London
Imperial College Press
1999
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | IX, 293 S. graph. Darst. |
| ISBN: | 1860941443 |
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| 245 | 1 | 0 | |a Modified cyclodextrins |b scaffolds and templates for supramolecular chemistry |c Christopher J. Easton ; Stephen F. Lincoln |
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Record in the Search Index
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| adam_text | Contents
Chapter 1
CYCLODEXTRIN STRUCTURE AND COMPLEXATION BEHAVIOUR 1
1 1 Introduction 1
1 2 Natural Cyclodextrins and Their Structures 2
1 3 Cyclodextrin Complexation Processes 5
1 4 Enthalpy-Entropy Compensation in Cyclodextrin Complexation 9
1 5 Examples of Cyclodextrin Complexation 12
1 6 Kinetics of Cyclodextrin Complexation 18
1 7 Chiral Discrimination in Cyclodextrin Complexes 30
1 8 References 32
Chapter 2
STRATEGIES FOR SYNTHESIS 43
2 1 Introduction 43
2 2a Modifications Involving Reaction of a Single C(6)
Primary Hydroxy Group 45
2 2b Facial Modifications Involving Reaction of All the
C(6) Primary Hydroxy Groups 49
2 2c Modifications Involving Reaction of Two, Three
or Four C(6) Primary Hydroxy Groups 52
2 3a Modifications Involving Reaction of a Single C(2)
Secondary Hydroxy Group 54
2 3b Modifications Involving Reaction of Multiple C(2)
Secondary Hydroxy Groups 58
2 4a Modifications Involving Reaction of a Single C(3)
Secondary Hydroxy Group 60
2 4b Modifications Involving Reaction of Multiple C(3)
Secondary Hydroxy Groups 62
2 5 Conclusion 64
2 6 References 64
Vll
viii Contents
Chapter 3
INTRAMOLECULAR COMPLEXATION, CHIRAL
DISCRIMINATION AND PHOTOCHEMICAL DEVICES 71
3 1 Intramolecular Complexation Modes Displayed
by Modified Cyclodextrins 71
3 2 Molecular Recognition by Intramolecular Complexes
of Substituted Cyclodextrins 79
3 3 Molecular Sensors Based on Guest-Induced Dissociation
of Intramolecular Complexes 86
3 4 Towards Photochemical Frequency Switches and Related
Molecular Devices 89
3 5 References 96
Chapter 4
CYCLODEXTRIN CATALYSTS AND ENZYME MIMICS 101
4 1 Introduction 101
4 2 Cyclodextrin Hydrolases 102
4 3 Cyclodextrin Isomerases 113
4 4 Cyclodextrin Lyases 117
4 5 Cyclodextrin Transferases 121
4 6 Cyclodextrin Oxidoreductases 124
4 7 Future Prospects 125
4 8 References 129
Chapter 5
MET ALLOC YCLODEXTRINS 13 3
5 1 Cyclodextrins, Metal Complexes and Metallocyclodextrins 133
5 2 Metallocyclodextrins of Modified Cyclodextrins 136
5 3 Metallocyclodextrins and Chiral Discrimination 143
5 4 Catalytic Metallocyclodextrins: Mono-Cyclodextrin Systems 147
5 5 Catalytic Organometallocyclodextrins: Mono-Cyclodextrin
Systems 155
5 6 Catalytic Metallocyclodextrins: Multi-Cyclodextrin Systems 161
5 7 Corrin and Porphyrin Metallocyclodextrins and Catalysis 170
Contents ix
5 8 Energy and Electron Transfer in Metallocyclodextrins 180
5 9 References 184
Chapter 6
MULTISITE COMPLEXATION OF GUESTS
AND LINKED CYCLODEXTRINS 191
6 1 Multiple Complexation of Guest Species by Cyclodextrins 191
6 2 Dimerisation of Modified Cyclodextrins 194
6 3 Covalently Linked Cyclodextrin Dimers 197
6 4 Porphyrin Complexing, Porphyrin Substituted Cyclodextrins and Related Systems 208
6 5 Calixarene Substituted Cyclodextrins 215
6 6 Polymeric Cyclodextrins 217
6 7 References 222
Chapter 7 CYCLODEXTRIN ROTAXANES AND CATENATES 227
7 1 Introduction 227
7 2 Cyclodextrin Pseudorotaxanes 229
7 3 Cyclodextrin Rotaxanes with Organic End Groups 236
7 4 Cyclodextrin Rotaxanes with Metal Complex End Groups 241
7 5 Cyclodextrin Catenanes 249
7 6 Cyclodextrin Pseudopolyrotaxanes and Polyrotaxanes 252
7 7 References 261
Chapter 8 SURFACE AND INTERFACE BEHAVIOUR 265
8 1 Introduction 265
8 2 Amphiphilic Cyclodextrin Monolayers at the Air-Water Interface 265
8 3 Langmuir-Blodgett Films 272
8 4 Cyclodextrin Monolayers on Gold and Silver 275
8 5 Micelles and Vesicles of Amphiphilic Cyclodextrins 281
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| spelling | Easton, Christopher J. Verfasser aut Modified cyclodextrins scaffolds and templates for supramolecular chemistry Christopher J. Easton ; Stephen F. Lincoln London Imperial College Press 1999 IX, 293 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Cyclodextrine gtt Cyclodextrins Macromolecules Synthesis Cyclodextrine (DE-588)4148527-0 gnd rswk-swf Cyclodextrine (DE-588)4148527-0 s DE-604 Lincoln, Stephen F. Verfasser aut HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008712832&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Easton, Christopher J. Lincoln, Stephen F. Modified cyclodextrins scaffolds and templates for supramolecular chemistry Cyclodextrine gtt Cyclodextrins Macromolecules Synthesis Cyclodextrine (DE-588)4148527-0 gnd |
| subject_GND | (DE-588)4148527-0 |
| title | Modified cyclodextrins scaffolds and templates for supramolecular chemistry |
| title_auth | Modified cyclodextrins scaffolds and templates for supramolecular chemistry |
| title_exact_search | Modified cyclodextrins scaffolds and templates for supramolecular chemistry |
| title_full | Modified cyclodextrins scaffolds and templates for supramolecular chemistry Christopher J. Easton ; Stephen F. Lincoln |
| title_fullStr | Modified cyclodextrins scaffolds and templates for supramolecular chemistry Christopher J. Easton ; Stephen F. Lincoln |
| title_full_unstemmed | Modified cyclodextrins scaffolds and templates for supramolecular chemistry Christopher J. Easton ; Stephen F. Lincoln |
| title_short | Modified cyclodextrins |
| title_sort | modified cyclodextrins scaffolds and templates for supramolecular chemistry |
| title_sub | scaffolds and templates for supramolecular chemistry |
| topic | Cyclodextrine gtt Cyclodextrins Macromolecules Synthesis Cyclodextrine (DE-588)4148527-0 gnd |
| topic_facet | Cyclodextrine Cyclodextrins Macromolecules Synthesis |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008712832&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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