Fundamentals of steelmaking:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
London
Inst. of Materials
1996
|
| Ausgabe: | 1. publ. |
| Schriftenreihe: | Institute of Materials: Book
656 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIV, 331 S. Ill., graph. Darst. |
| ISBN: | 1861250045 |
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| 245 | 1 | 0 | |a Fundamentals of steelmaking |c E. T. Turkdogan |
| 250 | |a 1. publ. | ||
| 264 | 1 | |a London |b Inst. of Materials |c 1996 | |
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Datensatz im Suchindex
| _version_ | 1804127245837533184 |
|---|---|
| adam_text | CONTENTS ACKNOWLEDGEMENTS XI CHAPTER 1 THERMOCHEMISTRY AND
THERMODYNAMICS 1 1.1 IDEAL GAS LAWS 1 1.1.1 THE GAS CONSTANT 2 1.1.2 GAS
PARTIAL PRESSURE 2 1.1.3 NONIDEAL GASES 3 1.2 THE FIRST LAW OF
THERMODYNAMICS 3 1.2.1 ENERGY 3 1.2.2 ENTHALPY 3 1.2.3 HEAT CAPACITY 4
1.2.4 STANDARD STATE 5 1.2.5 ENTHALPY OF REACTION 5 1.2.6 HESS S LAW 6
1.2.7 SPECIAL TERMS OF HEAT OF REACTION 6 1.2.8 ADIABATIC REACTIONS 6
1.3 THE SECOND LAW OF THERMODYNAMICS 7 1.3.1 ENTROPY 7 1.4 THE THIRD LAW
OF THERMODYNAMICS 7 1.5 GIBBS FREE ENERGY 8 1.5.1 GENERALISATION OF
ENTROPY OF REACTION 8 1.5.2 THE STANDARD FREE ENERGIES OF FORMATION OF
COMPOUNDS 9 1.6 EMPIRICAL CORRELATIONS 9 1.6.1 HEAT CAPACITIES OF SOLID
ELEMENTS AND SIMPLE COMPOUNDS 9 1.6.2 HEAT CAPACITIES OF POLYMERIC
SUBSTANCES 10 1.6.3 HEAT CONTENTS AT MELTING POINTS 11 1.6.4 HEAT OF
MELTING 13 1.7 THERMODYNAMIC ACTIVITY 13 1.7.1 TEMPERATURE EFFECT ON
ACTIVITY 14 1.7.2 SOLUTIONS 15 1.7.3 MOLAR QUANTITIES OF SOLUTIONS 15
1.7.4 IDEAL SOLUTIONS - RAOULT S LAW 16 1.7.5 NONIDEAL SOLUTIONS 16
1.7.6 ACTIVITY COEFFICIENT 16 1.7.6A HENRY S LAW FOR DILUTE SOLUTIONS 17
1.7.6B INTERACTION COEFFICIENTS 17 1.7.7 CONVERSION FROM ONE STANDARD
STATE TO ANOTHER 18 1.8 REACTION EQUILIBRIUM CONSTANT 19 1.8.1 EFFECT OF
TEMPERATURE 19 1.9 PHASE RULE 20 1.10 PHASE EQUILIBRIUM DIAGRAMS 20
1.10.1 BINARY SYSTEMS 21 1.10.2 TERNARY SYSTEMS 23 1.11 SURFACE TENSION
25 1.11.1 CHEMISORBED LAYER 27 1.11.2 LANGMUIR ADSORPTION ISOTHERM 27
1.11.3 EFFECT OF SURFACE CURVATURE ON SURFACE TENSION 29 1.12
INTERFACIAL TENSION 29 1.12.1 CONTACT ANGLE 29 1.12.2 WORK OF COHESION,
WORK OF ADHESION AND SPREADING COEFFICIENT 30 1.13 COMPUTER-BASED
PACKAGES 31 CHAPTER 2 RATE PHENOMENA 34 2.1 KINETICS OF INTERFACIAL
REACTIONS 34 2.1.1 EXAMPLES OF EXPERIMENTS ON RATES OF INTERFACIAL
REACTIONS 38 2.1.1A NITROGEN TRANSFER ACROSS IRON SURFACE 38 2.1.1B RATE
OF DECARBURISATION OF LIQUID FE-C ALLOYS BY CO 2 39 2.2 FICK S DIFFUSION
LAWS 41 2.2.1 FIRST LAW-STEADY STATE DIFFUSION 41 2.2.2 SECOND
LAW-NONSTEADY STATE DIFFUSION 41 2.2.3 INTERDIFFUSION IN BINARY METALLIC
SOLUTIONS 43 2.2.4 DIFFUSION IN IONIC MEDIA (SLAGS) 44 2.3 MASS AND HEAT
TRANSFER THROUGH REACTION PRODUCT LAYER 44 2.3.1 PARABOLIC RATE OF
EXIDATION OF IRON 44 2.3.2 HEAT-TRANSFER CONTROLLED CALCINATION OF
LIMESTONE 46 2.4 REACTION OF GASES WITH POROUS MATERIALS 48 2.4.1
MATHEMATICAL ANALYSIS OF THIELE 48 2.4.2 OXIDATION OF CARBON IN CO 2 -CO
MIXTURES 51 2.4.2A ELECTRODE CONSUMPTION IN EAF STEELMAKING 56 2.4.3
REDUCTION OF IRON OXIDES 57 2.4.4 EFFECT OF REACTION TEMPERATURE ON PORE
STRUCTURE OF REACTED MATERIAL 63 2.5 VAPORISATION IN REACTIVE GASES 67
2.6 KINETICS OF GAS BUBBLES IN OXYGEN STEELMAKING 70 2.6.1 BUBBLE
NUCLEATION AND GROWTH 70 2.6.2 GAS HOLDUP IN STEEL BATH 71 2.6.3
ESTIMATION OF BUBBLE SIZE FOR UNIFORMLY DISPERSED BUBBLES IN THE STEEL
BATH 74 2.6.4 RATE EQUATION FOR TRANSPORT CONTROLLED GAS BUBBLE
REACTIONS IN LIQUID STEEL 76 2.6.5 AN EXAMPLE OF CALCULATED RATE OF
NITROGEN REMOVAL 77 2.7 MAXIMUM RATE OF DEGASSING OF LIQUID STEEL WITH
ARGON PURGING 78 2.8 COMPUTER-BASED PACKAGES 80 CHAPTER 3 THERMOCHEMICAL
AND TRANSPOR T PROPERTIES OF GASES 82 3.1 THERMOCHEMICAL PROPERTIES 82
3.1.1 MOLAR HEAT CAPACITY 82 3.1.2 HEAT CONTENT 83 3.1.3 EQUILIBRIUM
STATES IN GAS MIXTURES 83 3.2 TRANSPORT PROPERTIES 86 3.2.1
INTERRELATIONS BETWEEN TRANSPORT PROPERTIES 88 3.2.1A VISCOSITY/THERMAL
CONDUCTIVITY 88 3.2.1B THERMAL DIFFUSIVITY/THERMAL CONDUCTIVITY 88
3.2.1C TEMPERATURE AND PRESSURE EFFECTS 88 3.2.1D MOLECULAR MASS EFFECT
89 3.3 PORE DIFFUSION 89 CHAPTER 4 PHYSICOCHEMICAL PROPERTIES OF STEEL
91 4.1 SELECTED THERMODYNAMIC ACTIVITIES 91 4.1.1 ACTIVITY COEFFICIENTS
IN FE-X BINARY MELTS 91 4.1.2 ACTIVITY COEFFICIENTS IN MULTICOMPONENT
MELTS 94 4.1.3 FREE ENERGIES OF SOLUTION IN LIQUID IRON 94 4.2 GAS
SOLUBILITIES IN SOLID AND LIQUID IRON 95 4.2.1 SIEVERT S LAW 95 4.2.2
SOLUBILITY OF HYDROGEN 96 4.2.3 SOLUBILITY OF NITROGEN 97 4.2.4
SOLUBILITY OF CARBON MONOXIDE 98 4.2.5 SOLUBILITY OF WATER VAPOUR 98
4.2.6 SOLUBILITY OF SULPHUR DIOXIDE 99 4.2.7 SOLUBILITY OF HYDROGEN
SULPHIDE 99 4.3 SELECTED IRON-BASE PHASE DIAGRAMS 100 4.3.1
CRYSTALLOGRAPHIC FORMS OF IRON 100 4.3.2 IRON-CARBON SYSTEM 101 4.3.2A
PERITECTIC REACTION 104 4.3.2B EFFECT OF ALLOYING ELEMENTS ON PERITECTIC
INVARIANT 105 4.3.2C LIQUIDUS TEMPERATURES OF LOW ALLOY STEELS 109 4.3.3
IRON-OXYGEN SYSTEM 110 4.3.4 IRON-SULPHUR SYSTEM 114 4.3.5 IRON
OXYSULPHIDE 115 4.3.6 IRON-MANGANESE OXYSULPHIDE 117 4.3.7 ELEMENTS OF
LOW SOLUBILITY IN LIQUID IRON 119 4.4 SOLUBILITIES OF CAO, CAS, MGO AND
MGS IN LIQUID IRON 123 4.5 SOLUBILITIES OF NITRIDES AND CARBIDES IN
SOLID AND LIQUID IRON 125 4.6 SURFACE TENSION OF LIQUID IRON ALLOYS 126
4.7 DENSITY OF LIQUID STEEL 129 4.8 VISCOSITY 130 4.9 MASS DIFFUSIVIES
IN SOLID AND LIQUID IRON 132 4.10 ELECTRICAL CONDUCTIVITY 133 4.11
THERMAL CONDUCTIVITY 134 4.12 THERMAL DIFFUSIVITY 136 CHAPTER 5
PHYSICOCHEMICAL PROPERTIES OF MOLTEN SLAGS 138 5.1 STRUCTURAL ASPECTS
138 5.2 SLAG BASICITY 140 5.3 SELECTED PHASE DIAGRAMS OF BINARY AND
TERNARY OXIDE SYSTEMS 142 5.3.1 BINARY OXIDE SYSTEMS 142 5.3.2 TERNARY
AND QUATERNARY OXIDE SYSTEMS 145 5.4 THERMODYNAMIC ACTIVITIES OF OXIDES
IN SIMPLE AND COM 5.4.1 ACTIVITIES IN CAO-FEO-SIO 2 SYSTEM 150 5.4.2
ACTIVITIES IN CAO-AL 2 O 3 -SIO 2 SYSTEM 152 5.4.3 ACTIVITIES IN MNO-AL
2 O 3 -SIO 2 SYSTEM 153 5.4.4 ACTIVITY COEFFICIENT OF FEO IN SLAGS 153
5.4.5 ACTIVITY COEFFICIENT OF MNO IN SLAGS 156 5.5 OXYGEN POTENTIAL
DIAGRAM 158 5.6 GAS SOLUBILITIES IN SLAGS 160 5.6.1 SOLUBILITY OF H 2 O
160 5.6.2 SOLUBILITY OF N 2 160 5.6.2A SLAG/METAL DISTRIBUTION RATIO
(N)/[N] 5.6.3 SOLUBILITY OF S 2 163 5.6.4 SOLUBILITY OF O 2 165 5.7
SURFACE TENSION 166 5.7.1 SLAG-METAL INTERFACIAL TENSION 166 5.7.2
SOLUTE-INDUCED INTERFACIAL TURBULENCE 167 5.S DENSITY 170 5.9 VISCOSITY
172 5.10 MASS DIFFUSIVITY 176 5.11 ELECTRICAL CONDUCTIVITY 177 5.12
THERMAL CONDUCTIVITY 178 CHAPTER 6 EQUILIBRIUM DATA ON LIQUID STEEL-SLAG
REACTIONS 6.1 OXIDATION OF IRON 180 6.2 OXIDATION OF MANGANESE 181 6.3
OXIDATION OF CARBON 182 6.4 OXIDATION OF SILICON 183 6.5 OXIDATION OF
CHROMIUM 184 6.6 OXIDATION OF PHOSPHORUS 186 6.7 REDUCTION OF SULPHUR
189 6.8 DEOXIDATION REACTION EQUILIBRIUM 193 6.8.1 DEOXIDATION WITH
FE/MN 193 6.8.2 DEOXIDATION WITH SI/MN 193 6.8.3 DEOXIDATION WITH
SI/MN/AL 197 6.8.4 DEOXIDATION WITH AL 197 CHAPTER 7 PRETREATMENT OF
BLAST FURNACE IRON 200 7.1 DESILICONISATION 200 7.2 DEPHOSPHORISATION
AND DESULPHURISATION 202 7.3 DESULPHURISATION 205 7.4 BENEFITS OF HOT
METAL REFINING 208 CHAPTER 8 OXYGEN STEELMAKING 20 9 8.1 INTRODUCTION
209 8.2 FURNACE CHARGE 209 8.2.1 STATIC CHARGE CONTROL 211 8.2.1A
MATERIAL BALANCE 211 8.2.1B HEAT BALANCE 213 8.2.1C RELIABILITY OF
STATIC CHARGE-CONTROL SYSTEM 214 8.3 DYNAMIC CONTROL OF OXYGEN BLOWING
214 8.3.1 AUTOMATED CONTROL OF OXYGEN BLOWING 215 8.4 STEELMAKING SLAGS
217 8.4.1 SLAG FORMATION IN BOF STEELMAKING 217 8.4.2 SLAG FORMATION IN
Q-BOP STEELMAKING 219 8.4.3 SLAG COMPOSITION AT TURNDOWN 219 8.5
DECARBURISATION 220 8.6 COMBINED-BLOWING IN BOF STEELMAKING 222 8.7
METAL EMULSION IN FOAMING SLAGS 226 8.8 CONTROL OF SLAG FOAMING 227 8.9
STATES OF STEELMAKING REACTIONS AT THE END OF OXYGEN BLOWING 230 8.9.1
OXYGEN-CARBON RELATION 231 8.9.2 IRON OXIDE-CARBON RELATION 232 8.9.3
MANGANESE OXIDE-CARBON RELATION 234 8.9.4 FEO-MNO-MN-O RELATIONS 234
8.9.5 STATE OF PHOSPHORUS REACTION 236 8.9.6 STATE OF SULPHUR REACTION
237 8.9.7 HYDROGEN AND NITROGEN CONTENTS IN BOF AND Q-BOP STEELMAKING
238 8.9.8 GENERAL COMMENTS 239 8.10 STATES OF SLAG-METAL REACTIONS IN
EAF STEELMAKING 240 8.10.1 SLAG COMPOSITION 240 8.10.2 IRON OXIDE-CARBON
RELATION 241 8.10.3 FEO-MNO-MN RELATION 242 8.10.4 STATE OF CHROMIUM
OXIDATION 242 8.10.5 STATE OF PHOSPHORUS REACTION 242 8.10.6 STATE OF
SULPHUR REACTION 242 8.10.7 SUMMARY 243 CHAPTER 9 STEEL REFINING IN THE
LADLE 245 9.1 TAP LADLE 245 9.1.1 LADLE REFRACTORY LINING 245 9.1.2
LADLE PREHEATING 246 9.1.3 POROUS PLUG ON THE LADLE BOTTOM 249 9.2 STEEL
HOMOGENISATION WITH GAS STIRRING 249 9.2.1 MIXING TIME 251 9.2.2 RATE OF
SLAG-METAL REACTION IN GAS STIRRED MELTS 252 9.3 LADLE SLAGS 253 9.4
CHILL FACTORS FOR LADLE ADDITIONS 254 9.5 REACTIONS OCCURRING DURING
FURNACE TAPPING 255 9.5.1 NITROGEN PICKUP 255 9.5.2 HYDROGEN PICKUP 257
9.5.3 FURNACE SLAG CARRY OVER 257 9.6 LADLE FURNACE 259 9.6.1 ARC
REHEATING IN THE LADLE FURNACE 259 9.6.2 REHEATING WITH OXYGEN INJECTION
262 9.7 STEEL DEOXIDATION 262 9.7.1 OPEN HEAT TAPPING 263 9.7.2 SLAG
AIDED DEOXIDATION 263 9.7.2A PARTIAL DEOXIDATION WITH FE/MN 263 9.7.2B
DEOXIDATION WITH SI/MN 266 9.7.2C DEOXIDATION WITH AL 266 9.7.3
DEOXIDATION WITH CA-SI 268 9.7.4 ARGON RINSING FOR INCLUSION FLOATATION
268 9.8 DESULPHURISATION 269 9.8.1 DESULPHURISATION METHODS 270 9.8.2
RATE OF DESULPHURISATION 274 9.9 VACUUM DEGASSING 277 9.9.1 VACUUM
DEGASSER WITH ARC REHEATING 277 9.9.2 VACUUM LADLE DEGASSING 277 9.9.3
RECIRCULATION DEGASSING 278 9.9.4 CARBON DEOXIDATION 279 9.9.5
DECARBURISATION 280 9.9.6 RATE OF DECARBURISATION 281 9.9.7
DEHYDROGENATION 283 9.9.8 DENITROGENISATION 284 9.10 CALCIUM TREATMENT
285 9.10.1 OBJECTIVES OF INCLUSION MORPHOLOGY CONTROL 285 9.10.2
REACTION OF CALCIUM IN LIQUID STEEL 286 9.10.3 EFFICIENCY OF CALCIUM
USAGE AND RETENTION IN STEEL 288 9.10.4 SULPHIDE MORPHOLOGY (SHAPE)
CONTROL 289 9.11 INCLUSION CONTROL IN BEARING STEELS 290 9.12 OTHER
REFERENCES ON INCLUSIONS IN STEEL 292 CHAPTER 10 REACTIONS DURING STEEL
SOLIDIFICATION 297 10.1 SOLUTE ENRICHMENT IN INTERDENDRITIC LIQUID 297
10.1.1 SCHEIL EQUATION 297 10.1.2 REACTIONS IN INTERDENDRITIC LIQUID 298
10.1.3 LIQUIDUS TEMPERATURE AND SOLUTE ACTIVITY COEFFICIENTS IN THE
INTER- DENDRITIC LIQUID 302 10.2 SUBSURFACE BLOWHOLE FORMATION 302 10.3
CASTABILITY OF RESULPHURISED STEEL 305 10.4 CRITICAL RATIO (MN/S) C TO
SUPPRESS HOT SHORTNESS OF STEEL 307 10.5 CAS FORMATION DURING
SOLIDIFICATION 307 10.6 CAUSES AND EFFECTS OF NITRIDE PRECIPITATION IN
CONTINUOUS CASTING 310 10.6.1 HOT DUCTILITY 310 10.6.2 MODES OF NITRIDE
AND CARBONITRIDE PRECIPITATION 315 10.6.3 INTERDENDRITIC PRECIPITATION
OF TIN 316 10.6.4 CRITICAL MICROALLOYING ELEMENTS IN HSLA STEEL 318
INDEX 321
|
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| spelling | Turkdogan, Ethem T. Verfasser aut Fundamentals of steelmaking E. T. Turkdogan 1. publ. London Inst. of Materials 1996 XIV, 331 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Institute of Materials: Book 656 Steel Metallurgy Stahlherstellung (DE-588)4116592-5 gnd rswk-swf Stahlherstellung (DE-588)4116592-5 s DE-604 Institute of Materials: Book 656 (DE-604)BV007847337 656 OEBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008553702&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Turkdogan, Ethem T. Fundamentals of steelmaking Institute of Materials: Book Steel Metallurgy Stahlherstellung (DE-588)4116592-5 gnd |
| subject_GND | (DE-588)4116592-5 |
| title | Fundamentals of steelmaking |
| title_auth | Fundamentals of steelmaking |
| title_exact_search | Fundamentals of steelmaking |
| title_full | Fundamentals of steelmaking E. T. Turkdogan |
| title_fullStr | Fundamentals of steelmaking E. T. Turkdogan |
| title_full_unstemmed | Fundamentals of steelmaking E. T. Turkdogan |
| title_short | Fundamentals of steelmaking |
| title_sort | fundamentals of steelmaking |
| topic | Steel Metallurgy Stahlherstellung (DE-588)4116592-5 gnd |
| topic_facet | Steel Metallurgy Stahlherstellung |
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