Preparation of solid catalysts:
Saved in:
| Format: | Book |
|---|---|
| Language: | English |
| Published: |
Weinheim [u.a.]
Wiley-VCH
1999
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Literaturangaben |
| Physical Description: | XVII, 622 S. Ill., graph. Darst. |
| ISBN: | 3527298266 |
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Record in the Search Index
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| adam_text | PREPARATION OF SOLID CATALYSTS EDITED BY G. ERTL, H. KNOEZINGER. J.
WEITKAMP WILEY-VCH WEINHEIM * NEW YORK * CHICHESTER * BRISBANE *
SINGAPORE * TORONTO CONTENTS 1 INTRODUCTION 1 2 DEVELOPING INDUSTRIAL
CATALYSTS (J. F. LEPAGE) 3 2.1 PROPERTIES AND CHARACTERISTICS OF
INDUSTRIAL CATALYSTS 3 2.1.1 ACTIVITY 3 2.1.2 SELECTIVITY 3 2.1.3
STABILITY 4 2.1.4 MORPHOLOGY 4 2.1.5 MECHANICAL STRENGTH 5 2.1.6 THERMAL
CHARACTERISTICS 5 2.1.7 REGENERABILITY 5 2.1.8 REPRODUCIBILITY 5 2.1.9
ORIGINALITY 6 2.1.10 COST 6 2.2 THE IDEAL CATALYST AND THE OPTIMUM
CATALYST 6 2.2.1 CATALYST DEVELOPMENT 7 2.2.2 DEVISING THE FIRST
CATALYTIC FORMULAS 8 2.2.3 OPTIMIZATION OF A TYPICAL CATALYTIC FORMULA
10 3 BULK CATALYSTS AND SUPPORTS N 3.1 FUSED CATALYSTS (R. SCHLOEGL) 11
3.1.1 INTRODUCTION 11 3.1.2 CONCEPT OF FUSED CATALYSTS 12 3.1.3
THERMODYNAMIC AND KINETIC CONSIDERATIONS 17 3.1.4 SULFURIC ACID CATALYST
19 VIII CONTENTS 3.1.5 METALLIC GLASSES 21 3.1.6 MESOSTRUCTURE OF FUSED
CATALYST MATERIALS 25 3.2 SKELETAL METAL CATALYSTS (M. S. WAINWRIGHT) 28
3.2.1 INTRODUCTION 28 3.2.2 GENERAL ASPECTS 29 3.2.3 SKELETAL NICKEL
CATALYSTS 31 3.2.4 PROMOTED SKELETAL NICKEL CATALYSTS 34 3.2.5 SKELETAL
COBALT CATALYSTS 34 3.2.6 SKELETAL COPPER CATALYSTS 35 3.2.7 PROMOTED
SKELETAL COPPER CATALYSTS 37 3.2.8 SKELETAL COPPER-ZINC CATALYSTS 38 3.3
METALLIC GLASSES (A. BAIKER) 43 3.3.1 INTRODUCTION 43 3.3.2 PREPARATION
43 3.3.3 CHEMICAL AND STRUCTURAL PROPERTIES 44 3.3.4 METALLIC GLASSES IN
CATALYSIS RESEARCH 46 3.3.4.1 RESEARCH ON METALLIC GLASSES IN
AS-QUENCHED STATE 46 3.3.4.2 METALLIC GLASSES AS PRECURSORS TO
CATALYTICALLY ACTIVE MATERIALS 49 3.3.5 CASE STUDIES: CO OXIDATION
CATALYSTS PREPARED FROM METALLIC GLASSES 50 3.3.5.1 PD/ZR0 2 CATALYSTS
FROM AMORPHOUS PD-ZR ALLOYS 50 3.3.5.2 PROMOTED GOLD-ZIRCONIA CATALYSTS
FROM TERNARY GOLD- CONTAINING GLASSY ALLOYS 52 3.3.6 FACTORS INFLUENCING
CHEMICAL AND STRUCTURAL PROPERTIES OF CATALYTIC MATERIALS DERIVED FROM
METALLIC GLASSES 53 3.3.6.1 CHEMICAL COMPOSITION 53 3.3.6.2 CHEMICAL AND
STRUCTURAL HOMOGENEITY 54 3.3.6.3 THERMAL STABILITY AND CRYSTALLIZATION
BEHAVIOR 54 3.3.6.4 OXIDATION BEHAVIOR 55 3.3.6.5 DISSOLUTION OF GASES
56 3.3.6.6 SEGREGATION PHENOMENA 56 3.3.7 CONCLUSIONS AND OUTLOOK 56 3.4
PRECIPITATION AND COPRECIPITATION (F. SCHUETH AND K. UNGER) 60 3.4.1
INTRODUCTION 60 3.4.2 GENERAL PRINCIPLES GOVERNING PRECIPITATION FROM
SOLUTIONS ... 61 3.4.3 INFLUENCING THE PROPERTIES OF THE FINAL PRODUCT
69 3.4.4 PROTOTYPICAL EXAMPLES OF PRECIPITATED CATALYSTS AND SUPPORTS 75
CONTENTS IX 3.5 SOL-GEL PROCESS (E.I.KO) 85 3.5.1 INTRODUCTION 85 3.5.2
IMPORTANT PARAMETERS IN SOL-GEL PREPARATION 85 3.5.3 ADVANTAGES OF
SOL-GEL PREPARATION 91 3.5.4 CATALYTIC MEMBRANES 96 3.5.5 OTHER SOL-GEL
MATERIALS 97 3.5.6 SUMMARY 97 3.6 FLAME HYDROLYSIS (H. JACOBSEN AND P.
KLEINSCHNITT) 99 3.6.1 MANUFACTURE 99 3.6.2 PHYSICOCHEMICAL PROPERTIES
OF FUMED OXIDES 101 3.6.3 PREPARATION OF FORMED SUPPORTS 104 3.6.4
APPLICATIONS 107 3.7 SOLID-STATE REACTIONS (P. G. MENON AND B. DELMON)
109 3.7.1 WHY SOLID-STATE REACTIONS? 109 3.7.2 DESCRIPTION OF
PREPARATIVE METHODS 117 3.7.3 CONCLUSIONS AND PROSPECTS 1 36 3.8
HIGH-SURFACE TRANSITION METAL CARBIDES AND NITRIDES (S. T. OYAMA) 139
3.8.1 GENERAL PROPERTIES OF TRANSITION METAL CARBIDES AND NITRIDES 139
3.8.2 THERMODYNAMIC CONSIDERATIONS IN THE PREPARATION OF CARBIDES AND
NITRIDES 139 3.8.3 SURVEY OF PREPARATIVE METHODS 142 3.9 CARBONS (R.
SCHLOEGL) 150 3.9.1 INTRODUCTION 150 3.9.2 STRUCTURAL CHEMISTRY OF CARBON
151 3.9.3 OVERVIEW 151 3.9.4 BASIC STRUCTURES 153 3.9.5 LOOSELY DEFINED
STRUCTURES 157 3.9.6 FORMATION OF CARBON MATERIALS, GENERAL PATHWAYS 167
3.9.7 FORMATION OF CARBON MATERIALS, MECHANISTIC ASPECTS 169 3.9.8
CATALYTIC FORMATION OF CARBON FROM MOLECULES 171 3.9.9 CARBON ON
NOBLE-METAL CATALYSTS 173 3.9.10 CARBON FORMATION IN ZEOLITES 175 3.9.11
GRAPHITIZATION OF CARBONS 178 X CONTENTS 3.9.12 REACTION OF OXYGEN WITH
CARBON 180 3.9.13 SURFACE CHEMISTRY OF CARBON 188 3.9.14 NON-OXYGEN
HETEROELEMENTS ON CARBON SURFACES 191 3.9.15 SURFACE OXYGEN CROUPS 195
3.9.16 CARBON AS CATALYST SUPPORT 216 3.9.17 CARBON AS CATALYST 223
3.9.18 CASE STUDIES OF CATALYTIC APPLICATIONS 224 3.9.19 CATALYTIC
REMOVAL OF NO BY CARBON 225 3.9.20 REMOVAL OF CARBON DEPOSITS FROM
CATALYST MATERIALS 227 3.9.21 ACTIVATION OF OXYGEN ON CARBON SURFACES
229 3.9.22 CONCLUSIONS 234 3.10 HETEROPOLY COMPOUNDS (K. - Y. LEE AND M.
MISONO) 240 3.10.1 STRUCTURE AND CATALYTIC PROPERTIES 240 3.10.2
HETEROPOLYACIDS - ACID FORMS IN SOLID STATE AND IN SOLUTION . 245 3.10.3
SALTS OF HETEROPOLYACIDS - CATION-EXCHANGED FORMS 247 3.10.4
MIXED-COORDINATED HETEROPOLY COMPOUNDS 251 3.10.5 METAL-COORDINATED
HETEROPOLYANIONS 253 3.10.6 HETEROPOLYANIONS INTERCALATED IN LAYERED
DOUBLE HYDROXIDES 256 3.10.7 SUPPORTED HETEROPOLY COMPOUNDS 257 3.11
HYDROTHERMAL ZEOLITE SYNTHESIS (E. J. P. FEIJEN, J. A. MARTENS AND P. A.
JACOBS) 262 3.11.1 INTRODUCTION 262 3.11.2 ZEOLITIZATION IN GENERAL 262
3.11.3 SYNTHESIS OF INDUSTRIAL ZEOLITES 279 3.12 PILLARED CLAYS (J. J.
FRIPIAT) 284 3.12.1 INTRODUCTION 284 3.12.2 PILLARS 290 3.12.3 PILLARED
CLAYS 296 3.12.4 CATALYTIC PROPERTIES 308 3.12.5 CONCLUSIONS 311 4
SUPPORTED CATALYSTS 315 4.1 DEPOSITION OF ACTIVE COMPONENT 315 4.1.1
IMPREGNATION AND ION EXCHANGE (M. CHE, O. CLAUSE AND CH. MARCILLY) 315
CONTENTS XI 4.1.2 ANCHORING AND GRAFTING OF COORDINATION METAL COMPLEXES
ONTO OXIDE SURFACES (C. LOUIS AND M. CHE) 341 4.1.3 HETEROGENIZATION OF
COMPLEXES AND ENZYMES ( W. KEIM AND B. DRIESSEN-HOELSCHER) 355 4.2
SUPPORTED METAL CLUSTER CATALYSTS (B. C GATES) 371 4.2.1 INTRODUCTION
371 4.2.2 PREPARATION OF SUPPORTED METAL CLUSTERS 373 4.2.2.1 SYNTHESIS
OF SUPPORTED METAL CARBONYL CLUSTERS 373 4.2.2.2 DECARBONYLATION OF
SUPPORTED METAL CARBONYL CLUSTERS 374 4.2.2.3 FORMATION OF METAL
CLUSTERS IN ZEOLITE CAGES BY REDUCTION OF EXCHANGE CATIONS 374 4.2.2.4
DEPOSITION OF SIZE-SELECTED GAS-PHASE METAL CLUSTERS 375 4.2.2.5
FORMATION OF NEARLY UNIFORM METAL PARTICLES ON SUPPORTS... 375 4.2.3
STRUCTURAL CHARACTERIZATION OF SUPPORTED METAL CLUSTERS 376 4.2.4
CATALYSIS BY SUPPORTED METAL CLUSTERS 378 4.2.4.1 CATALYSIS BY SUPPORTED
IR4 AND IR 6 CLUSTERS 380 4.2.4.2 CATALYSIS BY CLUSTERS OF PT AND OF IR
IN ZEOLITE LTL 385 4.2.5 SUMMARY AND ASSESSMENT 386 4.2.6 ACKNOWLEDGMENT
386 4.3 METAL CLUSTERS IN ZEOLITES (W. M. H. SACHTIER) 388 4.3.1
INTRODUCTION 388 4.3.2 METAL CLUSTERS VERSUS MACROSCOPIC METALS 389
4.3.3 PREPARATION OF MONO- OR BIMETALLIC CLUSTERS IN ZEOLITES 390 4.3.4
INTERACTION OF METAL CLUSTERS AND ZEOLITE PROTONS 393 4.3.5 EFFECTS OF
ZEOLITE GEOMETRY ON CATALYSIS 399 4.4 ZEOLITE-ENTRAPPED METAL COMPLEXES
(G. SCHULZ-EKLOFF AND S. ERNST) 405 4.4.1 SYNTHESIS OF ZEOLITE-ENTRAPPED
METAL COMPLEXES 405 4.4.2 CHARACTERIZATION 411 4.4.3 CATALYSIS BY
ZEOLITE-ENTRAPPED TRANSITION METAL COMPLEXES.. 420 4.5 SUPPORTED
CATALYSTS FROM CHEMICAL VAPOR DEPOSITION AND RELATED TECHNIQUES ( Y.
IWASAWA) 427 4.5.1 CHEMICAL VAPOR DEPOSITION PROCESS 427 4.5.2 CVD
PRECURSORS 428 4.5.3 CVD APPLICATION 430 XII CONTENTS 4.5.4 CVD
CATALYSTS 430 4.5.4.1 NICKEL 430 4.5.4.2 CHROMIUM 432 4.5.4.3 COPPER AND
CALCIUM 433 4.5.4.4 IRON 434 4.5.4.5 MOLYBDENUM 434 4.5.4.6 COBALT 439
4.5.4.7 VANADIUM 442 4.5.4.8 TITANIUM 445 4.5.4.9 ZIRCONIUM 445 4.5.4.10
TIN 447 4.5.4.11 RUTHENIUM 448 4.5.4.12 PALLADIUM FILMS 448 4.5.4.13
PALLADIUM/ZEOLITES 448 4.5.4.14 BIMETALS 449 4.5.4.15 MIXED METAL OXIDES
451 4.5.4.16 SILICA 453 4.5.5 CVD-RELATED TECHNIQUES 455 4.5.6
CONCLUSIONS 456 4.6 PREPARATION OF SUPPORTED CATALYSTS BY DEPOSITION-
PRECIPITATION (J. W. GEUS AND A. J. VAN DILLEN) 460 4.7 SOLID SUPERACIDS
(K. TANABE AND H. HATTORI) 487 4.7.1 SULFATE-TREATED METAL OXIDES, MIXED
OXIDES, AND THOSE MODIFIED WITH PLATINUM 488 4.7.1.1 PREPARATIVE METHODS
488 4.7.1.2 MORPHOLOGY AND SURFACE PROPERTIES 490 4.7.1.3 STRUCTURE OF
SUPERACID SITES 493 4.7.1.4 CATALYTIC PROPERTIES 495 4.7.2 OTHER SOLID
SUPERACIDS 498 4.8 SPREADING AND WETTING (H. KNOEZINGER AND E. TAGLAUER)
501 4.9 REDOX METHODS FOR PREPARATION OF BIMETALLIC CATALYSTS (J.
BARBIER) 526 5 FROM THE PRECURSOR TO THE FINAL CATALYST 541 5.1
FORMATION OF FINAL CATALYSTS (B. DELMON) 541 CONTENTS XIII 5.1.1
INTRODUCTION AND BACKGROUND 541 5.1.2 ACTIVATION OF SUPPORTED CATALYSTS
BY CALCINATION 553 5.1.3 ACTIVATION OF SUPPORTED CATALYSTS BY REDUCTION
555 5.1.4 REDUCTION-SULFIDATION 565 5.1.5 OTHER METHODS OF ACTIVATION
574 5.1.6 CONCLUSIONS 574 5.2 CATALYST FORMING (J. F. LE PAGE) 579 5.2.1
FORMING MICROGRANULES 579 5.2.2 FORMING GRANULES 583 5.2.2.1 PELLETIZING
583 5.2.2.2 EXTRUSION 584 5.2.2.3 PAN GRANULATION 586 5.2.2.4
MISCELLANEOUS FORMING OPERATIONS 586 5.2.3 ORGANIZING A
CATALYST-MANUFACTURING PROCESS 587 6 COMPUTER-AIDED CATALYST DESIGN (M.
BAERNS AND E. KOERTING) 591 6.1 INTRODUCTION 591 6.2 HEURISTICS IN
CATALYST DESIGN 594 6.2. 1 KNOWLEDGE-BASED SYSTEMS 594 6.2.2 NEURAL
NETWORKS 597 6.3 DETERMINISTIC METHODS IN CATALYST DESIGN 599 6.4
CHEMICAL REACTION ENGINEERING ASPECTS 601 6.5 CONCLUSIONS 601 INDEX 605
|
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| illustrated | Illustrated |
| indexdate | 2024-07-09T18:32:38Z |
| institution | BVB |
| isbn | 3527298266 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-008653529 |
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| physical | XVII, 622 S. Ill., graph. Darst. |
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| spelling | Preparation of solid catalysts ed. by G. Ertl ... Weinheim [u.a.] Wiley-VCH 1999 XVII, 622 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Literaturangaben Catalyseurs métalliques Catalyseurs métalliques ram Metal catalysts Katalysator (DE-588)4029919-3 gnd rswk-swf Festkörper (DE-588)4016918-2 gnd rswk-swf Herstellung (DE-588)4159653-5 gnd rswk-swf Katalysator (DE-588)4029919-3 s Festkörper (DE-588)4016918-2 s Herstellung (DE-588)4159653-5 s DE-604 Ertl, Gerhard 1936- Sonstige (DE-588)106105507 oth GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008653529&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Preparation of solid catalysts Catalyseurs métalliques Catalyseurs métalliques ram Metal catalysts Katalysator (DE-588)4029919-3 gnd Festkörper (DE-588)4016918-2 gnd Herstellung (DE-588)4159653-5 gnd |
| subject_GND | (DE-588)4029919-3 (DE-588)4016918-2 (DE-588)4159653-5 |
| title | Preparation of solid catalysts |
| title_auth | Preparation of solid catalysts |
| title_exact_search | Preparation of solid catalysts |
| title_full | Preparation of solid catalysts ed. by G. Ertl ... |
| title_fullStr | Preparation of solid catalysts ed. by G. Ertl ... |
| title_full_unstemmed | Preparation of solid catalysts ed. by G. Ertl ... |
| title_short | Preparation of solid catalysts |
| title_sort | preparation of solid catalysts |
| topic | Catalyseurs métalliques Catalyseurs métalliques ram Metal catalysts Katalysator (DE-588)4029919-3 gnd Festkörper (DE-588)4016918-2 gnd Herstellung (DE-588)4159653-5 gnd |
| topic_facet | Catalyseurs métalliques Metal catalysts Katalysator Festkörper Herstellung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008653529&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT ertlgerhard preparationofsolidcatalysts |